共查询到20条相似文献,搜索用时 62 毫秒
1.
2.
Al掺杂ZnO薄膜的表面形貌和光学性质 总被引:3,自引:0,他引:3
用原子力显微镜、紫外-可见分光光度计和荧光光谱仪观察采用溶胶-凝胶法制备的Al掺杂ZnO薄膜的表面形貌、透射光谱和光致发光谱.结果表明,Al掺杂量为0.5at 9/6的ZnO薄膜经550℃退火处理后,粗糙度为1.817,Al掺杂量为1.0at%的ZnO薄膜经600℃退火处理后,粗糙度增大到4.625.样品在可见光范围内的平均透过率均大于80%.当激发波长为325 nm时,在397 nm(3.13 eV)附近出现紫外发光峰;当激发波长为360 nm时,在443 nm(2.80 eV)附近出现蓝色发光峰.探讨了样品的蓝光发光机制. 相似文献
3.
采用直流反应磁控溅射的方法制备ZnO薄膜, 用X射线衍射仪(XRD)、扫描电镜(SEM)和紫外-可见光谱仪(UV-Vis)分别表征ZnO薄膜的晶体结构和表面形貌等特征。并用此材料制备Au/ZnO/Au金属-半导体-金属(MSM)结构光电导型ZnO薄膜紫外光探测器。实验结果表明, ZnO探测器在360 nm出现明显光响应,其光电流为2.5 mA, 在5 V偏置电压下暗电流为250 μA; ZnO紫外探测器在250~380 nm的紫外波段, 探测器有很明显的光响应, 且光电流响应比较平坦; 在380~430 nm区域, 光响应明显下降; 其光响应的上升与下降弛豫时间分别为20 s与80 s。从光谱响应图中可以看出紫外(360 nm)比可见区(450 nm)的光响应高出3个数量级, 薄膜表面存在的缺陷(如氧空位)在ZnO紫外探测器的光电效应中有重要作用。 相似文献
4.
采用溶胶-凝胶旋涂法在FTO玻璃衬底上制备得到了不同Al掺杂浓度的ZnO薄膜(AZO)。利用XRD、FESEM、UV-vis和PL等测试手段对样品结构、形貌和光学性能进行了表征。结果表明,合成的AZO薄膜均为六方纤锌矿结构且峰强随掺杂浓度的升高而减弱;同时,颗粒形貌由不规则向规则球形转变且尺寸逐渐减小;PL谱中的近紫外发射峰和晶格缺陷峰值随掺杂浓度的升高先增大后降低;由UV-vis吸收光谱可知,AZO薄膜在设定波长内的光吸收处于波动状态,且当Al掺杂浓度为3%时,光吸收强度最高,禁带宽度减小到3.12eV。 相似文献
5.
6.
7.
8.
9.
为了研究氧气对Al掺杂ZnO薄膜性能的影响,用射频反应磁控溅射方法制备了氧化锌掺铝(ZAO)薄膜,靶材为锌铝合金靶,并研究了薄膜的透光率跟氧氩流量比的关系以及同一氧氩流量比下薄膜光学性能随温度变化的规律.实验结果表明,200℃下氧氩流量比为135时有最佳的透光率.250℃下氧氩流量比为130时有最佳的透光率;300℃下氧氩流量比为115时有最佳的透光率.同一氧氩流量比125时,200℃下制备的ZAO薄膜有最佳的透光性.温度更高或者更低都导致薄膜的透光性能变差. 相似文献
10.
利用溶胶-凝胶法在蓝宝石(0001)衬底上制备了多晶ZnO∶Al薄膜,薄膜表面具有特殊的交叉链状形貌。随着掺铝浓度的提高,链条有明显变细的趋势。X射线衍射证实,提高掺铝浓度有利于促进薄膜沿(002)方向的生长,并且光学带隙随着掺杂浓度的提高从3.21 eV增大到3.25 eV。光致发光光谱显示,薄膜在390 nm处出现较强的紫外峰,同时还出现了与Zn空位和Zn填隙缺陷能级有关的415 nm和440 nm两个比较弱的蓝峰。对实验结果以及产生的机理进行了分析和讨论。 相似文献
11.
为了解决紫外光探测器的光谱响应难以准确测量的问题,采用光声光谱的方法,以自制的高灵敏度光声探测器为标准探测器,建立了一套紫外光探测器的光谱响应测量系统,分别进行了理论分析和实验论证,取得了两种紫外光探测器的光谱响应的数据。实验结果表明,该测量系统结构简单、工作可靠、重复性好,在250nm~450nm范围内,能较准确地测量紫外光探测器的光谱响应曲线。这一结果对解决紫外光探测器的光谱响应难以准确测量的问题是有帮助的;该系统也适用于可见光探测器的光谱响应的测量和固体样品的光声光谱分析。 相似文献
12.
13.
14.
15.
16.
Based on the principles of metal-semiconductor-metal Schottky barrier photodetectors(MSM-PD), using the carrier rate equations,the circuit simulation model of a GaN-based MSM photovoltaic ultraviolet detector is constructed through an appropriately equivalent process.By using the Pspice analytical function of Cadence soft on the model,the relationship between the photocurrent and the terminal voltage under different UV light powers is analyzed.The result shows that under the given UV power,the photocurrent increases and tends to become saturated gradually as the terminal voltage of the device increases,and that under different UV powers,the photocurrent increases with increasing incident power.Then the analysis of the relationship between the photocurrent and the terminal voltage under the different ratios of interdigital electrode space and width is carried out when the UV power is given.The results show that when the ratio of interdigital electrode space and width(L/W) equals 1,the photocurrent tends to be at a maximum. 相似文献
17.
Based on the principles of metal-semiconductor-metal Schottky barrier photodetectors(MSM-PD), using the carrier rate equations,the circuit simulation model of a GaN-based MSM photovoltaic ultraviolet detector is constructed through an appropriately equivalent process.By using the Pspice analytical function of Cadence soft on the model,the relationship between the photocurrent and the terminal voltage under different UV light powers is analyzed.The result shows that under the given UV power,the photocurre... 相似文献
18.
紫外与红外大气窗口蕴含着与人类密切相关的信息。基于新型的时域有限差分光子学分析方法联合有限元电学分析方法研究了Pt/CdS紫外与InSb 红外双色焦平面阵列探测器的双色探测机理。研究发现,超薄 Pt金属膜与CdS形成肖特基结可以获得较大的紫外光响应并能更好耦合红外光。采用像元间距为50μm的Pt/CdS与InSb键合结构,可以很好的抑制像元间的串音。结果证明了紫外-红外双色探测的可行性,该方法将为紫外-红外双色探测器的设计提供基础指导。 相似文献
19.
We present low cost hydrothermally deposited uniform zinc oxide (ZnO) nanorods with high haze ratios for the a-Si thin film solar cells. The problem of low transmittance and conductivity of hydrothermally deposited ZnO nanorods was overcome by using RF magnetron sputtered aluminum doped zinc oxide (ZnO:Al ~300 nm) films as a seed layer. The length and diameters of the ZnO nanorods were controlled by varying growth times from 1 to 4 h. The length of the ZnO nanorods was varied from 1 to 1.5 µm, while the diameter was kept larger than 300 nm to obtain various aspect ratios. The uniform ZnO nanorods showed higher transmittance (~89.07%) and haze ratio in the visible wavelength region. We also observed that the large diameters (>300 nm) and average aspect ratio (3–4) of ZnO nanorods favored the light scattering in the longer wavelength region. Therefore, we proposed uniformly deposited ZnO nanorods with high haze ratio for the future low cost and large area amorphous silicon thin film solar cells. 相似文献