The tensile fatigue behaviour of a silica nanoparticle-modified glass fibre reinforced epoxy composite

An anhydride-cured thermosetting epoxy polymer was modified by incorporating 10 wt.% of well-dispersed silica nanoparticles. The stress-controlled tensile fatigue behaviour at a stress ratio of R = 0.1 was investigated for bulk specimens of the neat and the nanoparticle-modified epoxy. The addition of the silica nanoparticles increased the fatigue life by about three to four times. The neat and the nanoparticle-modified epoxy resins were used to fabricate glass fibre reinforced plastic (GFRP) composite laminates by resin infusion under flexible tooling (RIFT) technique. Tensile fatigue tests were performed on these composites, during which the matrix cracking and stiffness degradation was monitored. The fatigue life of the GFRP composite was increased by about three to four times due to the silica nanoparticles. Suppressed matrix cracking and reduced crack propagation rate in the nanoparticle-modified matrix were observed to contribute towards the enhanced fatigue life of the GFRP composite employing silica nanoparticle-modified epoxy matrix.     

Electrically conductive glass fibre reinforced epoxy resin

 The research on an industrially manufactured, electrically conductive glass fibre reinforced epoxy prepreg for aviation applications is reported. In a co-operative effort between Technical University Hamburg-Harburg (TUHH) and Daimler-Benz Aerospace Airbus (DASA) a new glass-epoxy composite with both electrical and good mechanical properties was successfully developed. The electrical conductivity was achieved adding carbon black as a conductive filler into the epoxy matrix and this at a very low level of content. The range of possible applications for this new material is not only limited to aviation. It can also be used in other transport systems or in electric and electronic devices. Received: 21 July 1998 / Accepted: 28 August 1998     

The wear resistance of glass fibre reinforced epoxy composites

Polymers are usually characterized by low moduli and strength. Epoxy, as a thermoset material, has a low wear resistance. Additions of glass fibres improve the elastic modulus and tensile strength and can improve the wear resistance. The composites were prepared by pultrusion of the glass fibres after saturation of epoxy. The fibre volume fraction was varied up to 50%. Tensile and wear tests were carried out to examine the improvement in the composite properties. A small deviation of the tensile strength and the elastic modulus from the calculated values using the rule of mixture was observed due to the existence of porosities. The wear resistance increases with increasing the sliding velocity, with decreasing the applied contact pressure and with selecting the most favourable glass fibre volume fraction.     

Anomalies in moisture absorption of glass fibre reinforced epoxy tubes

This paper describes the moisture absorption of glass/epoxy panels and tubes produced by filament winding. Panels have been immersed in distilled water for up to 10 years at temperatures up to 60°C to establish baseline data. Tubes of the same material were wound at ±55° to the tube axis with two diameters, 60 and 150 mm. These were also immersed in water and lower absorption levels were measured than in panels. Another series of tubes was subjected to internal and external water contact and it was established for both tube diameters that virtually no water enters through the inner wall. Reasons for this apparent internal barrier effect are examined.     

Mechanical and electrical performance of Roystonea regia/glass fibre reinforced epoxy hybrid composites

The present paper investigates mechanical and electrical properties of Roystonea regia/glass fibre reinforced epoxy hybrid composites. Five varieties of hybrid composites have been prepared by varying the glass fibre loading. Roystonea regia (royal palm), a natural fibre was collected from the foliage of locally available royal palm tree through the process of water retting and mechanical extraction. Roystonea regia, E-glass short fibres were used together as reinforcement in epoxy matrix to form hybrid composites. It has been observed that tensile, flexural, impact and hardness properties of hybrid composites considerably increased with increase in glass fibre loading. But electrical conductivity and dielectric constant values decreased with increase in glass fibre content in the hybrid composites at all frequencies. Scanning electron microscopy of fractured hybrid composites has been carried out to study the fibre matrix adhesion.     

