The potential of harakeke fibre as reinforcement in polymer matrix composites including modelling of long harakeke fibre composite strength

Mechanical properties of aligned long harakeke fibre reinforced epoxy with different fibre contents were evaluated. Addition of fibre was found to enhance tensile properties of epoxy; tensile strength and Young’s modulus increased with increasing content of harakeke fibre up to 223 MPa at a fibre content of 55 wt% and 17 GPa at a fibre content of 63 wt%, respectively. The flexural strength and flexural modulus increased to a maximum of 223 MPa and 14 GPa, respectively, as the fibre content increased up to 49 wt% with no further increase with increased fibre content. The Rule of Mixtures based model for estimating tensile strength of aligned long fibre composites was also developed assuming composite failure occurred as a consequence of the fracture of the lowest failure strain fibres taking account porosity of composites. The model was shown to have good accuracy for predicting the strength of aligned long natural fibre composites.     

The effect of reprocessing on the mechanical properties of polypropylene reinforced with wood pulp,flax or glass fibre

Composites of polypropylene, substitutable for a given application and reinforced with: Medium Density Fibreboard fibre (MDF) (40 wt%); flax (30 wt%); and glass fibre (20 wt%), were evaluated after 6 injection moulding and extrusion reprocessing cycles. Of the range of tensile, flexural and impact properties examined, MDF composites showed the best mean property retention after reprocessing (87%) compared to flax (72%) and glass (59%). After 1 reprocessing cycle the glass composite had higher tensile strength (56.2 MPa) compared to the MDF composite (44.4) but after 6 cycles the MDF was stronger (35.0 compared to 29.6 MPa for the glass composite). Property reductions were attributed to reduced fibre length. MDF fibres showed the lowest reduction in fibre length between 1 and 6 cycles (39%), compared to glass (51%) and flax (62%). Flax fibres showed greater increases in damage (cell wall dislocations) with reprocessing than was shown by MDF fibres.     

Influence of palm oil fuel ash on ultimate flexural and uniaxial tensile strength of green ultra-high performance fiber reinforced cementitious composites

This study focuses on the measurement of the ultimate flexural and tensile strength of GUSMRC, a new class of green ultra-high performance fiber reinforced cementitious composites (GUHPFRCCs) in which 75% of the volume contains ultrafine palm oil fuel ash (UPOFA). This green concrete is currently under development at the Universiti Sains Malaysia (GUSMRC). The main objective of this study is to investigate the potential of UPOFA as a partial binder replacement for the ultimate flexural and uniaxial tensile strength of GUSMRC mixtures. Results showed that UPOFA enhances the flexural and uniaxial tensile responses of fresh UHPFRCCs. The highest flexural and uniaxial tensile strength values at the 50% replacement level after 28 days were at 42.38 MPa and 13.35 MPa, respectively, indicating the potential of utilizing UPOFA as an efficient pozzolanic mineral admixture for the production of GUSMRC with superior engineering properties.     

Quasi-static and dynamic mechanical elastic moduli of alkaline aged pultruded fibre reinforced polymer composite rebar

Due to the increased use of glass fibre reinforced polymer composite (GFRP) rebar in concrete structures, the durability performance of GFRP rebar has been an important research topic in recent years. This paper presents elastic modulus of alkaline environment (pH ≈ 13) aged pultruded GFRP rebar as evaluated by three different methods, namely, quasi-static tensile, quasi-static flexural and dynamic mechanical thermal tests. It was found that elastic modulus of the GFRP rebar samples did not change significantly due to exposure in alkaline environment at 60 °C for 1, 2, 3, 4, 6 and 14 months when compared with that of control sample. Elastic modulus was found to be in the range of 52.5–56.5 GPa irrespective to testing methods and ageing time. In addition, it was estimated from the long time projected results that quasi-static tensile, quasi-static flexural and dynamic mechanical moduli will be retained by about 93%, 95% and 85%, respectively, after 100 years in alkaline environment at 60 °C. Microscopic analysis indicated that quasi-static tensile and flexural failure was mainly due to matrix cracking and shear failure of fibre/matrix interface.     

