共查询到19条相似文献,搜索用时 156 毫秒
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采用水热法合成了一系列不同Ag2CO3含量的新型Ag2CO3/ZnO异质结复合光催化剂,运用X射线粉末衍射(XRD)、扫描电镜(SEM)、X射线光电子能谱(XPS)、傅里叶变换红外光谱(FT-IR)、紫外-可见漫反射吸收光谱(UV-vis DRS)等系列手段对所制备的光催化剂进行了表征,并以紫外光(254 nm)为光源,评价了催化剂光催化降解甲基橙的活性,考察了不同Ag2CO3复合量、不同水热温度对ZnO复合光催化剂反应活性的影响.结果表明,当Ag2CO3含量为2%、水热温度为140℃,复合光催化剂具有最大的光催化活性,降解率达到86.31%.Ag2CO3/ZnO异质结复合光催化剂具有更高的光催化活性主要原因是复合光催化剂对紫外光有很强的吸收能力,适量Ag2CO3能提高光生电子-空穴对的分离效率,并改善催化剂的物理性能. 相似文献
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采用水热法合成了一系列不同Ag2CO3含量的新型Ag2CO/ZnO异质结复合光催化剂,运用X射线粉末衍射(XRD)、扫描电镜(SEM)、X射线光电子能谱(XPS)、傅里叶变换红外光谱(FT-IR)、紫外-可见漫反射吸收光谱(UV-visDRS)等系列手段对所制备的光催化剂进行了表征,并以紫外光(254nm)为光源,评价了催化剂光催化降解甲基橙的活性,考察了不同Ag2CO3复合量、不同水热温度对ZnO复合光催化剂反应活性的影响.结果表明.当Ag2CO3含量为2%、水热温度为140℃,复合光催化剂具有最大的光催化活性,降解率达到86.31%.Ag2CO3/ZnO异质结复合光催化剂具有更高的光催化活性主要原因是复合光催化剂对紫外光有很强的吸收能力,适量A龅C03能提高光生电子一空穴对的分离效率,并改善催化剂的物理性能. 相似文献
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采用水热法合成了一系列不同Ag2CO3含量的新型Ag2CO3/ZnO异质结复合光催化剂, 运用X射线粉末衍射(XRD)、扫描电镜(SEM)、X射线光电子能谱(XPS)、傅里叶变换红外光谱(FT-IR)、紫外-可见漫反射吸收光谱(UV-vis DRS)等系列手段对所制备的光催化剂进行了表征, 并以紫外光(254 nm)为光源, 评价了催化剂光催化降解甲基橙的活性, 考察了不同Ag2CO3复合量、不同水热温度对ZnO复合光催化剂反应活性的影响.结果表明, 当Ag2CO3含量为2 %、水热温度为140 ℃, 复合光催化剂具有最大的光催化活性, 降解率达到86.31 %.Ag2CO3/ZnO异质结复合光催化剂具有更高的光催化活性主要原因是复合光催化剂对紫外光有很强的吸收能力, 适量Ag2CO3能提高光生电子-空穴对的分离效率, 并改善催化剂的物理性能. 相似文献
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用沉淀法制得CdS纳米粒子,用氨水催化分解正硅酸乙酯制得复合光催化剂CdS-SiO2。光还原沉积法对CdS表面载Pt。借助X射线衍射(XRD)、紫外-可见漫反射(UV-Vis)对催化剂进行表征,用电化学法测定CdS的光腐蚀度,以甲酸水溶液的可见光催化制氢反应为探针,评价催化剂活性。结果表明,SiO2的复合提高了CdS的分散性,抑制了CdS光腐蚀,从而使CdS的可见光制氢活性大大提高。 相似文献
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《稀有金属》2016,(12)
采用溶胶-凝胶法将多壁碳纳米管(MWCNT)和BiVO_4有效复合,制备出一系列不同掺杂量的异质结构复合光催化剂MWCNT/BiVO_4,通过X射线衍射(XRD)、扫描电镜(SEM)、傅里叶变换红外光谱(FT-IR)、X射线光电子能谱(XPS)等对催化剂进行表征分析,以罗丹明B为目标污染物,考察了光催化活性和稳定性。结果表明,合成的复合光催化剂均为单斜相晶体结构,MWCNT的引入没有改变BiVO_4的主体物相,两者充分接触、结合形成了复合结构;MWCNT较强的电子俘获能力和大的比表面积增加了复合材料表面的活性位点,MWCNT,BiVO_4存在于MWCNT-BiVO_4复合体系中且都保持各自化合态;综合分析,MWCNT/BiVO_4形成的复合结构为异质结构,异质结构具有典型的提高量子效率的特点,能够有效抑制电子-空穴再复合现象的发生。当MWCNT的含量为2%(质量分数)时,催化剂的效果最好,实验条件下光降解罗丹明B的去除率高达84.08%,五次重复性实验之后,MWCNT/BiVO_4的降解率仍在80%左右。 相似文献
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Modified-EISA synthesis of mesoporous high surface area CeO_2 and catalytic property for CO oxidation 总被引:1,自引:0,他引:1
Mesoporous CeO2 particles with high surface area were synthesized using a modified evaporation-induced self assembly(EISA) method which combined citric acid as complexing agent.As-prepared powder and further thermal treatment samples were characterized by X-ray diffraction(XRD),transmission electron microscopy(TEM),selected area electron diffraction(SAED),Fourier transform infrared spectrometer(FTIR),thermogravimetry and differential thermal analysis(TG-DTA),Brunauer-Emmett-Teller(BET) and Barrett-Joyner-Ha... 相似文献
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Metallurgist - X-ray fluorescence analysis, X-ray powder diffraction, electron microprobe analysis, scanning electron microscopy, and thermal analysis are used to evaluate the material composition,... 相似文献
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Thiago Fernandes de Aquino Humberto Gracher Riella 《Mineral Processing and Extractive Metallurgy Review》2013,34(3):137-149
Bauxite is widely used for refractory production owing to its high alumina content and high melting point. Brazil is one of the world's biggest producers of bauxite for refractory applications, and Santa Catarina State can be highlighted as one of the biggest reservoirs of bauxite ore. In spite of this fact, its chemical and mineralogical characteristics are not well known as well as its high temperature properties. The studied ore was completely characterized [chemical (X-ray fluroscence), thermal (differential thermal analysis), mineralogical (X-ray diffraction), and microscopic (optical microscopy and scanning electron microscopy) analyses] and the results showed that the bauxite ore is suitable to be used as a raw material for refractory applications. 相似文献
