Equation of state of3He near its liquid-vapor critical point

We report high-resolution measurements of the pressure coefficient (P/T) for³He in both the one-phase and two-phase regions close to the critical point. These include data on 40 isochores over the intervals–0.1t+0.1 and–0.2+0.2, wheret=(T–T _c )/T _c and =(– _c )/ _c . We have determined the discontinuity (P/T) of (P/T) between the one-phase and the two-phase regions along the coexistence curve as a function of . The asymptotic behavior of (1/) (P/T) versus near the critical point gives a power law with an exponent (+–1)^–1=1.39±0.02 for0.010.2 or–1×10 ^–2t–10 ^–6 , from which we deduce =1.14±0.01, using =0.361 determined from the shape of the coexistence curve. An analysis of the discontinuity (P/T) with a correction-to-scaling term gives =1.17±0.02. The quoted errors are fromstatistics alone. Furthermore, we combine our data with heat capacity results by Brown and Meyer to calculate (/T) _c as a function oft. In the two-phase region the slope (²/T ²)_c is different from that in the one-phase region. These findings are discussed in the light of the predictions from simple scaling and more refined theories and model calculations. For the isochores 0 we form a scaling plot to test whether the data follow simple scaling, which assumes antisymmetry of – ( _c ,t) as a function of on both sides of the critical isochore. We find that indeed this plot shows that the assumption of simple scaling holds reasonably well for our data over the ranget0.1. A fit of our data to the linear model approximation is obtained for0.10 andt0.02, giving a value of =1.16±0.02. Beyond this range, deviations between the fit and the data are greater than the experimental scatter. Finally we discuss the (P/T) data analysis for ⁴ He by Kierstead. A power law plot of (1/) P/T) versus belowT _c leads to =1.13±0.10. An analysis with a correction-to-scaling term gives =1.06±0.02. In contrast to ³ He, the slopes (²/T ²)_c above and belowT _c are only marginally different.Work supported by a grant from the National Science Foundation.     

Solution of thermal conductivity problems with boundary condition of the third kind and arbitrary coordinate and time dependence of the biot number

An analytical solution of the thermal conductivity problem with boundary conditions of the third kind and arbitrary coordinate and time dependence of the Biot number is found in the form of a converging series of quadratures.Notation , z dimensionless coordinates - dimensionless temperature - Q dimensionless volume heat-liberation density per unit time - Fo=/² Fourier number - Bi₁(, Fo)=(, Fo) · / Biot number - thermal diffusivity coefficient - plate thickness - time - (, Fo) heat-liberation coefficient - thermal conductivity coefficient - i summation index - Jo zero order Bessel function of the first kind Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 41, No. 3, pp. 536–540, September, 1981.     

Ordinary size effects and deviations from Matthiessen's rule in the resistance of fine wires

Contrary to previous statements in the literature, large deviations from Matthiessen's rule in fine wiresare to be expected on the basis of a straight-forward solution of the ordinary transport equation, assuming the relaxation-time approximation and imposing the idealized condition of diffuse scattering of electrons at the boundaries. Using Chambers' path-integral method to evaluate the current density in a wire of arbitrary cross-sectional shape, the effects of boundary scattering on the resistivity in the regimed 0.1 have been calculated for two model Fermi surface geometries. For the temperature-dependent part of the resistivity, _d (T) _d (T)– _d (0), two distinct types of behavior are found in the alternative cases: (1) for a spherical Fermi surface, _d(T) increases logarithmically with _d(0); (2) for a cylindrical Fermi surface, _d (T) increases essentially linearly with _d (0). [In each case the qualitative dependence of _d(0) on /d is, for practical purposes, linear. However, the correct value of the product in the cylindrical case is not simply given in the ordinary way by the slope of an empirical plot of _d (0) vs.d ^–1.] A comparison of theoretical results for the two simple models with the published data for indium and gallium shows that the actual temperature-dependent size effects are consistent, both qualitatively and, by a rough estimation, quantitatively, with the expected behavior.     

