North American economic integration and industrial pollution in the Great Lakes region

This paper provides an assessment of the impact of increased economic integration within North America on industrial pollution intensities within the Great Lake states of the United States. It utilizes a three-country, applied general equilibrium model of the North American economy, data from the World Bank's Industrial Pollution Projection System, and employment data from the US Bureau of Economic Analysis to simulate the industrial pollution impacts of North American trade liberalization within the Great Lakes region. The results reflect the liberalization of tariff and non-tariff barriers, their trade and production impacts, state-level shares in the production changes, and the resulting industrial effluent changes. Two trade liberalization experiments show that, in many cases, the Great Lake states account for a substantial portion of the total emission changes caused by North American economic integration. Of particular concern to the Great Lake states are the emissions of the base metals, transportation equipment, and petroleum sectors. Received: October 2001/Accepted: December 2001 This research was supported by the Office of the Great Lakes through the Michigan Great Lakes Protection Fund. We would like to thank Roger Stough and three referees for very helpful comments.     

Quality of dredged material in the River Seine basin (France). I. Physico-chemical properties

In rivers, sediments are frequently accumulating persistent chemicals, especially for those that are more contaminated as a consequence of pressure related to environmental pollution and human activity. The Seine river basin (France) is heavily polluted from nearby industrial activities, and the urban expansion of Paris and its suburbs within the Ile de France region and the sediments present in the Seine river basin are contaminated. To ensure safe, navigable waters, rivers and waterways must be dredged. In this paper, the quality of the sediment dredged in 1996, 1999 and 2000 is discussed. Physico-chemical characteristics of the sediment itself and of the pore-water are presented. Seine basin sediments show very diverse compositions depending on the sampling site. Nevertheless, a geographic distribution study illustrated that the Paris impact is far from being the only explanation to this diversity, the quality of this sediment is also of great concern. The sediment once dredged is transported via barges to a wet disposal site, where the dredged material is mixed with Seine water in order to be pumped into the receiving site. This sort of dumping might be responsible for the potential release of contaminants to the overlying water from the significantly contaminated sediments.     

Large watershed management and restoration: dioxin sediment remediation case study

This paper reviews continuing, long-term remediation of river sediments containing dioxin and other chemical compounds in a large watershed of the Great Lakes Region. Chlorinated dibenzo-p-dioxins are a ‘family’ of chemically related compounds commonly known as chlorinated dioxins or simply, dioxins. The highest levels are usually found in sediments, soil and animal fats. The most toxic chemical in this group is 2,3,7,8-tetrachlorodibenzo-para-dioxin, the ‘standard’ to which other dioxins are compared and which has been shown to be very toxic in animal studies. The US Environmental Protection Agency (EPA) and Michigan Department of Environmental Quality (MDEQ) have made a lengthy effort to assess and remediate portions of the Saginaw Bay Watershed, including the Tittabawassee River. The paper reviews the EPA-proposed ‘phased approach’ to restoration and remediation of a short segment (Segment 1) of the Tittabawassee River sediments. Sediments are contaminated with a number of chemical pollutants other than dioxins, including arsenic, cholorbenzenes, cholorphenols, ethyl parathion, o-phenylphenol and polycyclic aromatic hydrocarbons. The paper evaluates three proposed ‘cleanup alternatives’, with final action method suggested based on effectiveness, feasibility for implementation and cost.     

