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1.
This work investigates the ability of 1‐ethyl‐3‐methylimidazolium methanesulphate ([EMIM][MeSO3]) as a green and tuneable solvent for denitrification and desulphurisation studies. Experimental density, surface tension and refractive index data have been measured for the following systems: [EMIM][MeSO3] (1) + pyridine (2), [EMIM][MeSO3] (1) + pyrrole (2), [EMIM][MeSO3] (1) + quinoline (2), [EMIM][MeSO3] (1) + indoline (2), [EMIM][MeSO3] (1) + thiophene (2) and [EMIM][MeSO3] (1) + water (2) over the entire mole fraction of [EMIM][MeSO3] at T = 298.15–323.15 K and P = 1 bar. Further from experimental density, surface tension and refractive index, coefficient of thermal expansivity, excess molar volume, deviation of surface tension and refractive index deviation were also calculated. It was found that the heteroaromatic nitrogen/sulphur compounds are completely miscible in [EMIM][MeSO3]. The surface tension values were found to increase while the refractive index decreases with increasing mole fraction of [EMIM][MeSO3]. The experimental values for surface tension increased in the order: pyridine > thiophene > pyrrole > indoline > quinoline > water and for refractive index: pyridine > pyrrole > indoline > quinoline > thiophene > water. It was found that the composition of [EMIM][MeSO3] has a greater influence than temperature in deciding the surface, optical and thermodynamic properties for similar molecular interaction such as IL–thiophene and IL–pyrrole than dissimilar molecules such as IL–water. Further quantum chemical‐based COSMO‐RS tool was used to estimate the activity coefficient at different composition. © 2012 Canadian Society for Chemical Engineering 相似文献
2.
Chengmin Gui Ruisong Zhu Minghao Song Guoxuan Li Zhigang Lei 《American Institute of Chemical Engineers》2023,69(11):e18180
A new methyl chloride (CH3Cl) capture and dehydration process using two ionic liquids (ILs) was designed and systematically studied. ILs [EMIM][Ac] and [EMIM][BF4] were screened out as CH3Cl capture and drying absorbents through the COSMO-RS model. The result of solubility experiment suggests [EMIM][Ac] has an excellent solvent capacity for CH3Cl at mild operation conditions. The bench-scale CH3Cl absorption experiments further confirmed the outstanding CH3Cl capture ability of [EMIM][Ac]. Besides, the water content of outlet gas can be decreased to 452 ppm (mass fraction) using [EMIM][BF4] in the dehydration experiment. The industrial-scale CH3Cl capture and dehydration process was simulated and optimized. Compared to the benchmarked triethylene glycol process, IL process has higher product purity (99.99 wt%), and lower energy consumption. The quantum chemical calculations clearly revealed the relationship between hydrogen bond and separation performance. This study provides a decision-making basis for designing green process associated with volatile organic compounds. 相似文献
3.
Ramalingam Anantharaj Tamal Banerjee 《American Institute of Chemical Engineers》2013,59(12):4806-4815
The tie‐line composition of three quaternary system namely 1‐ethyl‐3‐methylimidazolium acetate ([EMIM][OAc]) ([EMIM][OAc]) (1) + thiophene (2) + pyridine (3) + toluene (4), 1‐ethyl‐3‐methylimidazolium ethylsulphate ([EMIM][EtSO4]) (1) + thiophene (2) + pyridine (3) + toluene (4), 1‐ethyl‐3‐methylimidazolium methylsulphonate ([EMIM][MeSO3]) (1) + thiophene (2) + pyridine (3) + toluene (4) were experimentally determined at 298.15 K. The measured tie‐line data were successfully correlated with the nonrandom two liquid and UNIversal QUAsiChemical model prediction which gave less than 1% root mean square deviation (RMSD). [EMIM][MeSO3] looks to be a promising solvent for the simultaneous separation having distribution ratios less than unity for both thiophene and pyridine. The quantum chemical‐based conductor like screening model for real solvent (COSMO‐RS) model was then used to predict the tie‐line composition of quaternary systems. COSMO‐RS gave the RMSD for the studied systems to be 8.41, 8.74, and 6.53% for the ionic liquids, respectively. © 2013 American Institute of Chemical Engineers AIChE J, 59: 4806–4815, 2013 相似文献
4.