Effect of short nylon-6 fibres on natural rubber-toughened polystyrene

Composites based on polystyrene and natural rubber at a ratio of 85/15 were prepared by melt mixing with nylon-6 fibres using an internal mixer. The loading of short nylon-6 fibre, untreated and resorcinol formaldehyde latex (RFL)-treated, was varied from 0 to 3 wt.%. Tensile and flexural test samples were punched out from sheets and tested to study the variation of mechanical and dynamic mechanical properties. The tensile behaviour of the composite has been determined at three different strain rates (4.1 × 10⁻⁴ s⁻¹, 2 × 10⁻³ s⁻¹ and 2 × 10⁻² s⁻¹). Both the tensile strength and Young’s modulus of the composite increased with strain rate. The tensile strength, tensile modulus, flexural strength and flexural modulus increased with the increase in fibre content up to 1 wt.%, above which there was a significant deterioration in the properties. The RFL-treated fibre composites showed improved mechanical properties compared to the untreated one. Dynamic mechanical analysis (DMA) showed that the storage modulus of the composite with RFL-treated fibre was better compared to the untreated one. The fibre–matrix morphology of the tensile fractured specimens was studied by scanning electron microscopy (SEM). The results suggested that the RFL treatment of nylon fibre promoted adhesion to the natural rubber phase of the blend, thereby improving the mechanical properties of the composite.     

Manufacture and characterisation of thermoplastic composites made from PLA/hemp co-wrapped hybrid yarn prepregs

PLA/hemp co-wrapped hybrid yarns were produced by wrapping PLA filaments around a core composed of a 400 twists/m and 25 tex hemp yarn (Cannabis sativa L) and 18 tex PLA filaments. The hemp content varied between 10 and 45 mass%, and the PLA wrapping density around the core was 150 and 250 turns/m. Composites were fabricated by compression moulding of 0/90 bidirectional prepregs, and characterised regarding porosity, mechanical strength and thermal properties by dynamic mechanical thermal analysis (DMTA) and differential scanning calorimetry (DSC). Mechanical tests showed that the tensile and flexural strengths of the composites markedly increased with the fibre content, reaching 59.3 and 124.2 MPa when reinforced with 45 mass% fibre, which is approximately 2 and 3.3 times higher compared to neat PLA. Impact strength of the composites decreased initially up to 10 mass% fibre; while higher fibre loading (up to 45 mass%) caused an increase in impact strength up to 26.3 kJ/m², an improvement of about 2 times higher compared to neat PLA. The composites made from the hybrid yarn with a wrapping density of 250 turns/m showed improvements in mechanical properties, due to the lower porosity. The fractured surfaces were investigated by scanning electron microscopy to study the fibre/matrix interface.     

Influence of alkali treatment and fibre length on mechanical properties of short Agave fibre reinforced epoxy composites

Composites based on short Agave fibres (untreated and alkali treated) reinforced epoxy resin using three different fibre lengths (3 mm, 7 mm and 10 mm length) are prepared by using hand lay up and compression mould technique. The materials were characterized in terms of tensile, compressive, flexural, impact, water absorption properties and machinability behaviour. All mechanical tests showed that alkali treated fibre composites withstand more fracture strain than untreated fibre composites. As evidenced by the dynamic mechanical analysis (DMA) tests, the thermo-mechanical properties of the composite with alkali treated Agave fibre were considerably good as alkali treatment had facilitated more sites of fibre resin interface. The machinability and atomic force microscope (AFM) studies were carried out to analyze the fibre–matrix interaction in untreated and alkali treated Agave fibre–epoxy composites.     

Grafting of nano-TiO2 onto flax fibers and the enhancement of the mechanical properties of the flax fiber and flax fiber/epoxy composite

In this article, a flax fiber yarn was grafted with nanometer sized TiO₂, and the effects on the tensile and bonding properties of the single fibers and unidirectional fiber reinforced epoxy plates were studied. The flax fiber yarn was grafted with nanometer sized TiO₂ through immersion in nano-TiO₂/KH560 suspensions under sonification. The measured grafting content of the nano-TiO₂ ranged from 0.89 wt.% to 7.14 wt.%, dependent on the suspension concentration. With the optimized nano-TiO₂ grafting content (∼2.34 wt.%), the tensile strength of the flax fibers and the interfacial shear strength to an epoxy resin were enhanced by 23.1% and 40.5%, respectively. The formation of Si–O–Ti and C–O–Si bonds and the presence of the nano-TiO₂ particles on the fiber surfaces contributed to the property enhancements. Unidirectional flax fiber reinforced epoxy composite (V_f = 35.4%) plates prepared manually showed significantly enhanced flexural properties with the grafting of nano-TiO₂.     