High-field galvano- and thermomagnetic effects in cadmium

Detailed results are presented of investigations on the galvano- and thermomagnetic coefficients of pure Cd ( ₁₁ , ₂₁ , ₁₁ , and ₂₁ ). The transverse resistivity ₁₁ is almost perfectly quadratic in magnetic field (B ^1.99 ) at the lowest temperatures, thus throwing doubt on the applicability of intersheet scattering models, which suggest significant departures fromB ² . The lattice conductivity _g is extracted from the high-field thermal data and is found to exhibit no pronounced anomalies, in contrast to the previously obtained data on the zero-field electronic thermal conductivity (to which _g should be related in the simplest theory). The Hall resistivity ₂₁ is qualitatively similar to that obtained by previous workers, but the detailed field dependence is different. After corrections are made for the effects of _g , the Righi-Leduc thermal resistivity ₂₁ is found to behave like ₂₁ , though it is more sensitive to temperature, as might be expected for a thermal coefficient.Work supported by National Research Council of Canada.     

A modified Weibull treatment for the analysis of strength-test data from non-identical brittle specimens

Powder compacts (e.g., pharmaceutical tablets) manufactured on commerically available machines are not strictly identical but show inevitable variability in their weights, thicknesses and compaction pressures. Consequently, the variability in fracture-stress data obtained from such brittle specimens is greater than that due to the inherent strength variability of the material itself. A modified Weibull analysis has been developed so that a more accurate estimate of the inherent variability of the mechanical strength of the material can be derived from test data obtained from commercially produced compacts; its application is illustrated.Nomenclature D diameter - f() relative frequency of occurrence of specimens with density and volume - F minimization function - i ascending rank number of a fracture stress - m Weibull modulus - N _tot number of specimens in a batch - N() number of specimens with densities in the range to + d and volumes in the range to + d - P _f failure probability - p _u upper punch compaction pressure - t thickness - volume - w weight - W _f fracture load - density - _f fracture stress - ¯ _f mean fracture stress of a batch - ¯ _f() mean fracture stress of specimens with density and volume - ₀ scale parameter or normalizing factor - _u location parameter or threshold stress     

Temperature dependence of electrical resistivity of deformed and undeformed V-rich V3Si single crystals

The electrical resistivity (T) of V-rich V₃Si single crystals (T _c-11.4 K) was measured from 4.2 to 300 K along the directions of [1 0 0] and [1 1 1] before and after plastic deformation at 1573 K. Anisotropy of (T) was observed although V₃Si has the cubic A15 structure. Plastic deformation does not affect the normal-state (T) behaviour but changes the normal-superconducting transition width T_c. At low temperatures (T _c<T 40 K), (T) varies approximately as T ⁿ where n-2.5 and this behaviour does not contradict the (0)- phase-diagram plot proposed by Gurvitch, where is the electron-phonon coupling constant and (0) is the residual resistivity.     

In-Plane Fourfold Symmetry of the Upper Critical Field Observed in La(Sr)214 Single Crystals

In order to establish the existence of in-plane anisotropy of the upper critical field H _c2 (), the out-of-plane resistivity _c measurements were performed on La(Sr)214 single crystals with rectangular and cylindrical shape under rotating magnetic field applied within the ab-plane. Although observed _c shows non-sinusoidal twofold symmetry, clear fourfold symmetry was obtained after subtracting twofold sinusoidal component in _c which is due to the unavoidable misalignment of the magnetic field with respect to ab-plane. H _c2 () is estimated from the extracted fourfold component of _c with the flux flow theory. Angular dependence of H _c2 () was well fitted by cos(4). Since the fourfold component of H _c2 () was largest at = n/2, which corresponds to the a-axis direction, the present results strongly suggest the type symmetry in La(Sr)214. In addition, the difference in fourfold component of H _c2 at = n/2 and n/2+/4 was found to increase with decreasing temperature.     

