Effects of environment and temperature on ceramic tensile strength–grain size relations

Overall strength ()–grain size (G), i.e. –G-1/2, relations retain the same basic two-branched character to at least 1200–1300°C. However, some polycrystalline as well as single crystal strength shifts or deviations are seen relative to each other, and especially relative to Young's moduli versus temperature for poly- and single crystals. The variety and complexity of these deviations are illustrated mainly by Al2O3, BeO, MgO and ZrO2 for which there is considerable data. At 22°C, Al2O3 polycrystals show substantial strength decrease due to H2O while MgO, ZrO2 and BeO polycrystals have limited, variable decreases. Al2O3 single crystals (sapphire) also show substantial strength decreases, but ZrO2 and MgO single crystals show little or none. Sapphire's strength markedly decreases from at least –196°C to a minimum in the 400–600°C range, then rises to a maximum at1000°C, followed by an accelerating decrease with further temperature increase. Polycrystalline Al2O3 shows similar (but less pronounced) strength minima and maxima, or alternatively an approximate strength plateau from 22 to 1000°C interrupting the normally expected strength decreases with increasing temperature at suitably large grain size and absence of defects (e.g. pores) dominating failure. BeO crystals show a linear strength decrease with increasing temperature (T) similar to that of Young's modulus. BeO polycrystals often show a significant strength (apparently grain size and impurity dependent) maximum (at 500–800°C) or plateau (from 22 to 1000°C) interrupting an otherwise continuous decrease. MgO shows similar temperature behaviour to BeO, but more pronounced crystal strength decrease and less pronounced polycrystalline strength maxima. Polycrystalline ZrO2 shows more rapid Young's modulus (E), and especially strength, decreases at 200–500°C than single crystals. More limited data for other materials also shows greater, variable –T versus E–T trends, e.g. MgAl2O4 has a similar, but less pronounced decrease than ZrO2. Collectively these deviations suggest variable impacts on primarily flaw controlled –G-1/2 behaviour due to factors such as microplasticity, machining stresses, and thermal expansion and elastic anisotropies requiring more comprehensive testing and evaluation to better sort out these effects.     

Effects of interphase strength on the damage modes and mechanical behaviour of metal–matrix composites

A numerical version of the generalized self-consistent method previously developed by the authors is combined with the Gurson model to undertake a parametric investigation of the damage mechanisms and their relations with the macroscopic tensile properties of SiC reinforced aluminium, for three different interphase strengths. The results show that the interphase strength is a governing factor for damage propagation in the composite. Thus, transformation of the failure mechanism from reinforcement fracture to void nucleation and growth can be achieved by reducing the interphase bond strength, although the strengthening effects on the composite decrease unfavourably.     

Micromechanics modeling of the electrical conductivity of carbon nanotube (CNT)–polymer nanocomposites

A mixed micromechanics model was developed to predict the overall electrical conductivity of carbon nanotube (CNT)–polymer nanocomposites. Two electrical conductivity mechanisms, electron hopping and conductive networks, were incorporated into the model by introducing an interphase layer and considering the effective aspect ratio of CNTs. It was found that the modeling results agree well with the experimental data for both single-wall carbon nanotube and multi-wall carbon nanotube based nanocomposites. Simulation results suggest that both electron hopping and conductive networks contribute to the electrical conductivity of the nanocomposites, while conductive networks become dominant as CNT volume fraction increases. It was also indicated that the sizes of CNTs have significant effects on the percolation threshold and the overall electrical conductivity of the nanocomposites. This developed model is expected to provide a more accurate prediction on the electrical conductivity of CNT–polymer nanocomposites and useful guidelines for the design and optimization of conductive polymer nanocomposites.     

