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采用MDA催化加氢的方法,对H12MDA制备工艺进行了系统的研究.对RC系列负载钌催化剂进行了活性、选择性、寿命评价和筛选,并考察了温度、压力工艺条件对加氢反应的影响.结果表明,温度、压力对吸氢速率有较大的影响.选择RC3-2作为MDA加氢催化剂,在8.0MPa,150℃的条件下,3~4h内MDA转换率可以达到99%以上,H12MDA收率大于90%,且反一反异构体含量低于24%.催化剂套用实验结果表明,经过15次套用,催化剂活性、选择性依然维持在较好的水平,证明该催化剂耐用性好,具有工业应用价值.通过减压精馏的方法,制得了纯度大于99.5%的H12MDA. 相似文献
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聚合物梯度材料的制备及应用研究 总被引:1,自引:0,他引:1
作为一种新型的梯度材料,聚合物梯度材料凭借其独特的性能受到广泛瞩目。本文介绍了聚合物梯度材料的制备方法和应用,结合研究状况,简单介绍了其在未来的发展趋势。 相似文献
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Carbaugh EH 《Radiation protection dosimetry》2003,105(1-4):391-394
This paper suggests that minimum detectable dose (MDD) be used to describe the capability of bioassay programmes for which intakes are expected to be rare. This allows expression of the capability in units that correspond directly to primary dose limits. The concept uses the well established analytical statistic minimum detectable amount (MDA) as the starting point, and assumes MDA detection at a prescribed time post-intake. The resulting dose can then be used as an indication of the adequacy or capability of the programme for demonstrating compliance with the performance criteria. MDDs can be readily tabulated or plotted to demonstrate the effectiveness of different types of monitoring programmes. The inclusion of cost factors for bioassay measurements can allow optimisation. 相似文献
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目的 探讨壳聚糖基抗菌保鲜膜(Chitosan-based Antibacterial Preservative Film,CAPF)对采后油豆角的保鲜效果.方法 分别以质量损失率、腐烂率、色差、呼吸强度、Vc含量、还原糖含量、超氧化物歧化酶(SOD)活性和丙二醛(MDA)含量为指标,考察CAPF对油豆角的贮藏效果.结果 CAPF对油豆角的保鲜效果良好,在贮藏18 d时,CAPF处理组的质量损失率为15.27%,是对照组的62.71%;腐烂率为6.3%,仅是对照组的31.3%.相较于其他组,CAPF组有效地降低了贮藏期间油豆角的黄化速率,抑制呼吸强度的上升,更好地延缓了油豆角中维生素C和还原糖的降低,使油豆角维持了较好的SOD活性,有效抑制了MDA的积累.结论 CAPF能有效提高油豆角的贮藏质量,可用于其保鲜. 相似文献
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以浙江省主栽茭白品种浙茭911为对照,比较它与新品种龙茭2号在低温下叶片丙二醛含量、相对电导率的变化以及冷胁迫指数和耐寒性.结果表明,龙茭2号在低温,尤其是持续低温下,电导率变化小,丙二醛含量少,对寒冷适应较快,恢复能力较强.两个茭白品种的冷胁迫指数只有在5℃的恢复阶段存在显著差异,且龙茭2号的茎和叶冷胁迫指数都较低,干物质积累受寒冷胁迫影响小,具有较强的耐寒性. 相似文献
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目的为了探究不同贮藏温度对采后上海青叶片衰老及活性成分的影响。方法以上海青为实验材料,分别在0,5,10,15,20,25,30℃下贮藏,对上海青叶片的感官品质、色差、叶绿素含量、丙二醛(MDA)含量、类胡萝卜素含量、叶黄素含量、叶酸含量和亚硝酸盐含量的变化进行分析。结果与20,25,30℃相比,在10℃和15℃下贮藏可减缓上海青叶片L^*值、b^*值、MDA含量和亚硝酸盐含量的增加,以及|a^*|值、叶绿素含量、类胡萝卜素含量、叶黄素含量和叶酸含量的降低;与10℃和15℃贮藏条件相比,在0℃和5℃下贮藏可显著抑制上海青叶片L^*值、b^*值、MDA含量和亚硝酸盐含量的增加,以及|a^*|值、叶绿素含量、类胡萝卜素含量、叶黄素含量和叶酸含量的降低,减缓上海青叶片的黄化衰老进程,从而维持上海青良好的外观品质。在贮藏温度为20,25,30℃时,上海青的最大贮藏期不超过4 d;贮藏温度为10℃和15℃时,最大贮藏期分别不超过9 d和7 d;贮藏温度为0℃和5℃时,最大贮藏期分别不超过40 d和15 d。结论在低温条件下贮藏,尤其是在0℃下贮藏可最大限度地减缓采后上海青叶片的衰老进程,可维持其较高的活性成分,并抑制其组织中亚硝酸盐的积累,显著延长上海青的贮藏期。 相似文献
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根据塑闪型车载式放射性探测系统的性能特点,通过理论模型和实验相结合的方法研究最小可探测活度的测量与估算方法。结果表明:(1) 估算塑闪型车载式放射性探测系统最小可探测活度时,探测系统的参考活度响应应在距离车体20m范围内进行测量;(2) 参考活度响应与距离x之间的关系模型为2个e指数相加模型,可据此模型估算具体位置处的最小可探测活度,也可在参考源活度已知的情况下,估算该车载式放射性探测系统的可探测距离。研究建立的最小可探测活度估算方法可为塑闪型车载式放射性探测系统技术性能评价与应用提供参考。 相似文献
