Using HHO (Hydroxy) and hydrogen enriched castor oil biodiesel in compression ignition engine

Hydrogen and HHO enriched biodiesel fuels have not been investigated extensively for compression ignition engine. This study investigated the performance and emissions characteristics of a diesel engine fueled with hydrogen or HHO enriched Castor oil methyl ester (CME)-diesel blends. The production and blending of CME was carried out with a 20% volumetric ratio (CME20) using diesel fuel. In addition, the enrichment of intake air was carried out using pure HHO or hydrogen through the intake manifold with no structural changes – with the exception of the reduction of the amount of diesel fuel – for a naturally aspirated, four cylinder diesel engine with a volume of 3.6 L. Hydrogen amount was kept constant with a ratio of 10 L/min throughout the experiments. Engine performance parameters, including Brake Power, Brake Torque, Brake Specific Fuel Consumption and exhaust emissions – including NOx and CO, – were tested at engine speeds between 1200 and 2600 rpm. It is seen that HHO enriched CME has better results compared to pure hydrogen enrichment to CME. An average improvement of 4.3% with HHO enriched CME20 was found compared to diesel fuel results while pure hydrogen enriched CME20 fuel resulted with an average increase of 2.6%. Also, it was found that the addition of pure hydrogen to CME had a positive effect on exhaust gas emissions compared to that adding HHO. The effects of both enriched fuels on the engine performance were minimal compared to that of diesel fuel. However, the improvements on exhaust gas emissions were significant.     

Performance, emission and combustion characteristics of biodiesel fuelled variable compression ratio engine

Experiments has been carried out to estimate the performance, emission and combustion characteristics of a single cylinder; four stroke variable compression ratio multi fuel engine fuelled with waste cooking oil methyl ester and its blends with standard diesel. Tests has been conducted using the fuel blends of 20%, 40%, 60% and 80% biodiesel with standard diesel, with an engine speed of 1500 rpm, fixed compression ratio 21 and at different loading conditions. The performance parameters elucidated includes brake thermal efficiency, specific fuel consumption, brake power, indicated mean effective pressure, mechanical efficiency and exhaust gas temperature. The exhaust gas emission is found to contain carbon monoxide, hydrocarbon, nitrogen oxides and carbon dioxide. The results of the experiment has been compared and analyzed with standard diesel and it confirms considerable improvement in the performance parameters as well as exhaust emissions. The blends when used as fuel results in the reduction of carbon monoxide, hydrocarbon, carbon dioxide at the expense of nitrogen oxides emissions. It has found that the combustion characteristics of waste cooking oil methyl ester and its diesel blends closely followed those of standard diesel.     

Characterisation and effect of using waste plastic oil and diesel fuel blends in compression ignition engine

Plastics have now become indispensable materials in the modern world and application in the industrial field is continually increasing. The properties of the oil derived from waste plastics were analyzed and found that it has properties similar to that of diesel. Waste plastic oil (WPO) was tested as a fuel in a D.I. diesel engine and its performance characteristics were analysed and compared with diesel fuel (DF) operation. It is observed that the engine could operate with 100% waste plastic oil and can be used as fuel in diesel engines. Oxides of nitrogen (NO_x) was higher by about 25% and carbon monoxide (CO) increased by 5% for waste plastic oil operation compared to diesel fuel (DF) operation. Hydrocarbon was higher by about 15%. Smoke increased by 40% at full load with waste plastic oil compared to DF. Engine fueled with waste plastic oil exhibits higher thermal efficiency upto 80% of the full load and the exhaust gas temperature was higher at all loads compared to DF operation.     

