Theory of magnetographic printing

The magnetic force of attraction between a recording surface and magnetic particles (the "developer" or "toner") is analyzed. The recording medium is assumed to be magnetically hard, the toner particles to be magnetically soft. The distribution of recording magnetization is taken to be periodic in the interior of an image area and uniform in an image free area. The toner particles are assumed to be part magnetic, part nonmagnetic material. In most of the calculations it is assumed that the magnetic susceptibility of the toner particles is small compared to unity. In the interior of an image area the force density has primarily a component perpendicular to the recording plane. This component decreases exponentially with distance from the recording plane, if the distribution of magnetization is sinusoidal. Near the edge of an image area the force density also has a tangential component, but this is generally smaller than the normal component. For toner particles with similar internal structure the force per unit mass always decreases with increasing particle size. Considered as a function of recording wavelength (at constant particle size) it shows a maximum at a wavelength comparable to the particle diameter.The force acting on a small particle (simeq 10mum) in the immediate vicinity of the recording surface can be several hundred times the force of gravity. The implications of these results in regard to color printing are discussed.     

Angular dependence of nucleation field in magnetic recording particles

Nucleation field of particles used for magnetic recording increases sharply for large angles between the applied field and the particle easy axis. This effect is shown to be consistent with the magnetization curling mechanism in these particles.     

Permanent magnets based on materials with high crystal anisotropy

The properties of Alnicos and elongated single-domain fine-particle materials, both interpreted as due to shape anisotropy of fine particles, are still far short of those predicted by simple theory. The hard ferrites, with properties due to magnetocrystalline anisotropy, come much closer, but are restricted by their low magnetization. The search for a combination of high magnetization and high magnetocrystalline anisotropy has led to the investigation of a variety of intermetallic compounds. Some of them, particularly the cobalt-rare earths, appear quite promising. Mechanical grinding often has an adverse effect on the magnetic properties of crystal anisotropy materials. Chemical stability is also often a problem. Crystal anisotropy materials in general have high values of intrinsic coercive force. This makes them especially suitable for applications involving widely varying dynamic conditions. Their proper evaluation may be best done using criteria other than the usual maximum energy product.     

Simultaneous substitution of Co2+and Zn2+ions in submicronic acicular γ - Fe2O3particles

In iron sesquioxide of acicular shaded γ-Fe2O3simultaneous substitution of Co²⁺and Zn²⁺ions leads to the formation of mixed-defect ferrites and modulation of magnetic properties is of interest for their application to high density magnetic recording. It is shown that the coercive force, remanent magnetization and saturation-magnetization are controlled by a judicious choice of the contents of Co²⁺and Zn²⁺, while it is indispensable to optimize the morphological features like the average size of the crystallites, the shape, the size and texture of the particles. A high value of coercive force (650-700 Oe) and of the remanent magnetization (35-45 emu/g) had been obtained with a minimal content of cobalt ions (Co²⁺= 2.5 to 3% by wt.) permitting limits to the magnetocrystalline anisotropy of these compounds and their thermal variation near the ambient temperature. The influence of the zinc content had been systematically studied notably in relation to its effect on the structural, morphological and magnetic properties of the ferrites.     

Theoretical study of vector magnetization distribution using rotational magnetization model

In magnetic recording, the recording fields are essentially vectorial, and the magnetization process in the recording medium has to be analyzed using vector magnetization. From this fact, a vector magnetization distribution in the recording medium must be evaluated by both magnitude and direction of magnetization. This paper describes the vector magnetization distributions obtained by a new method, using reversible and irreversible rotational magnetization model of single domain acicular particles with uniaxial anisotropy. Calculations are done self-consistently at an instant when the head field is applied and after it is removed. Although the results are, at present, limited to the case where the recording medium is standing still, they show quite good agreement with the results of scaled up model experiments, and can clearly explain the demagnetization mechanism in terms of the vector rotation. This new calculation method will, in principle, display its real power in analyzing the dynamical recording process when the recording medium is moving along the head or the head field is changing.     

The Role of Carbon Content: A Comparison of the Nickel Particle Size and Magnetic Property of Nickel/Polysiloxane-Derived Silicon Oxycarbide

A facile and novel processable method to synthesize the Ni nanoparticles (Ni NPs) by tailoring their size in the matrix of the silicon oxycarbide (SiOC) ceramic system is reported. This method is based on polymer-derived ceramics (PDCs), instead of the conventional powder route. The specific structural characteristics and magnetic properties of the various Ni NPs/SiOC composites as a function of carbon content are systematically investigated. The magnetic properties are experimentally investigated as a function of NP size and measurement temperature. It is demonstrated that the change in the size of Ni NPs (average from ≈4 to ≈ 19 nm) determines the magnetic nature of superparamagnetism. Zero-field-cooled (ZFC) and field-cooled (FC) magnetization studies under magnetic fields of 100 Oe are performed. The saturated M versus H (M–H) loops (saturation magnetization) increase and the coercivity decreases with the size reduction of Ni NPs. It is an indicator of the presence of superparamagnetic behavior and single-domain NP for ceramic materials.     