Healthy Port Futures: Rethinking Sediments for Rivermouth Landscapes

Throughout the Great Lakes, port cities are often located on the rivermouth and where rivermouths once sorted, shaped, and moved the riverine sediment into the lake. Their current use as industrial navigation channels requires cyclical mechanical maintenance dredging. Past sediment management practices have either placed the riverine sediment nearshore in confined disposal facilities (CDFs) or out in deeper open water. Both practices remove the sediment from the nearshore system, preventing its potential use in coastal protection, habitat creation, wave attenuation, and sediment nourishment. However, novel rivermouth wetlands can draw from both strategies of containment (as in a CDF) and cost-efficiency of non-containment (open lake disposal) to allow for the processing and use of sediment. This article will describe one such attempt, conducted by the Great Lakes Protection Fund-supported Healthy Port Futures project. Through a collaborative design-research process, Healthy Port Futures used a range of tools to generate, speculate, model, visualize, and test wetland forms under a range of social, ecological, and hydrological conditions. This project, understood colloquially as “the Crescent,” proposed a semi-circular, partially open-cell wetland design as a response to the complexity of rivermouth conditions. Throughout this design-research process, the project sought to acknowledge uncertainty, assess risk, and explore a range of outcomes in order to redefine the public expectations around wetland creation and restoration, and reimagine innovation along the Great Lakes coast.     

Erosion investigation and sediment quality measurements for a comprehensive risk assessment of contaminated aquatic sediments

In this paper, an assessment strategy is introduced which allows one to evaluate the ecological hazard of contaminated sediments in connection with the risk of in-stream erosion. Special techniques for sediment sampling, non-intrusive density profiling, and depth related measurement of erosion are presented, which, in combination with ecological aspects, lead to a comprehensive risk assessment of fluvial sediments. The strategy was applied to a lock-regulated reach of the River Neckar in Germany. The spatial pattern of contamination in the river reservoir was found to be remarkably heterogeneous. At some sites, very high heavy metal concentrations were detected at the sediment surface. A sudden increase in contamination with depth at other sites could be attributed to an erosional unconformity. The critical shear stress of erosion for old contaminated sediments is higher than for recently deposited material. Nevertheless, during major flood events, bottom shear stress in the river exceeds the critical shear stresses of erosion of all sediments. Accordingly, there is a substantial risk that old contaminated sediment can be mobilised from the reservoir and transported downstream.     

Cycling and ecosystem impact of metals in contaminated calcareous dredged sediment-derived soils (Flanders, Belgium)

Significant areas in Flanders, Belgium exhibit moderate contamination with trace metals caused by disposal of contaminated dredged sediments. After disposal, the sediments develop into a soil-like material, on which vegetation is planted or develops spontaneously. Behaviour, cycling and ecosystem impacts of trace metals in calcareous dredged sediment disposal sites in Flanders is reviewed. Although soil physico-chemical properties favour a low metal bioavailability, pore water concentrations can be elevated compared to pore water in uncontaminated soils. While metal leaching is not considered to be of concern, several plants accumulate elevated levels of Cd and Zn in leaves. Also metal levels in soil dwelling organisms and small mammals, particularly Cd, are elevated compared to reference situations. This raises concern for an enhanced transfer of metals to the food chain. Future research should identify biological effects on organisms caused by the contamination. A comprehensive knowledge of metal behaviour in these sites is essential for developing appropriate management options for these sites.     

Modeling toxaphene behavior in the Great Lakes

Chlorinated camphenes, toxaphene, are persistent organic pollutants of concern in the Great Lakes since elevated concentrations are found in various media throughout the system. While concentrations have decreased since their peak values in the 1970s and 80s, recent measurements have shown that the rate of this decline in Lake Superior has decreased significantly. This modeling study focused on toxaphene cycling in the Great Lakes and was performed primarily to determine if elevated water and fish concentrations in Lake Superior can be explained by physical differences among the lakes. Specifically, the coastal zone model for persistent organic pollutants (CoZMo-POP), a fugacity-based multimedia fate model, was used to calculate toxaphene concentrations in the atmosphere, water, soil, sediment, and biota. The performance of the model was evaluated by comparing calculated and reported concentrations in these compartments. In general, simulated and observed concentrations agree within one order of magnitude. Both model results and observed values indicate that toxaphene concentrations have declined in water and biota since the 1980s primarily as the result of decreased atmospheric deposition rates. Overall the model results suggest that the CoZMo-POP2 model does a reasonable job in simulating toxaphene variations in the Great Lakes basin. The results suggest that the recent findings of higher toxaphene concentrations in Lake Superior can be explained by differences in the physical properties of the lake (primarily large volume, large residence time and cold temperatures) compared to the lower lakes and increased recent inputs are not needed to explain the measured values.     

