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1.
Two phosphorescent iridium complexes with bipolar transporting ability, namely FPPCA (500 nm) and BZQPG (600 nm), are synthesized and employed as an ideal host‐guest system for phosphorescent organic light emitting diodes (PHOLEDs).The devices give very high‐efficiency orange‐red emission from BZQPG with maximum external quantum efficiency (EQE or ηext) of >27% and maximum power efficiency (PE or ηp) of >75 lm/W, and maintain high levels of 26% and 55 lm/W, 25% and 40 lm/W at high luminance of 1000 and 5000 cd m?2, respectively, within a range of 8–15 wt% of BZQPG. The realization of such high and stable EL performance results from the coexistence of two parallel paths: i) effective energy transfer from host (FPPCA) to guest (BZQPG) and ii) direct exciton formation on the BZQPG emitter, which can alternately dominate the electrophosphorescent emission. This all‐phosphor doping system removes the charge‐injection barrier from the charge‐transport process to the emissive layer (EML) due to the inherent narrow Eg of both phosphors. Therefore, this ideal host–guest system represents a new design to produce PHOLEDs with high efficiency and low efficiency roll‐off using a simple device configuration.  相似文献   

2.
Increasing exciton utilization and reducing exciton annihilation are crucial to achieve high performance of organic light‐emitting diodes (OLEDs), which greatly depend on molecular engineering of emitters and hosts. A novel luminogen (SBF‐BP‐DMAC) is synthesized and characterized. Its crystal and electronic structures, thermal stability, electrochemical behavior, carrier transport, photoluminescence, and electroluminescence are investigated. SBF‐BP‐DMAC exhibits enhanced photoluminescence and promotes delayed fluorescence in solid state and bipolar carrier transport ability, and thus holds multifunctionality of emitter and host for OLEDs. Using SBF‐BP‐DMAC as an emitter, the nondoped OLEDs exhibit maximum electroluminescence (EL) efficiencies of 67.2 cd A?1, 65.9 lm W?1, and 20.1%, and the doped OLEDs provide maximum EL efficiencies of 79.1 cd A?1, 70.7 lm W?1, and 24.5%. A representative orange phosphor, Ir(tptpy)2acac, is doped into SBF‐BP‐DMAC for OLED fabrication, giving rise to superior EL efficiencies of 88.0 cd A?1, 108.0 lm W?1, and 26.8% for orange phosphorescent OLEDs, and forward‐viewing EL efficiencies of 69.3 cd A?1, 45.8 lm W?1, and 21.0% for two‐color hybrid warm‐white OLEDs. All of these OLEDs can retain high EL efficiencies at high luminance, with very small efficiency roll‐offs. The outstanding EL performance demonstrates the great potentials of SBF‐BP‐DMAC in practical display and lighting devices.  相似文献   

3.
We report the synthesis and organic light‐emitting devices (OLEDs) made from a series of 1‐phenyl‐ and 3‐phenylisoquinolinyliridium complexes in which the phenyl group is linked to the C1 and C3 carbons of isoquinoline, respectively. These linkage isomers show distinct differences in their photophysical and electroluminescence (EL) properties, including the magnitude of phosphorescent lifetimes and photoluminescence (PL) and EL emission wavelengths, as well as the phenomenon of triplet–triplet (T–T) annihilation. Complexes of these two families show a strong absorption band in the region 440–490 nm assignable to spin‐forbidden 3MLCT (metal–ligand charge‐transfer) bands. The extinction coefficients of these bands are similar to those of spin‐allowed 1MLCT bands, indicative of an anomalously strong spin–orbital coupling. Upon excitation, 1‐phenylisoquinolinyliridium complexes exhibit a single phosphorescent emission band in the red region (595–631 nm). All of these red phosphors show outstanding EL performance with negligible T–T annihilation because of short phosphorescent lifetimes (1.04–2.46 μs in CH2Cl2) and good emission quantum yields. One representative, [Ir(5‐f‐1piq)2(acac)] (acac = acetylacetonate) ( 3 ) (5‐f‐1piqH = 5‐fluoro‐1‐phenylisoquinoline), is not only the brightest at low voltages (1883 cd m–2 at 7.1 V; 8320 cd m–2 at 9.0 V) but also shows a ηext value of. 6.50 % at high current (J = 400 mA cm–2). The maximum brightness is 38 218 cd m–2 (x = 0.68, y = 0.31) with the full width at half maximum (FWHM) only 50 nm at 8 V. In contrast, 3‐phenylisoquinolinyliridium complexes show phosphorescent emissions in the yellow region (534–562 nm) but with a long phosphorescent lifetime (3.90–15.6 μs in CH2Cl2). Most of these yellow phosphors suffer T–T annihilation in the EL performance. The exception is [Ir(3‐piq)2(acac)] ( 5 ) (3‐piqH = 3‐phenylisoquinoline), which has a relatively short lifetime 3.90 μs in CH2Cl2. Complex 5 achieves an external efficiency (ηext) value of 5.27 % at J = 20 mA cm–2 and maintains a ηext value of 3.58 at J = 400 mA cm–2 with a maximum brightness of 65 448 cd m–2 (x = 0.49, y = 0.51).  相似文献   

