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在N2、Ar气氛中,采用反应直流磁控溅射法在Al2O3基陶瓷及玻璃基底上制备了Ta-N薄膜,并对各样品的形貌结构、化学组分及电学特性进行了比较分析研究。结果表明,沉积于Al2O3陶瓷及玻璃基底的Ta-N薄膜分别呈团簇状生长与层状紧密堆积生长;Al2O3陶瓷基底沉积的Ta-N为单相薄膜,而玻璃基底上的Ta-N薄膜,随N2、Ar流量比增加,呈单相向多相共存转变;薄膜表面形貌和微结构与基底材料的原始形貌和微结构紧密相关,这说明基底材料对薄膜的形成有重要的影响;N2、Ar流量比相同时,玻璃基底上沉积的Ta-N薄膜电性能优于Al2O3基陶瓷基底上沉积的Ta-N薄膜。 相似文献
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采用电子束蒸发法以普通玻璃为基板制备了重掺硅薄膜,通过SEM、EDS、透射光谱对其形貌、成分以及透射率进行了测试表征.进一步采用铝诱导低温晶化法在玻璃基板上沉积Al薄膜,对重掺硅薄膜进行铝诱导晶化.XRD测试、电学性能测试以及可见-红外光谱透射率测试结果表明,硅薄膜在温度为300℃以上出现了Si(111)的衍射峰,薄膜的导电性得到了提高,且具有较强的红外反射能力,表明在低辐射玻璃上具有一定的应用价值.同时采用电子束蒸发法制备了结构为glass/Si/Ag/Si的Ag基低辐射玻璃,通过光学性质测试和腐蚀情况观察结果表明硅薄膜具有保护低辐射薄膜的作用. 相似文献
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硬质薄膜的膜/基结合力是表征材料可靠性的重要特性参数。采用划痕法测试硬质薄膜的结合力时,有很多因素会影响到临界载荷Lc的判定,例如薄膜和基底的硬度、模量,薄膜的表面粗糙度等;此外,仪器机架刚度、划痕速率、压头的曲率半径等仪器的测量参数也会影响临界载荷Lc的判定。采用划痕测量法,研究了曲率半径为20μm,50μm和100μm的压头对单晶硅和304基底的亚微米类金刚石薄膜与基底的结合力测量的影响。研究结果显示:随着压头曲率半径的增加,2种材料的临界载荷也随之增大。 相似文献
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合理使用划痕法及显微法测定TiN薄膜与基体结合力 总被引:1,自引:0,他引:1
《理化检验(物理分册)》2015,(9)
采用反应磁控溅射的方法在TC4钛合金基板上制备了TiN薄膜,利用划痕法测试了TiN薄膜与基体之间的结合力,并结合薄膜硬度与显微法判断的临界载荷进行了对比分析。结果表明:单纯依靠划痕法判断临界载荷较为局限,结合显微法同时考虑硬度等力学性能共同判断临界载荷,是更为科学合理的办法。 相似文献
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用电子束蒸发技术在K9玻璃及两种不同取向的钇铝石榴石(Y3Al5O12, 简称YAG)晶体上沉积了SiO2薄膜, 采用X射线衍射仪和纳米划痕仪对薄膜显微结构和力学性能进行了研究。实验结果表明: 薄膜在K9 、YAG(100) 和YAG(111)基底上分别呈现非晶态和多晶态; 沉积在不同基底上的薄膜的弹性模量并无明显差异; SiO2薄膜在K9和YAG基底上呈现不同的划痕破坏模式, 并且YAG晶体上薄膜的粘附失效临界附着力远远小于SiO2薄膜与K9基底的附着力。本文从薄膜的结构和弹性模量两方面分析解释了不同基底上薄膜的力学行为。 相似文献
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多种基底上溅射沉积ZnO薄膜的结构 总被引:4,自引:0,他引:4
在玻璃基底和四种硅基底上用反应式直流磁控溅射法制备了ZnO薄膜。用AES和XRD对薄膜结构和组分进行测试,结果表明,五种基底上生长的ZnO薄膜在不同程度上都具有优良的纵均匀性、明显的c轴择优取向和较高的结晶度,而硅基底上薄膜的结构普遍优于玻璃基底上沉积的薄膜。 相似文献
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采用磁控溅射在硅晶基体上制备NiZnCo铁氧体磁性薄膜,研究了溅射功率对溅射(沉积)速率和微观形貌的影响规律:随着溅射功率由80W增大到150W,薄膜的沉积速率增大;薄膜却由整齐均匀分布的小颗粒状向片状结构变化,分布也不均匀,晶粒明显长大.由此确定最佳溅射功率为120 W,薄膜的微观形貌最理想,溅射(沉积)速率也很快. 相似文献
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Thin gold films have been deposited on glass and silicon substrates using ion-assisted deposition techniques. The adhesion of the films to the substrates is assessed by a scratch test. Deposition assisted by 100 eV-1 keV oxygen ions yields highly adhesive films that can only be removed by damaging the substrate. Argon and hydrogen ions produce films with relatively poor adhesion. The results show that the reflectance of oxygen-assisted films is reduced by trapping of the oxygen in the gold but no bulk chemical or structural changes are detected. It is proposed that a thin stable layer of gold oxide is formed during film growth and diffuses into the substrate, providing a strong bond for subsequent film deposition. Highly adhesive films with bulk optical properties are deposited on glass and silicon using oxygen-ion assistance only to the point of continuous film formation. 相似文献
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The cantilevered substrate technique has been used to measure the stress in aluminium and silicon monoxide films deposited in sequence on glass substrates. The stress is compressive in aluminium and tensile in silicon monoxide although the latter may be changed by prior exposure of the aluminium film to atmosphere.Electrical measurements were made on capacitors fabricated during the stress experiments. These showed that a definite relation existed between the dielectric loss and the stress.Possible reasons are suggested for these results. 相似文献
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Chemical vapor deposition of aluminum from a recently developed precursor, methylpyrrolidine alane complex, has been studied. Aluminum films deposited on conducting surfaces (titanium nitride, copper, gold), but not on insulating surfaces (silicon, silicon dioxide, glass) at low substrate temperatures, showing deposition selectivity, while the deposition selectivity was lost at high substrate temperatures (> 210 °C). Al deposition rates on TiN and Cu were very close, but much higher than on Au. Deposition rates on all conducting substrates increased with the temperature and reached maximum at 180 °C. Al films deposited on as-sputtered TiN or Cu have no preferred orientations. Al–Au alloys and intermetallics were observed in the films deposited on Au. Surface morphology observation revealed that the film growth on TiN or Cu is different from that on Au. The surface roughness of Al films increased with the deposition time or the film thickness. 相似文献