Structure of unidimensional temperature stresses

Using the structural approach, the temperature stresses are examined in a semiinfinite rod, insulated on the lateral faces and rigidly fixed at the end. A comparative analysis is made for three heat-transfer models.Notation k(t) heat flux relaxation function - (t) internal energy relaxation function - T rod temperature - ambient temperature - t time - x coordinate along the rod - _xx(x, t) stress - u(x, t) displacement - (x, t) deformation - c₀=(E/)^1/2 speed of sound in the rod under isothermal conditions - E elasticity modulus - density of the material - _t coefficient of thermal expansion - thermal-conductivity coefficient - a thermal-diffusivity coefficient - b thermal-activity coefficient - c_q=(a/_r)^1/2 velocity of heat propagation - _r heat flux relaxation time - (t) unique Heaviside function Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 33, No. 5, pp. 912–921, November, 1977.     

Interpretation of Resistivity of Nd1.85Ce0.15CuO4: Electron–Phonon Mechanism

The temperature-dependent normal state resistivity of single crystal Nd_1.85Ce_0.15CuO_{4 –} is theoretically analyzed within the framework of classical electron–phonon i.e., Bloch-Gruneisen model of resistivity. For the reason of inherent acoustic (low frequency) phonons (_ac) as well as high-frequency optical phonons (_op), the contributions to the resistivity were first derived. The optical phonons of the oxygen breathing mode yields a relatively larger contribution to the resistivity compared to the contribution of acoustic phonons. Estimated contribution to in-plane resistivity by considering both phonons, i.e., _ac and _op, along with the zero-temperature-limited resistivity, when subtracted from single crystal data infers a quadratic temperature dependence over most of the temperature range [25 T 300]. Quadratic temperature dependence of _diff. = [_exp. – {₀ + _e–ph (=_ac + _op)}] is understood in terms of 3D electron–electron inelastic scattering. The comparison of single crystal experimental data appears favorable with the present analysis.     

Nucleate boiling

The study deals with the effect of the surface conditions on the nucleate boiling curve. A relation is proposed which describes the complete nucleate boiling curve.Notation q thermal flux - q* thermal flux at which the liquid boils after one-phase convection - q_c thermal flux during one-phase convection - q_cr1, q_cr2 first and the second critical thermal flux - T saturation temperature - T superheat of the heating surface relative to the saturation temperature - T* superheat prior to boiling of the liquid after one-phase convection - T_cr1 superheat during the first boiling crisis - T_cr3min minimum superheat at which the third boiling crisis can occur - P pressure - P_cr critical pressure - heat transfer coefficient during nucleate boiling - R_cr radius of a critical vapor forming nucleus - coefficient of surface tension - r latent heat of evaporation - thermal conductivity of the liquid - kinematic viscosity of the liquid - , densities of the liquid and the vapor - g gravitational constant - k Boltzmann constant - N Avogadro number - h Planck's constant Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 40, No. 3, pp. 394–401, March, 1981.     

Thermal conductivity of hydrocarbons in the naphthene group under high pressures

The thermal conductivity of hydrocarbons in the naphthene group has been experimentally determined. An equation is now proposed for calculating the thermal conductivity over the given temperature and pressure ranges.Notation thermal conductivity - ₂₀ and ₃₀ values of the thermal conductivity at 20 and 30°C, respectively - t₀,P₀ thermal conductivity at t₀, p₀ - _t p thermal conductivity at temperature t and under pressure P - change in thermal conductivity - P pressure - P_melt melting pressure - P₀ atmospheric pressure - t₀ 20°C temperature - T, t temperature - T_cr critical temperature - temperature coefficient of thermal conductivity - ₂₀ temperature coefficient of density - density - ₂₀ density at 20°C - _cr critical density - M molar mass - =T/T_cr referred temperature - v specific volume - v₀ specific volume at 20°C - v change in specific volume - _{3 0} a coefficient - B (t) a function of the temperature - S a quadratic functional - W_i, weight of the i-th experimental point - _i error of the i-th experimental value of thermal conductivity - B _{y, =0.6} value of B (t) at T = 0.6T_cr - B = B (t)/B_{, =0.6} referred value of coefficient B (t) Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 41, No. 3, pp. 491–499, September, 1981.     