4.
By attaching a bulky, inductively electron‐withdrawing trifluoromethyl (CF3) group on the pyridyl ring of the rigid 2‐[3‐ (N‐phenylcarbazolyl)]pyridine cyclometalated ligand, we successfully synthesized a new heteroleptic orange‐emitting phosphorescent iridium(III) complex [Ir( L 1 )2(acac)] 1 ( HL 1 = 5‐trifluoromethyl‐2‐[3‐(N‐phenylcarbazolyl)]pyridine, Hacac = acetylacetone) in good yield. The structural and electronic properties of 1 were examined by X‐ray crystallography and time‐dependent DFT calculations. The influence of CF3 substituents on the optical, electrochemical and electroluminescence (EL) properties of 1 were studied. We note that incorporation of the carbazolyl unit facilitates the hole‐transporting ability of the complex, and more importantly, attachment of CF3 group provides an access to a highly efficient electrophosphor for the fabrication of orange phosphorescent organic light‐emitting diodes (OLEDs) with outstanding device performance. These orange OLEDs can produce a maximum current efficiency of ~40 cd A?1, corresponding to an external quantum efficiency of ~12% ph/el (photons per electron) and a power efficiency of ~24 lm W?1. Remarkably, high‐performance simple two‐element white OLEDs (WOLEDs) with excellent color stability can be fabricated using an orange triplet‐harvesting emitter 1 in conjunction with a blue singlet‐harvesting emitter. By using such a new system where the host singlet is resonant with the blue fluorophore singlet state and the host triplet is resonant with the orange phosphor triplet level, this white light‐emitting structure can achieve peak EL efficiencies of 26.6 cd A?1 and 13.5 lm W?1 that are generally superior to other two‐element all‐fluorophore or all‐phosphor OLED counterparts in terms of both color stability and emission efficiency.  相似文献   

5.
A sensitization‐based cascade energy transfer channel is proposed to boost the electroluminescent performances of the solution‐processed near‐infrared organic light‐emitting devices (OLEDs) featuring an electroluminescent peak of 786 nm from a new fluorescent emitter of N4,N4,N9,N9‐tetra‐p‐tolylnaphtho[2,3‐c][1,2,5]thiadiazole‐4,9‐diamine (NZ2mDPA) with unique aggregation‐induced emission (AIE) property. The optimized device is composed of 4,4′‐N,N‐dicarbazole‐biphenyl (CBP) as the host, bis(2‐phenyl‐1,3‐benzothiozolato‐N,C2′)iridium (Ir(bt)2(acac)) as the sensitizer, and NZ2mDPA as the emitter, where the cascade energy transfer can occur via two steps realizing unexpected triplet–singlet energy transfer by the Förster mechanism. The first step features efficient triplet harvesting from CBP to Ir(bt)2(acac), and then the second step involves in resonant energy transfer from the phosphorescent sensitizer to the near‐infrared AIE emitter of NZ2mDPA, which finally endows two channels of harvesting singlet and triplet excitons. The unique scheme achieves not only more efficient Förster energy transfer but also the higher utilization efficiency of triplet excitons. As a result, the near‐infrared OLEDs can realize a factor of 2.7 enhancement of external quantum efficiency by employing the phosphor‐sensitized AIE lumogen compared with the commonly used binary host–guest system.  相似文献   