Evidence of the impact of ENSO events on temporal trends of hexachlorobenzene air concentrations over the Great Lakes

This study presents an evidence for association of the air concentrations of HCB measured in the Great Lakes region with the El Ni?o-Southern Oscillation (ENSO) during the 1990s. The measured HCB concentrations in the atmosphere collected by the Integrated Atmospheric Deposition Network (IADN) program in the Great Lakes during the 1990s show strong correlations with the Multivariate ENSO index (MEI) during winter (December-February) and spring (March-May) seasons. These correlations are stronger in the western upper Great Lakes than in the eastern portion of the Great Lakes ecosystem (lake Ontario), and correspond well to the spatial variability of the surface air temperature in North America during El Ni?o years. Departures of HCB air concentrations for each winter during 1992-1999 from that averaged over all winters of 1992-1999, i.e. the anomaly, also show the same temporal trend as that of the MEI during the same period. In the same time period, it has been reported that direct HCB emissions from application of HCB in agriculture, from industrial sources in North America and in the rest of the world have decreased substantially compared to those in the 1970s and could not by themselves account for observed HCB air concentrations around the Great Lakes since the 1990s. Interannual fluctuations of HCB concentrations are caused most likely by reemission due to volatilization of HCB from the soil contaminated from past use, followed by long-range transport associated with ENSO events. In addition to the high correlation (R(2)=0.61) between winter HCB air concentrations averaged over the Great Lakes region and the MEI the atmospheric circulation patterns associated with ENSO events are conducive to the long-range transport of HCB into the Great Lakes region.     

DYNAMICS OF SEDIMENT-ASSOCIATED METALS IN A HIGHLY URBANISED CATCHMENT: BRADFORD, WEST YORKSHIRE

Urban watercourses are potential hazards because of their rapid flow changes, poor water quality and contaminated sediments. This study is a preliminary field investigation into fine sediment-associated metal contamination and its transport dynamics in a highly urbanised catchment in West Yorkshire, UK. Spatial and temporal changes in the concentration of channel-bed sediment-associated metals are investigated, and the fluxes of selected suspended sediment-associated metals, during an extreme high flow event, are determined. Channel-bed sediments were more contaminated at the most heavily urbanised sites. Data suggest that contaminated bed sediments could accumulate and possibly become increasingly contaminated between high-flow events, prior to being flushed from the system. Fluxes of contaminated suspended sediments were very high at the peak of the high flow event. The spatial and temporal dynamics of contaminated fine sediment which were identified in this study could inform planners with regard to future monitoring strategies.     

Nutrient release from integrated constructed wetlands sediment receiving farmyard run‐off and domestic wastewater

Constructed wetland sediments are frequently contaminated with nitrogen and phosphorus. There is a risk that accumulated pollutants can either be remobilised or reach the groundwater. Five identical mesocosms, which were filled with subsoil collected from full‐scale integrated constructed wetland (the first cell receives the most contaminated influent), were set up to examine nutrient removal within sediment layers. The results indicated that accumulated nutrients leached out into inflow water and that the sediment capacity of nutrient retention decreased as the wetlands aged. Furthermore, the mesocosm planted with Phragmites australis achieved better treatment results compared with the one planted with Agrostis stolonifera. The risk of contamination to groundwater does not exist because none of the treated water reached the bottom outlet during the study period. Both the bentonite (clay) and biogeochemical processes taking place within sediments proved to be efficient in preventing polluted water from infiltrating into lower lying soils.     