Potential of biodiesel from waste cooking oil in Mexico

The aim of this study is to evaluate the potential use of biodiesel produced from waste cooking oil (WCO) in Mexico and its CO₂ emission reduction potential for the Mexican transport sector and associated costs. The results show, based on 2010 data, that the potential of biodiesel from WCO is between 7.8 PJ and 17.7 PJ that represent between 1.5% and 3.3% of petro-diesel consumption for the road transport sector and can reduce between 0.51 and 1.02 Mt of CO₂, (1.0%–2.7% of CO₂-associated emissions), depending on the recovery ratio of WCO from vegetable oil consumption for cooking and considering CO₂ emissions for biodiesel production and methanol emissions during production and combustion in the blend. Primary energy used to produce 1 MJ of WCO-biodiesel is 0.8727 MJ, while literature reports 1.2007 MJ to produce 1 MJ of petro-diesel. Biodiesel costs are similar to petro-diesel costs if WCO is free. The paper offers suggestions for policies that promote increased recollection of WCO for biodiesel production and reduced illegal marketing of WCO, which is the main barrier to increase biodiesel production from WCO. The data used for the analysis is based on a case study of a WCO biodiesel plant that operates in Mexico City.     

Effect of injection parameters on the combustion and emission characteristics in a common-rail direct injection diesel engine fueled with waste cooking oil biodiesel

The objective of this paper was to study the effects of the injection pressure and injection timing on the combustion and emission characteristics in a single-cylinder common-rail direct injection (CRDI) diesel engine fueled with waste cooking oil (WCO) biodiesel and commercial diesel fuel. The fuel property including fatty acid composition for the biodiesel were measured and compared with those of the conventional diesel fuel. The engine tests were conducted at two injection pressures (80 and 160 MPa) and different injection timings from −25 to 0 crank angle degree (CAD) after top dead center (aTDC) under two different engine loads. The results showed that the indicated specific fuel consumption (ISFC) with respect to the injection timings of the biodiesel was higher than that of the diesel fuel under all experimental conditions. The peak cylinder pressure and the peak heat release rate of the biodiesel were slightly lower, while the ignition delay was slightly longer under all operating conditions. In terms of emissions, the biodiesel had benefits in reduction of smoke, carbon monoxide (CO), hydrocarbon (HC) emissions especially with high fuel injection pressure. The nitrogen oxide (NO_x) emissions of the biodiesel were relatively higher than those of the diesel under all experimental conditions.     

Synergistic effect of hydrogen and waste lubricating oil on the performance and emissions of a compression ignition engine

The demand for energy is increasing every year. For a long time, fossil fuels have been used to satiate this energy demand. However, using hydrocarbon-based fossil fuels has led to an enormous rise of carbon dioxide levels in the atmosphere resulting in global warming. It is therefore necessary to look for alternatives to fossil fuels. The research carried out till date have shown biomass and waste-derived fuels as plausible alternatives to fossil fuels. The biomass feedstock includes jatropha oil, Karanja oil, cottonseed oil, and hemp oil among others and wastes include used cooking oil, used engine oil, used tire and used plastics etc. In this study, the authors aim to explore waste lubrication oil as a fuel for the diesel engine. The used lubrication oil was pyrolyzed and diesel-like fuel with 80% conversion efficiency was obtained. A blend of the fuel and diesel in the ratio of 80:20 on volume basis was prepared. Engine experiments at various load conditions was carried out with the blend. As compared to diesel, a 2% increase in thermal efficiency, 6.3%, 16.1% and 13.6% decrease in smoke, CO and HC emissions & 3.2% and 1.8% increase in NOx and CO₂ emission were observed at full load with the blend. With an aim to further improve the engine performance and reduce the overall emissions from the engine exhaust, a zero-carbon fuel namely gaseous hydrogen was inducted in the intake manifold. The flow rate of hydrogen was varied from 3 to 12 Litres per minute (LPM). As compared to diesel, at maximum hydrogen flow rate the thermal efficiency increased by 12.2%. HC, CO and smoke emissions decreased by 42.4%, 51.6% and 16.8%, whereas NOx emissions increased by 22%. The study shows that the combination of pyrolyzed waste lubricant and hydrogen were found to be suitable as a fuel for an unmodified diesel engine. Such fuel combination can be used for stationary applications such as power backups.     

