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长期以来辽河原油生产的喷气燃料一直存在安定性差,储存变色问题。研究发现影响其安定性及颜色的主要原因是喷气燃料中含有的碱性氮化物。在试验基础上,提出了浸酸活性炭-白土联合精制工艺,解决了喷气燃料安定性差及储存变化问题,并形成了工业生产规模。 相似文献
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采用脱硫醇工艺提高喷气燃料质量 总被引:5,自引:1,他引:4
针对目前喷气燃料的质量问题,对航煤精制工艺进行了改造,阐述了对炼油厂喷气燃料精制装置进行改造的工艺原理及工艺流程,分析了改造后的标定数据,结果碱性硫含量、碱性氮含量大幅度降低,经白土精制后颜色全部达到30,经过RB-01后,赛氏比色、水反应、铜片腐蚀、银片腐蚀等项指标全部合格。 相似文献
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长期以来辽河原油生产的喷气燃料一直存在安定性差,储存变色问题。研究发现影响其安定性及颜色的主要原因是喷气燃料中含有的碱性氮化物。在试验基础上,提出了浸酸活性炭-白土联合精制工艺,解决了喷气燃料安定性差及储存变色问题,并形成了工业生产规模。 相似文献
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为扩大喷气燃料资源,满足民航对喷气燃料的需求,对焦化全馏分油加氢后的喷气燃料馏分性质进行了分析,发现碱性氮的存在是影响焦化全馏分加氢后喷气燃料馏分颜色安定性的主要因素。在实验室里采用RA-01和RB-01特种吸附剂的非加氢组合工艺对焦化全馏分加氢后喷气燃料进行精制试验,结果表明,喷气燃料馏分经过非加氢精制后,颜色提高到 29,其它性质未见明显改变,所有性质均符合GB6537-94 3号喷气燃料标准。使用性能评定试验结果表明,焦化全馏分加氢后喷气燃料经过非加氢精制后其组成、橡胶相溶性、动态氧化热安定性、润滑性均可达到使用要求。 相似文献
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对九江分公司柴油加氢精制装置在切换生产3号喷气燃料时银片腐蚀不合格的问题进行了研究。结果表明,喷气燃料携带微量硫化氢且没有有效的脱除是导致银片腐蚀不合格的主要原因。提出了调整加氢精制工艺条件以减少硫化氢的生成、改用氮气汽提、使用不含硫化氢的塔底喷气燃料作顶回流介质以及增设硫化氢吸附罐等措施以更好地脱除硫化氢。采取这些措施后,喷气燃料产品的银片腐蚀达到0级,并且其它性质均符合3号喷气燃料质量指标要求,年经济效益可达64.9万元。 相似文献
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《Petroleum Science and Technology》2013,31(9-10):1109-1118
The effect of water contamination in jet fuels on the adsorbent capacity of Attapulgite clay to adsorb and retain N compounds was studied. The effluent jet fuel showed the presence of N molecules indicating that the clay, contaminated with water, does not retain N compounds. The GC/MS analysis of spent clay indicated that only quinolines were adsorbed and retained on the clay. The interfacial tension (IFT) values measured at the jet fuel/water interface were found to increase with a decrease in basic N content of clay treated jet fuels. Quinolines and pyridines present in jet fuel are surface active and adsorb on the Attapulgite clay, however, in the presence of water some N molecules adsorb at the jet fuel/water interface. Since pyridines were not found on the spent clay, the results indicate that the pyridines adsorb at the jet fuel/water interface. The tendency of pyridines to adsorb at the jet fuel/water interface will lead to their poor retention on the clay. The presence of N compounds and water contamination in jet fuel might lead to inefficient operation of clay treaters. The jet fuels having the IFT value below 40 mN/m were found to contain basic N molecules and have poor stability. The clay treated jet fuels having the IFT values in the range of 42.6–46.2 mN/m were found to have a good stability. The use of IFT measurements at the jet fuel/water interface provides an opportunity to better monitor the efficiency of clay treatment and the quality of jet fuels. 相似文献
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Lilianna Z. Pillon 《Petroleum Science and Technology》2001,19(9):1109-1118
The effect of water contamination in jet fuels on the adsorbent capacity of Attapulgite clay to adsorb and retain N compounds was studied. The effluent jet fuel showed the presence of N molecules indicating that the clay, contaminated with water, does not retain N compounds. The GC/MS analysis of spent clay indicated that only quinolines were adsorbed and retained on the clay. The interfacial tension (IFT) values measured at the jet fuel/water interface were found to increase with a decrease in basic N content of clay treated jet fuels. Quinolines and pyridines present in jet fuel are surface active and adsorb on the Attapulgite clay, however, in the presence of water some N molecules adsorb at the jet fuel/water interface. Since pyridines were not found on the spent clay, the results indicate that the pyridines adsorb at the jet fuel/water interface. The tendency of pyridines to adsorb at the jet fuel/water interface will lead to their poor retention on the clay. The presence of N compounds and water contamination in jet fuel might lead to inefficient operation of clay treaters. The jet fuels having the IFT value below 40 mN/m were found to contain basic N molecules and have poor stability. The clay treated jet fuels having the IFT values in the range of 42.6-46.2 mN/m were found to have a good stability. The use of IFT measurements at the jet fuel/water interface provides an opportunity to better monitor the efficiency of clay treatment and the quality of jet fuels. 相似文献
