共查询到20条相似文献,搜索用时 359 毫秒
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《广东建材》2020,(6)
本文以相对分子质量为2400、3000、4000、5000的烯丙基聚醚(SPEG)为大单体,以丙烯酸(AA)、丙烯酰胺(AM)、2-丙烯酰胺-2-甲基丙烯磺酸(AMPS)等为小单体,采取氧化还原体系,在常温条件下通过水溶液自由基聚合来制备一种具有早强性能的聚羧酸减水剂。同时本文讨论了酸醚比的大小、丙烯酰胺用量以及2-丙烯酰胺-2-甲基丙烯磺酸的掺量对早强性能的影响。实验结果表明当采用酸醚比为3.8时,所合成聚羧酸减水剂对水泥分散性能最好;当使用较大相对分子质量为4000的聚醚合成聚羧酸减水剂时,水泥净浆的凝结时长最短;当分别掺入单体质量1.6%的AMPS以及等质量替代4g丙烯酸的AM时,所合成聚羧酸减水剂具有较好的早强效果;在实际应用中,使用PCE-1调整出来的混凝土具有和易性好、凝结时间短、早期强度高的优点。 相似文献
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以异戊烯醇聚氧乙烯醚(TPEG)和丙烯酸(AA)为主要聚合单体,选用丙烯酰胺(AM)、2-丙烯酰胺-2-甲基丙磺酸(AMPS)和N-羟甲基丙烯酰胺(HAM)3种含酰胺基团的早强功能单体,在双氧水-抗坏血酸氧化还原引发体系和巯基乙酸链转移剂条件下制备了早强型聚羧酸减水剂。性能测试及红外光谱分析结果表明:当n(TPEG)∶n(AA)∶n(HAM)=1.0∶3.6∶0.4时,制备的减水剂早强效果优异,该减水剂折固掺量为0.2%时,与掺普通型聚羧酸减水剂的胶砂强度相比,其1 d、3 d抗压强度分别提高了15.35%、8.83%;酰胺官能团红外特征峰明显,表明早强型聚羧酸减水剂分子主链上含有酰胺基团。 相似文献
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通过以甲基烯丙基聚氧乙烯醚(TPEG),丙烯酸(AA)为主要原料合成缓释型聚羧酸减水剂,研究了反应温度、反应时间、酸醚比,以及2-丙烯酰胺-2-甲基丙磺酸(AMPS)、丙烯酰胺(AM)和不同引发剂的用量等因素对缓释型聚羧酸减水剂性能的影响.结果表明,缓释型聚羧酸减水剂最佳合成工艺为:n (AA)∶n (AMPS)∶n (AM)∶n (TPEG) =3.25:0.27:0.40:1.00,引发剂用量为TPEG总质量的0.25%,反应温度为70℃,滴加反应时间为4h.所合成的缓释型聚羧酸减水剂,在水灰比为0.29,掺量为0.4%的条件下,水泥初始净浆流动度达280 mm,净浆流动度损失较小,混凝土坍落度损失小,1h几乎无损失,2h损失30 mm,与其它缓释型聚羧酸减水剂相比具有更好的缓释效果. 相似文献
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《新型建筑材料》2015,(9)
以甲基烯丙基聚氧乙烯醚(TPEG)、丙烯酸(AA)、2-丙烯酰胺-2-甲基丙磺酸(AMPS)、丙烯酰胺(AM)等作为合成的主要原材料,按n(AA)∶n(AMPS)∶n(AM)∶n(TPEG)=(3.5~2.0)∶0.3∶0.3∶1.0,选取酸醚比[n(AA)∶n(TPEG)]为3.5、2.75、2.0,催化剂用量为大单体质量的0.05%、0.10%、0.15%,在不同温度下合成缓释型聚羧酸系减水剂。通过测试水泥净浆经时流动度,确定不同合成温度下最佳的酸醚比和催化剂用量。并对按最佳配比合成的减水剂进行性能试验研究,结果表明,采用适当的合成工艺,常温和高温条件下合成的缓释型聚羧酸减水剂的性能基本相同。 相似文献
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再生混凝土的基本性能研究 总被引:1,自引:0,他引:1
设计并完成了在掺与不掺减水剂两种配合比下,再生粗骨料取代率分别为0、30%、50%、100%的再生混凝土的和易性、立方体抗压强度、棱柱体抗压强度的相关试验,并以天然骨料混凝土作为基准进行了对比分析。试验结果表明,粗骨料取代率对混凝土的流动性、粘聚性与保水性有不同的影响,适量的减水剂可以增强混凝土的流动性;在水灰比相同的情况下,再生粗骨料取代率为30%时再生混凝土立方体抗压强度和轴心抗压强度都高于普通混凝土;再生混凝土的抗压强度随龄期的发展和普通混凝土比较相近。 相似文献
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The performance of high workability mortar mix, applicable for the casting of thin ferrocement elements by using slag as cement replacement and superplasticizer as water reducing agent is investigated. Cement mortars (1:2. 1:2.5 and 1:3) incorporating various percentages of slag and superplasticizer were designed to have high workability (136±3% flow). Performance of the mortars is studied in terms of compressive strength, unit weight, strength development and water absorption. Effect of three different curing regimes on strength and strength development of the mortars is also the part of this study. The results showed that the high workability slag cement mortars of reasonably high strength, low water absorption and exhibiting early age strength comparable to that of the OPC mortars can be designed in order to cast thin ferrocement elements by the method of pouring. 相似文献
