Maximum dry density test to quantify pumice content in natural soils

Crushable volcanic soils are well-known for their distinctive texture, vesicular nature and grain fragility. These features of volcanic soils lead to difficulty in interpreting the results of laboratory and field testing because of the occurrence of particle crushing. Sands containing pumice particles are commonly found in the Hamilton Basin in the North Island of New Zealand. The pumice particles originated from a series of volcanic eruptions centered in the Taupo and Rotorua regions. As a result of flooding and erosion along the Waikato River, the pumice particles have become mixed with other materials and have been distributed over the Hamilton Basin; these mixtures are referred to herein as natural pumiceous (NP) sands. This paper initially investigates an appropriate technique for measuring the maximum dry density (MDD) of NP sands; then a modified MDD test is proposed for estimating the pumice contents of these sands. In order to examine the applicability of different standard methods for determining MDD, New Zealand and Japanese standards are employed. The results using the Japanese standard show consistent MDD values when repeating the tests due to negligible particle crushing. On the other hand, the results of MDD tests according to the New Zealand standard indicate that a significant amount of particle crushing occurs after each repeated test and, consequently, it is not possible to get the same result when the test is repeated. NP sands reach their ultimate potential breakage during the modified MDD tests (at least, for the level of loading applied) and they experience different levels of particle crushing which may be a function of their pumice content. As a way forward, the relative breakages of the materials tested are used to estimate the pumice contents of the NP sands.     

A dynamic gradient ratio test apparatus

The soil-geotextile filtration mechanism is a complex process which depends on physical compatibility between the geotextile and the soil to be retained. Several methods have been proposed by researchers for assessing the filtration behaviour of soil-geotextile composite systems under steady state conditions. The Gradient Ratio (GR) test is the most commonly used method for measuring filtration compatibility of soil-geotextile systems. This paper describes the design of a modified GR permeability test apparatus to overcome disadvantages associated with traditional GR test devices. The apparatus can perform filtration tests under static and dynamic conditions and can be used to evaluate the filtration compatibility of fine-grained soils with geotextiles. The apparatus is incorporated within a triaxial testing system, hence representative field stress conditions can be applied to test specimens. Some exemplar GR tests performed on coarse and fine-grained soils with a non-woven geotextile are presented in this paper. Unidirectional dynamic loads are applied within the filtration tests to replicate highway traffic loading. Test results show that dynamic loading affects the filtration behaviour at the soil-geotextile interface by increasing the fine particles migration towards the geotextile, but that, for the soil evaluated here, this effect was small.     

Geotechnical Properties of a Pumice Sand

The pumice sand found in the North Island of New Zealand has properties which lie beyond those usually associated with cohesionless soils. The grains are very soft and the sand has a high void ratio, thus forming a compressible material. This paper presents the results of a series of drained triaxial and K₀ tests on dry pumice sand. The tests were conducted to evaluate the geotechnical properties, particularly the critical state parameters, of the sand and also to provide background information for interpretation of cone penetration tests in the material. The K₀ tests were used to evaluate the compression envelope under conditions of no lateral strain and to determine values of constrained modulus. Significant grain crushing was found to occur during testing even at low confining stress, in fact the stress-strain-strength behaviour of the material is dominated by particle crushing. Routine soil testing techniques were found to be inadequate for the evaluation of the specific gravity of pumice sand particles and a different technique was used for this purpose. The angle of friction of pumice sand was found to be larger than that of quartz sands, however pumice sand required very large shear strains to mobilise the peak and critical state shear strength and, for several tests, critical state conditions were not reached.     