Fatigue behaviour of glass fibre reinforced epoxy composites enhanced with nanoparticles

Nanoparticle reinforcement of the matrix in laminates has been recently explored to improve mechanical properties, particularly the interlaminar strength. This study analyses the fatigue behaviour of nanoclay and multiwalled carbon nanotubes enhanced glass/epoxy laminates. The matrix used was the epoxy resin Biresin® CR120, combined with the hardener CH120-3. Multiwalled carbon nanotubes (MWCNTs) 98% and organo-montmorillonite Nanomer I30 E nanoclay were used. Composites plates were manufactured by moulding in vacuum. Fatigue tests were performed under constant amplitude, both under tension–tension and three points bending loadings. The fatigue results show that composites with small amounts of nanoparticles addition into the matrix have bending fatigue strength similar to the obtained for the neat glass fibre reinforced epoxy matrix composite. On the contrary, for higher percentages of nanoclays or carbon nanotubes addition the fatigue strength tend to decrease caused by poor nanoparticles dispersion and formation of agglomerates. Tensile fatigue strength is only marginally affected by the addition of small amount of particles. The fatigue ratio in tension–tension loading increases with the addition of nanoclays and multi-walled carbon nanotubes, suggesting that both nanoparticles can act as barriers to fatigue crack propagation.     

Aligned short glass fibre/epoxy composites

An orientation system based on the principles of the ERDE glycerine process was built and used to prepare short glass fibre mats of known orientation distributions. The mats were subsequently impregnated with epoxy, B staged to yield partially cured prepregs and finally compression moulded. Mechanical characterization and comparison with theoretical formulations were performed on longitudinal, transverse and off-axis specimens. The mechanical characteristics of specimens with different orientation patterns were compared with analytical predicitions based on ‘Laminate analogy’ methods. Fracture surfaces were studied by optical and scanning electron microscopy techniques.     

Effect of fibre volume fraction on fatigue behaviour of glass fibre reinforced composite

The aim of this paper is to study the fatigue behavior of GFRP composites manufactured by vacuum bagging process by varying the volume fraction. Constant‐amplitude flexural fatigue tests were performed at zero mean stress, i.e. a cyclic stress ratio R=?1 by varying the frequency of the testing machine. The relationship between stiffness degradation rate and fibre volume fraction, was observed, and the influence of volume fraction on the tensile strength was also investigated. The results show that, as the volume fraction increases the stiffness degradation rate initially decreases and then increases after reaching a certain limit for the volume fraction. Graph between volume fraction and Young's modulus shows that as the volume fraction increases Young's modulus also increases and reaches a limit and then it decreases with further increase in volume fraction, due to the increase in fibre content which changes the material properties of the composite material. The obtained results are in agreement with the available results.     

Carbon fibre reinforced glass matrix composite tension and flexure properties

Carbon fibre reinforced borosilicate glass matrix composites have been fabricated to determine their mechanical properties in tension and flexure. Composite tensile stress-strain properties, including elastic modulus, proportional limit and ultimate tensile strength, have been measured as a function of fibre content. Composite tensile properties were also obtained at temperatures of up to 625° C through the testing of 0/90 cross-plied specimens. Composite short-beam shear strength was found to depend on specimen orientation and also on the composition of the glass matrix. This compositional dependence was associated with an independent measurement of the fibre-matrix interfacial shear strength and was related to the degree of fibre-matrix reaction taking place during composite fabrication.     

Fabrication and mechanical properties of glass fibre reinforced thermoplastic elastomer composite

The paper investigates the effects of fabrication conditions on mechanical properties of glass fibre reinforced thermoplastic elastomer composites. The impregnation time was varied between 5 and 30 min and the cooling conditions were rapid and gradual cooling. Tensile testing was carried out on samples with different fibre orientations. Double Cantilever Beam (DCB) tests were carried out to evaluate the fracture toughness of the composites. The degree of crystallinity and morphology of the composite were studied by using differential scanning calorimetry (DSC) and scanning electron microscopy (SEM). Impregnation of matrix resin into glass fibre was found to be complete before 30 min and tensile properties increased with increasing impregnation time. SEM micrographs of fractured surfaces revealed poor adhesion between the matrix and the reinforcing agent. Due to the flexible nature of the composite, the fracture toughness (G_IC) could not be determined because of the formation of ridges on the surface.     