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Chung YB Park HK Lee SH Song JH Hwang NM 《Journal of nanoscience and nanotechnology》2011,11(9):8242-8245
Since n-type crystalline silicon films have the electric property much better than those of hydrogenated amorphous and microcrystalline silicon films, they can enhance the performance of advanced electronic devices such as solar cells and thin film transistors (TFTs). Since the formation of amorphous silicon is unavoidable in the low temperature deposition of microcrystalline silicon on a glass substrate at temperatures less than 550 degrees C in the plasma-enhanced chemical vapour deposition and hot wire chemical vapour deposition (HWCVD), crystalline silicon films have not been deposited directly on a glass substrate but fabricated by the post treatment of amorphous silicon films. In this work, by adding the HCl gas, amorphous silicon-free n-type crystalline silicon films could be deposited directly on a glass substrate by HWCVD. The resistivity of the n-type crystalline silicon film for the flow rate ratio of [HCl]/[SiH4] = 7.5 and [PH3]/[SiH4] = 0.042 was 5.31 x 10(-4) ohms cm, which is comparable to the resistivity 1.23 x 10(-3) ohms cm of films prepared by thermal annealing of amorphous silicon films. The absence of amorphous silicon in the film could be confirmed by high resolution transmission electron microscopy. 相似文献
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Zhengrong Shi 《Journal of Materials Science: Materials in Electronics》1994,5(5):305-309
Borosilicate glass was chosen as a substrate for solution growth of silicon due to its potential role as the superstrate of a solar module. The deposition of polycrystalline silicon on glass from solutions containing aluminium or magnesium is reported. Island growth was usually obtained when the deposition temperature was below 750 C. Large-grain, continuous, silicon thin films with an area of 10 cm2 were grown on glass substrates at temperatures around the softening points of the glass. The growth of silicon on glass can be explained on the basis that the presence of aluminium and magnesium in the solution reduces SiO2 and exposes silicon on the glass surface. The silicon-rich surface improves the wetting of the glass by the solution and acts as seeding sites for silicon nucleation. The periodic-regrowth technique was used to improve the quality of the polycrystalline silicon thin films deposited on the glass substrates. Periodic repetition of the melt-back and regrowth procedures removed the small-grained crystals, suppressed the rapid growth of crystals perpendicular to the substrate and enhanced the growth of slower-growing crystals in the lateral direction. This process markedly improved the smoothness, the grain size, the crystal quality and the (1 1 1) preferred orientation of the silicon thin films. Diode characteristics were obtained for p-n junction devices made on these polycrystalline silicon thin films deposited on glass substrates. 相似文献
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Gas-phase phosphorous and boron doping of hydrogenated nanocrystalline thin films deposited by HWCVD at a substrate temperature of 150 °C on flexible-plastic (polyethylene naphthalate, polyimide) and rigid-glass substrates is reported. The influence of the substrate, hydrogen dilution, dopant concentration and film thickness on the structural and electrical properties of the films was investigated. The dark conductivity of B- and P-doped films (σd = 2.8 S/cm and 4.7 S/cm, respectively) deposited on plastic was found to be somewhat higher than that found in similar films deposited on glass. n- and p-type films with thickness below ∼ 50 nm have values of crystalline fraction, activation energy and dark conductivity typical of doped hydrogenated amorphous silicon. This effect is observed both on glass and on plastic substrates. 相似文献