Assessing chemical behavior and developing remedial actions using a mass balance model of chemical fate in the Bay of Quinte

A multi-segment model of chemical fate and transport in the Bay of Quinte and a food chain model that simulate average annual conditions, are used to examine the behavior of arsenic (As), pentachlorophenol (PCP) and polychlorinated biphenyls (PCBs) in the Bay, an “Area of Concern” in the Great Lakes. The Bay model was used to predict the status of As and PCP from known loading data, but for PCBs with unknown loadings, the Bay and food chain models were used to “back-calculate” total loadings to the Bay. Chemical behavior depends on the characteristics of the Bay and physical-chemical properties of chemicals. Short water residence times of less than a week to several months result in chemicals being advected, unless subject to other, more rapid processes. In Upper Bay, rapid rates of sediment deposition and resuspension retard losses by advection of persistent chemicals such as PCBs and As, despite As being largely dissolved in the water column. Overall, behavior in Upper Bay is dominated by sediment-water exchange, and in Lower Bay by water exchange with Lake Ontario. Because of PCP's rapid transformation rate in the water column, most chemical is transformed before it reaches the sediments or downstream segments. It is recommended that elevated As inputs from the Moira River must be controlled to reduce in-Bay water and sediment concentrations, and for PCP, industrial discharges must be reduced. If reduced, concentrations in the Bay would respond within 3 months, 1 month and 3 years in the water, and about 6, 3 and 10 years in sediments for As, PCP and PCBs, respectively.     

Analysis on acoustic velocity characteristics of sediments in the northern slope of the South China Sea

To understand the spatial characteristics of the acoustic velocity within sediments in the northern slope of the South China Sea, an ultrasonic technique was employed to measure the vertical and horizontal acoustic velocities of sediment core samples. Combined with the physical and mechanical properties test results of sediments, the relationships between acoustic velocity and physical properties were analyzed. The research results showed that the acoustic velocity presented irregular variations at the same depth among different stations, and that, in general, the acoustic velocities in the vertical direction were greater than those in the horizontal direction. For different sampling stations and different depths, the acoustic velocities showed a great variability; they exhibited large differences and there was almost no relation between the vertical and horizontal velocities. In addition, the results clearly exhibited strong anisotropic characteristic among the acoustic velocities. This variation of acoustic velocity was due to complex changes of physical and mechanical properties of seabed sediments in the study area. The results of the study also showed that there was a large deviation between the measured and the predicted acoustic velocities. The predicted results were calculated by empirical equations using the relationships between single geotechnical parameters and the acoustic velocity. The research results improve the understanding of engineering geological properties of the sediments in the study area.     

Role of inland water sediments as sinks for anthropogenic sulfur

The accumulation of sulfur in the sediments of lakes and reservoirs has been estimated to be about 0.7 and 8.0 million tonnes per year respectively. Such a sink thus accounts for about 10% of the sulfur released annually from fossil fuel combustion and for a significant fraction of the “missing” sulfur in the current global budgets. The recent increases in the sulfur contents of inland water sediments (about 3-fold in the Great Lakes ecosystems, for example) have been attributed to the increased pollution of water bodies with sulfur.     

Analytical solutions for contaminant diffusion in four-layer sediment-cap system for subaqueous in-situ capping

This paper presents analytical solutions for predicting one-dimensional contaminant diffusion in a four-layer sediment-cap system, which is typically encountered in subaqueous in-situ capping of contaminated sediments. The sediment-cap system is comprised of, from top to bottom, a layer of capping material (e.g., clean sand), a layer of reactive core mat (RCM), a layer of contaminated sediment and a layer of uncontaminated sediment. Two different bottom boundary conditions are considered, i.e., zero-concentration-gradient bottom boundary condition and zero-concentration bottom boundary condition, for which the method of separation of variables is used to obtain the analytical solutions. The extensively verified CST3 (Consolidation and Solute Transport 3) model is used to verify the proposed analytical solutions. Using the verified analytical solutions, parametric studies are conducted to investigate the effect of several important parameters on contaminant transport in the four-layer sediment-cap system. The results indicate that the cap thickness, the contaminated sediment thickness, the uncontaminated sediment thickness, the effect of RCM, and the RCM distribution coefficient have significant impact on contaminant diffusion in the four-layer sediment-cap system. The analytical solutions presented herein can be used to assist the design of subaqueous in-situ capping of contaminated sediments and to verify other numerical models.     

