Fe－40Al合金与Al_2O_3陶瓷的界面润湿现象

本文采用座滴法研究了金属间化合物Ｆｅ－４０Ａｌ与Ａｌ＿２Ｏ＿３陶瓷的润湿性及界面的相互作用，重点考察了温度、保温时间以及合金元素对Ｆｅ－４０Ａ１合金／Ａｌ＿２Ｏ＿３润湿行为和界面反应的影响。     

快速凝固Al-Fe基合金的组织演化和相选择

对Ａｌ－７．８３Ｆｅ,Ａｌ－５．１６Ｆｅ（ｗｔ％）两种Ａｌ－Ｆｅ快凝条带中不同冷速部位组织进行了ＴＥＭ分析,着重考察了Ａｌ－Ｆｅ快凝合金的组织演化演化及其各竞争初生相的析出次序。结果表明,Ａｌ－Ｆｅ合金快凝组织与成分及熔体的冷速有关,对一定成分的合金,当增加其熔体冷速时,亚稳ＡｌｍＦｅ相优先于Ａｌ６Ｆｅ相析出,初生α－Ａｌ相优先金属间化合物相析出,当合金中Ｆｅ含量越低,形成无一金属间化合物的相单－     

Fe—40La及其含Mn或Ti合金的Mossbauer谱

用Ｍｏｓｓｂａｕｅｒ谱研究了Ｂ２结构金属间化合物Ｆｅ－４０Ａｌ及其加Ｍｎ或Ｔｉ量分别为１，５，１０ａｔ．－％的合金，在室温下，Ｆｅ－４０Ａｌ及其合金的Ｍｏｓｓｂａｕｅｒ谱均接近单峰谱线，Ｆｅ原子无明显磁矩。对加入第三组元的Ｆｅ－４０Ａｌ合金的Ｍｏｓｓｂａｕｅｒ谱用最小二乘法拟合为两条洛仑兹曲线之和，认为Ｍｎ原子既占据Ｆ原子位置，也占据Ａｌ原子位置；而Ｔｉ原子优先占据了Ｆｅ原子位置，超过５ａｔ．－％     

Fe—40Al及其含Mn或Ti合金的Mossbauer谱

用Ｍｏｓｓｂａｕｅｒ谱研究了Ｂ２结构金属间化合物Ｆｅ－４０Ａｌ及其加Ｍｎ或Ｔｉ量分别为１，５，１０ａｔ．－％的合金．在室温下，Ｆｅ－４０Ａｌ及其合金的Ｍｏｓｓｂａｕｅｒ谱均接近单峰谱线，Ｆｅ原子无明显磁矩对加入第三组元的Ｆｅ—４０Ａｌ合金的Ｍｏｓｓｂａｕｅｒ谱用最小二乘法拟合为两条洛仑兹曲线之和，认为Ｍｎ原子既占据Ｆｅ原子位置，也占据Ａｌ原子位置；而Ｔｉ原子优先占据Ｆｅ原子位置，超过５ａｔ．－％时，才有少量Ｔｉ原子占据Ａｌ原子位置．     

SiC／Al合金层状复合材料的机械性能及损伤行为

在室温条件下测定了Ａｌ合金以连续层状形式存在于ＳｉＣ陶瓷层间并渗透入ＳｉＣ陶瓷层内、Ａｌ合金浓度呈层状变化高低相间，以及Ａｌ合金和ＳｉＣ陶瓷均匀分布相互渗透三种ＳｉＣ含量相同而结构形式不同的ＳｉＣ／Ａｌ合金复合材料的机械性能；用ＳＥＭ和光学显微镜观察分析了复合材料的断口形貌及裂纹扩展过程。结果表明，在ＳｉＣ陶瓷层间以连续层状形式存在的Ａｌ合金在应力作用下发生较大程度的塑性变形，在裂纹尾部被拉伸和形成桥接，引起能量耗散，减缓裂纹扩展速度，防止裂纹张开，使复合材料的韧性得到明显改善；ＳｉＣ／Ａｌ合金陶瓷─金属层状复合材料的损伤形式主要是ＳｉＣ陶瓷层开裂、金属层桥接和裂纹偏转。     