Qian Wang Xingmei Lu Xueyuan Zhou Minli Zhu Hongyan He Xiangping Zhang 《应用聚合物科学杂志》2013,129(6):3574-3581
Series of 1‐allyl‐3‐methylimidazolium halometallate ionic liquids (ILs) were synthesized and used to degrade poly(ethylene terephthalate) (PET) as catalysts in the solvent of ethylene glycol. One important feature of these new IL catalysts is that most of them, especially [amim][CoCl3] and [amim][ZnCl3], exhibit higher catalytic activity under mild reaction condition, compared to the traditional catalysts [e.g., Zn(Ac)2], the conventional IL catalysts (e.g., [bmim]Cl), Fe‐containing magnetic IL catalysts (e.g., [bmim][FeCl4]), and metallic acetate IL catalysts (e.g., [Deim][Zn(OAc)3]). For example, using [amim][ZnCl3] as catalyst, the conversion of PET and the selectivity of bis(hydroxyethyl) terephthalate (BHET) reach up to 100% and 80.1%, respectively, under atmospheric pressure at 175°C for only 1.25 h. Another important feature is that BHET can be easily separated from the catalyst and has a high purity. Finally, based on the experimental phenomena, in ‐situ infrared spectra, and experimental results, the possible mechanism of degradation with synthesized IL is proposed. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013 相似文献
5.
Rupeng Bu Xiaoqing Zhou Qi Huang Yanwu Yu Hongzhen Li 《Propellants, Explosives, Pyrotechnics》2017,42(12):1347-1351
The solubility of insensitive explosive 2,6‐diamino‐3,5‐dinitropyrazine‐1‐oxide (LLM‐105) in dimethyl sulphoxide (DMSO), N,N‐dimethylformamide (DMF), N‐methyl‐2‐pyrrolidone (NMP), N,N‐diethylformamide (DEF), 1,4‐dioxane, 1,4‐butyrolactone, ethyl acetate and 1‐butyl‐3‐methylimidazolium trifluoromethanesulfonate ([Bmim]CF3SO3), were measured by a polythermal method in the temperature range of 293.15 K to 375.15 K at the atmospheric pressure. The solubility of LLM‐105 decreased in the order of DMSO, NMP, DMF, DEF, 1,4‐butyrolactone, [Bmim]CF3SO3, 1,4‐dioxane, ethyl acetate. With higher temperature, the solubility of LLM‐105 increased in all solvents. The solubility data was correlated against temperature with the modified Apelblat equation and Ideal solution model. In addition, the dissolution enthalpy, entropy, and mole Gibbs free energy of LLM‐105 in each solvent were also calculated from the experimental solubility data by using van′t Hoff equation with the temperature dependence. The results show that the dissolution process of LLM‐105 in these solvents is endothermic and the mechanism is the entropy‐driving. DMSO is suggested as the appropriate solvent for the cooling crystallization or drowning‐out crystallization of LLM‐105. 相似文献
6.
Promoted adsorption of CO2 on amine‐impregnated adsorbents by functionalized ionic liquids
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Amine‐impregnated adsorbents are promising alternatives to aqueous amines for CO2 capture. However, the diffusion‐controlled CO2 adsorption process is a significant issue associated with them, resulting in the insufficient utilization of amine groups. Herein, we propose the use of functionalized ionic liquids 1‐ethyl‐3‐methylimidazolium acetate ([emim][Ac]) with chemical reactivity to CO2 and low viscosity as the additive to amine‐impregnated adsorbents. The key is that [emim][Ac] does not show drastic increase in viscosity after reacting with CO2. Taking the polyethyleneimine (PEI)‐impregnated SBA‐15 as a model system, it is found that the CO2 capacities of PEI/SBA‐15 composites are improved by 86%, and the active site efficiencies are improved by 270%, after the addition of [emim][Ac]. The addition of [emim][Ac] to PEI/SBA‐15 composites also helps improve the CO2 adsorption rate and recycling stability of composites. Therefore, [emim][Ac] offers the opportunity to fabricate amine‐impregnated adsorbents with simultaneously improved CO2 capacities, adsorption kinetics, and recycling stability. © 2018 American Institute of Chemical Engineers AIChE J, 64: 3671–3680, 2018 相似文献
7.
