包钢烧结矿配加FMG西部粉矿试验研究

文章利用烧结杯开展了FMG西部粉替代毛塔粉试验研究,对不同替代比例的烧结矿质量指标以及高温冶金性能进行了系统研究。研究结果表明:FMG西部粉可以替代毛塔粉用于烧结生产,在保证烧结矿质量指标以及高温冶金性能指标稳定的前提下,建议FMG西部粉替代毛塔粉的比例控制在12%以内。     

降低巴西CVRD粉矿配比烧结试验研究

为了解巴西CVRD粉矿比例降低对烧结的影响,在试验室条件下进行了5组烧结试验研究,包括烧结矿的冶金性能试验以及矿物组成及结构的研究。研究表明,配用20%巴西CVRD粉矿的第4组烧结矿较为理想,采用澳粉3代替部分巴西CVRD粉矿是可行的;5组烧结矿都是以铁酸钙为主要粘结相的高品位烧结矿,具有较高的强度;在高碱度、高料层的烧结工艺条件下,马钢烧结配矿时可以部分降低巴西CVRD粉矿,对烧结矿质量指标影响不大。     

杨迪矿替代巴西矿对烧结过程的影响机理

杨迪矿和巴西矿为国内钢铁企业大规模使用的进口矿种。为降低铁前生产成本,在烧结生产中提高廉价的杨迪矿配比已成为各大钢铁企业关注的焦点。本文基于某钢铁公司的原料条件,通过烧结杯试验系统研究杨迪矿替代巴西矿对混匀料性质和烧结过程产、质量指标的影响。结果表明：杨迪矿替代巴西矿后,烧结混合料的平均粒度减小、透气性指数略有降低,该矿替代巴西矿烧结的最佳配比为23.81%,所得烧结矿的成品率为72.03%,转鼓强度为67.07%,固体燃料消耗为69.56%;相较于基准配矿方案,转鼓强度和成品率分别提高3.31%和0.40%。烧结矿微观结构和物相分析显示：适当的杨迪矿替代比(≤23.81%)会改善黏结相侵入烧结矿孔隙中与铁矿颗粒的胶结状态,提高烧结矿强度;过高的替代比(>23.81%),会使得混合料中黏附粉的含量减少、料层温度降低,导致黏结相含量不足,烧结矿强度下降。     

铬精粉矿+红土镍矿混合烧结的研究与实践

针对铬精粉矿、红土镍矿单独烧结能耗高的问题,结合不锈钢生产对镍铬金属产品的需求,研究铬精粉矿、红土镍矿混合烧结工艺,取消粘接剂以降低能耗。通过对铬精粉、红土镍矿的物理性质研究,在实验室完成烧结工艺配方,进行试验研究,得出优化配比结果:铬精粉矿、红土镍配比65%∶35%,混合矿总水分配比15%~16%、焦粉5%~6%。同时,介绍了某公司铬精粉矿、红土镍矿混合烧结工艺生产实践,得出优化配方及烧结指标。生产实践证明:铬精粉矿、红土镍矿混合烧结,可以不配加粘接剂,并且烧结指标较好,比铬精矿烧结矿降低焦粉用量18.7 kg/t,降低动力电30.6 kWh/t,烧结矿质量指标适宜于矿热炉冶炼镍铬铁合金的生产,该混合烧结方式已经得到产业化应用。     

铬精粉矿带式烧结工艺研究与实践

针对铬精粉矿的特性和烧结难题,对其烧结制粒和烧结工艺配方进行了研究,得出优化配比结论:水分配比11%~13%、焦粉5%~8%、膨润土3%~6%为宜,配加部分颗粒物料对制粒和烧结均有益。同时,介绍了某公司建设的45 m~2带式烧结机设备参数和工艺流程,对烧结铬精粉矿的工艺进行了优化实践,得出优化配方和烧结指标。烧结实践证明:带式烧结机可烧结处理铬精粉矿,并且烧结指标较好,烧结矿质量指标适宜于矿热炉冶炼生产,该烧结方式得到产业化应用。     