低密阻尼金属/金属复合体材料的组织与性能研究

采用快速凝固／粉末冶金法成功地研制出Ａｌ－７．０９％Ｆｅ－１．３４％Ｍｏ－１．４５％Ｓｉ（ＦＭＳ０７１４）合金及其金属／金属复合体材料ＦＭＳ０７１４／１５％Ａｌ和ＦＭＳ０７１４／１０％（Ｚｎ－３０％Ａｌ）,考察了其组织、拉伸性能、阻尼性能和密度,产散锻铝ＬＤ７ＣＳ合金进行了对比。结果表明：ＦＭＳ０７１４合金本身就具有较好的拉伸与阻尼性能。添加纯Ａｌ和Ｚｎ－３０％Ａｌ合金粉均使其强度下降,而 ＦＭＷ     

一种新型陶瓷材料及其耐磨性

对新型Ａｌ２Ｏ３－ＴｉＣ－Ｃｏ陶瓷的磨粒磨损，冲蚀磨损及其在单颗粒作用下的摩擦磨损行为进行了研究。与ＡＴ３０（７０ｗｔ％Ａｌ２Ｏ３－３０ｗｔ％ＴｉＣ）陶瓷相比，Ａｌ２Ｏ３－ＴｉＣ－Ｃｏ陶瓷具有更为良好的耐磨性，金属钴的存在提高了基体的韧性，细化了晶粒，其综合力学性能得到了显著提高，ＡＴＣ陶瓷样品耐磨性与其强韧化水平和细致的组织结构有关。     

耐高温陶瓷接头的合金化--用Al/Ni/Al复合层连接Si3N4陶瓷

用Ａｌ／Ｎｉ／Ａｌ复合层真空连接Ｓｉ３Ｎ４陶瓷,研究了Ａｌ与Ｎｉ的匹配对接头显微组织的影响以及影响接头强度的因素。结果表明,当Ａｌ与Ｎｉ的匹配合理并采用适当的连接工艺时,Ａｌ与Ｓｉ３Ｎ４和Ａｌ与Ｎｉ的互扩散和反应可分别获得牢固的结合界面和以Ａｌ３Ｎｉ耐高温相为主的焊缝金属,获得耐高温的陶瓷接头;Ｎｉ的厚度、连接温度及保温时间是影响接头强度的重要参数,它们的最佳值分别为４０μｍ、９００℃和６０ｍｉｎ     

汽车用热镀锌板Fe—Al合金层的研究

用Ｘ射线衍射，萃取碳复型样品的电子衍射等方法对汽车用热镀反Ｆｅ－Ａｌ合金的组织结构进行了分析，结果表明，当锌液中的Ａｌ浓度小于０．１５％时，Ｆｅ－Ａｌ层主要由Ｆｅ２Ａｌ５金属间化合物组成。     

爆炸喷涂Al2O3陶瓷梯度涂层的组织与性能

用爆炸喷涂法制备了Ａｌ２Ｏ３与自熔性合金的陶瓷梯度涂层。结果表明,基体／Ｎｉ６０／２５％Ａｌ２Ｏ３＋７５％Ｎｉ６０／５０％Ａｌ２Ｏ３＋５０％Ｎｉ６０／Ａｌ２Ｏ３的陶瓷梯度涂层具有较好的结合力,较低的残余内应力及和缓的热应力,对粉末及涂层的ＸＲＤ谱分析表明,爆炸喷涂的Ａｌ２Ｏ３陶瓷涂层结构为γ－Ａｌ２Ｏ３,而其粉末结构为α－Ａｌ２Ｏ３,这说明在爆炸喷涂中存在相变过程。爆炸喷涂Ａｌ２Ｏ３陶瓷梯度涂层适合于工作环境较恶劣的热障耐磨涂层。     

A Review on Dissimilar Friction Stir Welding of Copper to Aluminum: Process,Properties, and Variants

Copper and aluminum materials are extensively used in different industries because of its great conductivities and corrosion resistant nature. It is important to join dissimilar materials such as copper and aluminum to permit maximum use of the special properties of both the materials. The joining of dissimilar materials is one of the most advanced topics, which researchers have found from last few years. Friction stir welding (FSW) technology is feasible to join dissimilar materials because of its solid state nature. Present article provides a comprehensive insight on dissimilar copper to aluminum materials joined by FSW technology. FSW parameters such as tool design, tool pin offset, rotational speed, welding speed, tool tilt angle, and position of workpiece material in fixture for dissimilar Cu–Al system are summarized in the present review article. Additionally, welding defects, microstructure, and intermetallic compound generation for Cu–Al FSW system have been also discussed in this article. Furthermore, the new developments and future scope of dissimilar Cu–Al FSW system have been addressed.     

