空气与水逆流直接接触热质交换模型计算及与实验比较

According to general equations deducted from a model of heat and mass transfer of air and water in direct contact counter flow reported in the author‘s previous work, the outlet parameters of air and water counter flow through a paper wet pad were calculated by using the MATLAB-software. Comparing the calculation results with experiment data of prior researchers, the deviation of calculated outlet air wet bulb temperature from experimental outlet air wet bulb temperature was less than 10%, the deviation of calculated outlet water temperature from experimental outlet water temperature was less thang 9%, and the deviation of calculated outlet air dry bulb temperature from experimental outlet air dry bulb temperature was less than 10% when NTUh was more than 0. 6. The deviation of calculated outlet air dry bulb temperature from experimental outlet air dry bulb temperature was more than 10% when NTUh was less than 0. 6. The model calculations were in good agreement with experiments and the general equations could be used to design evaporation cooling equipment, such as wet pad and so on.     

流化床喷雾造粒过程的传热传质

This article presents a mathematical model of heat and mass transfer for the process of fluidized-bed spray granulation, which can be applied in the analysis of bed temperature profile, temperature and humidity of outlet gas and moisture content of particles. Effects of operation parameters on the batch granulation are investigated. The theoretical calculation agrees reasonably well with the experimental data.Keywords fluidized-bed spray granulation, mathematical model, heat and mass transfer     

充碳塑料管壳式增湿-去湿淡化装置及过程：模拟和实验研究

The modelling and experimental investigation of a thermally coupled humidification-dehumidification desalination process using a carbon-filled-polypropylene shell-tube column are presented. A heat/mass transfer model is established to study the correlation among productivity, thermal efficiency, physicochemical parameters （gas/liquid phase temperature, heat/mass transfer coefficient, Reynolds number etc.）, and operating conditions （the temperature of feed water, the flow rates of external steam, feed water, and carrier air）; at the same time, the effects of operating conditions on the productivity and thermal eficiency of the column are investigated both theoretically and experimentally, which indicate that the optimum flow rates of external steam, feed water, and carder gas are 0.18, 60, and 10kg.h^-l, respectively, and the higher the feed water temperature （≤95℃） is, the greater the productivity and the thermal efficiency will be. Furthermore, performance comparison with the previous study shows that the condensate productivity of this carbon-filled-plastic column is not lower than that of the copper column, which demonstrates the practicability and feasibility of applying such a plastic column to the humidification-dehumidification desalination process.     

Heat and Mass Transfer in Process of Fluidized-Bed Spray Granulation

This article presents a mathematical model of heat and mass transfer for the process of fluidized-bed spray granulation, which can be applied in the analysis of bed temperature profile, temperature and humidity of outlet gas and moisture content of particles. Effects of operation parameters on the batch granulation are investigated. The theoretical calculation agrees reasonably well with the experimental data.     

MASS TRANSFER IN TURBULENT PULSATING FLOWS

The effect of flow oscillation to the mass transfer between turbulent fluid and solid wall was investigatedby measuring the mass transfer rate between fluid and pipe wall with imposed oscillating flow usingelectrochemical method.The velocity and concentration field in the viscous sublayer which controls the mass trans-fer in such a process was simulated by a simple wave model of single harmonics.Experimental results confirmthat the flow oscillation has no influene on time averaged mass transfer rate,but the phase difference betweenphase averaged velocity field and concentration field shifts with the frequency of imposed oscillating flow.Numeri-cal analysis reveals that the concentration boundarylayer which is responsible for the mass transfer is muchthinner than the viscous sublayer which greatly weakens the influence of imposed oscillating flow on mass transfer.     

A Reynolds mass flux model for gas separation process simulation:I. Modeling and validation

Separation process undertaken in packed columns often displays anisotropic turbulent mass diffusion. The aniso-tropic turbulent mass diffusion can be characterized rigorously by using the Reynolds mass flux (RMF) model. With the RMF model, the concentration and temperature as well as the velocity distributions can be simulated numerical y. The modeled Reynolds mass flux equation is adopted to close the turbulent mass transfer equation, while the modeled Reynolds heat flux and Reynolds stress equations are used to close the turbulent heat and mo-mentum transfer equations, so that the Boussinesq postulate and the isotropic assumption are abandoned. To val-idate the presented RMF model, simulation is carried out for CO2 absorption into aqueous NaOH solutions in a packed column (0.1 m id, packed with 12.7 mm Berl saddles up to a height of 6.55 m). The simulated results are compared with the experimental data and satisfactory agreement is found both in concentration and temper-ature distributions. The sequel Part II extends the model application to the simulation of an unsteady state ad-sorption process in a packed column.     

