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The kinetics of catalytic hydrogenation of ortho-nitrochlorobenzene to 2,2‘-dichloroazoxybenzene on platinum/carbon catalyst is investigated in a slurry reactor with the temperature range of 313--343 K, and orthochloroaniline is formed as a byproduct. Models based on Rideal-Eley and Langmuir-Hinshelwood mechanism have been proposed based on the rate data and the kinetic regime. The former model can be used to fit the experimental data better. Reaction controlling steps are physical adsorption of hydrogen and adsorbed ortho-nitrochlorobenzene reacted on the surface of catalyst. 相似文献
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Ana Cristina Alves Monteiro-Gezork Reyna Natividad John Mike Winterbottom 《Catalysis Today》2008,130(2-4):471-485
The importance of the hydrodearomatisation (HDA) is increasing together with tightening legislation of fuel quality and exhaust emissions. The present study focuses on hydrogenation (HYD) kinetics of the model aromatic compound naphthalene, found in typical diesel fraction, in n-hexadecane over a NiMo (nickel molybdenum), Ni (nickel) and Ru (ruthenium) supported on trilobe alumina (Al2O3) catalysts. Kinetic reaction expressions based on the mechanistic Langmuir–Hinshelwood (L–H) model were derived and tested by regressing the experimental data that translated the effect of both naphthalene and hydrogen concentration at a constant temperature (523.15 and 573.15 K over the NiMo catalyst and at 373.15 K over the Ni and Ru/Al2O3 catalysts) on the initial reaction rate. The L–H equation, giving an adequate fit to the experimental data with physically meaningful parameters, suggested a competitive adsorption between hydrogen and naphthalene over the presulphided NiMo catalyst and a non-competitive adsorption between these two reactants over the prereduced Ni and Ru/Al2O3 catalysts. In addition, the adsorption constant values indicated that the prereduced Ru catalyst was a much more active catalyst towards naphthalene HYD than the prereduced Ni/Al2O3 or the presulphided NiMo/Al2O3 catalyst. 相似文献
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Ni-W/F-Al_2O_3-SiO_2催化剂的表面吸附维朱建军,林西平(江苏石油化工学院,化工系,常州,213016)关键词表面吸附,分形维,Ni-W/F-Al_2O_3-SiO_2催化剂1引言催化现象与多相催化剂的表面性质密切相关,催化剂表面形状是影响... 相似文献
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The catalytic activity of nanosized Au/γ‐Al2O3, synthesized by a deposition‐precipitation process, on oxidative decomposition of hydrazine in air is discussed. The catalyst exhibited an excellent activity at low temperatures. The activity was strongly dependent upon the gold cluster size. The impacts of certain pertinent operating parameters including the particle size of the catalyst, temperature, hydrazine concentration, and feed flow rate on the extent of the reaction were investigated. The results were reproducible with a mean absolute deviation of 3 %. Deactivation of the catalyst during the reaction was found to be unlikely. Finally, a kinetic model based on the Eley‐Rideal formulation was proposed for the reaction and a correlation was made between the data predicted from the model and those determined experimentally. 相似文献
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Catalyst design is key to the improvement of chemical process efficiency. The required work for the development of new catalysts can be supported through the proper application of artificial intelligence to identify optimal compositions. A generic methodology for the application of machine learning to catalysis research is therefore outlined in this work. The catalytic oxidation of SO2 was used to exemplify the first iteration of this methodology. 1784 data points from 31 published papers were compiled into a databank. The inlet SO2 concentration ranged from 0 to 66 mol%. An artificial neural network (ANN) was trained on the databank in order to predict SO2 conversion based on the catalyst composition and the reactor operating conditions (temperature, pressure, catalyst mass: volumetric flowrate ratio (w/v), and feed composition). The model achieved a root-mean-square error of 6.6%. A preliminary screening step identified 3:1 V-Mg/SiO2 catalysts as exhibiting high conversion at 648 K. A multi-objective optimization was then performed on a single catalyst to identify solutions exhibiting high conversion and high productivity at 648 K while minimizing the catalyst cost. The optimal solution was predicted to be a 2.9 wt% V/0.2 wt% Mg/SiO2 catalyst operating at a w/v of 7.49 kg-cat · s/m3 STP, achieving 100% SO2 conversion with a material cost among the bottom third of cost values. Artificial intelligence can then be employed to extract useful knowledge from published catalytic data and orient future search for novel catalyst development. 相似文献
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SO_4~(2-)/La_2O_3-TiO_2-HZSM-5催化合成乙酸丁酯 总被引:1,自引:0,他引:1
将SO42/TiO2-HZSM-5负载镧制备了新型催化剂SO42/La2O3-TiO2-HZSM-5,以乙酸和正丁醇的酯化反应为探针,考察了不同制备条件对催化剂性能的影响。结果表明:La3+浸渍浓度为0.07mol/L,经110℃烘干后于500℃焙烧3h所得催化剂活性最好。采用正交实验法对影响酯化反应的因素进行考察,最佳实验条件为n(醇)∶n(酸)=1.5∶1,反应时间2h,催化剂用量2%(总物料),酯化率可达97.8%。且该催化剂具有良好的重复使用和再生能力。 相似文献