Mechanical,thermal expansion,and flammability properties of co-extruded wood polymer composites with basalt fiber reinforced shells

Basalt fiber (BF) filled high density polyethylene (HDPE) and co-extruded wood plastic composites (WPCs) with BF/HDPE composite shell were successfully prepared and their mechanical, morphological and thermal properties characterized. The BFs had an average diameter of 7 μm with an organic surfactant surface coating, which was thermally decomposed at about 210 °C. Incorporating BFs into HDPE matrix substantially enhanced flexural, tensile and dynamic modulus without causing a noticeable decrease in the tensile and impact strength of the composites. Micromechanical modeling of tensile properties for the BF/HDPE composites showed a good fit of the selected models to the experimental data. Compared to neat HDPE, BF/HDPE composites had reduced linear coefficient of thermal expansion (LCTE) values. The use of the pure HDPE and BF/HDPE layers over a WPC core greatly improved impact strength of core–shell structured composites. However, the relatively less-stiff HDPE shell with large LCTE values decreased the overall composite modulus and thermal stability. Both flexural and thermal expansion properties were enhanced with BF reinforced HDPE shells, leading to well-balanced properties of core–shell structured material. Cone calorimetry analysis indicated that flammability performance of core–shell structured composites was improved as the BF content increased in the shell layer.     

Flexural toughness characteristics of steel–polypropylene hybrid fibre-reinforced oil palm shell concrete

Hybridization of steel–polypropylene leads to improvements of both the mechanical and ductility characteristics of concrete. In this investigation, the effect of steel, polypropylene (PP) and steel-PP hybrid fibres on the compressive strength, tensile strength, flexural toughness and ductility of oil palm shell fibre reinforced concrete (OPSFRC) was studied. The comparison on the above said properties between the specimens prepared with crushed and uncrushed oil palm shell (OPS) as lightweight coarse aggregate was also carried out. The experimental results showed that the highest compressive strength of about 50 MPa was produced by the mix with 0.9% steel and 0.1% PP hybrid fibres. The highest increments in the splitting tensile and the flexural strengths of the OPSFRC were found up to 83% and 34%, respectively. However, the mixes with 1% PP fibres produced negative effects on both the compressive and tensile strengths. The results on the toughness indices showed that the OPSC possess no post-cracking flexural toughness. Though, the flexural deflection and toughness of the OPSC was significantly enhanced by the addition of fibres; the dominance of the steel fibre on the first crack flexural deflection and toughness of OPSFRC was evident. The mixes with 0.9% steel and 0.1% PP hybrid fibres reported the highest improvement in toughness index and residual strength factor.     

Experimental investigations on bond strength between coconut fibre and concrete

Effect of fibre embedment lengths, diameters, pretreatment conditions and concrete mix design ratios on the bond strength between single coconut fibre and concrete is investigated. Fibres are prepared and categorised manually. Fibre diameters are measured by a stereomicroscope. Fibre and concrete properties are also determined experimentally. The simplified equations are proposed for estimating the fibre tensile stress, elastic modulus and toughness. Single fibre pull-out tests are carried out to determine load–slippage curves with the help of an Instron tensile machine having load cell. Bond strength and energy required for fibre pullout are calculated from the experimental data. The results show that fibres have the maximum bond strength with concrete when (i) embedment length is 30 mm, (ii) fibres are thick, (iii) treated with boiling water, and (iv) concrete mix design ratio is 1:3:3. Similar effects are observed for energy required for fibre pullout. With the obtained knowledge, empirical equations are also developed to determine the bond strength and energy required for fibre pullout.     