In situ thermal properties characterization using frequential methods

In numerous fields, especially that of geothermal energy, we need to know about the thermal behaviour of the soil now that the monitoring of renewable forms of energy is an ecological, economic and scientific issue. Thus heat from the soil is widely used for air-conditioning systems in buildings both in Canada and in the Scandinavian countries, and it is spreading. The effectiveness of this technique is based on the soils calorific potential and its thermophysical properties which will define the quality of the exchanges between the soil and a heat transfer fluid. This article puts forward a method to be used for the in situ thermophysical characterisation of a soil. It is based upon measuring the heat exchanges on the surface of the soil and on measuring a temperature a few centimetres below the surface. The system is light, inexpensive, well-suited to the taking of measurements in situ without the sensors used introducing any disturbance into the heat exchanges. Whereas the majority of methods require excitation, the one presented here is passive and exploits natural signals. Based upon a few hours of recording, the natural signals allow us to identify the soils thermophysical properties continuously. The identification is based upon frequency methods the quality of which can be seen when the thermophysical properties are injected into a model with finite elements by means of a comparison of the temperatures modelled and those actually measured on site.     

Modelling of the long-term fate of pesticide residues in agricultural soils and their surface exchange with the atmosphere: Part II. Projected long-term fate of pesticide residues

In the first part of this paper, a simple coupled dynamic soil-atmosphere model for studying the gaseous exchange of pesticide soil residues with the atmosphere is described and evaluated by comparing model results with published measurements of pesticide concentrations in air and soil. In Part II, the model is used to study the concentration profiles of pesticide residues in both undisturbed and annually tilled agricultural soils. Future trends are estimated for the measured air and soil concentrations of lindane and six highly persistent pesticides (toxaphene, p,p'-DDE, dieldrin, cis- and trans-chlordane and trans-nonachlor) over a twenty-year period due to volatilization and leaching into the deeper soil. Wet deposition and particle associated pesticide deposition (that increase soil residue concentrations) and soil erosion, degradation in the soil (other than for lindane) and run-off in precipitation are not considered in this study. Estimates of the rain deposition fluxes are reported that show that, other than for lindane, net volatilization fluxes greatly exceed rain deposition fluxes. The model shows that the persistent pesticides studied are highly immobile in soil and that loss of these highly persistent residues from the soil is by volatilization rather than leaching into the deeper soil. The soil residue levels of these six pesticides are currently sources of net volatilization to the atmosphere and will remain so for many years. The maximum rate of volatilization from the soil was simulated by setting the atmospheric background concentration to zero; these simulations show that the rates of volatilization will not be significantly increased since soil resistance rather than the atmospheric concentration controls the volatilization rates. Annual tilling of the soils increases the volatilization loss to the atmosphere. Nonetheless, the model predicts that, if only air-soil exchange is considered, more than 76% of current persistent pesticide residues will remain after 20 years in the top 7 cm of annually tilled soils. In contrast, lindane is relatively mobile in soil due to weaker binding to soil carbon and leaching of lindane into soil is the main removal route for current lindane residues near the soil surface. The model predicts that the soil is a sink for lindane in the atmosphere and that soil residue levels of lindane in the surface soil are determined by a balance between dry gaseous deposition to the soil from the atmosphere and leaching from the surface soil into the deeper soil where degradation is the dominant loss route. The model suggests that deposition of lindane from the atmosphere will sustain residues in the soil and, in the absence of fresh applications of lindane to the soil, eliminating lindane from the atmosphere would lead to a rapid decline of lindane residues in agricultural soils of the southern U.S.     

Effect of wetting and drying and dilution on moisture migration through oil contaminated hydrophobic soils

Hydrophobic soils display resistance to wetting and frequently do not hold water to support good plant growth. A laboratory investigation was conducted to study moisture movement through hydrophobic soils. Test results indicated that hydrophobic soils have a critical moisture content beyond which they behave as wettable or hydrophilic soils. Soil hydrophobicity decreased and water infiltration increased when the soil was subjected to an increasing number of wetting and drying cycles. The effect of diluting hydrophobic soil with hydrophilic soil on water infiltration was also studied. The results indicated that water infiltration into soil becomes more rapid and uniform as the mass fraction of hydrophilic soil is increased in the mix. Water infiltration was observed even in hydrophobic-hydrophilic soil mixtures classified as severely water-repellent by commonly used arbitrary ordinal scales.     

