Synthesis, Characterization and Fluorescence Properties of Europium, Terbium Complexes with Biphenyl-4-Carboxylic Acid and o-Phenanthroline

Two series of solid complexes of europium and terbium with biphenyl 4-carboxylic acid and phen were synthesized and characterized in this report. Their elemental analysis, molar conductivities and TG-DTA studies indicate that the complexes have the composition of Eu(phen)L3·1/2H2O, Eu0.5RE0.5(phen)L3·1/2H2O; Tb(phen)L3·H2O and Tb0.5RE0.5(Phen)L3·1/2H2O. (RE=Y3 , La3 and Gd3 ; L=biphenyl 4-carboxylic acid; phen=o-Phenanthroline). The studies of their IR, UV 1H NMR and molar conductivities demonstrate that biphenyl 4-carboylic acid is bounded with RE(Ⅲ) ion. Rare earth ions coordinate with two nitrogen atoms of phen molecules directly in these rare earth complexes. The fluorescence spectra and fluorescence lifetimes of the rare earth complexes show that the fluorescent intensity and lifetime of a series of europium complexes are longer than those of the series of terbium complexes as having the some ligands. There are better fluorescent intensity and lifetime of hetero-nuclear rare earth complexes than homo-nuclear rare earth complexes for europium complexes. The fluorescence emission intensity of Eu3 is raised by inert fluorescent rare earth ions (Y3 , Gd3 and La3 ), but in Tb3 hetero-nuclear rare earth complexes the intensity of Tb3 ions are quenched by the inert fluorescent rare earth ions.     

Synthesis,crystal structures of novel complexes of rare earth with norfloxacin,interaction with DNA and BSA

Three novel rare earth complexes [N(CH 3) 4 ][Ln(NF) 4 ]·6H 2 O(Ln=Nd(III)(1),Sm(III)(2),Ho(III)(3)) were synthesized using hydrothermal method from norfloxacin HNF=1-ethyl-6-fluoro-1,4-dihydro-4-oxo-7-(1-piperazinyl)-3-quinoline carboxylic acid,C 16 H 18 FN 3 O 3),imidazole and rare earth nitrates.The complexes were characterized by elemental analysis,FT-IR,TG-DTG and X-ray single crystal diffraction.Each rare earth ion was eight-coordinated with carboxyl-O atoms and keto-O atoms from norfloxacin.Four of the norfloxacin ions acted as bidentate chelate group took part in the coordination with rare earth ion.The structures of complexes were tetragonal system with space group I4 1 /acd,which were allomerism.The interaction between complex 1 and DNA was studied by electronic absorption spectra and fluorescence spectroscopy.The binding interaction between the complex 1 and bovine serum albumin(BSA) was studied by fluorescence spectroscopy.The complex 1 bound to DNA by the mode of partial intercalation.Complex 1 had a strong ability to quench the fluorescence from BSA.The complex interaction was mainly a static quenching process with BSA together with formation of two binding sites.     

Synthesis, Catalysis of Rare Earth Complexes with Aliphatic Noncyclic Polyether-Amino Acid Schiff Base

Coordination chemistry of rare earth with Schiffbase has developed rapidly in the last fewyears ,butthe majority of the complexes studied are derivedfromaromatic Schiff base .So far less papers of rare earthcomplex with aliphatic Schiff base have been rep…     

Synthesis and Fluorescence Property of Eu^3 ＋ , Tb^3＋ Perchlorate Complexes with Diphenyl Sulfoxide and 1,10-Phenanthroline

Eu3 ,Tb3 canemitfluorescenceinconjugatedsystemcontainingorganicligand[1,2 ] ,forexample ,1 ,1 0 phenanthroline ,becauseithasbettercoordina tionabilityandbiggerconjugationsystem ,soitcantransmitenergyeffectivelytoEu3 ,Tb3 ,leadingtofluorescenceemission ,andthestabilityisveryhigh ,butsolubilityisverypoor .Inaddition ,diphenylsul foxidehasbettercoordinationabilityandbiggerconju gationsystem ,too .Soitcanalsotransmitenergyef fectivelytoEu3 ,Tb3 ,resutlinginfluorescencee mission ,andsolubi…     

Synthesis, characterization and properties of some rare earth complexes with 2,6-pyridine dicarboxylic acid and α-Picolinic acid

Five novel ternary complexes were synthesized by the rare earth with 2,6-pyridine dicarboxylic acid andα-picolinic acid.These complexes were characterized by elemental analysis,molar conductivity,FT-IR,UV-Vis,Raman,TG-DTA and XRD.The general formula of the complexes was[RE(DPA)(L α )(H2O)]·2H2O(RE=Pr 3+ ,Nd 3+ ,Sm 3+ ,Eu,Er 3+ ;DPA=2,6-pyridine dicarboxylic acid;L α =α-picolinic acid). The investigation of fluorescence properties of the Eu-complex showed that the Eu(III)ion could be sensitized efficiently by the ligand to some extent.The antibacterial activity test indicated that all the five complexes exhibited antibacterial ability against Escherichia coli and Staphylococcus aureus with broad antimicrobial spectrums.     