Effects of dispersion and interfacial modification on the macroscale properties of TiO2 polymer–matrix nanocomposites

This paper quantifies how the quality of dispersion and the quality of the interfacial interaction between TiO₂ nanoparticles and host polymer independently affect benchmark properties such as glass transition temperature (T_g), elastic modulus and loss modulus. By examining these composites with differential scanning calorimetry (DSC), dynamic mechanical analysis (DMA) and scanning electron microscopy (SEM), we demonstrate changes in properties depending on the adhesive/wetting or repulsive/dewetting interactions the nanoparticles have with the bulk polymer. We further quantify the dispersion of TiO₂ nanoparticles in polymethylmethacrylate (PMMA) matrices by a digital–optical method and correlate those values to the degree of T_g depression compared to neat PMMA. Samples with the same weight percent of nanoparticles but better dispersion show larger shifts in T_g.     

Structure and biological response of polymer/silica nanocomposites prepared by sol–gel technique

Structure of P(EMA-co-HEA)/SiO₂ nanocomposites with silica content in the range from 0 to 30 wt.% was correlated with cell behavior on substrates of those compositions by making use of two different populations of primary human cells: articular cartilage chondrocytes and dental pulp cells. Substrates were prepared by the simultaneous copolymerization of the organic monomers and the sol–gel reaction of the silica precursor in different proportions, which led to weight fractions of the silica phase in the materials closely matching the stoichiometric ratios employed during the preparation, both in the bulk and at the material surface. The silica nanophase increases surface wettability and improves the mechanical properties of the base materials. Both chondrocytes and dental pulp cells were cultured on serum-coated nanocomposite substrates in the same conditions, but very different cellular responses were obtained. While chondrocytes adhered and proliferated, dental pulp cells formed viable aggregates weakly adhered on the sample that were viable up to 11 days. The results suggest that these sol–gel derived nancomposites may be used as culture surfaces maintaining the dental pulp cell phenotype in vitro.     

Size effects on tensile strength of aluminum–bronze alloy at room temperature

Variations in tensile yield strength of annealed CuAl7 copper alloy were investigated. Both grain and feature size effects could be observed. Statistical analysis revealed that the grain size effect was greater than the feature size effect. The grain size effect on the tensile yield strength of the alloy was very significant. The feature size effect was very significant or significant when the specimen thickness was no more than 0.50 mm, while the effect was insignificant or completely absent when the specimen thickness was greater than 0.50 mm. In addition to grain size d and specimen thickness t, the t/d ratio of the specimen can also affect the tensile yield strength. The tensile yield strength of the alloy was almost a constant when the t/d ratio was greater than a critical value (approximately 21). Otherwise, the strength tended to increase with an increasing value of t/d, except for the specimen with a thickness of 0.25 mm. The size effects on the tensile strength of the CuAl7 copper alloy were compared with the effects on the compression strength. It was found that the size effect intensity on the compression yield strength was greater than that on the tensile yield strength.     

Investigation of the effect of nanoclay and processing parameters on the tensile strength and hardness of injection molded Acrylonitrile Butadiene Styrene–organoclay nanocomposites

Polymer–clay nanocomposites have attracted considerable interest over recent years due to their dramatic improved mechanical properties. In the present study, compatibility of Acrylonitrile Butadiene Styrene (ABS) and organically modified montmorillonite nanoclay (Cloisite 30B) and composition capability of them are investigated. Polymethylmethacrylate (PMMA) in varying amount (0, 2, and 4 wt%) is used as the compatibilizer. In order to produce nanocomposite parts, the material is first compounded using a twin-screw extruder and then injected into a mold. The effect of the nanoclay percentage and processing parameters on the tensile strength and hardness of nanocomposite parts is also explored using Taguchi Design of Experiments method. Nanoclay content (in three levels: 0, 2 and 4 wt%), melt temperature (in three levels: 190, 200 and 210 °C), holding pressure (in three levels: 80, 105 and 130 MPa) and holding pressure time (in three levels: 1, 2.5 and 4 s) are considered as the variable parameters. Moreover, distribution of nanoclay layers is analyzed using Wide Angle X-ray Diffraction (XRD) test. XRD results displayed that with the presence of PMMA, nanoclay in ABS matrix is compounded in more exfoliated and less intercalated dispersion mode. Adding PMMA also leads to a remarkable increase in the fluidity of the melt during injection molding process. Results also illustrated that nanocomposites with medium loading level (i.e. 2%) of nanoclay have the highest tensile strength, while the highest hardness number belongs to nanocomposites with 4 wt% nanoclay. Obtained results also indicated that injection temperature has the most important effect on tensile strength and hardness of ABS–clay nanocomposites.     