Implications of soil complexity for environmental monitoring

International proposals for national soil and environmental monitoring lack adequate awareness of the diversity and complexity of soils. These need to be considered in sampling and reporting. This paper provides examples of the diversity and complexity of soil and environmental conditions in Bangladesh and Ghana, including differences between physiographic regions, within soil toposequences, between and within neighbouring fields, and in areas of shifting cultivation. These examples show that large numbers of sites would need to be sampled and monitored to provide the information required for the national environmental accounting envisaged. Detailed studies are needed in countries with relevant soil monitoring capacities to determine the scale of sampling required and the feasibility of conducting national monitoring. Where the latter is considered infeasible, the contribution that more limited measures could make to environmental monitoring needs to be examined. There is scope for useful academic studies to be made of environmental variability and practical monitoring techniques.     

The effects of chromium VI on the fitness and on the beta-tubulin genes during in vivo development of the nematode Steinernema feltiae

The entomopathogenic nematode (EPN), Steinernema feltiae, is a commonly occurring nematode in the soil in Ireland. Consequently, we have conducted investigations as to the utility of this species as a candidate organism for the detection of chromium in Irish soils. These experiments have demonstrated that S. feltiae can survive and reproduce in the presence of high concentrations of chromium VI. It was observed that concentrations as high as 1000 ppm have little effect on the ability of this organism to produce large numbers of progeny. Nematodes were not observed to reproduce above 1800 ppm. However, an increase in development times for the nematode in vivo was noted at concentrations of 400 ppm upwards. This paper also illustrates the effects upon the beta-tubulin genes within nematode populations exposed to chromium VI in vivo. DNA sequencing has shown that elevated levels of variations occur among the population treatments, although these variations do not appear to be dependent upon chromium concentration. These findings constitute this organism appropriate for further investigation for the development of sub-lethal end points and biomarkers for the detection and biomonitoring of chromium VI contamination in soil.     

Filtration performance of non- woven geotextiles with internally-stable and -unstable soils under dynamic loading

In many applications, geotextiles are subjected to dynamic loading conditions, for example, below roads and railways, for which a Gradient Ratio (GR) test is often used to assess filtration compatibility of soil-geotextile systems. This paper presents results from GR filtration tests with internally-stable and -unstable soils under dynamic loading conditions. In the tests, four non-woven geotextiles were used with varying types of soils under a hydraulic gradient of 5. Test results were interpreted in terms of GR values, permeability values, and mass and gradation characteristics of the soil before/after testing as well as the particles passing through the geotextiles. The test results show that the dynamic loading resulted in an increase of soil migration within the soil as well as an increase in the quantity of soil passing through the geotextiles. The available criteria for evaluating the internal stability of soils are evaluated based on the experimental data. Based on the test results, improvements to filter retention design criteria are suggested which take into account the internal stability of soils under dynamic loading.     

Cyclic strength of sand mixed with biochar: Some preliminary results

Biochar is a recycled material obtained through the thermal degradation of any organic biomass in the manufacture of bio-fuel inside a reactor in a process known as pyrolysis. It is an organic material that can endure in soil for thousands of years. Given its aromatic nature, biochar is highly recalcitrant, and has been considered to have great potential to sequester carbon and reduce greenhouse gas emissions. This material has been commonly used in environmental and agricultural applications, as it can store plant minerals in its pore spaces and provide a large water-holding capacity. However, little research has been done on the geomechanical properties of the resulting mixture of biochar and soil. Some studies have shown that biochar can increase the shear strength of clays and desaturate soil particles, and it may be possible that it can also increase the resistance to liquefaction in loose sand. Therefore, it would be very interesting to assess whether this material is able to present a more environmentally friendly alternative for improving the properties of soil. In this study, samples of pure sand are dry-mixed with 0%, 3%, and 5% biochar by weight and tested under cyclic undrained shearing using a simple shear test apparatus. The preliminary results indicate that biochar can increase the cyclic resistance of sand.     