Co-Fe metal/native-oxide multilayers: a new direction in soft magnetic thin film design I. Quasi-static properties and dynamic response

The progression toward gigahertz data rates in magnetic recording has introduced considerable challenges to soft magnetic materials design. The difficulties lie in satisfying two sets of conflicting demands: 1) simultaneously achieving soft magnetic properties, high saturation magnetization, and a high resistivity, with the latter required to limit eddy-current losses and 2) balancing the inherent tradeoff between bandwidth and permeability imposed by the direct and inverse dependences, respectively, of these two parameters on the anisotropy field. This paper describes a new soft magnetic composite system that meets these requirements: a metal/native-oxide multilayer (MNOM) film consisting of nanogranular high-moment Co/sub x/Fe/sub 100-x/ layers separated by ultrathin magnetic native oxide layers. The high-resistivity magnetic oxide layers isolate the metallic layers electrically, while coupling them magnetically and minimizing the decrease in volume-averaged saturation magnetization that exists in traditional metal/nonmagnetic oxide composites. In addition, the "exchange-averaged" soft magnetic properties of the MNOM composite include an ideal low-dispersion in-plane uniaxial anisotropy whose magnitude varies linearly with the fraction x of Co in the alloy. The resulting anisotropy control, together with the large saturation magnetization, permits the permeability and resonance frequency to be tuned over a wide range to meet specific application requirements.     

Magnetic nanoparticles with core/shell structures

Magnetic nanoparticles with core/shell structures are an important class of functional materials, possessing unique magnetic properties due to their tailored dimensions and compositions. This paper reviews mainly our recent advances in the preparation and characterizations of core/shell structured magnetic materials, focusing in nonmagnetic, antiferromagnetic, or ferro/ferri-magnetic shell coated magnetic core particles. And some of the unique properties of core-shell materials and their self-assembly are presented. Shell layers are shown to serve various functions. A broad demonstration of the successful blend of these types of materials synthesis, microstructural evolution and control, new physics and novel applications that is central to research in this field is presented.     

Strain induced anomalous red shift in mesoscopic iron oxide prepared by a novel technique

Nano magnetic oxides are promising candidates for high density magnetic storage and other applications. Nonspherical mesoscopic iron oxide particles are also candidate materials for studying the shape, size and strain induced modifications of various physical properties viz. optical, magnetic and structural. Spherical and nonspherical iron oxides having an aspect ratio, ∼2, are synthesized by employing starch and ethylene glycol and starch and water, respectively by a novel technique. Their optical, structural, thermal and magnetic properties are evaluated. A red shift of 0·24 eV is observed in the case of nonspherical particles when compared to spherical ones. The red shift is attributed to strain induced changes in internal pressure inside the elongated iron oxide particles. Pressure induced effects are due to the increased overlap of wave functions. Magnetic measurements reveal that particles are superparamagnetic. The marked increase in coercivity in the case of elongated particles is a clear evidence for shape induced anisotropy. The decreased specific saturation magnetization of the samples is explained on the basis of weight percentage of starch, a nonmagnetic component and is verified by TGA and FTIR studies. This technique can be modified for tailoring the aspect ratio and these particles are promising candidates for drug delivery and contrast enhancement agents in magnetic resonance imaging.     

Fe/C复合纳米炭粉的制备及其磁学性能研究

以高温煤焦油沥青为原料,以体积比7∶3的浓硫酸和浓硝酸混合酸为氧化剂,制备水性中间相沥青;采用溶胶-凝胶法先形成碳基溶胶,加入FeCl3后进一步形成复合Fe/C凝胶;凝胶经醇水交换、常温干燥和900℃炭化制备出Fe/C复合磁性纳米炭粉。利用FT-IR、XRD、TG和TEM等对水性中间相沥青、磁性纳米炭原粉以及磁性纳米炭粉进行表征。结果表明:采用溶胶-凝胶和常温干燥的方法可以制备出粒度均匀、形状近似于椭圆形的Fe/C复合磁性纳米炭;其磁性纳米炭粉的平均粒径约5 nm,以聚集成粒度为20 nm～30 nm的团聚体形式存在。磁性纳米炭粉中的碳以无定型结构的形式存在,Fe元素以α-Fe、Fe2O3和Fe3C的形式存在,Fe/C复合磁性纳米炭粉具有软磁性和较高的磁响应性。     

Recommendation of a simple and universally applicable method for measuring the switching field distribution of magneting recording media

The most common methods for assessing the switching field distribution (SFD) of magnetic recording media are compared for samples of acicular magnetic particles made of different types of magnetic materials and having various degrees of particle orientation. It is shown that the method of using the maximum slopedM/dH = M_{R}/H_{c}(1-S*)atM = 0of the magnetic hysteresis loopM(H)can be used to characterize SFD of the irreversible magnetization processes which correlate to the recording performance. Thus, (1-S*) is recommended as the most easily accessible and universally applicable figure of merit for SFD.     