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Synthesis of La3+ and Nd3+ co-doped yttria nanopowder for transparent ceramics by oxalate precipitation method 总被引:1,自引:0,他引:1
Polycrystalline Nd3+ and La3+ co-doped yttria nanopowder Nd3+:Y1.90La0.10O3 for transparent ceramics was synthesized by co-precipitation method using oxalate acid as the precipitant and(NH4)2SO4 as the electrical stabilizer under ultrasonic radiation.Nanopowders calcined at different temperatures were characterized with thermal gravimetric-differential thermal analysis(TG/DTA),X-ray diffraction(XRD),transmitting electron microscopy(TEM),energy dispersive spectrometry(EDS) and spectral analysis techniques.Th... 相似文献
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R. K. Khatirkar 《Transactions of the Indian Institute of Metals》2009,62(6):567-571
X-ray diffraction peak profile analysis is a powerful and convenient method to investigate the microstructural characteristics
of plastically deformed materials. The selection of a suitable and reliable analysis method is critical to derive correct
microstructural/material property values. Different techniques of the X-ray diffraction peak profile analysis have been used
to study the microstructural parameters of plastically deformed iron powder viz., coherent domain size, dislocation density
and their nature. In particular, the classical and modified Williamson-Hall method and the momentum method are used. The nature
(screw or edge) of dislocations is also determined for the deformed steel using X-ray diffraction while the morphology was
studied using scanning electron microscopy. 相似文献
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A different method was employed for the preparation of a metal supported perovskite catalyst for the catalytic combustion of methane.The prepared metallic catalysts were characterized by means of X-ray diffractometer(XRD),scanning electron microscopy(SEM),transmission electron microscopy(TEM),and also by ultrasonic and thermal shock tests and catalytic activity.It was found that the process factors during the preparation,e.g.the preparation of the catalyst precursor and the coating slurry,the calcination te... 相似文献
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Rare-earth doped YAG nanopowders are widely used as luminescence material because of its technological importance in opto-electronic applications especially for solid state lasers. In this work, YAG and Yb:YAG were prepared by co-precipitation method. The thermal behavior was investigated by differential thermal analysis and thermo gravimetric analysis. The phase formation, elemental analysis, particle size distribution, optical absorbance, fluorescence behavior and morphology of YAG and Yb:YAG nanopowder were analyzed through powder X-ray diffraction technique, energy dispersive X-ray analysis, dynamic light scattering, UV–Vis, photoluminescence spectroscopy, high resolution scanning electron microscopy, high resolution transmission electron spectroscopy respectively. From the optical study, Yb:YAG gives optical absorption at 975 nm and predominant infrared emission at 1030 nm. 相似文献
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锰氧化物的性能很大程度上受其形貌结构的影响。以高锰酸为氧化剂,乙酸锰、双氧水和硫酸锰为还原剂制备锰氧化物,对产物的结构、形貌和热稳定性分别用XRD、SEM、TEM和TG分析,讨论了不同还原剂对产物、结构、形貌和热稳定性的影响。 相似文献