Thermal property measurements for ecoroof soils common in the western U.S.

To model the impacts of ecoroofs on building envelope heat transfer accurately, thermal property data for ecoroof soils are needed. To address this need we have measured thermal conductivity, specific heat capacity, thermal emissivity, short wave reflectivity (albedo) and density for ecoroof soil samples over a range of moisture states. To represent a wide range of commonly used ecoroof soils we created eight test samples using an aggregate (expanded shale or pumice), sand, and organic matter in varying volumetric composition ratios. The results indicate significant variability in properties as a function both of soil composition and soil wetness. Thermal conductivity ranged from 0.25 to 0.34 W/(m K) for dry samples and 0.31–0.62 W/(m K) for wet samples. Specific heat capacity ranged from 830 to 1123 J/(kg K) for dry samples and 1085–1602 J/(kg K) for wet samples. Albedo was consistently higher for dry samples (0.17–0.40) decreasing substantially (0.04–0.20) as moisture was added. Thermal emissivities were relatively constant at 0.96 ± 0.02 regardless of soil type or moisture status. These results are discussed in the context of their impacts on building energy consumption and the importance of including daily and seasonal property variation within models of the ecoroof energy balance.     

Some special geotechnical properties of pumice deposits

 This paper describes the characteristics of pumice soils from the area of Mount Vesuvius and discusses sinking, watering and other geotechnical tests on pumice from a number of sites. Attention is drawn to the presence of both inter- and intra-particle voids within this material and appropriate modifications to the standard solid-water-air phase diagram are suggested to take account of this. The importance of understanding the structure of the pumice and its response to rainfall/ground water conditions is discussed in relation to both landslips and stabilisation works. Received: 30 September 1997 · Accepted: 20 January 1998     

Feasibility of using electrokinetics and nanomaterials to stabilize and improve collapsible soils

Loess as a subcategory of collapsible soils is a well-known aeolian deposit generally characterized as a highly-porous medium with relatively low natural density and water content and a high percentage of fine-grained particles.Such collapsible soil sustains large stresses under a dry condition with natural water content.However,it can experience high and relatively sudden decreases in its volume once it reaches a certain water content under a certain load and therefore,the natural condition of the soil might not be suitable for construction if the possibility of the exposure of the soil to excessive water exists during the lifetime of the project.This research presents the utilization of an innovative method for stabilization and improvement of Gorgan loessial soil.This method uses electrokinetics and nanomaterials to instigate additives to move through soil pores,as an in situ remedial measure.To assess the acceptability of this measure,the deformability and strength characteristics of the improved collapsible soil are measured and compared with those of the unimproved soil,implementing several unsaturated oedometer tests under constant vertical stress and varying matric suction.The result emphasizes the importance of the matric suction on the behavior of both improved and unimproved soils.The test results indicate that the resistance of the soil was highly dependent on the water content and matric suction of the soil.The oedometer tests on samples improved by 3% lime and 5% nanomaterials show considerable improvement of the collapse potential.Results also reveal that stabilized samples experience notably lower volume decrease under the same applied stresses.     

Gaseous elemental mercury emissions and CO2 respiration rates in terrestrial soils under controlled aerobic and anaerobic laboratory conditions