6.
In principle, the ratio (Φ) of the maximum quantum efficiencies for electroluminescence (EL) to photoluminescence (PL) can be expected to approach unity, if the exciton (bound electron–hole pair) generated from the recombination of injected electrons and holes in OLEDs has a sufficiently weak binding energy. However, seldom are examples of Φ > 25% reported in OLEDs because of the strongly bound excitons for most organic semiconductors in nature. Here, a twisting donor–acceptor triphenylamine‐thiadiazol molecule (TPA‐NZP) exhibits fluorescent emission through a hybridized local and charge‐transfer excited state (HLCT), which is demonstrated from both fluorescent solvatochromic experiment and quantum chemical calculations. The HLCT state possesses two combined and compatible characteristics: a large transition moment from a local excited (LE) state and a weakly bound exciton from a charge transfer (CT) state. The former contributes to a high‐efficiency radiation of fluorescence, while the latter is responsible for the generation of a high fraction of singlet excitons. Using TPA‐NZP as the light‐emitting layer in an OLED, high Φ values of 93% (at low brightness) and 50% (at high brightness) are achieved, reflecting sufficient employment of the excitons in the OLED. Characterization of the EL device shows a saturated deep‐red emission with CIE coordinates of (0.67, 0.32), accompanied by a rather excellent performance with a maximum luminance of 4574 cd m?2 and a maximum external quantum efficiency (ηext) of ~2.8%. The HLCT state is a new way to realize high‐efficiency of EL devices.  相似文献   

7.
The electron‐transporting material (ETM) is one of the key factors to determine the efficiency and stability of organic light‐emitting diodes (OLEDs). A novel ETM with a “(Acceptor)n–Donor–(Acceptor)n” (“(A)n–D–(A)n”) structure, 2,7‐di([2,2′:6′,2″‐terpyridin]‐4′‐yl)‐9,9′‐spirobifluorene (27‐TPSF), is synthesized by combining electron‐withdrawing terpyridine (TPY) moieties and rigid twisted spirobifluorene, in which the TPY moieties facilitate electron transport and injection while the spirobifluorene moiety ensures high triplet energy (T1 = 2.5 eV) as well as enhances glass transition temperature (Tg = 195 °C) for better stability. By using tris[2‐(p‐tolyl)pyridine]iridium(III) (Ir(mppy)3) as the emitter, the 27‐TPSF‐based device exhibits a maximum external quantum efficiency (ηext, max) of 24.5%, and a half‐life (T50) of 121, 6804, and 382 636 h at an initial luminance of 10 000, 1000, and 100 cd m?2, respectively, which are much better than the commercialized ETM of 9,10‐bis(6‐phenylpyridin‐3‐yl)anthracene (DPPyA). Furthermore, a higher efficiency, a ηext, max of 28.2% and a maximum power efficiency (ηPE, max) of 129.3 lm W?1, can be achieved by adopting bis(2‐phenylpyridine)iridium(III)(2,2,6,6‐tetramethylheptane‐3,5‐diketonate) (Ir(ppy)2tmd) as the emitter and 27‐TPSF as the ETM. These results indicate that the derivative of TPY to form “(A)n–D–(A)n” structure is a promising way to design an ETM with good comprehensive properties for OLEDs.  相似文献   

8.
An exciplex forming co‐host is introduced in order to fabricate orange organic light‐emitting diodes (OLEDs) with high efficiency, low driving voltage and an extremely low efficiency roll‐off, by the co‐doping of green and red emitting phosphorescence dyes in the host. The orange OLEDs achieves a low turn‐on voltage of 2.4 V, which is equivalent to the triplet energy gap of the phosphorescent‐green emitting dopant, and a very high external quantum efficiency (EQE) of 25.0%. Moreover, the OLEDs show low efficiency roll‐off with an EQE of over 21% at 10 000 cdm?2. The device displays a very good orange color (CIE of (0.501, 0.478) at 1000 cdm?2) with very little color shift with increasing luminance. The transient electroluminescence of the OLEDs indicate that both energy transfer and direct charge trapping takes place in the devices.  相似文献   