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目的为了研究低温胁迫对青椒膜脂代谢的影响。方法以“晋黎”青椒为实验材料,测定10℃(对照)和4℃(低温胁迫)等不同贮藏温度下青椒相对电导率、丙二醛(MDA)、脯氨酸、磷脂酶D(PLD)、脂氧合酶(LOX)活性、脂肪酸组分的变化情况。结果在低温胁迫下,青椒的相对电导率升高,MDA积累,脯氨酸含量增加,PLD和LOX活性升高,亚油酸、亚麻酸减少,硬脂酸增加,脂肪酸不饱和指数降低。结论低温胁迫诱导青椒PLD和LOX活性上升,引起不饱和脂肪酸降解,饱和脂肪酸增加,膜流动性减弱,最终导致膜失去完整性,在这过程中脯氨酸含量明显升高。 相似文献
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Using the Lawrence Livermore National Laboratory (LLNL) torso phantom to calibrate a lung counting system can lead to the conclusion that three large area (i.e. >70 mm diameter) Ge detectors will outperform a four-detector array and provide a lower MDA as a four-detector array of large area Ge detectors covers a significant portion of inactive tissue (i.e. non-lung tissue). The lungs of the LLNL phantom, which are approximately 10 cm too short compared with real lungs, also suggests that a two-detector array could be used under limited circumstances. When tested with modified lungs that are more human-like, it was found that the four-detector array showed the best counting efficiency and the lowest MDA. Fortunately, these findings indicate that, although the LLNL phantom's lungs are too short, there is no adverse impact on the calibration of a lung counter. 相似文献
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目的研究低强度LED白光处理对采后油麦菜品质的影响。方法采用光照强度为5μmol/(m^2·s)的LED白光于(20±1)℃下持续照射油麦菜7 d,以黑暗条件下贮藏的样品为对照,测定贮藏期间样品的感官评分、腐烂率、呼吸强度,叶绿素、维生素C、总酚及丙二醛(MDA)含量,多酚氧化酶(PPO)、过氧化氢酶(CAT)、叶绿素降解酶(叶绿素酶、脱镁鳌合酶、叶绿素过氧化物酶、脱镁叶绿素酶)活性的变化。结果与对照组相比,在贮藏期间,LED处理可有效维持油麦菜的感官品质,抑制其呼吸强度和MDA含量的上升,维持叶绿素、维生素C及总酚含量,提高抗氧化酶活性,并降低叶绿素降解酶的活性。结论 LED处理可通过抑制采后油麦菜的呼吸强度和叶绿素降解速率,维持非酶抗氧化物质含量和抗氧化酶活性,保持细胞膜完整性,从而延缓其采后衰老,并保持其较好的感官和营养品质。 相似文献
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With the rapid development of nano-technology, a “colorimetric sensor array” (CSA) that is referred to as an optical electronic nose has been developed for the identification of toxicants. Unlike traditional sensors that rely on a single chemical interaction, CSA can measure multiple chemical interactions by using chemo-responsive dyes. The color changes of the chemo-responsive dyes are recorded before and after exposure to toxicants and serve as a template for classification. The color changes are digitalized in the form of a matrix with rows representing dye effects and columns representing the spectrum of colors. Thus, matrix-classification methods are highly desirable. In this article, we develop a novel classification method, matrix discriminant analysis (MDA), which is a generalization of linear discriminant analysis (LDA) for the data in matrix form. By incorporating the intrinsic matrix-structure of the data in discriminant analysis, the proposed method can improve CSA’s sensitivity and more importantly, specificity. A penalized MDA method, PMDA, is also introduced to further incorporate sparsity structure in discriminant function. Numerical studies suggest that the proposed MDA and PMDA methods outperform LDA and other competing discriminant methods for matrix predictors. The asymptotic consistency of MDA is also established. R code and data are available online as supplementary material. 相似文献