Preparation and magnetic properties of fibrous gamma iron oxide nanoparticles via a nonaqueous medium

Fibrous shape γ-Fe₂O₃ nanoparticles (the length of ∼850 nm; the width of ∼5 nm) have been prepared using lauryl alcohol as a nonaqueous medium. The resultant products were investigated by IR, TG–DTA, XRD, TEM and magnetization measurements. For the preparation of pure γ-Fe₂O₃ nanoparticles, the suitable condition of the molar ratio of lauryl alcohol to iron nitrate is determined to be 1 : 2 and the appropriate temperature is in the range of 300–400 °C. The magnetization measurements reveal that the obtained γ-Fe₂O₃ particles possess better magnetic properties for application in magnetic recording. It can be concluded that lauryl alcohol plays an important role not only in controlling the dimension, shape of the products, but also in helping the increase of magnetic properties.     

5.25 inch floppy disk drive using perpendicular magnetic recording

5.25 inch high density perpendicular magnetic recording floppy disk drive has beer developed by employing new types of high saturation magnetization ring head, Co-Cr single layer medium with Ge underlayer, head slider with ellipsoidal surface configuration to assure intimate head to medium contact, and signal equalization. By these combination, recording density D50 of 145 kFCI, peakshift of 28 % at 100 kFCI, signal to noise ratio of 40.4 dB for cut-off frequency 4.25 MHz, overwrite signal to noise ratio of 27 dB, measured by writing signals at 48 kFCI over previously written 100 kFCI signals were obtained as typical recording characteristics. These results would indicate that floppy disk drive with 100 kFCI recording density has enough system margin by above-mentioned combination. In this paper, design and performance of newly developed floppy disk drive are described.     

基于磁流体独有特性的各种潜在传感器

详细分析磁流体所具有的磁通门原理、粘度智能性、液体流动性、可浸泡性、磁光效应等各种独有特性,探讨基于上述特性的潜在传感机理及应用方向,将上述特性单独或组合使用,将可以开发出各类新型磁流体传感器,具有用于倾斜、速度、加速度、体积、流量、非磁性体或磁流体密度、磁场以及磁流体磁化强度等传感的潜在可能性,对磁流体传感器研究具有指导意义.     

Nanomagnets with high shape anisotropy and strong crystalline anisotropy: perspectives on magnetic force microscopy

We report on a new approach for magnetic imaging, highly sensitive even in the presence of external, strong magnetic fields. Based on FIB-assisted fabricated high-aspect-ratio rare-earth nanomagnets, we produce groundbreaking magnetic force tips with hard magnetic character where we combine a high aspect ratio (shape anisotropy) together with strong crystalline anisotropy (rare-earth-based alloys). Rare-earth hard nanomagnets are then FIB-integrated to silicon microcantilevers as highly sharpened tips for high-field magnetic imaging applications. Force resolution and domain reversing and recovery capabilities are at least one order of magnitude better than for conventional magnetic tips. This work opens new, pioneering research fields on the surface magnetization process of nanostructures based either on relatively hard magnetic materials-used in magnetic storage media-or on materials like superparamagnetic particles, ferro/antiferromagnetic structures or paramagnetic materials.     

Ferromagnetic Liquid Metal Putty-Like Material with Transformed Shape and Reconfigurable Polarity

It is remarkably desirable and challenging to design reconfigurable ferromagnetic materials with high electrical conductivity. This has attracted great attention due to promising applications in many fields such as emerging flexible electronics and soft robotics. However, the shape and magnetic polarity of existing ferromagnetic materials with low conductivity are both hard to be reconfigured, and the magnetization of insulative ferrofluids is easily lost once the external magnetic field is removed. A novel reconfigurable ferromagnetic liquid metal (LM) putty-like material (FM-LMP) with high electrical conductivity and transformed shape, which is prepared through homogenously mixing neodymium–iron–boron microparticles into the gallium-based LM matrix, and turning this liquid-like suspension into the solid-like putty-like material by magnetization, is reported to achieve this. The induction magnetic field of FM-LMP is mainly attributed to the magnetic alignment of the dispersed ferromagnetic microparticles, which can be conveniently demagnetized by mechanical disordering and reversibly reconfigured through microparticle realignment by applying a weak magnetic field. FM-LMP with a low fraction of microparticles can be used as printable conductive ink for paper electronics, which are further exploited for applications including magnetic switching, flexible erasable magnetic recording paper, and self-sensing paper-based soft robotics using magnetic actuation.     