9.
We demonstrate novel organic light‐emitting diode (LED) materials that contain a green phosphorescent dye (dmbpy)Re(CO)3Cl (dmbpy = 4,4′‐dimethyl‐2,2′‐bipyridine), and a red fluorescent dye 4‐dicyanomethylene‐6‐(p‐dimethylaminostyryl)‐2‐methyl‐4H‐pyran (DCM) as dopants and polyvinylcarbazole (PVK) as the host. The photoluminescence (PL) and electroluminescence (EL) properties of these complex materials were studied. The energy transfer efficiency from PVK host to DCM is increased by the (dmbpy)Re(CO)3Cl co‐dopant, which has an emission energy between that of PVK and DCM. The (dmbpy)Re(CO)3Cl, which emits a long‐lived phosphorescence, is used as an energy coupler, providing the possibility to harvest both singlet and triplet energy in the devices. The pure red emission from DCM was observed from PL and EL spectra of (dmbpy)Re(CO)3‐Cl(> 2.0 wt.‐%):DCM(> 0.5 wt. %) doped PVK films, demonstrating an efficient energy transfer from PVK and (dmbpy)Re(CO)3‐Cl to DCM. By optimizing the concentration of DCM and (dmbpy)Re(CO)3Cl in PVK, a maximum EL quantum efficiency of 0.42 cd A–1 at a current density of 9.5 mA cm–2 was obtained. The EL quantum efficiency of the doubly doped device is significantly enhanced in comparison with both a DCM‐only doped PVK device and a DCM‐doped PVK device with the green fluorescent dye Alq3 as co‐dopant. The improvement in the operating characteristics of the phosphorescent and fluorescent dye doubly doped device is attributed to efficient energy transfer in the system, in which both triplet and singlet excitons are used for resultant emission in the polymer device.  相似文献   

10.
Aggregation‐induced emission (AIE) materials are highly attractive because of their excellent properties of high efficiency emission in nondoped organic light‐emitting diodes (OLEDs). Therefore, a deep understanding of the working mechanisms, further improving the electroluminescence (EL) efficiency of the resulting AIE‐based OLEDs, is necessary. Herein, the conversion process from higher energy triplet state (T2) to the lowest singlet state (SS1) is found in OLEDs based on a blue AIE material, 4′‐(4‐(diphenylamino)phenyl)‐5′‐phenyl‐[1,1′:2′,1′′‐terphenyl]‐4‐carbonitrile (TPB‐AC), obviously relating to the device efficiency, by magneto‐EL (MEL) measurements. A special line shape with rise at low field and reduction at high field is observed. The phenomenon is further clarified by theoretical calculations, temperature‐dependent MELs, and transient photoluminescence emission properties. On the basis of the T2‐S1 conversion process, the EL performances of the blue OLEDs based on TPB‐AC are further enhanced by introducing a phosphorescence doping emitter in the emitting layer, which effectively regulates the excitons on TPB‐AC molecules. The maximum external quantum efficiency (EQE) reaches 7.93% and the EQE keeps 7.57% at the luminance of 1000 cd m?2. This work establishes a physical insight for designing high‐performance AIE materials and devices in the future.  相似文献   