Performance of a diesel engine fueled by waste cooking oil biodiesel

A direct injection diesel engine fueled by a diesel/biodiesel blend from waste cooking oil up to B100 (a blend of 100% biodiesel content) indicated a combustion efficiency rise by 1.8% at full load. The soot peak volume fraction was reduced by 15.2%, while CO and HC concentrations respectively decreased by 20 and 28.5%. The physical and chemical delay periods respectively diminished by 1.2 and 15.8% for engine noise to pronounce 6.5% reduction. Injection retarding by 5° reduced NO_x to those original levels of B0 (a blend of zero biodiesel content) and combined respective reduction magnitudes of 10 and 7% in CO and HC at 75% load. Increasing the speed reduced CO and HC respectively by 26 and 42% at 2.36 times the droplet average strain rate. By coupling the turbulence model to the spray break-up and chemical kinetics models, increasing the injection pressure simultaneously reduced CO, HC and NO_x at 17% exhaust gas recirculation ratio.     

Comparative characteristics of compression ignited engines operating on biodiesel produced from waste vegetable oil

Performance and emission characteristics of two compression ignited engines of different compression ratios, number of cylinders, cooling system, and power output are studied. Waste vegetable oil-derived biofuel is used. Engines are fueled with B0, B20 and B100 mixtures. Thermal efficiency, brake specific consumption and engine emissions (CO, Unburned HC, O₂ and NO) are reported and comparisons are made for fuel mixtures running on both engines. Trends of emissions and performance curves are compared to the literature of the available data. It is noted that the biofuel certainly affects unburned HC emissions regardless of engine specifications and/or operating conditions. However, the type of fuel or adding biofuel to diesel may not affect parameters such as exhaust gas temperature and emissions (CO, Unburned HC, O₂, NO). These parameters may change as functions of engine specifications and operating conditions regardless of biofuel or diesel being used. These findings are supported by separate investigations using different biofuels in literature.     

Emission and performance characteristics of an indirect ignition diesel engine fuelled with waste cooking oil

Biofuel has so far been backed by government policies in the quest for low carbon fuel in the near future and promises to ensure energy security through partially replacing fossil fuels. At present biodiesel is mostly produced by transesterification reaction from oil-seed feedstock and has to conform to ASTM D6751 specifications. Biodiesel sustainability has sparked debate on the pros and cons of biodiesel and the question of food security. The use of waste cooking oil such as palm and coconut oil in diesel engines is more sustainable if they can perform similarly to ordinary diesel fuel (B0). This paper presents the experimental study carried out to evaluate emission and performance characteristics of a multi-cylinder diesel engine operating on waste cooking oil such as 5% palm oil with 95% ordinary diesel fuel (P5) and 5% coconut oil with 95% ordinary diesel fuel (C5). B0 was used for comparison purposes. The results show that there are reductions in brake power of 1.2% and 0.7% for P5 and C5 respectively compared with B0. In addition, reduction of exhaust emissions such as unburned hydrocarbon (HC), smoke, carbon mono-oxide (CO), and nitrogen oxides (NO_x) is offered by the blended fuels.     

Feasibility of edible oil vs. non-edible oil vs. waste edible oil as biodiesel feedstock

Biodiesel has high potential as a new and renewable energy source in the future, as a substitution fuel for petroleum-derived diesel and can be used in existing diesel engine without modification. Currently, more than 95% of the world biodiesel is produced from edible oil which is easily available on large scale from the agricultural industry. However, continuous and large-scale production of biodiesel from edible oil without proper planning may cause negative impact to the world, such as depletion of food supply leading to economic imbalance. A possible solution to overcome this problem is to use non-edible oil or waste edible oil (WEO). In this context, the next question that comes in mind would be if the use of non-edible oil overcomes the short-comings of using edible oil. Apart from that, if WEO were to be used, is it sufficient to meet the demand of biodiesel. All these issues will be addressed in this paper by discussing the advantages and disadvantages of using edible oil vs. non-edible vs. WEO as feedstock for biodiesel production. The discussion will cover various aspects ranging from oil composition, oil yield, economics, cultivation requirements, land availability and also the resources availability. Finally, a proposed solution will be presented.     