Jingli Han Chengna Dai Zhigang Lei Biaohua Chen 《American Institute of Chemical Engineers》2018,64(2):606-619
The gas drying technology with ionic liquids (ILs) was systematically studied ranging from the molecular level to industrial scale. The COSMO‐RS model was first used to screen the suitable IL and provide theoretical insights at the molecular level. Toward CO2 gas dehydration, we measured the CO2 solubility in single [EMIM][Tf2N] and in the [EMIM][Tf2N] + H2O mixture, as well as the vapor‐liquid equilibrium (VLE) of [EMIM][Tf2N] + H2O system, to justify the applicability of UNIFAC model. Based on the thermodynamic study, the rigorous equilibrium (EQ) stage mathematical model was established for process simulation. The gas drying experiment with IL was also performed and the water content in gas product can be reduced to 375 ppm. It was confirmed that a less flow rate of absorbent, a higher CO2 recovery ratio and a much lower energy consumption can be achieved with IL than with the conventional triethylene glycol (TEG). © 2017 American Institute of Chemical Engineers AIChE J, 64: 606–619, 2018 相似文献
8.
CO2 permeation through imidazolium-based ionic liquids (ILs, [BMIM][Ac], [EMIM][Ac], [OMIM][Ac], [BMIM][BF4], and [BMIM][PF6]) confined in 1.0, 2.0, and 3.5?nm γ-alumina pores was investigated using molecular dynamics simulation. It was found that the nanopore confinement effect influenced the structure of confined ILs greatly, resulting in a layered structure and anisotropic orientation of ILs. In the center of 2.0-nm pore, the long alkyl chain of [BMIM]+ tended to be parallel to the wall, providing a straight diffusion path benefiting the CO2 permeation. The CO2 diffusion coefficients in confined [EMIM][Ac], [BMIM][Ac], and [OMIM][Ac] were 2.3–4.1, 2.4–6.4, and 14.4–21.7?×?10?10?m2?s?1, respectively. This order was opposite to that in the bulk ILs, because the longer alkyl chain led to a more ordered structure, facilitating CO2 diffusion. In addition, the CO2 solubilities were 445–722?mol?m?3?MPa?1 for the five ILs confined in 1.0?nm pore, which were larger than those in 2.0 and 3.5?nm pores (196–335?mol·m?3?MPa?1), due to the larger free volume. Both parallel orientation of alkyl chain and large free volume could increase the CO2 permeability in confined ILs. 相似文献
9.
蔡涛 《纤维素科学与技术》2011,19(4):22-27
采用离子液体1-乙基-3-甲基咪唑醋酸盐([EMIM]Ac)为溶剂,制备了纤维素/[EMIM]Ac溶液,研究了该体系的流变性能,利用干喷湿纺的方式制备的新型再生纤维素纤维,并对纤维的结构与性能进行了分析。结果表明,纤维素/[EMIM]Ac溶液为典型的切力变稀流体,在较高剪切速率下,纺丝溶液的黏度变化较小;由该体系制备的新型再生纤维素纤维具有纤维素Ⅱ晶型的结构;随着拉伸比的提高,纤维的取向程度及结晶度增大,纤维力学性能提高。以离子液体为溶剂制备的再生纤维素纤维表面光滑,质地紧密。 相似文献
10.