11.
Efficient blue‐, green‐, and red‐light‐emitting organic diodes are fabricated using binuclear platinum complexes as phosphorescent dopants. The series of complexes used here have pyrazolate bridging ligands and the general formula CNPt(μ‐pz)2PtCN (where CN = 2‐(4′,6′‐difluorophenyl)pyridinato‐N,C2′, pz = pyrazole ( 1 ), 3‐methyl‐5‐tert‐butylpyrazole ( 2 ), and 3,5‐bis(tert‐butyl)pyrazole ( 3 )). The Pt–Pt distance in the complexes, which decreases in the order 1 > 2 > 3 , solely determines the electroluminescence color of the organic light‐emitting diodes (OLEDs). Blue OLEDs fabricated using 8 % 1 doped into a 3,5‐bis(N‐carbazolyl)benzene (mCP) host have a quantum efficiency of 4.3 % at 120 Cd m–2, a brightness of 3900 Cd m–2 at 12 V, and Commission Internationale de L'Eclairage (CIE) coordinates of (0.11, 0.24). Green and red OLEDs fabricated with 2 and 3 , respectively, also give high quantum efficiencies (~ 6.7 %), with CIE coordinates of (0.31, 0.63) and (0.59, 0.46), respectively. The current‐density–voltage characteristics of devices made using dopants 2 and 3 indicate that hole trapping is enhanced by short Pt–Pt distances (< 3.1 Å). Blue electrophosphorescence is achieved by taking advantage of the binuclear molecular geometry in order to suppress dopant intermolecular interactions. No evidence of low‐energy emission from aggregate states is observed in OLEDs made with 50 % 1 doped into mCP. OLEDs made using 100 % 1 as an emissive layer display red luminescence, which is believed to originate from distorted complexes with compressed Pt–Pt separations located in defect sites within the neat film. White OLEDs are fabricated using 1 and 3 in three different device architectures, either with one or two dopants in dual emissive layers or both dopants in a single emissive layer. All the white OLEDs have high quantum efficiency (~ 5 %) and brightness (~ 600 Cd m–2 at 10 V).  相似文献   

12.
A novel thermally activated delayed fluorescence (TADF) molecule, PHCz2BP, is synthesized and used to construct high performance organic light‐emitting diodes (OLEDs) in this work. PHCz2BP is not only the neat emitting layer for efficient sky‐blue OLED, with very high peak external quantum efficiency/power efficiency (EQE/PE) values of 4.0%/6.9 lm W?1, but also acts as a host to sensitize high‐luminance and high‐efficiency green, orange, and red electrophosphorescence with the universal high EQEs of >20%. More importantly, two hybrid white OLEDs based on the double‐layer emitting system of PHCz2BP:green phosphor/PHCz2BP:red phosphor are achieved. To the best of the knowledge, this is the first report for three‐color (blue–green–red) white devices that adopt a TADF blue host emitter and two phosphorescent dopants without any other additional host. Such simple emitting systems thus realized the best electroluminescent performance to date for the WOLEDs utilizing the hybrid TADF/phosphor strategy: forward‐viewing EQEs of 25.1/23.6% and PEs of 24.1/22.5 lm W?1 at the luminance of 1000 cd m?2 with the color rendering indexes of 85/87 and warm‐white Commission Internationale de L'Eclairage coordinates of (0.41, 0.46)/(0.42, 0.45), indicating its potential to be used as practical eye‐friendly solid‐state lighting in future.  相似文献   

13.
The efficiency roll‐off in blue phosphorescent organic light emitting diodes (OLEDs) using different carbazole compounds as the host is systematically studied. While there is no significant difference in device efficiency, OLEDs using ter‐carbazole as the host show a reduction in efficiency roll‐off at high luminance. Data from transient photoluminescence and electroluminescence measurements show that the lower triplet–triplet annihilation (TTA) and triplet–polaron quenching (TPQ) rates in devices with the ter‐carbazole host compared with other carbazole hosts are the reasons for this reduced efficiency roll‐off. It is also found that the host materials with low glass transition temperatures are more susceptible to the efficiency roll‐off problem.  相似文献   

14.
Organic light‐emitting diodes (OLEDs) can promise flexible, light weight, energy conservation, and many other advantages for next‐generation display and lighting applications. However, achieving efficient blue electroluminescence still remains a challenge. Though both phosphorescent and thermally activated delayed fluorescence materials can realize high‐efficiency via effective triplet utilization, they need to be doped into appropriate host materials and often suffer from certain degree of efficiency roll‐off. Therefore, developing efficient blue‐emitting materials suitable for nondoped device with little efficiency roll‐off is of great significance in terms of practical applications. Herein, a phenanthroimidazole?anthracene blue‐emitting material is reported that can attain high efficiency at high luminescence in nondoped OLEDs. The maximum external quantum efficiency (EQE) of nondoped device is 9.44% which is acquired at the luminescence of 1000 cd m?2. The EQE is still as high as 8.09% even the luminescence reaches 10 000 cd m?2. The maximum luminescence is ≈57 000 cd m?2. The electroluminescence (EL) spectrum shows an emission peak of 470 nm and the Commission International de L'Eclairage (CIE) coordinates is (0.14, 0.19) at the voltage of 7 V. To the best of the knowledge, this is among the best results of nondoped blue EL devices.  相似文献   