Eu(TTA)2(phen)(UAH)/SiR Fluorescence Materials Prepared by In-Situ Reaction Method

Eu(TTA)2(phen)(UAH) (UAH=undecylenic acid)with fine fluorescent property and active group was synthesized. The measurement and characterization of complexes were also carried out. A series of composites based silicon rubber were prepared by blending silicon rubber and Eu(TTA)2(phen)(UAH) rare earth complex with active groups. Next, the effect of vulcanizing time on the property of materials was mainly studied. The results show that the dispersed particle size of rare earth complexes decreases gradually in the vulcanizing process.     

Studies on synthesis and fluorescent property of rare earth complexes RE（ABMF）2AA and copolymers RE（ABMF）2AA-co-MMA

Four new complexes RE(ABMF)2AA (RE=Sm, Eu, Tb, Dy) were synthesized by the reaction of RECl3·6H2O with acrylic acid (HAA) and 1-(2-furyl)-3-phenyl-1,3-propanedione (ABMF). The copolymerization of the rare earth complexes with methyl methacrylate was studied by using 2,2-azobis-isobutyronitrile as an initiator. The composition and structure of the four complexes were characterized by elemental analysis, UV-vis and FTIR. The glass transition temperature and molecular weight of the copolymers were determined. Photoluminescent measurement showed that ligand ABMF could efficiently transfer the energy to Sm3+ and Eu3+ ions in the complexes and sensitize the luminescence of the rare earth ions, but could not sensitize Tb3+ and Dy3+ ions. As a result, both Sm3+ and Eu3+ complexes emitted the characteristic fluorescence of Sm3+ and Eu3+ ions due to the f-f transitions. The four copolymers could emit strong fluorescence of the rare earth ions.     

稀土钼合金力学和热发射性能的研究

稀土氧化物 (La2 O3 、Y2 O3 )在强化钼的同时 ,对钼具有显著的韧化作用 ,即具有综合强韧化作用。稀土钼材作为高温结构材料正逐步取代Al Si K掺杂钼 (ASK)和TZM钼合金 ;通过成分设计和加工工艺优化 ,稀土钼还是一种工作温度低、无放射性污染的新型阴极材料 ,由稀土钼作为阴极的电子管 ,发射性能与寿命均达到或超过同类型W ThO2 阴极电子管 ,达到实用化水平。因此 ,稀土钼作为一种集结构与功能于一身的新型材料 ,有广泛的应用前景     

Preparation of Eu （ TTA ）2 phen （ MA ）/SiR Fluorescent Materials under High Mechanical Blending Temperature

Eu（TTA）2（phen）（MA） complexes were synthesized, in which MA was introduced as the acidic ligand to increase the fluorescent intensity of the complexes. The complexes were characterized by scanning electron microscopy （SEM）, X-ray diffraction （XRD）, and fluorescent spectra, respectively. Different amounts of rare earth complexes were blended with silicon rubber over the melting point of Eu （TTA） 2 （phen） （MA）. Next, a definite amount of 2,5-dimethyl-2, 5-di （tert-butylperoxy） hexane was added as a cross linker to the composite, to get the uncured composites. Subsequently, the composites were vulcanized at 160℃, and silicon rubber-based composites with different contents of the complexes were prepared and their fluorescent properties were observed. The contents of rare earth complexes were 0.96 %, 2.83 %, 4.63 % and 6.36 % （mass fraction）, respectively. Moreover, the composites of Eu （TTA） 2 （phen） （ MA ）/SiR were measured by SEM, XRD, and fluorescent spectra. The measurement result shows that the fluorescent intensity of uncured rubber is similar to one of the pure rare earth complexes. However, there is no marked change of fluorescent intensity in the uncured rubber when the content of rare earth complexes continues to increase.     

Influence of Blending Temperature on Fluorescence Properties of Silicone Rubber Matrix Eu(TTA)2(phen)(MA) Composites

A series of fluorescent composites were prepared by blending silicone rubber with Eu(TTA)2(phen)(MA). The influence of mechanical blending temperature on fluorescent intensity of composites and dispersion of rare earth complexes in the SiR matrix were investigated. As for the cured rubber, it is found that its fluorescent intensity is relatively low compared with that of uncured rubber. Low temperature is beneficial to dispersion of Eu(TTA)2(phen)(MA) homogeneously. When the amount of rare earth complexes is low, the fluorescent intensity of composites prepared by mechanical blending method above melting point of Eu(TTA)2(phen)(MA) is much higher than that of composites prepared below melting point.     

