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Y. Okamoto 《The Journal of Adhesion》2013,89(4):227-235
Anaerobic adhesives are single-component acrylic adhesives which cure rapidly at or below room temperature when air is excluded, but they remain in an uncured stage over a long time when they are exposed to an adequate supply of air. Thus, anaerobic adhesives are widely used in retaining compounds for nuts and bolts, in sealants, and for impregnation. Recently, anaerobic adhesives have also been used in electrical and electronic applications because of their fast room temperature cure capability and their convenience.1 相似文献
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Y. Okamoto 《The Journal of Adhesion》1990,32(4):227-235
Anaerobic adhesives are single-component acrylic adhesives which cure rapidly at or below room temperature when air is excluded, but they remain in an uncured stage over a long time when they are exposed to an adequate supply of air. Thus, anaerobic adhesives are widely used in retaining compounds for nuts and bolts, in sealants, and for impregnation. Recently, anaerobic adhesives have also been used in electrical and electronic applications because of their fast room temperature cure capability and their convenience.1 相似文献
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D. Langbein 《The Journal of Adhesion》2013,89(4):237-245
A general dispersion formula is derived, which represents the dispersion energy between two bodies A and B by their macroscopic screened fluctuation fields. These fluctuation fields are calculated exactly in the case of half-spaces and spheres. In the case of half-spaces the Lifshitz dispersion formula is obtained. The dispersion energy between spheres is found to vary as 1/d for separations d small compared with the radii and to be proportional to 1/d 6 for separations d large compared with the radii. The effect of layers adsorbed on the surfaces of the spheres on the dispersion energy is calculated. The dielectric properties of the adsorbed layers predominate over those of the bulk material for separations d smaller than the layer thickness. 相似文献
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针对目前市场上双组分水基预涂厌氧胶使用中,由于B组分的渗透导致两组分混合后出现凝胶的现象,提出了快速测试B组分即微胶囊抗渗透性的方法。选择对芯材有良好溶解能力的溶剂作为浸泡液,利用气质联用仪测试渗透出的芯材含量,最终得到微胶囊的渗透曲线。同时通过贮存稳定性试验验证此方法的有效性,结果显示两种方法得到的结果一致。 相似文献
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在厌氧胶中添加了N,N’-4,4’-二苯甲烷双马来酰亚胺(BDM)和苯乙炔苯酐封端的聚酰亚胺(PBDB-I),测试了热强度、高温老化强度和热失重,考察了BDM和PBDB-I对厌氧胶的高温力学性能的影响,并借助FT-IR、DSC和SEM分析了耐高温树脂对厌氧胶耐热改性的机理。BDM与厌氧胶单体具有较好的热反应协同性,而PBDB-I与厌氧胶单体的热反应协同性较差,但将BDM与PBDB-I相结合作为耐热树脂可使耐热性大大提高,厌氧胶耐300℃老化的时间可超过60h。 相似文献
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The kinetics of acrylonitrile polymerization initiated by free radicals formed in situ in a potassium persulfate/ascorbic acid redox system was investigated in an aqueous sulfuric acid medium in the temperature range of 40–70°C. The rate of polymerization and the rate of the disappearance of potassium persulfate were measured. A kinetic scheme involving the production of initiating radicals from the oxidation of ascorbic acid by potassium persulfate ions and termination exclusively by the interaction of chain radicals with persulfate ions is proposed. The effects of some water‐miscible organic solvents on the rate of polymerization were investigated. The temperature dependence of the rate was studied. A possible mechanism consistent with the experimental data is proposed. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011 相似文献
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A first order kinetic reaction model is utilized to model the cure process of epoxy adhesive Metlbond 1113. Actual states of full cure corresponding to a spectrum of cure temperature-time schedules are identified using the DTA method. Comparison of these experimental results with the corresponding theoretical predictions reveals that the first order kinetic reaction model provides accurate prediction of full cure when low temperature-long time schedules in close proximity to Tg are used. These cure schedules also result in the highest adhesive bulk tensile strength. 相似文献
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研究了一种多元共聚丙烯酸酯压敏胶乳液,按照半连续乳液聚合法聚合而成,并讨论了软硬单体、功能单体、乳化剂的选择对乳液性能的影响。通过改变预聚单体乳化液数量来调节乳液的粘度以满足不同的涂布工艺的需要。 相似文献
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The kinetics and mechanism of acrylonitrile polymerization initiated by a redox pair [potassium chromate (K2CrO4) and sodium arsenite (NaAsO2)] were studied. The overall rate of polymerization was proportional to √[K2CrO4] × [NaAsO2], and the energy of activation was approximately 10.5 kJ/mol. Polyacrylonitrile was recovered as a coagulum in the medium. The formation of polyacrylonitrile was confirmed with Fourier transform infrared and 1H‐NMR analyses. Scanning electron microscopy analysis of the polymer revealed the formation of aggregates of polymer particles (3–67 nm). Thermogravimetric studies indicated 50% weight loss at 400°C, and dynamic thermal analysis scan studies revealed an exothermic peak at 507°C due to massive oxidative thermal degradation of the polyacrylonitrile backbone. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 96: 276–280, 2005 相似文献
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A Comment published in this issue and authored by B. C. Ennis refers extensively to one of our earlier papers entitled “Linking Cure Process to Adhesive Bulk Strength by Differential Thermal Analysis.” We are delighted to see that our work can capture the attention of scientists working in this area and stimulate them to write lengthy reviews. At the same time, however, we feel that this particular note, in various discussions, misinterprets our paper, and does not seem to contribute any new or substantial scientific information to the literature. 相似文献
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The cure of diglycidyl ether of bisphenol A (DGEBA) and a homologous series of poly(ethylene oxide) diglycidyl ether (PEODE) epoxy resins with 4,4′‐diaminodiphenyl sulfone (DDS) was studied by scanning and isothermal differential scanning calorimetry (DSC). The heat of polymerization was relatively independent of monomer structure and chain length when determined by isothermal DSC. Variations in the heats of polymerization determined by the scanning method were attributed to degradative reactions at higher temperatures during the scan. The activation energies determined by scanning DSC experiments were relatively constant at 61 ± 3 kJ/mol. However, using an isothermal cure method, the activation energies were found to vary with monomer structure and extent of cure. The isothermal kinetics were analyzed in terms of the autocatalytic model on the basis of competing reaction paths involving catalysis by either initial impurities or hydroxyl groups produced in situ. The activation energies of both reaction paths were found to vary with monomer structure and degree of conversion. © 1999 John Wiley & Sons, Inc. J Appl Polym Sci 72: 1479–1488, 1999 相似文献