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喷动载流床中温度对霍林河褐煤快速热解产物的影响 总被引:8,自引:1,他引:8
在喷动载流床反应器内对霍林河褐煤的快速热解进行了研究,并对该煤的热解机理进行了初步分析。考察了在500~850℃范围内温度对热解产品产率分布及气体和液体产品具体组成的影响。分别利用气相色谱和色质联用仪来分析气体和液体产物的组成。实验结果表明,气体总产率及CO、H2和C1~5烃类的产率随热解温度的提高而增大;在热解温度为650℃时,液体产率最高,在煤粉粒径为0.125~0.18mm,液体产品的总产率可达23%,其中正己烷可溶物的产率可达30%以上,沸点340℃前馏分也达30%以上。液体产品中酚类产品较多;温度对液体产品的组成有极大的影响。 相似文献
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针对煤制油项目中存在的煤炭资源利用效率低、吨油耗煤量高的问题,提出了流化床低温热解耦合输送床气化的原料煤利用方案(设想),并系统地阐述了该方案的原则流程、工艺特点和潜在的问题。该方案较好地整合了流化床低温热解技术和输送床气化技术的优点,可同时实现原料煤的高焦油收率、高合成气产率和高能量利用率,但仍存在潜在技术问题。 相似文献
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通过两段固定床反应器分离了煤热解和二次反应过程,模拟了传统外热式固定床反应器和外热式内构件固定床反应器内挥发性热解产物流动与固相反应颗粒间的相互作用,研究了不同温度的半焦对先锋褐煤热解产物分布和品质的影响。结果表明:当半焦的温度在500~900℃时,焦油发生剧烈的二次反应,热解气收率增加,焦油收率大幅下降,H/C同时大量降低且均低于空白样,油品质下降;在100~400℃半焦作用下,焦油发生轻微的二次反应,热解气收率略微增加,焦油收率缓慢下降,但H/C均高于空白样,油品质提升。该结果验证内构件外热式固定床反应器热解产生的焦油具有更高的收率及品质。 相似文献
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热解温度对半焦生成及其元素组成的影响 总被引:2,自引:0,他引:2
利用固定床反应器对3种煤样进行了Ar气气氛高温热解研究,考察了热解温度对半焦产率和其中C,H和O元素含量的影响.研究发现,挥发分主要释放温度范围集中在400℃~700℃;半焦的H/C和O/C原子比都是随温度的升高而减小,O/C原子比在300℃~600℃降低幅度很大,H/C原子比在300℃~900℃降幅较大,当热解温度达到900℃后,不同变质程度煤的半焦H/C和O/C趋于一致.热解过程中半焦的H/C和O/C变化关系与vanKrevelen图上典型煤阶的H/C和O/C关系类似. 相似文献
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在加压固定床反应器中进行淖毛湖煤在常压和1.5 MPa氢气和氮气中的热解试验,利用多种表征方法对比研究了氢气和氮气下的热解产物产率和组成及半焦结构的变化,并利用热重分析研究热解半焦的CO2气化反应性。结果表明:与常压N2中热解相比,煤在加压的H2中热解可有效提高热解气体中CH4和C2~C3的产率,在800℃热解CH4和C2~C3的体积产率分别由53.5和16.6 mL/g增至345.6和20.8 mL/g。焦油和轻质焦油产率也有效提升,在600℃下,与常压N2中热解相比,1.5 MPa H2中煤热解的焦油产率由19.3%升至22.8%,焦油中脂肪烃含量由35.5%降至14.8%,单环芳烃含量由8.3%增至28.9%,轻质焦油质量分数和产率分别升至95.0%和21.8%。半焦的N2吸附和拉曼光谱分析结果表明,煤在加压H... 相似文献
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在连续进料量为1.2 kg·h-1的输送床反应器中考察了热解温度和反应气氛对不连沟次烟煤快速热解的影响。N2气氛下,随着煤热解温度升高,焦油产率先增加后减小,600℃时达到最大值10.3%;对应的半焦产率下降,气体产率以及气油比增加。高温促进了煤挥发分的释放以及挥发分在气相中的二次反应,部分产物从固相和液相产品转化为气相产品,氢气、甲烷和乙烯等气体组分的产率明显增加。700℃下,H2气氛能够抑制挥发分二次反应的发生,起到稳定自由基和加氢的作用,显著提高焦油产率和油品品质,同时有利于甲烷的生成。CO气氛在一定程度上同时提高了轻质和重质焦油产率。CO2和水蒸气能够促进焦油的二次反应,特别是重质焦油的裂解,具有一定的提质作用,但会导致焦油产率下降。CH4气氛促进了重质焦油组分的生成,使得热解焦油产率提高。 相似文献
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玉米秸秆循环流化床气化中试试验 总被引:2,自引:0,他引:2
玉米秸秆是农业生产过程中产生的剩余物,其热解气化是秸秆类生物质处理应用的重要选择方向。为此,采用循环流化床气化中试装置对玉米秸秆进行了气化试验,研究空气当量比ER、原料含水率对反应温度、气化燃气组分与热值、气化效率及燃气中的焦油含量等气化特性影响规律,并通过改变进料量试验得到了在不同负荷运行条件下的优化工作参数。结果表明:①随着ER的增大,循环流化床气化炉内的反应温度升高,气化燃气中的CO2含量增加,焦油与CO含量及燃气热值降低,气化效率随ER的增大呈现先增大后减小趋势,较理想的ER为0.26,此时的气化效率达到70.2%、燃气热值为5.1MJ/m3;②原料含水率的增大降低了气化炉内的反应温度,当原料含水率在5%~15%之间逐渐增大时,燃气中的H2含量、燃气热值及气化效率均有提升,当含水率由15%继续增大到25%过程中,燃气热值与气化效率均出现了快速下降;③根据气化炉额定进料量设计值,改变进料负荷在66%~120%范围内,调节ER在0.26~0.3时均可得到较好的运行工况,对应得到的燃气热值为4.8~5.1MJ/m3、气化效率为69%~72%。 相似文献
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Antonio Coppola Aida Sattari Fabio Montagnaro Fabrizio Scala Piero Salatino 《American Institute of Chemical Engineers》2023,69(1):e17588
A possibility to carry out sorption-enhanced gasification (SEG) is represented by its integration with the calcium looping concept in dual interconnected fluidized beds (DIFB). This article is focused on the sorbent CO2 uptake performance and attrition/fragmentation tendency when operating conditions simulating those of a DIFB-SEG process are adopted. Experiments were carried out on a commercial Italian limestone in a laboratory-scale DIFB reactor. Carbonation was carried out in a range of test conditions, including variable temperature (600–700°C) and absence/presence of steam (10% by volume); CO2 concentration was set at 10% by volume. The characterization is extended by investigating the behavior of preprocessed DIFB-SEG samples on impact fragmentation tests, conducted in an ex situ apparatus. Tests were carried out for impact velocities in the range 17–45 m/s. Results were discussed considering both the impact velocity value and the operating conditions under which the sample was preprocessed in the fluidized bed. 相似文献