Effect of nanoparticles and hydrogen on combustion performance and exhaust emission of corn blended biodiesel in compression ignition engine with advanced timing

In this study, we have evaluated the influence of Zinc oxide and Titanium dioxide nanoparticles addition in hydrogen-corn blended biodiesel combustion performance and exhaust emission using a dual direct-injection compression-ignition engine. 5% of Zinc oxide and Titanium dioxide were mixed with corn-vegetable oil methyl ester under ultrasonication. Results revealed that the addition of nanoparticles improved the Brake power by 22% (Titanium dioxide) and 4% (Zinc oxide). Consequently, 18% and 15% reduction in brake specific fuel consumption indeed at 50% load compared to neat diesel. Furthermore, the addition of nanoparticles also resulted in a reduction of emission values of 37% and 26% in hydrocarbon, 26% and 36% for carbon monoxide, 19% and 15% in nitrogen oxide and followed by 13% and 8% of smoke opacity. Therefore, the results proved that hydrogen-corn biodiesel blended with nanoparticles additive reports a positive effect on compression-ignition diesel engines without major modifications in engine.     

Hydrogen dual-fuelling of compression ignition engines with emulsified biodiesel as pilot fuel

Dual-fuel compression ignition (CI) engine operation with hydrogen is a promising method of using hydrogen gas in CI engines via high-cetane pilot fuel ignition. However, hydrogen dual-fuel operation with neat pilot fuels typically produce: high NO_x emissions; and high combustion chamber pressure rise rates (leading to increased “Diesel knock” tendencies). While water-in-fuel emulsions have been used during normal CI engine operation to cool the charge and slow combustion rates in an effort to reduce NO_x emissions, these water-in-fuel emulsions have not been tested as pilot fuels during hydrogen dual-fuel combustion. In this work two water-in-biodiesel emulsions are tested as pilot fuels during hydrogen dual-fuel operation. Hydrogen dual-fuel operation generally produces at best comparable thermal efficiencies compared with normal CI engine operation, while the emulsified biodiesel pilot fuels generally increase thermal efficiencies when compared with the neat biodiesel pilot fuel during dual-fuel operation. There is also a clear reduction in NO_x emissions with emulsified pilot fuel use compared with the neat pilot fuel. The thermal efficiency increase is more apparent at higher engine speeds, while the NO_x reduction is more apparent at lower speeds. This is due to two conflicting effects (exclusive to emulsified pilot fuel) that occur in tandem. The first is the cooling effect of water vapourisation on the charge, while the second is the microexplosion phenomenon which enhances fuel-air mixing. The NO_x emission reduction is due to the emulsified pilot fuel lowering pressure rise rates compared with the neat pilot fuel, while the efficiency increase is due to a more homogeneous charge resulting from the violent microexplosion of the emulsified pilot fuel. Smoke, CO, HC and CO₂ emissions remain comparable to neat pilot fuel tests. Overall, emulsified pilot fuels can reduce NO_x emissions and increase thermal efficiencies, however not at the same instance and under different operating conditions. The general trends of reduced power output, reduced CO₂ and increased water vapour emission during hydrogen dual-fuel operation (with neat pilot fuels) are also maintained.     