深海环境下树脂基复合材料吸湿行为

通过自制压力容器模拟深海环境, 采用称量法获得玻璃纤维增强环氧树脂(GF/CYD-128)层合板在不同压力下吸湿数据, 研究GF/CYD-128层合板在深海环境的吸湿行为。结果表明: 0~3.0 MPa压力范围内GF/CYD-128层合板饱和吸湿量随着压力的增加呈现先下降后增加的趋势, 压力为2.5 MPa时饱和吸湿量最低, 其饱和吸湿量随浸泡压力变化的趋势可用二次多项式描述; GF/CYD-128层合板在深海环境中的吸湿行为呈现non-Fick特征, 但可以采用Langmuir 模型进行描述。利用Langmuir模型准确预测了深海环境中GF/CYD-128层合板的吸湿行为。     

Improvement of fatigue life by incorporation of nanoparticles in glass fibre reinforced epoxy

The fatigue properties of glass fibre reinforced epoxy laminates modified with small amounts (0.3 wt.%) of nanoparticles (fumed silica SiO₂ and multi-wall carbon nanotubes (MWCNT)) were evaluated by means of static (90°-tensile and stepped tensile) and dynamic fatigue tests. For the MWCNT-modified matrix, the electrical conductivity was measured in situ. The addition of nanoparticles lead to increases in inter fibre fracture strength of up to 16%. More significantly, the high cycle fatigue life is increased by several orders of magnitude in number of load cycles. The increased inter fibre fracture strength could be correlated to the improved fatigue behaviour, as final failure in high cycle fatigue is strongly correlated to matrix cracks. For the MWCNT-modified composites, the state of load and damage state was monitored by conductivity measurements. A correlation between the onset of matrix cracking and increase in electrical resistivity could be drawn enabling self sensing capabilities.     

An investigation into hybrid carbon/glass fiber reinforced epoxy composite automotive drive shaft

This paper examines the effect of fiber orientation angles and stacking sequence on the torsional stiffness, natural frequency, buckling strength, fatigue life and failure modes of composite tubes. Finite element analysis (FEA) has been used to predict the fatigue life of composite drive shaft (CDS) using linear dynamic analysis for different stacking sequence. Experimental program on scaled woven fabric composite models was carried out to investigate the torsional stiffness. FEA results showed that the natural frequency increases with decreasing fiber orientation angles. The CDS has a reduction equal to 54.3% of its frequency when the orientation angle of carbon fibers at one layer, among other three glass ones, transformed from 0° to 90°. On the other hand, the critical buckling torque has a peak value at 90° and lowest at a range of 20–40° when the angle of one or two layers in a hybrid or all layers in non-hybrid changed similarly. Experimentally, composite tubes of fiber orientation angles of ±45° experience higher load carrying capacity and higher torsional stiffness. Specimens of carbon/epoxy or glass/epoxy composites with fiber orientation angles of ±45° show catastrophic failure mode. In a hybrid of both materials, [±45°] configuration influenced the failure mode.     

紫外老化对碳纤维增强环氧树脂复合材料性能的影响

采用拉挤成型工艺制备碳纤维增强环氧树脂基复合材料,并对其进行人工加速紫外老化实验,对不同老化时间的试样进行弯曲强度测试、冲击强度测试、动态热机械分析(DMA)。结果表明,紫外老化仅影响到受紫外辐射的碳纤维环氧复合材料最外层,使对外层性能敏感的力学性能下降;紫外老化使复合材料玻璃化转变温度(Tg)提高,老化前期提高幅度相对较大,后期变化不明显;随着老化时间的增加,受到紫外辐射的最外层碳纤维/环氧树脂界面受到一定程度削弱。     

Mechanical properties of hybrid kenaf/glass reinforced epoxy composite for passenger car bumper beam

It is estimated that the annual world car production rate will reach 76 million vehicles per year by 2020. New regulations such as the EU End of Life Vehicles (ELV) regulations are forcing car manufacturers to consider the environmental impact of their production and possibly shift from the use of synthetic materials to the use of agro-based materials. Poor mechanical properties and certain manufacturing limitations currently limit the use of agro-based materials to non-structural and semi-structural automotive components. The hybridization of natural fiber with glass fiber provides a method to improve the mechanical properties over natural fibers alone. This research is focused on a hybrid of kenaf/glass fiber to enhance the desired mechanical properties for car bumper beams as automotive structural components with modified sheet molding compound (SMC). A specimen without any modifier is tested and compared with a typical bumper beam material called glass mat thermoplastic (GMT). The results indicate that some mechanical properties such as tensile strength, Young’s modulus, flexural strength and flexural modulus are similar to GMT, but impact strength is still low, and shows the potential for utilization of hybrid natural fiber in some car structural components such as bumper beams.     