Synthesis, characterization and antitumor activity of rare earth （Y, La） substituted phosphotungstates containing 5-fluorouracil

Two rare earth substituted Keggin-type phosphotungstates containing 5-fluorouracil,K10C4H4FN2O2Y(PW11O39)2·10H2O(FYPW) and K9(C4H4FN2O2)2La(PW11O39)2·18H2O(FLaPW)were synthesized in aqueous solution,and the structures were characterized by Fourier transform infrared spectroscopy(FT-IR),element analysis,inductively coupled plasma spectrometry(ICP),X-ray powder diffraction(XRD) and 1 H nuclear magnetic resonance(NMR).Thermal analysis showed that the decomposition processes of the two compounds could be divided into three steps,the loss of crystal water,the decomposition of 5-fluorouracil unit and the decomposition of Keggin-type polyanions. The in vitro cytotoxicities against HEK 293,HeLa and HepG-2 cells were studied by methyl thiazolyl tetrazolium(MTT)assay.The results showed that FYPW and FLaPW had higher antitumor activities than 5-fluorouracil,C4H4FN2O2H2PW12O40·8H2O and rare earth substituted polyoxometalates K11Ln(PW11O39)2·nH2O(Ln=Y,La).It was concluded that introducing 5-fluorouracil and rare earth(Y or La)into its structure was a considerable way to enhance antitumor activities of polyoxometalates.     

稀土元素Ce对Cu-Al2O3复合材料组织及性能的影响

采用机械合金化与放电等离子烧结的方法制备了不同质量分数的Cu-Al₂O₃-Ce复合材料,研究了稀土元素Ce对Cu-Al₂O₃复合材料显微组织形貌及硬度、抗拉强度、导电率、摩擦磨损等物理性能的影响。结果表明:Cu-Al₂O₃-Ce复合材料中的陶瓷颗粒更加均匀弥散的分布在基体中;加入稀土元素Ce后的Cu-Al₂O₃-Ce复合材料硬度为HV 108.2、拉伸强度为301 MPa、断面伸长率为19.6%、导电率为54.51 MS·m-1,与Cu-Al₂O₃相比有明显提升;Cu-Al₂O₃的磨损机理主要为磨粒磨损,Cu-Al₂O₃-Ce主要为黏着磨损,当摩擦速率较大时,Cu-Al₂O₃-Ce的摩擦系数和体积磨损率更小,耐磨性能优于Cu-Al₂O₃。     

Synthesis, Characterization of α-Oxopentanedioic Acid-Isonicotinoyl Hydrazone Rare Earth-Complexes and Relaxivity of Gd-complex

Themagneticresonanceimaging (MRI)tech niqueforthemedicineisveryusefultodiagnosepre tumorandbloodvesseldiseaseinheartandbrainandothermalignantpre diseases .Therefore ,specialatten tionhasbeenalsopaidtoMRIcontrastagents ,whichareindispensablediagnosingdrugsforthemagneticresonanceimagingtechnique[1,2 ] .Gadolinium (Ⅲ)complexwithsomepolycarboxylicandpolyaminelig ands ,suchasGd(DTPA)·nH2 O ,waswidelyusedincliniclongago .OurpreviousworkshowsthatsomepolycarboxylicSchiffbasecomplexeswithrareea…     

Application of Ce(IV) in industrial wastewater treatment

At present,rare earth application in wastewater treatment has become more and more widely,according to the fact that the Ce(IV) has the strong oxidation ability under acid condition,we have studied the application of Ce(IV) in industrial wastewater treatment originally.Results showed that oxidation-reduction reaction occurred between Ce(IV) and the organic compounds or other reducing substances in industrial wastewater,thereby the colority and CODcr reduced effectively.Ce(IV) formed [Ce(OH)x·nH2O](4-x)+ after hydrolyzation and Ce(III) obtained after Ce(IV) reduction formed [Ce(OH)x·nH2O](3-x)+ after hydrolyzation,these hydrate had big specific surface area,could adsorb the suspension substances and removed toxic or harmful ions in industrial wastewater.After treatment by Ce(IV),the analytical results of industrial wastewater are as follows:The CODcr became 58 mg/L from 1646 mg/L,the total COD removal efficiency was more than 95.0%.Turbidity reduced to no more than 10NTU from 87NTU.The chroma became 6 degree from 26 degree,suspension substances content decreased to no more than 2 mg/L from 36 mg/L,and total arsenic and fluorion became <0.05 mg/L and <0.10 mg/L from 0.60 and 15.3 mg/L.Total cadmium reduced to 0.01 mg/L from the 0.58 mg/L.These all indicated that Ce(IV) was one kind of latent good water treatment chemical.     