Total phosphorus content of river sediments in relationship to calcium,iron and organic matter concentrations

Data on the total concentrations of phosphorus, calcium, iron and organic matter in surface bed-sediments taken from rivers in the Thames catchment (Wey, Blackwater, Thame and Kennet), the River Swale in Yorkshire (data excludes the organic matter content) as well as the headwaters of the Great Ouse, are collated and compared. Total concentrations of phosphorus, iron and calcium range from 1.7–649, 12–8333 and 9–4605 μmol g⁻¹ (dry weight), respectively, with organic matter in the range of 0.6–19% by dry weight. For the Wey, Blackwater and Great Ouse, sewage inflows had no detectable effect on the sediment concentrations of total calcium, iron and organic matter whereas for the Blackwater and Great Ouse, the total phosphorus contents of the sediment were higher downstream of the effluent input in comparison with a less impacted upstream location. Relationships between the total phosphorus content of the sediments and contents of iron, calcium and organic matter indicated marked differences between the rivers. Although the organic matter content of the sediments was found to be a significant predictor for the total phosphorus concentration for the Blackwater and Great Ouse, the total iron content was also useful for the Blackwater and total calcium for the Great Ouse. It is postulated that this difference is a result of the sediment processes that are known to occur in these two systems, i.e. co-precipitation of phosphate with calcite in the Great Ouse and the formation of vivianite in anoxic sediments of the Blackwater.     

Estimation of apparent rate coefficients for radionuclides interacting with marine sediments from Novaya Zemlya

To assess the impact of radionuclides entering the marine environment from dumped nuclear waste, information on the physico-chemical forms of radionuclides and their mobility in seawater-sediment systems is essential. Due to interactions with sediment components, sediments may act as a sink, reducing the mobility of radionuclides in seawater. Due to remobilisation, however, contaminated sediments may also act as a potential source of radionuclides to the water phase. In the present work, time-dependent interactions of low molecular mass (LMM, i.e. species < 10 kDa) radionuclides with sediments from the Stepovogo Fjord, Novaya Zemlya and their influence on the distribution coefficients (Kd values) have been studied in tracer experiments using 109Cd2+ and 60Co2+ as gamma tracers. Sorption of the LMM tracers occurred rapidly and the estimated equilibrium Kd(eq)-values for 109Cd and 60Co were 500 and 20000 ml/g, respectively. Remobilisation of 109Cd and 60Co from contaminated sediment fractions as a function of contact time was studied using sequential extraction procedures. Due to redistribution, the reversibly bound fraction of the gamma tracers decreased with time, while the irreversibly (or slowly reversibly) associated fraction of the gamma tracers increased. Two different three-compartment models, one consecutive and one parallel, were applied to describe the time-dependent interaction of the LMM tracers with operationally defined reversible and irreversible (or slowly reversible) sediment fractions. The interactions between these fractions were described using first order differential equations. By fitting the models to the experimental data, apparent rate constants were obtained using numerical optimisation software. The model optimisations showed that the interactions of LMM 60Co were well described by the consecutive model, while the parallel model was more suitable to describe the interactions of LMM 109Cd with the sediments, when the squared sum of residuals were compared. The rate of sorption of the irreversibly (or slowly reversibly) associated fraction was greater than the rate of desorption of the reversibly bound fractions (i.e. k3 > k2) for both radionuclides. Thus, the Novaya Zemlya sediment are supposed to act as a sink for the radionuclides under oxic conditions, and transport to the water phase should mainly be attributed to resuspended particles.     