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Deposition and modification of titanium dioxide thin films by filtered arc deposition 总被引:4,自引:0,他引:4
Thin films of titanium dioxide have been deposited on glass substrates and conducting (100) silicon wafers by filtered arc deposition (FAD). The influence of the depositing Ti− energy, substrate types and substrate temperature on the structure, density, mechanical and optical properties have been investigated. The results of X-ray diffraction (XRD) showed that with increasing substrate bias, the film structure on silicon substrates changes from anatase to amorphous and then to rutile phase without auxiliary heating, the transition to rutile occurring at a depositing particle energy of about 100 eV. However, in the case of the glass substrate, no changes in the structure and optical properties were observed with increasing substrate bias. The optical properties over the range of 300–800 nm were measured using spectroscopic elliosometery, and found to be strongly dependent on the substrate bias, film density and substrate type. The refractive index values of the amorphous, anatase and rutile films on Si were found to be 2.56, 2.62 and 2.72 at a wavelength of 550 nm, respectively. The hardness and elastic modulus of the films were found to be strongly dependent on the film density. Measurements of the mechanical properties and stress also confirmed the structural transitions. The hardness and elastic modulus range of TiO2 films were found to be between 10–18 and 140–225 GPa, respectively. The compressive stress was found to vary from 0.7 to 2.6 GPa over the substrate bias range studied. The composition of the film was measured to be stoichiometric and no change was observed with increasing substrate bias. The density of the film varied with change in the substrate bias, and the density ranged between 3.62 and 4.09 g/cm3. 相似文献
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《Thin solid films》1999,337(1-2):27-31
Polycrystalline silicon (poly-Si) films were deposited on glass substrates (corning 7059) at 300°C by a plasma enhanced chemical vapor deposition (PECVD) from a SiH4/SiF4 mixture. All poly-Si films were prepared under the same deposition conditions on the substrates subjected to nitrogen, hydrogen and/or CF4 plasma with different gas pressures, just before deposition of the poly-Si films. Effects of such pretreatments for substrates on the structural properties of the resultant poly-Si films have been investigated. The Si film deposited on the substrates without any pretreatments was amorphous. However, formation of a strong 〈110〉 preferentially oriented poly-Si with improved crystallinity was obtained for the films deposited on the glass substrate after plasma pretreatments, which exhibit smoother surfaces. This result was interpreted in terms of a removal of weak Si–Si bonds during nucleation and the subsequent grain growth. 相似文献
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Hakan Kockar 《Journal of Superconductivity》2004,17(4):531-536
The Rotating Cryostat system consists of a rapidly rotating, liquid-nitrogen-cooled drum, around which a substrate can be placed. The possibility of using multiport sources gives the system wide capabilities for producing new materials. The effects of various rotation speeds of 1900, 1500, 1000, 500, and 0 rpm on the magnetic properties of thin iron films deposited on different (glass, silicon, and Kapton) substrates from a resistively heated evaporation source and a dc sputtering source have been investigated. Magnetic measurement showed that the films have an in-plane magnetic anisotropy for all films deposited at high speeds on all types of substrates and the degree of magnetic anisotropy decreased with decreasing rotational speed for flexible Kapton substrate. While the glass and silicon substrates was stationary, in-plane magnetic anisotropy of the films dropped down to zero. The films deposited on Kapton showed the rotational-speed-dependent magnetic properties. Estimation of magnetic anisotropy confirms in-plane anisotropy in the films. Furthermore, as expected for all iron films no magnetic anisotropy perpendicular to film plane was observed irrespective of rotation speed and type of substrate used. 相似文献