Cyclic shearing behaviour of a unidirectional glass/epoxy composite

Results from an experimental program consisting of monotonic and fatigue shear tests on a unidirectional glass–epoxy composite are presented in this paper. Unnotched and tabbed specimens were subjected to interlaminar and intralaminar shearing modes using an appropriate testing device called “Cube Test”. Shear mechanical characteristics are determined and cyclic resistance is analyzed. Fatigue results are in good agreement with three-point-bending tests with predominant shearing studied elsewhere on the same material. Modified Basquin relationship is established to characterize the shearing fatigue strength. Microstructural observations of the fracture surfaces by scanning electron microscopy show that hackle formation is the predominant damage mechanism.     

Polymer-modified glass fibre reinforced gypsum

Glass fibre reinforced gypsum, modified by addition of specially selected and developed thermosetting polymers, is the basis of a new composite material, called PGRG. An investigation has been performed into its mechanical properties such as bending strength, tensile strength and long-term performance under constant load and fatigue load. The influence of moisture and temperature on mechanical properties has been determined. The equilibrium moisture content at various relative humidities, the moisture content under natural weathering conditions, the coefficient of linear expansion and the microstructure have been studied. Furthermore, the durability has been investigated under accelerated ageing conditions and outdoor exposure. The results have shown that the polymer-modified glass fibre reinforced gypsum has good mechanical properties under tension and, unlike unmodified gypsum, is resistant to the Western European climate. A variety of new outdoor applications for gypsum are likely to be possible now: The material has already been used successfully for outdoor applications in the UK, the Middle East and The Netherlands.

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Resume Le platre renforcé de fibres de verre, modifié par l'addition de polymère thermodurcissable spécialement sélectionné et fabriqué, forme la base d'un nouveau matériau composite appelé PGRG, dont on a examiné certaines propriétés mécaniques: résistance à la flexion, à la traction et performance à long terme sous charge constante et charge de fatigue. On a déterminé l'influence de l'humidité et de la température sur les propriétés mécaniques. On a également étudié l'équilibre de la teneur en eau à différentes humidités relatives, la teneur en eau en exposition naturelle, le coefficient d'expansion linéaire et la microstructure. On a aussi examiné la durabilité dans des conditions de vieillissement accéléré et l'exposition à l'atmosphère. Les résultats ont montré que les propriétés mécaniques du composite sont bonnes et que, à la différence du platre non traité, il peut résister au climat d'Europe Occidentale. Ceci permet d'envisager maintenant pour le platre diverses applications en ouvrages extérieurs. Le matériau a déjà été utilisé avec succès pour ce type d'applications en Grande-Bretagne, aux Pays-Bas et au Moyen-Orient.

     

Low velocity impact response and damage of laminate composite glass fibre/epoxy based tri-block copolymer

Two types of laminate composites made of glass fibre/epoxy matrix (EPO_FV) and glass fibre/epoxy modified tri-block copolymer (Nanostrength) matrix (EPONS_FV) were manufactured by compression moulding. Some AFM investigations have been done to identify the Nanostrength dispersion in the epoxy matrix and some DMA analyses have been performed, at different frequencies, to understand the frequency or the strain rate sensitivity of both composites. Compared to EPO_FV, EPONS_FV exhibits a significant frequency/strain rate sensitivity. Impact resistance of the composite was investigated by means of low velocity impact tests. The low velocity impact results indicate that the addition of Nanostrength leads to the improved impact resistance and an increase in absorbed energy, especially at high impact energy level. SEM observations, performed on ion polished samples, reveal the presence of micro-cracks for both composites. Micro-cracks consist of a coalescence of fibre matrix de-bonding. It was also observed that EPONS_FV contains a lower density of micro-cracks compared to EPO_FV, confirming the fact that the composite with Nanostrength absorbs more energy by Nanostrength micelles cavitation.