共查询到20条相似文献,搜索用时 265 毫秒
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含铬R2O—CaO—Al2O3—SiO2系统结晶质玻璃球状析晶机理的研究 总被引:3,自引:0,他引:3
采用顺磁共振(ESR)、扫描电镜(SEM)、能谱分析(EDAX)、X射线衍射(XRD)等实验方法,研究了Cr2OE对R2O-CaO-Al2O3-SiO2系统更上一层楼的晶行为的影响,并对 球状析晶机理进行了分析。球晶是由放射状的针形晶体所构成,尺寸约为几个毫米,且呈均匀分布,主晶相为β-CaSiO3。析晶机理是玻璃中的铬在热处理过程中首先以铬钙尖晶石固熔体「CaCr2Or」的形式析出,然后β-Ca 相似文献
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金属醇盐法制备堇青石(Mg2Al4Si5O18)粉末 总被引:2,自引:1,他引:1
以金属铝、镁的复合醇盐,MgAl2(O^iPr)82^iPrOH,和正硅酸乙酯为原料,合成制备了堇青石粉末。利用热失重/差热(DTG-DTA)、X-射线衍射(XRD)、比表面测定(BET)、热膨胀曲线和电子扫描电镜(SEM)等检测手段分析了所得样品的结晶过程和烧结性能,与并其它胶体过程制备的堇青石粉末做了比较。 相似文献
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C2S的β与γ变体共存时X射线衍射谱的分解 总被引:2,自引:0,他引:2
采用分辨能力较高的X射线粉末数据的整体分解法,利用相互剥离的原理解析了C2S的β与γ变体共存时的粉末衍射谱。在剥离了样品次要相的衍射峰后,得到了β-C2S和γ-C2S的X射线粉末衍射的标准数据。与PDF卡片值对比后发现,卡片值与本文提供的测定结果有所不同。 相似文献
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采用半干法合成药片崩解剂羧甲基淀粉(CMS)。考察了碱和一氯乙酸用量对CMS取代度(DS)的影响;考察了DS和H/Na(CMS中游离羧基和成盐羧基比值)改变对CMS吸水溶胀性能和崩解性能的影响,应用红外光谱、X-射线衍射、扫描电镜等方法探索CMS结构与性能的关系。 相似文献
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聚丙烯的结构与性能表征 总被引:1,自引:0,他引:1
从高分子链结构、结晶行为、粘弹性、力学性能4个方面,利用红外光谱(IR)、核磁共振(NMR)、X射线衍射、示差扫描量热(DSC)、流变表征(DSR)等手段对国产YS-841催化剂和日本产TK催化剂生产的丙烯均聚物2401和共聚物1330的2个系列4种材料进行测试和分析,揭示并比较4种材料在结构和物理性能上的差异,从而指导对国产催化剂的改进。 相似文献
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EXPERIMENTALINVESTIGATIONOFKINETICANDTRANSPORTPARAMETERSINAWALL-COOLEDFIXED-BEDREACTORZhen-MinCHENGandWei-KangYUAN(UNILABRese... 相似文献
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采用等离子体原子发射光谱分析(ICP-AES)、热分析(DSC)、X射线衍射分析(XRD)、维氏显微硬度测试和扫描电镜(SEM)分析研究热处理对合作单位博德精工提供的CaO-MgO-Al2O3-SiO2系微晶玻璃瓷砖釉面力学性能的影响,以期提高耐磨性能和优化热处理工艺。分别采用传统的两步法和一步法处理瓷砖釉面,结果表明,试样经过750℃保温120min—950℃保温90min和900℃保温2h处理后均析出透辉石、钡长石和氧化锆,大约能够使釉面硬度提高15%和13.6%。另外,试样经940℃保温5min处理后,发生氧化锆相变增韧,硬度提高约11.5%。考虑到工厂的生产实际,氧化锆相变增韧处理是提高瓷砖秞面力学性能的最佳热处理方式。 相似文献
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S. Ghosh K.S. PalN. Dandapat A.K. MukhopadhyayS. Datta D. Basu 《Ceramics International》2011,37(3):1115-1119
Commercial Al powder was exposed to microwave radiation for 45 min. The as received and microwave heated Al powders were characterized by X-ray diffraction analysis (XRD), Fourier transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM), energy dispersive X-ray (EDX) analysis and transmission electron microscopy (TEM). XRD of the microwave treated Al powder confirmed the formation of Al-Al2O3 composite. FTIR studies and EDX analysis indicated the transformation of Al powder into Al-Al2O3 core-shell composite powder after microwave processing. SEM showed that the morphology of the microwave processed Al powder was quite different from that of the as-received Al powder. TEM image of the microwave treated Al powder supported the FTIR and EDX data. 相似文献
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This paper reports the successful synthesis and formation of nanoparticle forsterite powder by mechanical activation and its subsequent annealing. Talc and magnesium carbonate were used as basic starting reactants. Simultaneous thermal analysis (STA), X-ray diffraction (XRD), scanning electron microscopy (SEM), dynamic light scattering (DLS), atomic absorption spectrometry (AAS) and Fourier transform infrared spectroscopy (FT-IR) techniques were utilized to characterize the as-milled and annealed samples. The results showed that forsterite was not produced directly and that the formation of enstatite was unavoidable during the synthesis of forsterite. The nanoparticle forsterite powder obtained had a crystallite size of 30 nm and mean particle size of 135 nm after 10 h milling and subsequent annealing at 1000 °C for 10 min. 相似文献
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Márcio José dos Reis Vanessa Prévot Fabrice Leroux Fabiano Silvério João Barros Valim 《Journal of Porous Materials》2010,17(4):443-451
New organic/inorganic (O/I) hybrid assemblies based on Layered Double Hydroxide (LDH) with polyamide amine dendrimer (PAMAM,
generation −0.5 and generation +0.5) were prepared by two different routes using either the direct coprecipitation at constant
pH or the anion exchange procedure in double surfactant S+S− phases. The obtained materials were characterized by means of powder X-ray diffraction, thermal gravimetric analysis associated