改善武钢铁矿粉烧结强度的配矿试验

烧结生产中某一铁矿粉质量分数在20%以上时,对烧结矿指标有较大的影响。研究表明,在高比例使用同化温度高、粒度细、成球性差的铁矿粉后,烧结矿的强度明显下降,燃耗增加;在高比例使用流动性好的铁矿粉后,烧结矿强度和利用系数均会降低。利用铁矿粉的烧结基础特性指导烧结杯配矿研究的试验表明,使用25%左右A粉,30%左右C粉,15%左右E粉以及碱度为2.0左右的铁矿粉烧结,可以较大程度地提高转鼓强度,综合烧结指标较好。     

细粒级铁矿粉对烧结液相和矿结构的影响

利用基础烧结设备检测了细粒级铁矿粉同化速度、流动能力,并通过微型烧结杯模拟料层下部单元点烧结过程的方法来研究配加15%细粒级矿粉的烧结矿结构变化,有效分析了3种细粒级矿粉在烧结时的液相行为及对烧结矿结构和性能的影响。通过比较生产用混匀矿与配加质量分数为15%的A、B、C粉的烧结矿结构表明:A粉有利于减少烧结矿内部孔洞的尺寸,减少核颗粒和液相间较大孔洞的数量,并能促进针铁矿发展;B粉会增加烧结矿内部大孔洞,增加柱状或片状铁酸钙的生成;C粉同化速度慢,液相流动能力差,粘结效果差,会使液相与核颗粒间孔洞尺寸和数量增加。烧结杯试验结果表明:在生产用混匀矿中使用质量分数为15%的A粉,烧结矿的转鼓指数提高2.94%,低温还原粉化指数(RDI)降低3.37%。     

石钢烧结配加马来西亚粉烧结性能的研究

研究了石钢烧结生产配加马来西亚粉对烧结矿利用系数、烧结矿转鼓强度及返矿率等指标的影响,试验结果显示烧结矿的冶金性能有所改善,认为在生产条件下配加马来西亚粉烧结是可行的。通过生产跟踪,确定马来西亚粉的最佳配比为10%~15%。     

扬迪矿烧结基础特性的试验研究

对澳大利亚扬迪粉矿烧结基础特性的测试分析表明,扬迪粉矿同化温度低,同化能力大,液相流动性高,有效粘结范围大,但粘结相自身强度不高。烧结杯及工业性试验表明,在莱钢原料条件下,通过优化烧结配矿,当扬迪粉配比在20%左右时,烧结矿产质量指标最佳,超过20%后,指标稍有所下降,但仍高于基准配矿。     

烧结工艺合理使用粗粒级低质矿的研究

对武钢使用3种粗粒级低质铁矿的常温和高温烧结性能进行了研究,并比较了3种铁矿粉和生产用混匀矿的烧结液相生成规律和粘结效果。结果表明:依据矿粉的粒度和烧结液相行为能有效指导烧结配矿;配加8%的A粉或B粉有利于改善烧结矿强度(转鼓指数)、煤耗等指标,B粉会降低烧结矿的低温还原粉化性;粗粒级低质矿用量增加会降低烧结矿强度和低温还原粉化率。     

Sintering technology of superfine concentrate enhanced by flux coating

The fine ore sintering has problems such as deteriorated permeability of the sinter layer, poor oxidizing atmosphere, high sinter return rate, poor productivity and quality indexes, and increased fuel consumption. In order to increase the quality index of the sintered ore fines of the fine ore fines, and to meet the production needs of the ultra- large blast furnaces, experimental studies were carried out to enhance the sintering with external fluxes and fuels. Proper individual addition proportions of lime, limestone and coke were obtained by test trials. The feasible grain size of individual added limestone was optimized. The industrial production test achieved the similar result comparing to the outcome of the pilot trial. Both the sinter productivity and quality were improved, fuel consumption decreased, energy and emission reduced.     

Influence of Alumina on Iron Ore Sinter Properties and Productivity in the Conventional and Selective Granulation Sintering Process