15.
TFTPA (tris[4‐(9‐phenylfluoren‐9‐yl)phenyl]amine), a novel host material that contains a triphenylamine core and three 9‐phenyl‐9‐fluorenyl peripheries, was effectively synthesized through a Friedel‐Crafts‐type substitution reaction. Owing to the presence of its sterically bulky 9‐phenyl‐9‐fluorenyl groups, TFTPA exhibits a high glass transition temperature (186 °C) and is morphologically and electrochemically stable. In addition, as demonstrated from atomic force microscopy measurements, the aggregation of the triplet iridium dopant is significantly diminished in the TFTPA host, resulting in a highly efficient full‐color phosphorescence. The performance of TFTPA ‐based devices is far superior to those of the corresponding mCP‐ or CBP‐based devices, particularly in blue‐ and red‐emitting electrophosphorescent device systems. The efficiency of the FIrpic‐based blue‐emitting device reached 12 % (26 cd A–1) and 18 lm W–1 at a practical brightness of 100 cd m–2; the Ir(piq)2acac‐based red‐emitting device exhibited an extremely low turn‐on voltage (2.6 V) and a threefold enhancement in device efficiency (9.0 lm W–1) relative to those of reference devices based on the CBP host material.  相似文献   

16.
A new class of charge neutral, strongly luminescent cyclometalated platinum(II) complexes supported by dianionic tetradentate ligand are synthesized. One of these platinum(II) complexes, Y‐Pt , displays a high photoluminescence quantum yield of 86% and electroluminescence efficacy (ηpower) of up to 52 lm W?1, and is utilized as a yellow phosphorescent dopant in the fabrication of white organic light‐emitting devices (WOLEDs). WOLEDs based on conventional structures with yellow emission from Y‐Pt in combination with blue emission from bis(4,6‐difluorophenyl‐pyridinato‐N,C2′) (picolinate) iridium(III) (FIrpic) show a total ηpower of up to 31 lm W?1. A two‐fold increase in ηpower by utilizing a modified WOLED structure comprising of a composite blue host is realized. With this modified device structure, the total ηpower and driving voltage at a luminance of 1000 cd m?2 can be improved to 61 lm W?1 and 7.5 V (i.e., 10 V for control devices). The performance improvement is attributed to an effectively broaden exciton formation‐recombination zone and alleviation of localized exciton accumulation within the FIrpic‐doped composite host for reduced triplet‐triplet annihilation, yielding blue light‐emission with enhanced intensity. The modified device structure can also adopt a higher concentration of Y‐Pt towards its optimal value, leading to WOLEDs with high efficiency.  相似文献   

17.
This paper presents a new strategy to develop efficient organic light‐emitting devices (OLEDs) by doping fluorescent‐ and phosphorescent‐type emitters individually into two different hosts separated by an interlayer to form a fluorescence–interlayer–phosphorescence (FIP) emission architecture. One blue OLED with FIP emission structure comprising p‐bis(pN,N‐diphenylaminostyryl)benzene (DSA‐Ph) and bis[(4,6‐di‐fluorophenyl)‐pyridinate‐N,C2']picolinate (FIrpic) exhibiting a peak luminance efficiency of 15.8 cd A?1 at 1.54 mA cm?2 and a power efficiency of 10.2 lm W?1 at 0.1 mA cm?2 is successfully demonstrated. The results are higher than those of typical phosphorescent OLEDs with a single emission layer by 34% and 28%, respectively. From experimental and theoretical investigations on device performance, and the functions of the used emitters and interlayer, such enhancement should ascribe to the appropriate utilization of the two types of emitters. The fluorescent emitter of DSA‐Ph is used to facilitate the carrier transport, and thus accelerate the generation of excitons, while the phosphorescent emitter of FIrpic could convert the generated excitons into light efficiently. The method proposed here can be applied for developing other types of red, green, and white OLEDs.  相似文献   