工艺参数和搅拌头尺寸对2024铝合金和AZ31镁合金异种金属搅拌摩擦连接接头性能的影响

研究了2024铝合金与AZ31镁合金的异种搅拌摩擦连接工艺,并获得了良好的3mm板材对接接头。采用5种不同的工艺参数和两种不同尺寸的搅拌头进行加工。研究了不同工艺参数对接头微观组织、拉伸强度和硬度分布的影响。结果表明,使用15mm轴肩的搅拌头能够获得无缺陷的接头,在转速500r/min、连接速度500mm/min的工艺参数下,显微硬度分布均匀,材料边界明显,异种材料间的机械锁和结构增大了接头强度。在转速300r/min、连接速度30mm/min的工艺参数下,拉伸断裂位置位于铝合金一侧的热机影响区和材料混合区的交界处,虽然接头存在金属间化合物,但充分的材料混合使接头拉伸强度与前者相当。     

Interfacial bonding mechanism in Al/coated steel dissimilar refill friction stir spot welds

Defect-free dissimilar Al/zinc coated steel and Al/AlSi coated steel welds were successfully fabricated by refill friction stir spot welding. However, Al alloy and uncoated steel could not be welded under the same welding condition. Al-Zn eutectic layer formed at the Al/zinc coated steel interface showed non-uniformity in thickness and nanoscale intermetallic (IMC) produced was discontinuous. The bonding formation between the Al-Zn layer and the surrounding materials was attributed to a liquid/solid reaction mechanism. Bonding formation at Al alloy and AlSi coated steel interface was attributed to a solid/solid reaction mechanism, as the joining process did not involve with melting of base metals or AlSi coating materials. Kissing bond formed at the weld boundary acted as a crack initiation and propagation site, and the present study showed that weld strength of Al 5754/AlSi coated steel was greatly influenced by properties of original IMC layer.     

Effects of Al-Ni powder addition on dissimilar friction stir welding between AA7075-T6 and 304 L

Friction stir welding between AA7075-T6 aluminum alloy and 304 L stainless steel sheet metal was performed with the addition of Al−Ni powder between the joining interfaces to increase the joining performance. The welding tool was rotated at 200 min⁻¹ to 800 min⁻¹ with the constant traverse speed of 25 mm/min. The resulting joint interfaces were analyzed using a field emission-scanning electron microscope and energy-dispersive x-ray spectroscopy analysis. The tensile strength was greater for the Al−Ni powder added specimens at the lower tool rotational speeds. The tensile strength of 360 MPa was obtained for the ‘with-powder’ specimen as compared to 220 MPa for the ‘without-powder’ specimen at the 200 min⁻¹ tool speed. Electron microscope images of the stir zone showed a significant mixing of the Al−Ni powder with the base materials, increased contact at the interface, which resulted in increased joining strength at the lower tool rotational speeds. However, based on the images, intermetallic compound that may contribute to the joining strength in the vicinity of the interfacial region was not detected.     

The effect of weld parameters on friction stir welding of brass plates

More successful results have been obtained in butt‐ and overlap‐joining of Al‐alloy plates by a recently developed solid state joining technique, namely friction stir welding (FSW), than in more conventional fusion welding processes. In this joining technique, no fusion takes place in the joint area of the plates welded. This novel joining method also offers the potential to weld some other materials rather than Al‐alloys, such as Mg‐alloys, brasses and low strength steels. In this study, the applicability of friction stir welding to brasses, namely 90 %Cu‐10 %Zn and 70 %Cu‐30 %Zn alloys, has been investigated. The joint performance was determined by conducting optical microscopy, microhardness mesurements and mechanical testing (e.g. tensile and bend tests). The effect of welding speed on the joint quality at a given rotational speed of the stirring pin (i.e. 1600 rpm) was also determined for both alloys. The highest joint performances were obtained at a welding speed of 210 mm/min for both alloys.     