Analytical-geometrical percolation network model for piezoresistivity of hybrid CNT–CB polymer nanocomposites using Monte Carlo simulations

International Journal of Mechanics and Materials in Design - A 3D Monte Carlo simulation and percolation network model for hybrid nanocomposites reinforced by carbon nanotubes (CNTs) and carbon...     

Effects of friction on roller expanded tube–tubesheet joint strength

Roller expansion of new tubes in enlarged heat exchanger tubesheet holes requires higher rolling torques which may result in over-thinning of the tube wall. This affects adversely the tube–tubesheet joint strength, which is measured in terms of residual contact pressure between the expanded tube and tubesheet. The axial force required to cause the mechanical failure of the tube–tubesheet joint has therefore been considered as an indication of the integrity of the joint. This force is influenced by several parameters such as the type of tube and tubesheet materials, the initial clearance and coefficient of friction. In the present work, an axisymmetric finite element (FE) model is used to evaluate the combined effects of friction between tube and tubesheet, initial clearance and tube material strain hardening on the strength of the tube–tubesheet joint. The FE results show that the increase in friction between tube and tubesheet results in higher residual contact stress and lower cutoff clearances. The residual contact stress also increased linearly with increasing tube material strain hardening level for all friction coefficients.     

Influence of thermal conditions on the tensile properties of basalt fiber reinforced polypropylene–clay nanocomposites

In this paper, a comparative study on the tensile properties of clay reinforced polypropylene (PP) nanocomposites (PPCN) and chopped basalt fiber reinforced PP–clay nanocomposites (PPCN-B) is presented. PP matrix are filled with 1, 3 and 5 wt.% of nanoclays. The ultimate tensile strength, yield strength, Young’s modulus and toughness are measured at various temperature conditions. The thermal conditions are included the room temperature (RT), low temperature (LT) and high temperature (HT). The basal spacing of clay in the composites is measured by X-ray diffraction (XRD). Nanoscale morphology of the samples is observed by transmission electron microscopy (TEM). Addition of nanoclay improves the yield strength and Young’s modulus of PPCN and PPCN-B; however, it reduces the ultimate tensile strength. Furthermore, the addition of chopped basalt fibers to PPCN improves the Young’s modulus of the composites. The Young’s modulus and the yield strength of both PPCN and PPCN-B are significantly high at LT (−196 °C), descend at RT (25 °C) and then low at HT (120 °C).     

Effect of abnormal grain growth on tensile strength of Al–Cu–Mg alloy friction stir welded joints

An Al-4.5%Cu-1.5%Mg aluminum alloy with a T4 temper was friction stir welded, and the effect of the abnormal grain growth on the tensile strength of joints was investigated. Abnormal grain growth usually happens during post weld heat treatment. It is found that the tensile strength and elongation of the heat-treated joint will increase significantly if this phenomenon completely happens in stir zone. On the other hand stable grains in the stir zone have no effect on the mechanical properties of heat-treated joint.     

Effects of residual porosity on strength of Sn–Pb/Cu6 Sn5 particulate composites

Abstract

The effect of residual porosity on the flow stress of particulate composites was studied for a composite in which it is possible to create high porosity (>60%) by using particle coatings. The material was a eutectic composition Sn–Pb solder with additions of intermetaliic CU₆Sn₅ particles. It was found that porosity affects the strength of these composites much less than for non-composites, an effect attributed to particle bonding during solidification. At the same time, residual porosity was found to inhibit strongly or even to prevent hardening of this material. A micromechanical model is developed which simulates this behaviour over a wide range of porosities.