Iron ore sinter constitutes a major proportion of blast furnace burden. Hence, its quality and consistency have a significant impact on blast furnace performance. Iron ore fines are the main source for sinter, and the chemical composition of the iron ore fines, together with the thermal conditions that blends are subjected to, plays an important role in forming the primary melt during the sintering process and accordingly determines the sinter structure and quality. Therefore, considerable importance has been placed on the chemical composition and consistency of iron ore fines, particularly in terms of alumina content. Due to depletion of high grade iron ore resources, alumina content in the iron ore fines is expected to increase gradually. Ore with higher alumina content is usually expected to be detrimental in forming the sinter matrix, if sintered alone, due to the low reactivity of alumina bearing minerals and the high viscosity of primary melts. The selective granulation process is a new sintering process for high alumina iron ore fines, and can eliminate the adverse effects of ‘hard to sinter’ or ‘unsuitable – for ironmaking’ ores. In the present work laboratory sintering experiments have been carried out with iron ore fines of different alumina level (2.00 to 5.46 mass‐%) to know the influence of alumina on mineralogy, productivity, physical and metallurgical properties of sinter prepared by the conventional and the selective granulation process. With increasing alumina content in sinter of both the conventional and selective granulation process, the fractions of hematite and of silico‐ferrites of calcium and alumina (SFCA) as well as the pore phase increased whereas the magnetite and silicate phases decreased. With increase in alumina content sinter productivity and tumbler index (T.I.) decreased, and metallurgical properties like sinter RDI and reducibility improved. However, sinter of the selective granulation process showed better results compared to the conventional process.     

巴西CVRD矿石在莱钢的研究与应用

简述了巴西CVRD矿粉在莱钢的使用情况,并对各种矿粉的烧结性能及对烧结矿产质量的影响进行了分析和研究。认为巴西CVRD矿粉作为莱钢原料的主导矿石,可以优化烧结矿化学成分,改善烧结矿产、质量,是一种烧结性能较好的矿粉。     

冀东铁精矿配加细粒澳富粉烧结试验

澳富粉粒度很细,配入冀东铁精矿中烧结,使烧结矿质量下降。为改善烧结矿质量,在实验室进行了提高配碳量、增加高硅球团返矿量和提高碱度的试验研究。结果认为,提高碱度是最有效的措施。     

某钢厂常用4种铁矿粉烧结基础特性

以提高某钢厂烧结矿质量为目标,对烧结矿质量影响较大的铁矿粉高温特性进行了研究。利用FactSage 7.1热力学软件计算出铁矿粉在1 280 ℃、碱度为3.0时产生的液相量和液相黏度指数,并以热力学计算为基础采用TSJ-2型红外线快速高温烧结炉进行4种铁矿粉基础特性测定试验。试验结果表明,A、D 两种铁矿粉同化温度较高,同化性较差;C 种铁矿粉同化性较好,B种铁矿粉同化性最好。当试验温度为1 280 ℃、碱度为3.0时,A 和D两种铁矿粉的液相流动指数较低;C种铁矿粉的液相流动指数较好,B 种铁矿粉的液相流动指数最好。由FactSage 7.1热力学软件计算得出,A铁矿粉液相量为51.46%、黏度为0.031 Pa·s,B铁矿粉液相量为77.8%、黏度为0.032 Pa·s,C铁矿粉液相量为66.64%、黏度为0.035 Pa·s,D铁矿粉液相量为70.66%、黏度为0.044 Pa·s,根据流动性指数公式得出结果与试验结果相一致。     

Effect of Size Parameters of Mix Ingredients on the Porosity and Reduction Characteristics of Sinter

The paper aims to describe the effect of size parameters of the mix ingredients on the tumbler index, porosity and reduction properties of sinter. These parameters are important factors for the furnace performance when the sinter is fed as burden material Understandably, the fines generated inside the furnace in the stack zone or during reduction affect the permeability of the stack zone, which results in a decrease in driving rate and CO utilisation. Pot sintering studies were carried out using hematite ore mix from typical mines in India. The sinter basicity (CaO/SiO₂) and MgO content in the sinter were kept at 2.1 and 1.5% respectively. The effect of the size parameters of the mix ingredients, namely size of coke, size of ore fines and that of limestone, on the porosity and quality parameters of sinter was investigated. The studies have shown that reducibility of sinter was well correlated with the proportion of micro‐pores out of total pores available in the sinter. Micro‐porosity of the sinter samples and their reducibility increased with decrease in the size range of coke breeze. Sintering of ore fines with reduced size, also, increased the sinter micro‐porosity. Besides, the average pore radius and density of the sinter sample and consequently the sinter reducibility increased with decreasing ore size. When the size of flux was narrowed down to –3+0.5 mm from –3 mm, the reduction degradation index value declined from 26.8% to 25.6% with marginal decrease in sinter reducibility. Moreover, the speed of sintering increased as well.     