Variation of strength and stiffness of fibre reinforced polymer reinforcing bars with temperature

This paper presents the results of tensile mechanical properties of FRP reinforcement bars, used as internal reinforcement in concrete structures, at elevated temperatures. Detailed experimental studies were conducted to determine the strength and stiffness properties of FRP bars at elevated temperatures. Two types of FRP bars namely: carbon fibre reinforced polyester bars of 9.5 mm diameter and glass fibre reinforced polyester bars of 9.5 mm and 12.7 mm diameter were considered. For comparison, conventional steel reinforcement bars of 10 mm and 15 mm diameter were also tested. Data from the experiments was used to illustrate the comparative variation of tensile strength and stiffness of different types of FRP reinforcing bars with traditional steel reinforcing bars. Also, results from the strength tests were used to show that temperatures of about 325 °C and 250 °C appear to be critical (in terms of strength) for GFRP and CFRP reinforcing bars, respectively. A case study is presented to illustrate the application of critical temperatures for evaluating the fire performance of FRP-reinforced concrete slabs.     

Influence of alkali treatment on the interfacial and physico-mechanical properties of industrial hemp fibre reinforced polylactic acid composites

The focus of this work was to produce short (random and aligned) and long (aligned) industrial hemp fibre reinforced polylactic acid (PLA) composites by compression moulding. Fibres were treated with alkali to improve bonding with PLA. The percentage crystallinity of PLA in composites was found to be higher than that for neat PLA and increased with alkali treatment of fibres which is believed to be due to the nucleating ability of the fibres. Interfacial shear strength (IFSS) results demonstrated that interfacial bonding was also increased by alkali treatment of fibres which also lead to improved composite mechanical properties. The best overall properties were achieved with 30 wt.% long aligned alkali treated fibre/PLA composites produced by film stacking technique leading to a tensile strength of 82.9 MPa, Young’s modulus of 10.9 GPa, flexural strength of 142.5 MPa, flexural modulus of 6.5 GPa, impact strength of 9 kJ/m², and a fracture toughness of 3 MPa m^1/2.     

Mechanical properties of poly(butylene succinate) (PBS) biocomposites reinforced with surface modified jute fibre

A biocomposite was originally fabricated with biodegradable polymer PBS and jute fibre, and the effects of fibre surface modification on characteristics of jute fibre and mechanical properties of the biocomposite were evaluated in this paper. The experimental results show that surface modification can remove surface impurities and reduce diameter of jute fibres. Regarding the mechanical properties of biocomposites, it is observed that the biocomposites with jute fibres treated by 2% NaOH, 2 + 5% NaOH or coupling agent, respectively, an optimum in mechanical properties can obtain at fibre content of 20 wt.%, which exhibit an obvious enhancement in mechanical strength and modulus compared to the ones with untreated jute fibre. Furthermore, surface modification also exhibits less effects on flexural properties compared to tensile properties and more on flexural or tensile modulus than on the strength.     

Mechanical properties of natural fibre reinforced polyester composites: Jowar,sisal and bamboo

In this paper, the experiments of tensile and flexural tests were carried out on composites made by reinforcing jowar as a new natural fibre into polyester resin matrix. The samples were prepared up to a maximum volume fraction of approximately 0.40 from the fibres extracted by retting and manual process, and compared with established composites like sisal and bamboo developed under similar laboratory conditions. Jowar fibre has a tensile strength of 302 MPa, modulus of 6.99 GPa and an effective density of 922 kg/m³. It was observed that the tensile strength of jowar fibre composite is almost equal to that of bamboo composite, 1.89 times to that of sisal composite and the tensile modulus is 11% and 45% greater than those of bamboo and sisal composites, respectively at 0.40 volume fraction of fibre. The flexural strength of jowar composite is 4%, 35% and the flexural modulus is 1.12 times, 2.16 times greater than those of bamboo and sisal composites, respectively. The results of this study indicate that using jowar fibres as reinforcement in polyester matrix could successfully develop a composite material in terms of high strength and rigidity for light weight applications compared to conventional sisal and bamboo composites.     

Bond analysis of corroded reinforced concrete beams under monotonic and fatigue loads

This study investigated the fatigue bond behaviour of corroded steel reinforced concrete beams. Nine beams (152 × 254 × 2000 mm [6 × 10 × 78.74 in.]) were constructed and tested. Bond failure occurred in all the beams. The variables in this test series were: the type of load applied (monotonic or repeated loading), the repeated load range, whether the reinforcement inside the beam was corroded or not, and whether a carbon fibre reinforced polymer (CFRP) repair method was used or not. The fatigue life of the beams varied linearly with the range of applied load with a very shallow slope. Corroding the beams to a low corrosion level decreased the fatigue bond strength by about 30%. Corrosion caused the concrete in between the lugs of the reinforcing bars to be partially crushed due to the formation of the rust products from the corrosion process. This reduced the strength of the concrete keys and increased the rate of slip in the bar under repeated loading.     