Hong‐Zhang Chen Ning Wang Li‐Ying Liu 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2012,87(12):1634-1640
BACKGROUND: Currently, cellulose membranes are prepared by cellulose acetate hydrolysis or chemical derivatization dissolution and regeneration using cotton pulp or wood pulp. In this study, the concept ‘lignocelluloses biorefinery’ was used, and good quality long fiber was fractionated from wheat straw using clean technologies. The objective of this study is to develop wheat straw cellulose to prepare regenerated cellulose membrane with ionic liquid 1‐butyl‐3‐methylimidazolium chloride ([BMIM]Cl) as solvent. RESULTS: Wheat straw cellulose (WSC) fractionated from wheat straw contained 93.6% α‐cellulose and the degree of polymerization (DP) was 580. WSC was dissolved directly without derivatization in [BMIM]Cl. With increase in dissolving temperature, the DP of the regenerated cellulose dropped, which resulted in a decrease in the intensity of regenerated cellulose membrane. After regeneration in [BMIM]Cl, the WSC transformed from cellulose I to cellulose II, and the crystallinity of the regenerated cellulose was lower than the original cellulose. The regenerated WSC membrane had good mechanical performance and permeability, the tensile strength and breaking elongation were 170 MPa and 6.4%, respectively, the pure water flux was 238.9 L m?2 h?1 at 0.3 MPa pressure, and the rejection of BSA was stabilized at about 97%. CONCLUSION: Wheat straw cellulose fractionated from wheat straw satisfied the requirement to prepare regenerated cellulose membrane using ionic liquid [BMIM]Cl as solvent. Copyright © 2012 Society of Chemical Industry 相似文献
11.
两种咪唑型离子液体对纤维素的溶解及纺丝性能的比较 总被引:4,自引:2,他引:2
以1-乙基-3-甲基咪唑醋酸盐([EMIM]Ac)和1-丁基-3-甲基咪唑氯盐([BMIM]CI)两种咪唑型离子液体为溶剂,研究比较了它们对纤维素的溶解性能及其溶液的纺丝加工性能。结果发现:两种离子液体均能在一定条件下溶解纤维素,但[EMIM]Ac较[BMIM]Cl对纤维素具有更低的溶解温度和更快的溶解速率。从流变分析还发现:纤维素/[EMIM]Ac溶液与纤维素/[BMIMCl溶液均为切力变稀流体,相同条件下纤维素/[EMIM]Ac溶液的黏度远低于纤维素/[BMIM]Cl溶液,使其可在相对低的温度下纺丝。此外,GPC分析结果表明:纤维素在用[EMIM]Ac溶解及纺丝过程中降解程度较小,而用[BMIM]Cl进行溶解纺丝时,降解作用则较明显。对纤维结构与力学性能的分析结果进一步表明:与相同喷头拉伸比下制得的[EMIM]Ac法再生纤维素纤维相比,[BMIM]Cl法再生纤维素纤维的聚集态结构相对较完善,结晶度与取向度更高些,从而使其力学性能也相对较好。 相似文献
12.
Effect of small amount of water on the dynamics properties and microstructures of ionic liquids
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Jing Zhou Xiaomin Liu Suojiang Zhang Xiangping Zhang Guangren Yu 《American Institute of Chemical Engineers》2017,63(6):2248-2256
A series of systems of 1‐butyl‐3‐methylimidazolium acetate ([Bmim][Ac]), 1‐butyl‐3‐methylimidazolium tetrafluoroborate ([Bmim][BF4]), and 1‐butyl‐3‐methylimidazolium bis(trifluoromethylsulfonyl)imide ([Bmim][Tf2N]) with a small amount of water were simulated. Viscosities of systems were obtained by nonequilibrium molecule dynamics simulation and the results show that the viscosities change in different ways: for [Bmim][BF4] and [Bmim][Tf2N], viscosities decrease rapidly in the first stage, and then decrease slowly with the increase of water content. But for [Bmim][Ac], the viscosities increase first and then decrease. The unique phenomenon of [Bmim][Ac] can be attributed to the formation of chain‐like structure of anion???water???anion???. Hydrogen bond (HB) interaction between ion pairs is weakened, but the number of HB between water and anions increases with increase of water content. Besides, the microstructures of water in ionic liquids‐water systems were compared and found that the distribution of water is more concentrated in [Bmim][Tf2N]‐H2O system, while it is isotropy in [Bmim][Ac]‐H2O system. © 2016 American Institute of Chemical Engineers AIChE J, 63: 2248–2256, 2017 相似文献
13.