Remarks on wave solutions of the nonlinear heat-conduction equation

Wave solutions of the nonlinear heat-conduction equation are analyzed and their relation to self-similar solutions is established. Solutions of the hyperbolic and the nonlinear heat-conduction equations are compared.Notation k(T) thermal diffusivity coefficient - relaxation parameter - g²=₀/c_v@ square of the heat wave velocity - ₀ and k₀ heat-conduction and thermal diffusivity constant - density - c_v specific heat at constant volume - T temperature - t time - x, y, z space coordinates Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 40, No. 5, pp. 907–913, May, 1981.     

Velocity of second sound and superfluid density near the superfluid transition in3He-4He mixtures

Using superleak condenser transducers, the velocity of second soundU ₂ has been measured near the superfluid transition temperature T in³He-⁴He mixtures with molar concentrationsX of³He of 0.0, 0.038, 0.122, 0.297, and 0.440. We have obtained the superfluid density _s/ fromU ₂ on the basis of linearized two-fluid hydrodynamics. The results for _s/ are consistent with those obtained from the oscillating disk method, as expected from two-fluid hydrodynamics. The value of _s/ at eachX could be expressed by a single power law, _s/=k, where =1-T/R, with the experimental uncertainty. It is found that the exponent is independent of concentration forX0.44 within the experimental uncertainty. This concentration independence of is in agreement with the universality concept. From the conclusion that the values of are universal forX0.44, the concentration dependence of the superfluid component _s is expressed by an empirical equation _s(X, )=²_s(0, ). It is found that corresponds to the volume fraction of⁴He in the superfluid³He-⁴He mixture. The value of is in agreement with that obtained from the measurement of the molar volume by others.This paper is based on a thesis submitted to Tokyo University of Education in partial fulfillment of the requirements for the Ph.D. degree.     

Thermophysical properties data on molten semiconductors

Thermophysical properties of molten semiconductors are reviewed. Published data for viscosity, thermal conductivity, surface tension, and other properties are presented. Several measurement methods often used for molten semiconductors are described. Recommended values of thermophysical properties are tabulated for Si, Ge, GaAs, InP, InSb, GaSb, and other compounds. This review shows that further measurements of thermophysical properties of GaAs and InP in the molten state are required. It is also indicated that a very limited amount of data on emissivity is available. Space experiments relating to thermophysical property measurements are described briefly.Nomenclature Density - C _p Specific heat - Kinematic viscosity - Dynamic viscosity= - Thermal diffusivity - Thermal conductivity=C_p - Volumetric thermal expansion coefficient - Surface tension - d/dT Temperature coefficient of surface tension - g Gravitational acceleration - T Temperature - T Temperature difference - L Characteristic dimension     

Heat conduction in a multilayer composite wedge

A new method for analytically solving a problem of steady-state heat conduction for multilayer composite wedge-shaped bodies is suggested based on a generalization of the integral Mellin transform.Notation T temperature - _rr, thermal conductivity coefficients - thickness of composite material layers (1) - N₁(), N ₂ ⁽¹⁾ (), N ₂ ⁽²⁾ () auxiliary local functions from the rapid variable =r/ - m(r, p) auxiliary function entering the core of the generalized integral Mellin transform - ₀ half of the wedge aperture angle Moscow Institute of Chemical Engineering. Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 64, No. 4, pp. 487–491, April, 1993.     