Influence of Coating Granulation Process on Iron Ore Sinter Quality and Productivity

For better blast furnace performance, there has always been a need for better quality raw materials like sinter, lump ore, and pellets. Among these raw materials the usage of sinter in blast furnace is at higher side compared to other iron bearing materials. As the quality of sinter product improves, its usage in blast furnaces also increases. Iron ore fines are the main source for sinter making. To improve the sinter properties it is necessary to provide good quality of iron ore fines. Due to depletion of high grade iron ore resources, goethite and limonitic ore content in iron ore fines is expected to increase gradually. Usually limonitic and goethite ore are associated with higher alumina and LOI. The conventional sintering process is one of the well established processes for high quality hematite ore. It does not fully respond to the low grade iron ore associated with goethite and limonite. This has led to deterioration in sinter properties and productivity. In recent years the improvement in the quasi‐particle structure with the granulation process is an effective method for improving sinter quality and productivity. To improve the sinter quality and productivity for low grade iron ore fines, different granulation processes like the conventional one, and other two advanced granulation processes like coke breeze, and flux & coke breeze coating granulation were studied in detail by conducting laboratory pot grate sintering experiments. From the test results it was found that sinter productivity, physical and metallurgical properties of the sinter improved with flux & coke breeze coating granulation process compared to conventional and coke breeze coating granulation process. Proper selection of the granulation time is very important to achieve the desired sinter properties. In the present work detailed laboratory experiments have been carried out by varying the coating time from 30s to 110s to study the influence of flux & coke breeze coating granulation time on mineralogy, productivity, physical, and metallurgical properties of sinter. With a coating granulation time of 50s, higher productivity, higher yield, and stronger sinter (higher T.I) with lower RDI and ‐5mm size sinter were achieved.     

氧化铝对铁矿石烧结质量和生产率的影响(英文)

烧结矿是现代高炉生产的主要含铁原料。合理控制入炉烧结矿的理化性能与冶金性能对高炉生产和稳定操作是很必要的。铁矿粉是烧结矿的主要原料,其化学成分和烧结料层内的热量条件在烧结过程中起着重要的作用。化学成分等参数也决定着烧结矿矿相结构和质量。由于含氧化铝原料的低反应性及其液相的高粘性,因此在人们的预料中高铝矿石对烧结矿结构组成的影响并不好。烧结混合料中的氧化铝在同化过程中需要消耗大量热量,延迟烧结过程。在确保高炉渣的流动性方面,氧化铝也需要消耗较大热量。不论是烧结还是高炉的生产实绩均表明,氧化铝是有害的。一般而言,高含铁量与低脉石的印度矿与其他矿石的不同特点就是氧化铝含量高。由于高品味铁矿石的消耗殆尽,使用可利用的烧结原料成为生产必需。因此,必须要掌握氧化铝的作用及其对烧结矿质量和生产过程的影响。实验室完成了不同氧化铝含量水平(2.00%～5.46%)的实验,可从中了解氧化铝在烧结矿矿物学、生产率、物理性能和冶金性能方面的影响。随着烧结矿中氧化铝含量的增加,残存赤铁矿、复合铁酸钙(SFCA)和孔隙率增加,而磁铁矿和硅酸盐比例下降。烧结生产率和烧结矿转鼓强度(TI)随着氧化铝含量上升而下降,反映烧结矿冶金性能的诸如低温还原粉化率(RDI)和还原率(RI)提高。     

配用加拿大矿粉的烧结试验研究

通过对铁矿粉基础性能进行研究,比较了加拿大矿粉与其他5种矿粉的理化性能和高温烧结特性。依据基础研究结果进行了烧结杯试验,研究配用17％～25％加拿大矿粉的烧结指标变化和搭配矿粉的配比调节范围,得到烧结指标好的加拿大矿粉配用比例和使用方案。结果表明：加拿大矿粉配比在21％左右,火箭A粉配比在30％以下时,烧结矿性能指标较优。     

宏阳钢铁公司配加南非矿粉的试验研究

为了拓宽烧结用料,达到优化烧结原料结构的目的,宏阳钢铁公司对南非矿的烧结性能进行试验研究,结果表明:配用南非矿后,烧结矿的性能能够满足高炉炼铁生产的要求,可解决球团原料紧张的难题.