Performance evaluation of a vegetable oil fuelled compression ignition engine

Fuel crisis because of dramatic increase in vehicular population and environmental concerns have renewed interest of scientific community to look for alternative fuels of bio-origin such as vegetable oils. Vegetable oils can be produced from forests, vegetable oil crops, and oil bearing biomass materials. Non-edible vegetable oils such as linseed oil, mahua oil, rice bran oil, etc. are potentially effective diesel substitute. Vegetable oils have high-energy content. This study was carried out to investigate the performance and emission characteristics of linseed oil, mahua oil, rice bran oil and linseed oil methyl ester (LOME), in a stationary single cylinder, four-stroke diesel engine and compare it with mineral diesel. The linseed oil, mahua oil, rice bran oil and LOME were blended with diesel in different proportions. Baseline data for diesel fuel was collected. Engine tests were performed using all these blends of linseed, mahua, rice bran, and LOME. Straight vegetable oils posed operational and durability problems when subjected to long-term usage in CI engine. These problems are attributed to high viscosity, low volatility and polyunsaturated character of vegetable oils. However, these problems were not observed for LOME blends. Hence, process of transesterification is found to be an effective method of reducing vegetable oil viscosity and eliminating operational and durability problems. Economic analysis was also done in this study and it is found that use of vegetable oil and its derivative as diesel fuel substitutes has almost similar cost as that of mineral diesel.     

Effect of induction on exhaust gas recirculation and hydrogen gas in compression ignition engine with simarouba oil in dual fuel mode

Biofuels extracted from non-edible oil is sustainable and can be used as an alternative fuel for internal combustion engines. This study presents the performance, emission and combustion characteristic analysis by using simarouba oil (obtained from Simarouba seed) as an alternative fuel along with hydrogen and exhaust gas recirculation (EGR) in a compression ignition (CI) engine operating on dual fuel mode. Simarouba biofuel blend (B20) was prepared on volumetric basis by mixing simarouba oil and diesel in the proportion of 20% and 80% (v/v), respectively. Hydrogen gas was introduced at the flow rate of 2.67 kg/min, and EGR concentration was maintained at 30% of total air introduction. Performance, combustion and emission characteristics analysis were examined with biodiesel (B20), biodiesel with hydrogen substitution and biodiesel, hydrogen with EGR and were compared with neat diesel operation. Results indicate that BTE of the engine operating with biodiesel B20 was decreased when compared to neat diesel operation. However, introducing hydrogen along with B20 blend into the combustion chamber shows a slight increase in the BTE by 1%. NO_x emission was increased to 18.13% with the introduction of hydrogen than that of base fuel (diesel) operation. With the introduction of EGR, there is a significant reduction in NO_x emission due to decrease in in-cylinder temperature by 19.07%. A significant reduction in CO, CO_2, and smoke emissions were also noted with the introduction of both hydrogen and EGR. The ignition delay and combustion duration were increased with the introduction of hydrogen, EGR with biodiesel than neat diesel operation. Hence, the proposed biodiesel B20 with H₂ and EGR combination can be applied as an alternative fuel in CI engines.     

Energy,exergy and emission analysis on a DI single cylinder diesel engine using pyrolytic waste plastic oil diesel blend

Depletion of fossil fuels and stringent emission norms focus attention to discover an evitable source of alternative fuel in order to attribute a significant compensation on conventional fuels. Besides, waste management policies encourage the valorization of different wastes for the production of alternative fuels in order to reduce the challenges of waste management. In this context, pyrolysis has become an emerging trend to convert different wastes into alternate fuel and suitable to be used as a substitute fuel for CI engines. The current investigation provides a sustainable and feasible solution for waste plastic management by widening the gap between global plastic production and plastic waste generation. It investigates the performance and emission of a single cylinder DI four stroke diesel engine using waste plastic oil (WPO) derived from pyrolysis of waste plastics using Zeolite-A as catalyst. Engine load tests have been conducted taking waste plastic oil and subsequently a blend of waste plastic oil by 10%, 20%, and 30% in volume proportions with diesel as fuel. The performance of the test engine in terms of brake thermal efficiency is found marginally higher and brake specific fuel consumption comparatively lowest for 20% WPO-diesel blend than pure diesel. The NOx and HC emission is found lower under low load condition and became higher by increasing the load as compared to diesel. Fuel exergy was significantly increasing after blending of WPO with pure diesel, but exergetic efficiency of the blended fuels followed the reverse trend. However, increase in load of the engine improved the exergetic efficiency. The 20% WPO–diesel blended fuel is found suitable to be used as an alternative fuel for diesel engine.     