Consideration of hydromorphology and sediment in the implementation of the EU water framework and floods directives: a comparative analysis of selected EU member states

The EU Water Framework and Floods Directives represent important legislative instruments introduced in the water policy during the last two decades. Despite their holistic and complementary approaches, which should yield many benefits, the lack of importance given to the consideration of hydromorphology and sediments is a weakness. This will hinder the achievement of the Directives' goals, since hydrology and geomorphology of rivers and the character and dynamics of sediments are essential components of the aquatic habitat and ecosystem health. The entrainment, transport and deposition of sediments determine the interrelationships between river channel geometry and flow regime, which affect flood risk. The paper reports on the findings of a survey undertaken in 2015 as part of the HYTECH project, which questioned 20 EU Water Authorities about the importance they attached to hydromorphological quality elements and sediment transport during the implementation cycles of both Directives.     

Disposal of heavy metal‐contaminated sediment from Ulsan Bay,South Korea: treatment processes and legal framework

The effectiveness of two different management schemes to dispose of heavy metal‐contaminated sediments from Ulsan Bay, South Korea, soil washing and solidification/stabilization, were evaluated through a series of analyses. NaOH proved to be an effective washing reagent for As, extracting 75% of the As in sediment samples. EDTA was found to significantly enhance the extraction of Cu, Pb and Zn. However, complete removal of any metals was not achieved even after application of 100 mM concentrations of washing reagents. Therefore, a solidification/stabilization technique was applied to dredged sediment samples using ordinary Portland cement (1–40%) and fly ash (～20%). Solidified sediments did not release meaningful amount of the metals via leaching tests. Our results suggest that solidification/stabilization is a better option for effective disposal of heavy metal‐contaminated sediments than soil washing. A legal framework for the treatment of hazardous wastes and contaminated soils in Korea is discussed.     

A multi-component statistic analysis for the influence of sediment/soil composition on the sorption of a nonionic surfactant (Triton X-100) onto natural sediments/soils

The contents of soil/sediment organic carbon and clay minerals (i.e. montmorillonite, kaolinite, illite, gibbsite and 1.4 nm minerals) for 21 natural soil/sediment samples and the sorption of Triton X-100 on these samples were determined. A multi-component statistic analysis was employed to investigate the importance of soil/sediment organic matters and clay minerals on their sorption of Triton X-100. The sorption power of soil/sediment composition for Triton X-100 conforms to an order of montmorillonite>organic carbon>illite>1.4 nm minerals (vermiculite+chlorite+1.4 nm intergrade mineral)>kaolinite. The sorption of Triton X-100 on a montmorillonite, a kaolinite and a humic acid were also investigated and consistent with the result of multi-component statistic analysis. It is clear that the sorption of Triton X-100 on soils or sediments is the combined contribution of soil/sediment organic matters and clay minerals, which depended on both the contents of soil/sediment organic matters and the types and contents of clay minerals. The important influence of illite on the sorption of nonionic surfactants onto soils/sediments is suggested and demonstrated in this paper. Surfactants for aquifer remediation application may be more efficient for the contaminated soils/sediments that contain little clay minerals with 2:1 structure because of the less sorption of nonionic surfactants on these soils/sediments.     

Quality of dredged material in the river Seine basin (France). II. Micropollutants

Dredging rivers is needed to ensure safe navigable waters, rivers and waterways. To anticipate the management of dredged materials in the case of the river Seine basin, the quality of the sediments in the river is checked every 3 years before dredging operations. The river Seine Basin is heavily submitted to pollution pressure from nearby industrial activities and urban expansion of Paris and its region. Here, the micropollutant content of the sediment sampled in 1996, 1999 and 2000 before dredging is discussed compared to regulatory standards. The results indicate that most of the sediment samples from the river Seine basin are lightly to moderately contaminated with organic and inorganic micropollutants (heavy metals, PAH, PCB), which makes the management after dredging easier. This pollution is strongly correlated with the organic matter content and to the fine fraction (<50 microm) of the sediment. These results can lead to other management options than the ones already used in the river Seine basin: (1) dumping of lightly to moderately polluted sediments in quarries; and (2) physical treatment (sieving, hydrocycloning) of contaminated sediments issued from 'hot spots'.