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Diana Carolina Guío‐Pérez Hermann Hofbauer Tobias Pröll 《American Institute of Chemical Engineers》2013,59(10):3612-3623
The redistribution of solids in a counter‐current circulating fluidized bed (CFB) by effect of ring‐type internals was investigated in a downscaled cold‐flow model. The system consists of two interconnected CFB reactors, in which the primary reactor operates like a common riser while the secondary reactor operates in counter‐current. The unit works without circulation rate control devices and the inventory splits inherently between the two reactors by pressure balance and depending on the fluidization velocities. Previous studies showed an increment in the total pressure drop in the secondary reactor as result of the internals installation. With the purpose of obtaining comparable inventory in the secondary reactor with and without rings, a device for adjustment of total inventory was designed and installed. Effects of the aperture ratio, number of rings, fluidization velocity, and particles circulation rate were studied. The results obtained approach a guideline for the detailed design of similar configurations. © 2013 American Institute of Chemical Engineers AIChE J, 59: 3612–3623, 2013 相似文献
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Pyrolysis and steam gasification of nickel-loaded Yallourn coal were carried out in a fluidized bed reactor at ambient pressure. The pyrolysis mode was influenced by the addition of nickel catalyst. The yield of total volatile matter decreased whereas the gas yield markedly increased, when compared with uncatalysed pyrolysis. This is considered to result from tar decomposing on the catalyst and being converted to gases and deposited carbon. For the catalysed steam gasification, ≈ 80 wt% of coal conversion was achieved at 873 K and the gas yield was twelve times as much as that for the uncatalysed reaction. The homogeneous equilibrium in the gas phase controlled the composition of the product gas. The product gas contained little tarry material and a negligible amount of hydrogen sulphide. Nickel was efficiently recovered from the residue by an ammonia-leaching method. 相似文献
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Axial and radial profiles of gas and solids holdups have been studied in agas-liquid-solid circulating fluidized bed at 140mm i.d..Experimental results indicate that the axialand radial profiles of gas and solids holdups are more uniform than those in a conventionalfluidized bed.Axial and radial liquid dispersion coefficients in the gas-liquid-solid circulating fluidizedbed are investigated for the first time.It is found that axial and radial liquid dispersioncoefficients increases with increaes in gas velocity and solids holdup.The liquid velocity has littleinfluence on the axial liquid dispersion coefficient,but would adversely affect the redial liquiddispersion coefficient.It can be concluded that the gas-liquid-solid circulating fluidized bed hasadvantages such as better interphase contact and lower liquid dispersion along the axial directionover the expanded bed. 相似文献