with mass spectrometry, and Fourier-transform infrared spectroscopy. X-ray powder diffraction pattern of the O/I LDH assembly
exhibit characteristic profiles of LDH-based materials with basal spacing depending on the nature of the dendrimer. Indeed,
for both synthetic procedures, interleaved PAMAM −0.5 gives rise to an interlayer space in agreement with a perpendicular
molecular arrangement against the layer of the host structure. For PAMAM+0.5, considering its spherical dimension, a much
smaller basal spacing was observed. This observation was interpreted as shrinkage of the molecule to accommodate the interlayer
LDH gap, which was rendered possible by the bond angle twisting within PAMAM−0.5. FTIR spectra confirm the presence of both
moieties inside both Zn2Al/PAMAM G−0.5 and Zn2Al/PAMAM G+0.5 assemblies. Finally, thermal analysis associated with mass spectrometry confirm this composition, and in situ
temperature XRD data reveal that the highly constrained arrangement for the generation +0.5 is not accompanied by a gain in
thermal structural stability; in fact, the assembly prepared from PAMAM −0.5 is more stable. Both O/I PAMAM LDH assemblies
constitute well-defined materials which are candidate for catalytic applications. 相似文献
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Alien Blanco Flores Luis Ibrain Ortega Hernández Helen Paola Toledo Jaldin Víctor Sánchez Mendieta Héctor Víctor Cabadas Baéz Teresa Pi Puig 《分离科学与技术》2018,53(4):598-612
Tuffite has been studied for Cu(II) adsorption from aqueous and ammoniacal solutions. Tuffite was characterized by mercury porosimetry, Brunnauer–Emmet–Teller (BET), scanning electron microscopy–energy X-ray dispersive spectroscopy (SEM-EDS), Fourier transform infrared spectra (FTIR), X-ray powder diffraction (XRD), inductively coupled plasma-atomic emission spectrometry (ICP-OES) and petrographic microscopy. The equilibrium time was 50 min. The second-order model is the best model to describe the process. It was determined that the intraparticle diffusion was not the only limited step. Process variables were studied to improve the adsorption process. The material washed contributes to increase the Cu(II) adsorption from 213.05 to 276 mg/g. The flow countercurrent system requires at least 6 g of tuffite to achieve 90% of removal. 相似文献
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以水玻璃为原料,采用硫酸制备纳米白炭黑,并利用硅烷偶联剂S i-75对纳米白炭黑进行疏水改性。通过X射线衍射、透射电镜、红外光谱和热重分析对纳米白炭黑进行表征。粉末X射线衍射(XRD)分析结果显示,纳米白炭黑为非晶态二氧化硅;通过透射电镜(TEM)分析可知,改性后的纳米白炭黑分散性更好,团聚降低,白炭黑一次粒径在20 nm-40 nm,粒子之间相互连接形成链枝结构附聚体;红外光谱(FT-IR)和热重分析(TG)显示,硅烷偶联剂S i-75成功地接枝到纳米白炭黑。活化指数(99.6%)的测定表明,合成的纳米白炭黑具有超疏水性。 相似文献
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Synthesizing and Comparing the Photocatalytic Properties of High Surface Area Rutile and Anatase Titania Nanoparticles 总被引:2,自引:0,他引:2
Rutile titania nanocrystalline particles with high specific surface areas were directly prepared by thermal hydrolysis of titanium tetrachloride aqueous solution. The as-prepared rutile titania powder was characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), Brunauer–Emmett–Teller surface area analysis, and Fourier transform Raman and IR spectroscopies. Neither anatase nor amorphous titania could be detected in this titania powder by XRD, Raman spectroscopy, and high-resolution TEM. In the phenol degradation reaction, the rutile titania powder with an initial crystalline size of 7 nm was found to have higher photocatalytic activity than that of anatase titania with the same specific surface area. The rutile titania powders calcined at 300° and 450°C also showed a relatively high photocatalytic property. The high activity of the as-prepared rutile titania was attributed to the abundance of hydroxy groups in the powder, as was proven by thermogravimetric analysis data, which provided more active sites for the degradation reaction. 相似文献
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采用加热回流法制备了磺酸化无定形碳固体酸催化剂。通过电感耦合等离子体发射光谱(ICP-AES)、酸碱电位滴定、傅里叶变换红外光谱(FTIR)、X射线粉末衍射(XRD)、扫描电镜(SEM)和热重分析(TGA)等方法对催化剂进行了表征。结果表明,催化剂结构中—SO3H负载量为2.03 mmol/g,与其他固体酸类催化剂相比,磺酸化无定形碳在催化环酮类化合物的Baeyer-Villiger氧化反应以及苯甲醚和苄醇的傅-克烷基化反应中均显示了良好的催化活性。所得催化剂热稳定性好,制备过程简单。 相似文献