Experimental investigation of laser beam welding of explosion-welded steel/aluminum structural transition joints

The steel/aluminum structural transition joints are widely used in shipbuilding industry due to the advantages of joining these two materials with important weight savings while exploiting their best properties. The use of laser welding to strongly connect components made of Fe and Al alloys as base materials with Fe/Al structural transition joints is very attractive. The authors report results achieved during the laser welding of these particular joints with the scope to evaluate effects of the laser-induced thermal loads on the integrity of the Fe/Al bond interface, from metallurgical and mechanical points of view. The increase of both inter-metallic film thickness and extension were detected as a result of the laser beam induced heat on the Fe/Al bond interface. These increases did not cause severe reductions of the mechanical resistance of the investigated structural transition joint.     

Gap-free fibre laser welding of Zn-coated steel on Al alloy for light-weight automotive applications

As a result of new policies related to global warming announced by the European Union, avoiding unnecessary energy waste and reducing environmental pollution levels are becoming a major issue in the automotive industry. Accordingly, the lap welding of Zn-coated steels process, which is commonly used for producing car doors, has been gradually developed to lap welding of Zn-coated steel to light materials, such as Al alloy, Mg alloy and composite materials, in order to effectively reduce the vehicle weight. In certain part of car manufacture, organic glues are used to temporally join the Zn-coated steels and Al alloys before permanent welding takes place. The stability of such temporary joining by glues needs improving. Laser “stitching” or low strength welding could be considered as an alternative. However, challenges exist in joining Zn-coated steel on Al alloy by laser welding, due to significant differences of material properties between the two welding materials. Porosity, spatter and intermetallic brittle phases are readily produced in the weld. In this study, the effects of welding speed, laser power, number of the welding passes and type of shielding gas in gap-free welding of Zn-coated steel on Al alloy were investigated using a 1 kW single mode continuous wave fibre laser. Results show that a weld with higher shear strengths in the laser stitching application and less intermetallic phases could be obtained when nitrogen gas was used as the shielding gas. The corrosion resistance and the surface finish of the weld could be improved in double pass welding, especially when argon gas was used as the shielding gas.     

装配式中空凸轮轴凸轮材料及装配技术研究

研究了装配式中空凸轮轴的两个关键技术:凸轮材料和连接技术.本试验凸轮材料采用铁基粉末冶金材料,并对其工作表面进行宽带激光表面淬火处理.研究结果表明,经激光处理后,材料的耐磨性得到了明显的提高.凸轮与芯轴的连接采用滚花连接技术,对不同齿距的滚花式凸轮轴静连接强度及疲劳强度进行了实验研究.研究结果表明,制成的凸轮轴在静扭时的破坏扭矩约是凸轮轴实际工作扭矩的20～30倍,疲劳破坏方面亦符合工作要求.     

面向电子制造的功率超声微纳连接技术进展

为满足电子制造与封装对新材料与工艺的迫切需求,尤其是高功率、高温服役、高集成度以及高可靠性等新型器件的连接难题,开发了面向电子制造的功率超声微纳连接技术。从固相键合、超声复合钎焊和超声纳米连接3个方面,综述了面向电子制造的功率超声微纳连接技术的原理方法、优势与应用场合。功率超声由于其表面清洁、声流和空化作用,将大幅提升冶金反应速率,有效解决了传统TLP反应温度高时间长,以及Cu和Al等金属的易氧化等问题,甚至攻克了Al2O3,AlN,SiC等陶瓷基板的难润湿以及低温纳米颗粒烧结驱动力不足的难题。综述了该领域多年来的研究成果,聚焦电子制造中的功率超声微纳连接技术,从固相连接领域的引线键合、室温超声金属连接和超声增材制造,到钎焊领域的超声低温软钎焊、超声中高温连接以及超声瞬态液相连接,最后针对第三代半导体高功率器件简述了超声纳米连接,探讨了功率超声微纳连接技术的研究进展及趋势。     

SiC/Al层状梯度复合材料的制备与抗毁伤特性

用真空热压法制备了SiC/Al层状梯度复合材料;采用热压扩散工艺,实现了不同SiC含量的复合材料间的有效连接.实验表明SiC/Al层状梯度复合材料制备时,添加纯铝过渡层有助于提高层间结合强度.通过穿甲试验对SiC/Al层状复合材料的抗毁伤性能进行了分析,结果表明所制备的SiC/Al层状复合材料具有比纯铝材料更为良好的抗毁伤性能.