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Abstract A thiadiazole derivative as an environmentally friendly anti-corrosion additive was composed to obtain a new desulfurization agent called FS-A1 using the silver strip corrosion test for jet fuel, the anti-corrosion effect was discussed while the inhibitor was added in jet fuel, blending oil-like and the model oil samples, respectively. The results showed that FS-A1 inhibitor had a good desulfurization effect on jet fuel when the volume ratio of desulfurizer to oil was 1.7%, with a desulfurization rate of more than 96%. 相似文献
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Abstract Desulfurization of diesel fuel was investigated in a fixed bed adsorption column using activated carbon as an adsorbent. The experiments were carried out at different feed flow rates, bed depths, and temperatures, and each experiment resulted in at least one sample containing less than 10 mg/kg of sulfur. Experimental data were used to simulate/predict the dimensions of an adsorption column for potential industrial application of adsorptive desulfurization of diesel fuel. The calculation resulted with a height of adsorption column of 17.32 m and an adsorbent load of 93.5 tons. The calculated column height is within the limits for a typical industrial adsorption column. 相似文献
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新研制的NCT200O型喷气燃料常温液相精脱硫剂 总被引:2,自引:0,他引:2
新研制的NCT2000型喷气燃料常温液相精脱硫剂采用的原料为活性氧化锌、氧化钛胶、氢氧化铝和甲基纤维素。在实验室试验和工业应用一年多的结果表明,该剂的质量穿透硫容为8.8%,压碎强度为46N/cm;采用该剂对喷气燃料进行精制,银片腐蚀可以由3级降至0级,同时未发现精脱硫剂有粉化现象。该剂有推广应用价值。 相似文献
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用中性氧化铝吸附和无水乙酸脱附的方法制备了几种喷气燃料的吸附胶质(Adsorptive gum)。通过模拟加速储存试验考察了喷气燃料中生成的吸附胶质。采用色一质联用分析法(GC-MS)和红外光谱分析法(FT-IR)分析了吸附胶质的组成,并探讨了喷气燃料在储存过程中吸附胶质的变化规律。结果表明,变色喷气燃料中的颜色物质全部集中在吸附胶质中,吸附胶质的组成以烷基苯酚类(及其二聚物)和芳香酯类化合物为主。吸附胶质能有效地反映喷气燃料在储存过程中的变质情况,储存中吸附胶质和颜色增加显著,新生成的吸附胶质与储存前燃料中的吸附胶质无显著差别。吸附胶质的产生与喷气燃料在一定条件下的氧化和缩聚反应有关。吸附胶质可能是储存中所产生的不溶物的母体化合物。 相似文献
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Lilianna Z. Pillon 《Petroleum Science and Technology》2001,19(7):961-970
The effect of composition, surface area and pH of different clays and alumina adsorbents on the stability of jet fuel was studied. The stability of jet fuel was tested following the ASTMD 3241 procedure. Under the batch adsorption conditions, clays and adsorbents were not effective in adsorbing polar molecules and improving the stability of jet fuels. Under the column adsorption conditions, the effectiveness of clays and adsorbents in improving the stability of jet fuel was found to vary. Clays having a high surface area and an acidic pH were found to be more effective in adsorbing polar molecules and improving the stability of jet fuel. High surface area alumina adsorbents were found effective in adsorbing basic nitrogen molecules and improving the stability of jet fuel despite having a basic pH. The basic type nitrogen compounds, pyridines and quinolines, were found to affect the stability of jet fuel. The initial effluent jet fuel passed through fresh clays was found to have no N compounds and a good stability. However, the analysis of effluent jet fuel showed a gradual increase in N content reaching the level of N content in untreated jet fuel. The effluent jet fuel reaching 9-10 ppm of N content failed the stability test indicating that clays need to adsorb and retain N compounds. The adsorbent capacity of different clays was studied but no significant difference in retaining N molecules was observed. 相似文献