Effect of steel fiber on the mechanical properties of oil palm shell lightweight concrete

This paper reports the results of a study conducted to investigate the effect of low volume content of steel fiber on the slump, density, compressive strength under different curing conditions, splitting tensile strength, flexural strength and modulus of elasticity of a grade 35 oil palm shell (OPS) lightweight concrete mixture. The results indicate that an increase in steel fiber decreased the workability and increased the density. All the mechanical properties except the modulus of elasticity (E) improved significantly. The 28 day compressive strength of steel fiber OPS lightweight concrete in continuously moist curing was in the range of 41–45 MPa. The splitting tensile/compressive and the flexural/compressive strength ratio for plain OPS concrete are comparable with artificial lightweight aggregate. The (E) value measured in this study was about 15.5 GPa on average for all mixes, which is higher than previous studies and is in the range of normal weight concrete. Steel fiber can be used as an alternative material to reduce the sensitivity of OPS concrete in poor curing environments.     

Development of kenaf-glass reinforced unsaturated polyester hybrid composite for structural applications

The main aim of this paper is to develop kenaf-glass (KG) fibres reinforced unsaturated polyester hybrid composite on a source of green composite using sheet moulding compound process. Unsaturated polyester resin (UPE) and KG fibres in mat form were used at a ratio of 70:30 (by volume) with treated and untreated kenaf fibre. The kenaf fibre was treated with 6% sodium hydroxide (NaOH) diluted solution for 3 h using mercerization method. The hybrid composites were tested for flexural, tensile and Izod impact strength using ASTM D790-03, ASTM D618 and ASTM D256-04 standards respectively. The highest flexural, tensile and impact strength were obtained from treated kenaf with 15/15 v/v KG fibres reinforced UPE hybrid composite in this investigation.Scanning electron microscopy fractography showed fibre cracking, debonding and fibre pulled-out as the main fracture mode of composites and kenaf treated 15/15 v/v KG reinforced hybrid composite exhibited better interfacial bonding between the matrix and reinforcement compared to other combinations.     

Mechanical properties of soil buried kenaf fibre reinforced thermoplastic polyurethane composites

A study on mechanical properties of soil buried kenaf fibre reinforced thermoplastic polyurethane (TPU) composites is presented in this paper. Kenaf bast fibre reinforced TPU composites were prepared via melt-mixing method using Haake Polydrive R600 internal mixer. The composites with 30% fibre loading were prepared based on some important parameters; i.e. 190 °C for reaction temperature, 11 min for reaction time and 400 rpm for rotating speed. The composites were subjected to soil burial tests where the purpose of these tests was to study the effect of moisture absorption on the mechanical properties of the composites. Tensile and flexural properties of the composites were determined before and after the soil burial tests for 20, 40, 60 and 80 days. The percentages of both moisture uptake and weight gain after soil burial tests were recorded. Tensile strength of kenaf fibre reinforced TPU composite dropped to ∼16.14 MPa after 80 days of soil burial test. It was also observed that there was no significant change in flexural properties of soil buried kenaf fibre reinforced TPU composite specimens.     

Durability of GFRP nanocomposites subjected to hygrothermal ageing

This paper presents long term durability prediction of 0–5 wt.% nanoclay/vinylester/glass fibre nanocomposites based on their tensile strength retention in accelerated hygrothermal ageing using Arrhenius rate model. The specimens were exposed to 30 °C, 50 °C and 60 °C and 95% relative humidity for 75 days and tested for tensile strength retention as a function of duration of exposure. The predicted tensile strength retentions for one year of ageing of vinylester/glass at 30 °C, 50 °C and 60 °C using Arrhenius rate model were 59%, 48% and 43% respectively. The corresponding strength retentions predicted for 4 wt.% nanoclay/vinylester/glass were 81.1%, 77.9% and 76.4%. Strength retentions for ten years were predicted using the analytical model to assess their long-term performance.