稀土配合物[REL3(4-picNO)H2O]的合成与表征

合成了2,3-二氯异丁酸根和4-甲基吡啶氮氧化物稀土三元配合物(RE=La、Ce、Pr、Nd、Sm、Eu).通过元素分析、红外、紫外、荧光、X射线粉末衍射、XPS、热分析以及摩尔电导等分析手段,确定了配合物的组成为[REL3(4-picNO)H2O](L= CH3C2H2Cl2COO -),并对它们的性质进行了讨论.     

稀土茜素配合物的合成、表征及抗菌活性

本文用茜素与氯化稀土反应合成了六种稀土配合物,化学元素分析确定了它们的组成为LnL     

Effects of Rare Earth Elements on Photocatalytic Antibacterial Properties of Nanometer TiO2 Powders

Nanometer Ce/TiO2 functional materials with photocatalystic antibacterial properties were prepared by dipping TiO2 nanometer powders into RE( NO3 )·nH2O solutions, filtrating, drying and heat treatment, and the enhancement mechanisms of Ce on the nanometer TiO2 were studied by electronic spin resonance(ESR) The results show that TiO2 for photocatalystic antibacterial properties is strengthened evidently by adding Ce, which has a high efficiency of photocatalystic antibacterial properties with the light extent of visible light and ultraviolet radiation. The basic reason for obtaining the strengthened result is that the effective wave length of photocatalystic properties of TiO2 can be expanded to visible light area with the induction of the rare earth elements, whether or not ultraviolet light exists, nanometer TiO2 can produce a great deal of hydroxylic radical(·OH) by treating with rare earth elements.     

Synthesis, Characterization and Antibacterial Properties of Rare Earth (Ce3+, Pr3+, Nd3+, Sm3+, Er3+)Complexes with L-Aspartic Acid and o-Phenanthroline

Five novel ternary complexes of rare earth ions with L-Aspartic acid (Asp) and o-phenanthroline (Phen) were synthesized in ethanol aqueous solution. Their compositions were characterized by elemental analysis, molar conductance, FT-IR, Raman, UV-VIS and TG-DTA. The compositions of the complexes were confirmed to be: RE(Asp)3PhenCl3·3H2O (RE: Ce3 , Pr3 , Nd3 , Sm3 , Er3 ). The antibacterial activity test shows that all these complexes exhibit excellent antibacterial ability against Escherichia coli, Staphylococcus aureus and Candida albicans. The antimicrobial spectrum of the complexes are broad.     

A Study on La2O3－Y2O3－Mo Secondary Emission Material

The substrate molybdenum doped with La2O3, Y2O3 cathode material was made by the powder metallurgy method. The secondary emission coefficients of the materials were tested. The experimental results show that Mo cathodes doped with La2O3, Y2O3 have good secondary emission properties. When the cathodes are activated, the maximal secondary emission coefficients of these cathodes are higher than 2.0 and can meet the practical requirement. The distribution of the rare earth in the interior and at surface of this kind of cathode material before and after emission was studied using Scanning Electronic Microscopic (SEM) and X-Ray Photoelectron Spectrum(XPS). The analysis results show that the rare earth is easy to gather at grain boundaries and the relevant concentration of rare earth on the surface after emission is obviously greater than that before emission.     

Synthesis and Characterization of Rare Earth Complexes of Ferrocenylcarbonylhydrazine

Ｔｈｅｍｅｔａｌｃｏｍｐｌｅｘｅｓｏｆｈｙｄｒａｚｉｄｅｓｈａｖｅａｔｔｒａｃｔｅｄｃｏｎｓｉｄｅｒａｂｌｅｉｎｔｅｒｅｓｔｏｗｉｎｇｔｏｔｈｅｉｒａｎｔｉｆｕｎｇａｌａｎｄａｎｔｉｂａｃｔｅｒｉａｌａｃｔｉｖｉｔｉｅｓ[1 ,2 ] .Ｔｈｅｙｃａｎａｌｓｏｂｅｕｓｅｄａｓａｎａｌｙｔｉｃａｌｒｅａｇｅｎｔｓ[3 ]ａｎｄｅｘｔｒａｃｔｉｎｇａｇｅｎｔｓｆｏｒｍｅｔａｌｓａｌｔｓ[4 ] .Ｍａｎｙｃｏｍｐｌｅｘｅｓｏｆｈｙｄｒａｚｉｄｅｓｈａｖｅｂｅｅｎｓｙｎｔｈｅｓｉｚｅｄａｎｄｃｈａｒａｃｔｅｒｉｚｅｄ[5]…