Shear viscosity of liquid4He and3He-4He mixtures,especially near the superfluid transition

High-resolution measurements of are reported for liquid⁴He and³He-⁴He mixtures at saturated vapor pressures between 1.2 and 4.2 K with particular emphasis on the superfluid transition. Here is the mass density, the shear viscosity, and in the superfluid phase both and are the contributions from the normal component of the fluid ( _n and _n ). The experiments were performed with a torsional oscillator operating at 151 Hz. The mole fraction X of³He in the mixtures ranged from 0.03 to 0.65. New data for the total density and data for _n by various authors led to the calculation of . For⁴He, the results for are compared with published ones, both in the normal and superfluid phases, and also with predictions in the normal phase both over a broad range and close to T. The behavior of and of in mixtures if presented. The sloped/dT near T and its change at the superfluid transition are found to decrease with increasing³He concentration. Measurements at one temperature of versus pressure indicate a decreasing dependence of on molar volume asX(³He) increases. Comparison of at T, the minimum of _n in the superfluid phase and the temperature of this minimum is made with previous measurements. Thermal conductivity measurements in the mixtures, carried out simultaneously with those of , revealed no difference in the recorded superfluid transition, contrary to earlier work. In the appendices, we present data from new measurements of the total density for the same mixtures used in viscosity experiments. Furthermore, we discuss the data for _n determined for⁴He and for³He-⁴He mixtures, and which are used in the analysis of the data.     

Pulse determination of thermal diffusivity and thermal conductivity for hemispherical specimens: nickel

A method is described for determining the thermal diffusivity, specific heat, and thermal conductivity in a hemispherical volume on the basis of duration of the reference signal.Notation r radius - R radius - r dimensionless coordinate - dimensionless temperature - time - _i duration of heat pulse - _1/2 time for temperature signal at r to attain half the maximum value - q_o amount of heat - a thermal diffusivity - thermal conductivity - density - c_p heat capacity Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 40, No. 5, pp. 864–869, May, 1981.     

Spin Gap and Hole Pairing of Sr14−x A x Cu24O41(A = Ca and La) Single Crystals Studied by the Electrical Resistivity and Thermal Conductivity

We have measured the electrical resistivity and the thermal conductivity of Sr _14–x A _x Cu ₂₄ O ₄₁(A = Ca and La) single crystals. The Arrhenius plot of ln vs T ^–1 gives two kinds of activation energy with a boundary temperature T . The activation energy at T < T is in approximate agreement with the spin gap in the ladder estimated from the NMR measurements, suggesting that holes in the ladder are paired and localized at T < T. The observed has been analyzed to be composed of _ph , _spin and _hole due to phonons, spins and holes, respectively. The _ph exhibits a small peak at 30 K in every direction of every single-crystal. The contribution of _spin is observed along the c-axis except for x(Ca) 6, and the spin gap, which corresponds to the spin excitation from spin-singlet to spin-triplet, has been estimated to be 420 K. For x(Ca) 6, the spin gap, which corresponds to the destruction of spin-singlet pairs i. e. the dissociation of hole pairs, has been estimated from along the c-axis at T > T to decrease with increasing x(Ca).     

Temperature-density parameters of Freon-13 on the saturation line

Experimental data of a high degree of accuracy are presented on the temperature-density parameters of Freon-13 on the saturation line in the density range of (0.08246–1.6061)·10 kg/m³.Notation T absolute temperature of phase transition from two-phase to one-phase state (or vice versa) - T_c critical temperature - , densities of liquid and vapor, respectively, on saturation line - _c density at critical points - average density - =(T_c–T)/2 reduced temperature - parameter of order, equal to ' – _c – b for the liquid phase and _c + b – "for the vapor phase Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 37, No. 5, pp. 830–834, November, 1979.     

The variation of the index of refraction in a vortex tube

Three models of a vortex tube (isentropic, isothermal, and isochoric) are considered as optical inhomogeneities. Expressions relating the index of refraction to the coordinate are obtained. The possibility of obtaining Schlieren pictures of such flows is discussed.Notation a speed of sound - n index of refraction - p pressure - r radius - T absolute temperature - v linear velocity - angular deflection of the beam - x adiabatic exponent - density - angular velocity - ¯v, ¯p etc. dimensionless parameters - v₀, ₀ values at the core bounboundary - p, etc. stagnation values - n_c index of refraction at center of vortex