Mercury (Hg) levels in terrestrial soils are linked to the presence of organic carbon (C). Carbon pools are highly dynamic and subject to mineralization processes, but little is known about the fate of Hg during decomposition. This study evaluated relationships between gaseous Hg emissions from soils and carbon dioxide (CO₂) respiration under controlled laboratory conditions to assess potential losses of Hg to the atmosphere during C mineralization. Results showed a linear correlation (r² = 0.49) between Hg and CO₂ emissions in 41 soil samples, an effect unlikely to be caused by temperature, radiation, different Hg contents, or soil moisture. Stoichiometric comparisons of Hg/C ratios of emissions and underlying soil substrates suggest that 3% of soil Hg was subject to evasion. Even minute emissions of Hg upon mineralization, however, may be important on a global scale given the large Hg pools sequestered in terrestrial soils and C stocks.We induced changes in CO₂ respiration rates and observed Hg flux responses, including inducement of anaerobic conditions by changing chamber air supply from N₂/O₂ (80% and 20%, respectively) to pure N₂. Unexpectedly, Hg emissions almost quadrupled after O₂ deprivation while oxidative mineralization (i.e., CO₂ emissions) was greatly reduced. This Hg flux response to anaerobic conditions was lacking when repeated with sterilized soils, possibly due to involvement of microbial reduction of Hg²⁺ by anaerobes or indirect abiotic effects such as alterations in soil redox conditions. This study provides experimental evidence that Hg volatilization, and possibly Hg²⁺ reduction, is related to O₂ availability in soils from two Sierra Nevada forests. If this result is confirmed in soils from other areas, the implication is that Hg volatilization from terrestrial soils is partially controlled by soil aeration and that low soil O₂ levels and possibly low soil redox potentials lead to increased Hg volatilization from soils.     

提高软基深层加固效果的措施

经过现场对广东某高速公路监测断面的观测及试验资料分析发现,排水通道形式对深层软基加固有很大影响。研究表明,不同竖向排水通道中真空度的传递规律是不同的,对地基的真空预压加固效果的影响也不同。最后提出了能够有效减少真空压力沿程损失和消除地基深层沉降的新型竖向排水通道形式。     

Application of phytotoxicity data to a new Australian soil quality guideline framework for biosolids

To protect terrestrial ecosystems and humans from contaminants many countries and jurisdictions have developed soil quality guidelines (SQGs). This study proposes a new framework to derive SQGs and guidelines for amended soils and uses a case study based on phytotoxicity data of copper (Cu) and zinc (Zn) from field studies to illustrate how the framework could be applied. The proposed framework uses normalisation relationships to account for the effects of soil properties on toxicity data followed by a species sensitivity distribution (SSD) method to calculate a soil added contaminant limit (soil ACL) for a standard soil. The normalisation equations are then used to calculate soil ACLs for other soils. A soil amendment availability factor (SAAF) is then calculated as the toxicity and bioavailability of pure contaminants and contaminants in amendments can be different. The SAAF is used to modify soil ACLs to ACLs for amended soils.The framework was then used to calculate soil ACLs for copper (Cu) and zinc (Zn). For soils with pH of 4-8 and OC content of 1-6%, the ACLs range from 8 mg/kg to 970 mg/kg added Cu. The SAAF for Cu was pH dependant and varied from 1.44 at pH 4 to 2.15 at pH 8. For soils with pH of 4-8 and OC content of 1-6%, the ACLs for amended soils range from 11 mg/kg to 2080 mg/kg added Cu. For soils with pH of 4-8 and a CEC from 5-60, the ACLs for Zn ranged from 21 to 1470 mg/kg added Zn. A SAAF of one was used for Zn as it concentrations in plant tissue and soil to water partitioning showed no difference between biosolids and soluble Zn salt treatments, indicating that Zn from biosolids and Zn salts are equally bioavailable to plants.     

Grouted and concreted soils: residue mapping of foundation techniques in Flanders,Belgium

Sand is one of the main raw materials used in infrastructure and road construction. While it is a common natural raw material worldwide, the locations where it can be found are not evenly distributed. Because Flanders is highly dependent on imported sand, there is a need to find alternatives. One alternative might be found in the residues from foundation techniques like grout, soil mixed with bentonite, and cemented soils. This paper reports an attempt to determine the annual amount of residues from these foundation techniques available on the Flemish market, by use of a market study. This study estimated that the annual amount of grouted soils and cemented soil remainders is more than 40% of the annual amount of natural sands dredged from the Belgian Continental Shelf. Preliminary tests show that grout and cemented soil remainders could be a valuable replacement for natural sand currently used in low grade applications like sub foundations and stabilized sands.     