MST/1928     

Torsional,tensile and structural properties of acrylonitrile–butadiene–styrene clay nanocomposites

Torsional and tensile behaviour of acrylonitrile–butadiene–styrene (ABS)-clay nano-composites have been investigated and correlated with morphological and rheological characterisations. Nano-composites of ABS are prepared by melt compounding with different loading levels of nanoclay (Cloisite 30B) in a twin screw extruder and have been characterised in terms of torsional, axial and impact behaviour for their application in external orthotic devices. Tensile stress strain curve of nanocomposites are investigated to quantify resilience, toughness and ductility. Torque values of the nanocomposites are observed under torsion (10°–90°) and compared with that of neat ABS. Performance of ABS under torsional load improved by addition of nanoclay. Both modulus of elasticity and rigidity are found to improve in presence of nanoclay. State of dispersion in nano-composites is investigated using conventional methods such as transmission electron microscopy (TEM), X-ray diffraction (XRD), as well as by parallel plate rheometry. Addition of clay exhibits shear thinning effect and results in increase in storage modulus as well as complex viscosity of the nanocomposites. Zero shear viscosity rises tenfold with 1–2% addition of nanoclay, indicating the formation of structural network. It is found that state of dispersion of nanoclay governs the torsional and mechanical properties in ABS-clay nanocomposites.     

An experimental study of the influence of fibre–matrix interface on fatigue tensile strength of notched composite laminates

The objective of this study was to investigate the effect of fibre–matrix interfacial adhesion on fatigue residual strength of polymer matrix composite laminates containing a circular hole. Composite laminates were manufactured using surface-treated and -untreated carbon fibres, and the interfacial adhesion was quantified by measuring the transverse flexural strength of the two material systems. Tensile–tensile cyclic fatigue experiments were conducted at three load levels. Residual strength of notched laminates, subjected to cyclic loading was then measured for the two composite systems. Damage mechanisms were analysed using C-scan and SEM fractography and correlated with notched residual strength.     

Dispersion assessment and studies on AC percolative conductivity in polymer-derived Si–C–N/CNT ceramic nanocomposites

Nanocomposites comprise polysilazane-derived SiCN ceramic charged with carbon nanotubes (CNTs) have been prepared by dispersion of multi-walled CNTs with a diameter of 80 nm in a cross-linked polysilazane (HTT 1800, Clariant) using a simple roll-mixer method. Subsequently, the composites were warm pressed and pyrolyzed in argon atmosphere. Scanning electron microscopy (SEM) and 3D Raman imaging techniques were used as major tools to assess the dispersion of CNTs throughout the ceramic matrix. Furthermore, studies on the effect of the volume fraction of CNTs in the nanocomposites on their electrical properties have been performed. The specific bulk conductivities of the materials were analyzed by AC impedance spectroscopy, revealing percolation thresholds (ρ_c) at CNT loadings lower than 1 vol%. Maximum conductivity amounted to 7.6 × 10⁻² S/cm was observed at 5 vol% CNT. The conductivity exponent in the SiCN/CNT composites was found equal to 1.71, indicating transport in three dimensions.     

Tensile strength of glass fibres with carbon nanotube–epoxy nanocomposite coating: Effects of CNT morphology and dispersion state

The effects of carbon nanotube (CNT)–epoxy nanocomposite coating applied to glass fibre surface on tensile strength of single glass fibres are evaluated at different gauge lengths. The crack healing efficiencies obtained using two different types of CNTs with different structures, morphologies and dispersion characteristics in various concentrations are specifically studied. The results indicate that the tensile strength of single fibres increased significantly with increasing CNT content up to a certain level, depending on the type of CNTs. The crack healing efficiency was much higher for the fibres coated with straight, less entangled CNTs than those with highly entangled CNTs, indicating the CNT dispersion state in the coating played an important role. A strong correlation is established between the CNT dispersion state, the tensile properties of nanocomposite and the tensile strengths of fibres with the nanocomposite coating.     