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Ali Dashti Ahmad Ramazani SA Yuichi Hiraoka Sang Yull Kim Toshiaki Taniike Minoru Terano 《Polymer International》2009,58(1):40-45
BACKGROUND: Kinetic and morphological aspects of slurry propylene polymerization using a MgCl2‐supported Ziegler–Natta catalyst synthesized from a Mg(OEt)2 precursor are investigated in comparison with a ball‐milled Ziegler–Natta catalyst. RESULTS: The two types of catalyst show completely different polymerization profiles: mild activation and long‐standing activity with good replication of the catalyst particles for the Mg(OEt)2‐based catalyst, and rapid activation and deactivation with severe fragmentation of the catalyst particles for the ball‐milled catalyst. The observed differences are discussed in relation to spatial distribution of TiCl4 on the outermost part and inside of the catalyst particles. CONCLUSION: The Mg(OEt)2‐based Ziegler–Natta catalyst is believed to show highly stable polymerization activity and good replication because of the uniform titanium distribution all over the catalyst particles. Copyright © 2008 Society of Chemical Industry 相似文献
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对于不规则形状A301氨合成催化剂,测定了其形状系数和球化的当量直径及高压下本征动力学方程,用SPSR法测定了不规则催化剂颗粒的曲折因子,根据多组分单一反应等温球形A301氨合成催化剂内反应-扩散-维模型,用正交配置法结合解非线性方程组的Broyden拟牛顿法求解了模型,获得了催化剂粒内各组分的浓度分布和催化剂的内扩散有效因子.利用所测得的高压下A301催化剂的总体速率对模型进行了检验,模型计算值和实验值吻合,表明球化模型和所得当量直径、曲折因子等模型参数可用于描述A30l催化剂内的反应-扩散过程及工程设计计算. 相似文献
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Cu2Ag2O3 has been prepared by a precipitation method and evaluated for ambient temperature carbon monoxide oxidation. The Cu2Ag2O3 catalyst demonstrated appreciable activity and a relationship with preparation ageing time was observed. An ageing time of 4 h produced a catalyst with the highest oxidation performance. The catalyst precursor materials, prepared by drying at room temperature, displayed initial high activity, which decreased with time on line. The precursors were transformed during CO oxidation to form the mixed oxide Cu2Ag2O3 as the material was dried in situ. A comparison of the catalytic activity has been made with a representative sample of a high activity hopcalite, mixed copper/manganese oxide catalyst. On the basis of CO oxidation rate data corrected for the effect of catalyst surface area the Cu2Ag2O3, aged for 4 h was at least as active as the hopcalite catalyst. 相似文献
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Maryam Takht Ravanchi Saeed Sahebdelfar Maryam Rahimi Fard Siavash Fadaeerayeni Peyman Bigdeli 《化学工程与技术》2016,39(2):301-310
The selective hydrogenation of acetylene to ethylene over Pd‐Ag/α‐Al2O3 catalysts prepared by different impregnation/reduction methods was studied. The best catalytic performance was achieved with the sample prepared by sequential impregnation. A kinetic model based on first order in acetylene and 0.5th order in hydrogen for the main reaction and second‐order independent decay law for catalyst deactivation was used to fit the conversion time data and to obtain quantitative assessment of catalyst performances. Fair fits were observed from which the reaction and deactivation rate constants were evaluated. Coke deposition amounts showed a good correlation with catalyst deactivation rate constants, indicating that coke formation should be the main cause of catalyst deactivation. 相似文献
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Negar Manafi Rasi Ehsan Mostafavi Maria Angelica Retuta Moshfiqur M. Rahman Raj Gupta Nader Mahinpey 《加拿大化工杂志》2018,96(1):250-258
The purpose of this research was to study steam gasification of ash‐free coal integrated with CO2 capture in the presence of a K2O catalyst for enhancement of the key water‐gas shift reaction and promotion of hydrogen production. To achieve this goal, gasification experiments on ash‐free coal (AFC) were carried out at varying temperatures (600, 650, 675, 700, and 750 °C) with a sorbent‐to‐carbon (CaO/C) ratio of 2 and a catalyst (K2O) loading of 0.2 g/g (20 weight percent (wt%)) in a fixed‐bed reactor equipped with a gas chromatography analyzer. The sorbent‐to‐carbon (CaO/C) ratio of 2 is based on dry and ash‐free basis. The CaO/C ratio and K2O wt% were chosen to maximize hydrogen production based on our previously determined optimal values. The AFC was originally extracted from raw lignite coal using organic solvents, which allowed the sorption‐enhanced gasification to be conducted with minimal ash‐catalyst interactions. The effect of temperature on the yield and the initial reaction rate were investigated. The optimal reaction temperature of 675 °C was determined. Carbon balance and final carbon conversions were calculated based on the residue analysis. Activation energy was also calculated using intrinsic kinetics of the reaction. In this study, using AFC offered the potential advantage of operating the gasification process with catalyst recycle. 相似文献