Geochemical background--concept and reality

The definitions and use of the term 'background' in exploration and environmental geochemistry are reviewed. Based on data from two subcontinental-scale geochemical mapping projects, it is shown that trying to define 'a background' for a large area is fraught with problems. It is demonstrated that background may change from area to area within a region and between regions. Although global averages are of general use, no specific global background levels of elements, for example in soils, can be defined, at best regional or local operational estimates can be made, though with caveats. Using background estimates based on concentrations in deeper soil levels to judge element concentrations in upper soil horizons (e.g., the TOP/BOT-ratio) can lead to severe misinterpretations if natural biogeochemical soil formation processes are ignored. Because of large natural variations in element concentrations in, for example soils, even the establishment of maximum admissible concentration based on ecotoxicological investigations is a difficult exercise. Organisms may become adapted to natural differences. Furthermore, there are challenges in converting the concentrations of the soluble substances used in ecotoxicological studies to appropriate levels in solid phase material, for example soils, analysed by commonly employed acid digestion procedures. Toxicological thresholds may thus also need to consider a spatial component that is presently neglected.     

Mechanical properties of hybrid fiber reinforced lightweight aggregate concrete made with natural pumice

The purpose of this study is to improve the ductility of pumice lightweight aggregate concrete by incorporating hybrid steel and polypropylene fibers. The changes in mechanical properties and also bulk density and workability of pumice lightweight aggregate concrete due to the addition of hybrid steel and polypropylene fibers have been studied. The properties were investigated include bulk density and workability of fresh concrete as well as compressive strength, flexural tensile strength, splitting tensile strength and toughness of hardened concrete. Nine concrete mixtures with different volume fractions of steel and polypropylene fibers were tested. A large increase in compressive and flexural ductility and energy absorption capacity due to the addition of steel fibers was observed. Polypropylene fibers, on the other hand, caused a minor change in mechanical properties of hardened concrete especially in the mixtures made with both steel and polypropylene fibers. These observations provide insight into the benefits of different fiber reinforcement systems to the mechanical performance of pumice lightweight aggregate concrete which is considered to be brittle. These results provide guidance for design of concrete materials with reduced density and enhanced ductility for different applications, including construction of high-rise, earthquake-resistant buildings.     

Solubilization and desorption of methyl-parathion from porous media: a comparison of hydroxypropyl-beta-cyclodextrin and two nonionic surfactants

The removal of hydrophobic organic compounds (HOCs) from soils and sediments by water flushing is often constrained by sorption interactions. The development of improved methods for remediation of contaminated soils has emerged as a significant environmental priority. Increasing HOCs desorption and mobility in soil using surfactants is considered to be one of the most suitable on-site techniques for soil remediation. A major concern regarding the use of surfactants for environmental restoration is the potential loss to the environment of large amounts of surfactant through sorption of nonionic types. A study was conducted to investigate whether surfactants and cyclodextrins can be used to enhance the transport of methyl-parathion in a contaminated soil. At aqueous concentrations of surfactants tested, the proportion of each surfactant sorbed to the soil increased with increasing surfactant concentrations. The maximal adsorbed mass is about 5,130 and 14,200 microg/g for Brij 35 and Tween 80, respectively. In the case of nonionic surfactants, sorption attenuates surfactant effectiveness by increasing the organic carbon content of the soil matrix and retarding transport of methyl-parathion through batch and soil column experiments. However, in contrast with the surfactants, hydroxypropyl-beta-cyclodextrin (HPCD) does not interact with the soil tested. The nonreactive nature of cyclodextrins, combined with its large affinity for HOCs suggests that it should have an advantage versus adsorbing surfactants for decreasing HOC distribution coefficients in subsurface systems.