18.
High‐efficiency phosphorescent organic light‐emitting diodes (OLEDs) doped with Ir(ppy)2(acac) [bis(2‐phenylpyridine)iridium(III)‐acetylacetonate] in an exciplex forming co‐host have been optically analyzed. This emitter has a preferred orientation with the horizontal to vertical dipole ratio of 0.77:0.23 as compared to 0.67:0.33 in the isotropic case. Theoretical analysis based on the orientation factor (Θ, the ratio of the horizontal dipoles to total dipoles) and the photoluminescence quantum yield (qPL) of the emitter predicts that the maximum external quantum efficiency (EQE) of the OLEDs with this emitter is about 30%, which matches very well with the experimental data, indicating that the electrical loss of the OLEDs is negligible and the device structure can be utilized as a platform to demonstrate the validity of optical modeling. Based on the results, the maximum EQE achievable for a certain emitting dye in a host can be predicted by just measuring qPL and Θ in a neat film on glass without the need to fabricate devices, which offers a universal plot of the maximum EQE as a function of qPL and Θ.  相似文献   

19.
Three kinds of red electroluminescent (EL) polymers based on polyfluorene as blue host and 2,1,3‐benzothiadiazole derivatives with different emission wavelengths as red dopant units on the side chain are designed and synthesized. The influence of the photoluminescence (PL) efficiencies and emission wavelengths of red dopants on the EL efficiencies and color purities of the resulting polyfluorene copolymers of dopant/host system is investigated by adjusting the electron donating ability of the donor units in D‐π‐A‐D typed 2,1,3‐benzothiadiazole derivatives. The devices of these red‐emitting polymers realize remarkable EL efficiency/color purity trade‐offs. The single‐layer devices with the configuration of ITO/PEDOT:PSS/Polymer/Ca/Al show pure red emission at 624 nm with a luminous efficiency of 3.83 cd A?1 and CIE of (0.63, 0.35) for PFR1, saturated red emission at 636 nm with a luminous efficiency of 2.29 cd A?1 and CIE of (0.64, 0.33) for PFR2, respectively. By introduction of an additional electron injection layer PF‐EP(Ethanol soluble phosphonate‐functionalized polyfluorene), high performance pure and saturated red emission two‐layer devices (ITO/PEDOT:PSS/Polymer/PF‐EP/LiF/Al) were achieved with maximum luminous efficiencies of 5.50 cd A?1 and CIE of (0.62, 0.35) for PFR1, 3.10 cd A?1 and CIE of (0.63, 0.33) for PFR2, respectively, which are the best results for pure and saturated fluorescent red EL polymers reported so far.  相似文献   

20.
The host materials designed for highly efficient white phosphorescent organic light‐emitting diodes (PhOLEDs) with power efficiency (PE) >50 lm W‐1 and low efficiency roll‐off are very rare. In this work, three new indolocarbazole‐based materials (ICDP, 4ICPPy, and 4ICDPy) are presented composed of 6,7‐dimethylindolo[3,2‐a]carbazole and phenyl or 4‐pyridyl group for hosting blue, green, and red phosphors. Among this three host materials, 4ICDPy‐based devices reveal the best electroluminescent performance with maximum external quantum efficiencies (EQEs) of 22.1%, 27.0%, and 25.3% for blue (FIrpic), green (fac‐Ir(ppy)3), and red ((piq)2Ir(acac)) PhOLEDs. A two‐color and single‐emitting‐layer white organic light‐emitting diode hosted by 4ICDPy with FIrpic and Ir(pq)3 as dopants achieves high EQE of 20.3% and PE of 50.9 lm W?1 with good color stability; this performance is among the best for a single‐emitting‐layer white PhOLEDs. All 4ICDPy‐based devices show low efficiency roll‐off probably due to the excellent balanced carrier transport arisen from the bipolar character of 4ICDPy.  相似文献   

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