Dissolution and utilization of chitosan in a 1‐carboxymethyl‐3‐methylimidazolium hydrochloride ionic salt aqueous solution
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1‐Carboxymethyl‐3‐methylimidazolium hydrochloride ([IMIM–COOH]Cl), a new ionic salt, is proposed as a green, promising solvent for dissolving chitosan. However, because of the optimal dosage of chitosan dissolved in [IMIM–COOH]Cl, a 12 wt % [IMIM–COOH]Cl aqueous solution was selected as an optimum solvent system for dissolving chitosan. The structures of the original and regenerated chitosan were characterized by Fourier transform infrared spectroscopy and X‐ray diffraction analysis. Scanning electron microscopy was used to visualize the morphological features of the reconstituted chitosan membranes. Meanwhile, the absorbance, tensile strength, and breaking elongation of the chitosan membranes were measured. The results reveal that 10–11 wt % was an optimal chitosan concentration for preparing membranes. Furthermore, the adsorption capacity for Cu(II) ion of the chitosan membranes was increased with the chitosan concentration decreased from 12 to 8 wt %. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 41965. 相似文献
14.
采用离子交换法, 以1-丁基-3-甲基氯代咪唑([BMIM]Cl)为原料合成了咪唑醋酸盐型离子液体([BMIM]Ac), 以两者为溶剂研究了胶原纤维在咪唑类离子液体中的溶解行为及再生前后的结构与热稳定性变化。结果表明, 胶原纤维在CH3COO-和Cl-型离子液体中均能溶解, 但具有明显不同的溶解特性。相对[BMIM]Cl的溶解性能而言, [BMIM]Ac能够在较低的温度下获得高浓度和良好流动性的胶原溶液, 而且再生胶原的三股螺旋结构保留度更高。FTIR、UV、XRD、CD、TG分析结果表明, 胶原在咪唑离子液体中溶解前后其化学结构未发生明显变化, 而三股螺旋的保留度和热稳定性略有降低。 相似文献
15.
A soluble polyimide was synthesized from 2,2′‐bis[4‐(3,4‐dicarboxyphenoxy)phenyl]propane dianhydride (BPADA) and 3,3′‐dimethyl‐4,4′‐diaminodiphenylmethane (DMMDA) by a two‐step method, and it had good solubility both in strong bipolar solvents and in common low‐boiling‐point solvents. The BPADA–DMMDA polyimide was dissolved in chloroform (CHCl3) and cast onto a glass substrate in a humid atmosphere. The BPADA–DMMDA/CHCl3 solution easily formed honeycomb films. Some affecting factors, such as the polymer solution concentration, atmospheric humidity, and solvent volatility, were tested. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
16.
Continuous Gas Dehydration Using the Hygroscopic Ionic Liquid [EMIM][MeSO3] as a Promising Alternative Absorbent
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Continuous gas drying experiments with the hygroscopic ionic liquid [EMIM][MeSO3] show that it can be a very promising alternative drying agent to the absorbent triethylene glycol (TEG) commonly used in industrial gas drying processes. The HTU/NTU model in combination with the correlations of Onda et al. for mass transfer coefficients can be applied for the design of an absorption process with [EMIM][MeSO3]. The major advantage of this ionic liquid (IL) is that well‐known problems associated with the regeneration of the absorbent TEG can be avoided using [EMIM][MeSO3] due to extremely low vapor pressure and possible regeneration with air. The drying capacity of the IL system is about two times higher compared to TEG. Hence, a simple plant design comparable to that of industrial adsorption plants might be applied. 相似文献
17.
Crosslinked poly (4‐vinylpyridine)‐supported azide ion was used as an effective azidating agent for deazodination of stable arenediazonium salts under solvent‐free conditions in high yields. The diazotization of aromatic amines was prepared by grinding the combination of an aromatic amine, sodium nitrite (NaNO2), p‐toluene sulfonic acid (p‐TsOH), and 0.2 mL H2O in a mortar. Grinding was continued for deazodination–azidation of the obtained relatively stable diazonium salts, with addition of crosslinked poly (4‐vinylpyridine) supported azide ion to obtain the corresponding aryl azides. The spent polymeric reagents can usually be removed and regenerated. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2012 相似文献
18.