Media for high density magnetic recording

Longitudinal recording is limited at high bit densities by recording demagnetization, self-demagnetization, and adjacent-bit demagnetization, which occur during the writing-demagnetization processes. To minimize these adverse effects it becomes necessary to resort to extreme scaling of the media parameters and their thickness, with the consequence of greatly increasing the difficulty of fabrication and the cost of such optimized media. Pure perpendicular recording circumvents these writing and demagnetization problems because of the strong head coupling of a single pole head with a double layer medium, positive interaction between adjacent bits, and low self-demagnetization at high bit densities. Therefore, it does not require any extreme scaling of the media magnetic parameters and their thickness. Of great interest, at least for the next several years, are the quasi-perpendicular particulate media which can support perpendicular magnetization. These include the isotropic, high-squareness media, and oriented perpendicular media employing particles with uniaxial crystalline or shape anisotropies. The attractiveness of these media derives from their excellent recording performance and from the fact that they preserve the existing head/media interface and they utilize existing coating facilities which should reflect favorably on their cost. In this paper the advantages and disadvantages of the various media under development for high density magnetic recording are compared, and predictions are made for their potential application in future systems.     

Size-dependent structural and magnetic properties of chemically synthesized Co-Ni-Ga nanoparticles

Phase transitions and magnetic properties of shape-memory materials can be tailored by tuning the size of the constituent materials,such as nanoparticles.However,owing to the lack of suitable synthetic methods for size-controlled Heusler nanoparticles,there is no report on the size dependence of their properties and functionalities.In this contribution,we present the first chemical synthesis of size-selected Co-Ni-Ga Heusler nanoparticles.We also report the structure and magnetic properties of the biphasic Co-Ni-Ga nanoparticles with sizes in the range of 30-84 nm,prepared by a SBA-15 nanoporous silicatemplated approach.The particle sizes could be readily tuned by controlling the loading and concentration of the precursors.The fractions and crystallite sizes of each phase of the Co-Ni-Ga nanoparticles are closely related to their particle size.Enhanced magnetization and decreased coercivity are observed with increasing partide size.The Curie temperature (Tc) of the Co-Ni-Ga nanoparticles also depends on their size.The 84 nm-sized particles exhibit the highest Tc (≈ 1,174 K) among all known Heusler compounds.The very high Curie temperatures of the Co-Ni-Ga nanoparticles render them promising candidates for application in high-temperature shape memory alloy-based devices.     

Properties, preparation, advances and limitations of materials andmedia for perpendicular recording

The trends in perpendicular magnetic recording research are discussed, with emphasis on clarifying the trend of research on recording media, their materials, and head materials. Among numerous proposed perpendicular recording media materials, barium ferrite powder and evaporated Co-Cr films seem to lead in practical applications, since their mass production seems to be very successful. There still exist crucial points in their development. However, improvements are continuously taking place. Other candidate perpendicular recording media for a device which has a ring head are also discussed. It is concluded that, for future high-density magnetic recording, utilizing fully the perpendicular component of media magnetization will furnish the key to success     

Magnetic materials analyses by nuclear spectrometry: A joint approach to Mössbauer effect and nuclear magnetic resonance

The common physical basis of the Mossbauer effect (ME) and the nuclear magnetic resonance (NMR) methods is shortly reviewed by discussing the relevant physical properties of nuclei and the interactions of atomic nuclei with electric and magnetic fields. A survey is given of the measurement methods. In principle all those properties of materials can be measured by ME and NMR which influence the energy levels of atomic nuclei and change the shape and intensity of ME and NMR spectra. These properties include the magnetic hyperfine field present in magnetically ordered materials, the valency state of atoms influencing the charge density at the nucleus, the local symmetry of the neighborhood of an atom resulting in electric field gradients at the nucleus, etc. Macroscopic properties connected with these microscopic properties are the magnetization, the magnetic, electric and structural order of crystals, lattice imperfections, and size, shape, and texture of crystallites. Most of these physical properties are closely related to the magnetic properties of matter. Both ME and NMR are limited to specific isotopes and therefore only special groups of' materials are accessible for investigation by these methods. Extensive data about NMR investigations on these materials in the last five years and complementary information about ME investigations on these materials are presented in tabular form and are discussed for selected examples.