The effects of water aging on the interphase region and interlaminar fracture toughness in polymer–glass composites

Three different unidirectional polymer–glass composite systems involving phenolic and polyester resins were aged for 6 and 11 weeks in tap water and tested in the mode I double cantilever beam (DCB) test. The results showed a dramatic increase in water absorption and a decrease in fracture toughness for phenolic/glass systems. Fractographic analysis revealed interfacial debonding to be dominant failure mechanism, indicating a strong influence of water degradation on fracture toughness results. The interphase region of each system was investigated using the nano-indentation and the nano-scratch techniques before and after aging in water. The nano-indentation test produced a series of indents as small as 30 nm in depth, to detect water degradation of the material properties at the interphase region between the fibre and the matrix. The nano-hardness results indicated interdiffusion in water aged interphase regions. The nano-scratch test was used in conjuction with the nano-indentation test, in order to detect the width of the interphase regions before and after water degradation. It was shown, from the coefficient of friction and the scratch profile depth, that the interphase region width increased and the material properties degraded during water aging. Qualitative links between water degradation of the glass–polymer interphase on a nanometer level and interlaminar fracture toughness are discussed.     

Effects of intermediate metal layer on the properties of Ga–Al doped ZnO/metal/Ga–Al doped ZnO multilayers deposited on polymer substrate

Ga–Al doped ZnO/metal/Ga–Al doped ZnO multilayer films were deposited on polyethersulfone (PES) substrate at room temperature. The multilayer films consisted of intermediate Ag metal layers, top and bottom Ga–Al doped ZnO layer. The multilayer with PES substrate had advantages such as low sheet resistance, high optical transmittance in visible range and stable mechanical properties. From the results, sheet resistances of multilayer showed 9 Ω/sq with 12 nm of Ag metal layer thickness. Average optical transmittance of multilayer film showed 84% in visible range (380–770 nm) with 12 nm of Ag metal layer thickness. Moreover the multilayers showed stable mechanical properties than single-layered Ga–Al doped ZnO sample during the bending test due to the existence of ductile Ag metal layer.     

Effects of Zr and B on the structure and tensile properties of Al–20%Mg alloy

In current research, the effects of different Zr and B contents on the structure and tensile properties of Al–20%Mg alloy have been investigated by using Al–15Zr and Al–8B master alloys. Optical and scanning electron microscopy (SEM) were utilized to study the microstructures and fracture surfaces. Microstructural analysis of the cast alloy showed dendrites of primary α-phase within the eutectic matrix which consists of β-Al₃Mg₂ intermetallic and α-solid solution. After tensile testing, the optimum amounts for both Zr and B were found to be 0.5 wt.%. Ultimate tensile strength (UTS) value of the unrefined alloy increased from 168 MPa to 243 MPa and 236 MPa by adding 0.5% Zr and 0.5%B, respectively. The main mechanism for UTS enhancement was found to be due to the refinement of grains and also altering large dendrites of Al(α)-phase to finer structure. The study of fracture faces revealed that B/Zr addition changes the mode of fracture from brittle to rather ductile.     

Effects of post-aging cooling condition on structure and tensile properties of aged Ti–7.5Mo alloy

The present study investigated the effects of post-aging cooling condition on tensile properties of an aged Ti–7.5 wt% Mo alloy. Experimental results indicated that the solution-treated (ST) Ti–7.5Mo samples were comprised substantially of α″ phase, while all aged samples demonstrated the co-existence of α′ and β phases therein. The relative amount of β phase retained in the aged alloy was found sensitive to post-aging cooling condition. Water-quenched (WQ) alloy had the highest β phase content, while furnace-cooled (FC) alloy had the lowest β phase content. The Mo concentration in β phase was also sensitive to post-aging cooling condition. The average Mo concentration in β phase was found highest in FC samples and lowest in WQ samples. Compared to ST samples, all aged samples demonstrated significant increases in yield strength and modulus values, along with decreases in elongation. The effect of post-aging cooling condition on microhardness was similar to that on strength.