Chemical solvent in chemical solvent: A class of hybrid materials for effective capture of CO2
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Feng‐Feng Chen Kuan Huang Jie‐Ping Fan Duan‐Jian Tao 《American Institute of Chemical Engineers》2018,64(2):632-639
Amino acid ionic liquids (AAILs) are chemical solvents with high reactivity to CO2. However, they suffer from drastic increase in viscosity on the reaction with CO2, which significantly limits their application in the industrial capture of CO2. In this work, 1‐ethyl‐3‐methylimidazolium acetate ([emim][Ac]) which also exhibits chemical affinity to CO2 but low viscosity, and its viscosity does not increase drastically after CO2 absorption, was proposed as the diluent for AAILs to fabricate hybrid materials. The AAIL+[emim][Ac] hybrids were found to display enhanced kinetics for CO2 absorption, and their viscosity increase after CO2 absorption are much less significant than pure AAILs. More importantly, owing to the fact that [emim][Ac] itself can absorb large amount of CO2, the AAIL+[emim][Ac] hybrids still have high absolute capacities of CO2. Such hybrid materials consisting of a chemical solvent plus another chemical solvent are believed to be a class of effective absorbents for CO2 capture. © 2017 American Institute of Chemical Engineers AIChE J, 64: 632–639, 2018 相似文献
19.
N-ethyl-imidazolium-based alkylphosphate ionic liquid (IL), viz. N-ethyl-N-methyl-imidazolium dimethylphosphate ([EMIM][DMP]), N-ethyl-N-ethyl-imidazolium diethylphosphate ([EEIM][DEP]) and N-butyl-N-ethyl-imidazolium dibutylphosphate ([BEIM][DBP]) were demonstrated to be effective for the removal of aromatic sulfur compounds (S-compound) 3-methylthiophene (3-MT), benzothiophene (BT) and dibenzothiophene (DBT) from fuel oils in terms of sulfur partition coefficients (KN) at 298.15 K. It was shown that the extractive ability of the alkylphosphate ILs was dominated by the structure of the cation and followed the order [BEIM][DBP] > [EEIM][DEP] > [EMIM][DMP] for each S-compound studied with their KN-value being 1.72, 1.61 and 1.17, respectively for DBT. For a specified IL the sulfur selectivity followed the order DBT > BT > 3-MT with their KN-value being 1.61, 1.39 and 0.78, respectively for [EEIM][DEP]. The alkylphosphate ILs are insoluble in fuel while the fuel solubility in ILs varies from 20.6 mg(fuel)/g(IL) for [EMIM][DMP] to 266.9 mg(fuel)/g(IL) for [BEIM][DBP]. The results suggest that [EEIM][DEP] might be used as a promising solvent for the extractive desulfurization of fuel, considering its higher sulfur extractive ability, lower solubility for fuel and thus negligible influence on the constituent of fuel, and the ease of regeneration for the spent IL via water dilution process. 相似文献
20.
Adam McNeeley Chang-Che Tsai Shiang-Tai Lin Y. A. Liu 《American Institute of Chemical Engineers》2023,69(2):e17888
There is industrial incentive to extract aromatics from ethylene cracker feeds, but the conventional sulfolane solvent was found not economical by Meindersma and coworkers. Ionic liquids (ILs) have long been considered alternative aromatic extraction solvents. This work develops energy-optimum aromatic extraction processes for an ethylene cracker feed using IL solvents. We avoid pitfalls of using simplified feeds and a priori thermodynamic property estimates, with the largest set of experimentally regressed UNIQUAC binary parameters for the IL, 1-ethyl-3-methylimidazolium bis([trifluoromethyl]sulfonyl)imide ([EMIM][NTf2]). We screen process energy and operating conditions for [EMIM][NTf2] and sulfolane at varying aromatic feed contents and find [EMIM][NTf2] favorable at low aromatic feed contents. Adding light and heavy components of the ethylene cracker feed necessitates process modifications. Our novel steam-assisted extractive distillation developed for [EMIM][NTf2] is also suitable for sulfolane. We show that the [EMIM][NTf2] solvent can reduce 10.7% of energy consumption compared to sulfolane using the same novel process. 相似文献