The effect of biodiesel fuel obtained from waste frying oil on direct injection diesel engine performance and exhaust emissions

In this study, usage of methyl ester obtained from waste frying oil (WFO) is examined as an experimental material. A reactor was designed and installed for production of methyl ester from this kind of oil. Physical and chemical properties of methyl ester were determined in the laboratory. The methyl ester was tested in a diesel engine with turbocharged, four cylinders and direct injection. Gathered results were compared with No. 2 diesel fuel. Engine tests results obtained with the aim of comparison from the measures of torque, power; specific fuel consumptions are nearly the same. In addition, amount of emission such as CO, CO₂, NO_x, and smoke darkness of waste frying oils are less than No. 2 diesel fuel.     

Hydrogen combustion in a compression ignition diesel engine

The investigation presented in this paper concerns both pure hydrogen combustion under HCCI (homogeneous charge compression ignition) conditions and hydrogen–diesel co-combustion in a compression ignition (CI) engine.     

A comprehensive study on performance,emission and combustion behavior of a compression ignition engine fuelled with WCO (waste cooking oil) emulsion as fuel

This work aims at evaluating the performance, emission and combustion of a diesel engine fuelled with WCO (waste cooking oil obtained from palm oil) and its emulsion as fuel. A single cylinder water-cooled diesel engine was used. Base data was generated with diesel and neat WCO as fuels. Subsequently, WCO oil was converted into its emulsion and tested. Neat WCO resulted in higher smoke, hydrocarbon and carbon monoxide emissions as compared to neat diesel. Significant reduction in all emission was achieved with the WCO emulsion. Cylinder peak pressure and maximum rate of pressure rise were found to be higher with WCO emulsion as compared to neat WCO mainly at high power outputs. Ignition delay was found as higher with neat WCO and its emulsion. It is concluded that WCO emulsion can be used in diesel engines without any modifications in the engine with superior performance and reduced emissions at high power outputs.     

Potential of waste palm cooking oil for catalyst-free biodiesel production

Disposal of waste palm cooking oil (WPCO) via an environmental-friendly route is of major importance in the quest for sustainable development. In this study, WPCO was utilized instead of refined vegetable oils as the source of triglycerides for biodiesel production. WPCO contains several impurities, such as water and free fatty acids, which limit its application in catalytic transesterification processes. Consequently, a catalyst-free process using supercritical methanol was employed to investigate the potential of WPCO as an economical feedstock for biodiesel production. The parameters that influence the reaction, including reaction time, temperature and the molar ratio of alcohol to oil, were investigated. For comparison purposes, refined palm oil (RPO) was also subjected to supercritical methanol reaction and it was found that both processes produced comparable optimum yields of 80% at their respective optimum conditions. Hence, it can be concluded that WPCO has high potential as an economical and practical future source of biodiesel.     

Experimental investigation of the performance and emissions of a heavy-duty diesel engine fueled with waste cooking oil biodiesel/ultra-low sulfur diesel blends

The major obstacle to biodiesel commercialization is the high cost of raw materials. Biodiesel from waste cooking oil is an economical source and thus an effective strategy for reducing the raw material cost. Using waste cooking oil also solves the problem of waste oil disposal. This study investigated the emissions of polycyclic aromatic hydrocarbons (PAHs), carcinogenic potencies and regulated matters, and brake specific fuel consumption from a heavy-duty diesel engine under the US-HDD transient cycle for five test fuels: ultra-low sulfur diesel (ULSD), WCOB5 (5 vol% biodiesel made from waste cooking oil + 95 vol% ULSD), WCOB10, WCOB20, and WCOB30. Experimental results indicate using ULSD/WCOB blends decreased PAHs by 7.53%-37.5%, particulate matter by 5.29%-8.32%, total hydrocarbons by 10.5%-36.0%, and carbon monoxide by 3.33%-13.1% as compared to using ULSD. The wide usage of WCOB blends as alternative fuels could protect the environment.