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高强度等级混凝土因施工中存在黏度大、流速慢等问题使其发展受到限制.利用聚羧酸高性能减水剂分子的可设计性,引入具有保坍和降黏功能的分子基团,采用不同分子质量的聚醚大单体、丙烯酸、甲基丙烯酸羟乙酯和不饱和功能单体进行自由基共聚常温合成高保坍降黏型聚羧酸减水剂,并探讨了各共聚单体对合成减水剂性能的影响.结果表明,合成高保坍降... 相似文献
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超早强型聚羧酸盐超塑化剂对混凝土早期强度发展的影响 总被引:1,自引:0,他引:1
在优化梳形共聚物分子结构的基础上,开发出一种超早强型聚羧酸盐超塑化剂PCA-V.混凝土试验结果表明,环境温度越低,添加PCA-V后的早强效果越明显.在4℃低温环境下,24h混凝土抗压强度相当于掺普通PCA-I超塑化剂混凝土抗压强度的500%以上,30h抗压强度相当于掺PCA-1的480%. 相似文献
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Khalifa S. Al-Jabri Makoto Hisada Abdullah H. Al-Saidy S.K. Al-Oraimi 《Construction and Building Materials》2009,23(6):2132-2140
This research study was conducted to investigate the performance of high strength concrete (HSC) made with copper slag as a fine aggregate at constant workability and to study the effect of superplasticizer addition on the properties of HSC made with copper slag. Two series of concrete mixtures were prepared with different proportions of copper slag. The first series consisted of six concrete mixtures prepared with different proportions of copper slag at constant workability. The water content was adjusted in each mixture in order to achieve the same workability as that for the control mixture. Twelve concrete mixtures were prepared in the second series. Only the first mixture was prepared using superplasticizer whereas the other eleven mixtures were prepared without using superplasticizer and with different proportions of copper slag used as sand replacement. The results indicated that the water demand reduced by almost 22% at 100% copper slag replacement compared to the control mixture. The strength and durability of HSC were generally improved with the increase of copper slag content in the concrete mixture. However, the strength and durability characteristics of HSC were adversely affected by the absence of the superplasticizer from the concrete paste despite the improvement in the concrete strength with the increase of copper content. All concrete mixtures did not meet the strength and durability design requirements due to the segregation and dryness of the concrete paste. Therefore it can be concluded that the use of copper slag as sand substitution improves HSC strength and durability characteristics at same workability while superplasticizer is very important ingredient in HSC made with copper slag in order to provide good workability and better consistency for the concrete matrix. 相似文献