CO2-乙醇体系中界面对流的混合格子Boltzmann方法三维模拟及实验验证（英文）

By using a hybrid lattice-Boltzmann–finite-difference method (hybrid LBM–FDM method), three-dimensional simulations of solutal interfacial convection were conducted for the process of CO2 absorption into ethanol. A self-renewal interface model is adopted as an interfacial perturbation model. The simulation results revealed some three-dimensional features of the induced interfacial convection, such as the development of diverging cellular flow and Rayleigh plume-like convection in liquid phase. The concentration distribution of the simulation result is validated and found to be in wel agreement with the Schlieren visualization results qualitatively. Addi-tionally, the mass transfer enhancements by interfacial convection were investigated via both simulation and experiment for the absorption process, and the mass transfer is shown to be enhanced by the interfacial convec-tion by about two-fold comparing with that by diffusion.     

考虑界面蒸发时的降液膜流动传热

The interfacial evaporative heat transfer was included in the semi-empirical study of the heat transfer for the falling liquid film flow. The investigations showed that, the inclusion of the interfacial evaporative heat transfer in the turbulent model would lower the predicted convective heat transfer coefficient. Predictions of the new model resulted in a prominent deviation from that predictions of the normal model in the case of large mass flow rate and low wall heat flux. This deviation will be decreased with increasing wall heat flux, such that it will be asymptotic zero at very high wall heat flux. Predictions of the new model agreed well with the current experimental measurements. This study has verified that the Reynolds number is not the sole crucial parameter for heat transferof falling liquid film flow, and wall heat flux will be another important independent parameter. This result is consistent with our previous studies.     

A New Method to Solve Film Model for CO_2 Absorption with Aqueous Solution of AT-Methyldiethanolamine

The shooting method and the difference method are used for numerical simulation of CO2 absorption with aqueous solution of methyldiethanolamine (MDEA). It is demonstrated that these methods are available for the steady-state model, which may be expressed as a set of differential algebraic equations (DAEs) with two-point boundary values. This method makes it possible not only to obtain the concentration profiles for MDEA system, but also to reveal the effect of CO2 interfacial concentration on the enhancement factor. With this numerical simulation, the mass transfer process with multicomponent diffusion and reactions can be better understood.     

MDEA吸收CO2稳态模型的数值求解方法

The shooting method and the difference method are used for numerical simulation of CO2 absorption with aclueous solution of methyldiethanolamine (MDEA). It is demonstrated that these methods axe available for the steady-state model, which may be expressed as a set of differential algebraic equations (DAEs) with two-point boundary values. This method makes it possible not only to obtain the concentration profiles for MDEA system, but also to reveal the effect of CO2 interfacial concentration on the enhancement factor. With this numerical simulation,the mass transfer process with multicomponent diffusion and reactions can be better understood.     

空调用金属填料表面传热传质过程的数值分析

建立了填料塔的二维传热传质模型,考虑了因水蒸发或凝结而引起的水的质量变化和空气的质量变化.利用实验数据回归得到的传热系数和传质系数.用差分法求得了更接近实际的数值解.实验研究证明使用这个改进的方法,使得模型的数值解与实验结果吻合得较好.数值分析结果描述了金属填料内部空气的湿球温度场和填料表面水膜的温度场,有助于研究金属填料表面传热传质性能,为金属填料用于空调机组中的设计提供了计算方法,可以给出满足工程精度要求的设计依据.     

风洞真空排气系统直接接触传热过程

某风洞真空排气系统在运行过程中,会产生大量含水蒸气的混合气体。为了提高排气效率降低能耗,本文引入冷凝塔工艺,采用直接接触换热冷凝方式使来流含水蒸气的混合气体降温冷凝。基于微元塔高传质模型,对进入冷凝塔的热流气体与冷却水直接接触换热过程分析,推导出传质系数数学方程表达式。结合实验数据考察了进气压力与冷凝降温排出气体中水蒸气含量的影响,并拟合得到一定温度下进气压力与该气体水蒸气含量的数学表达式;也考察了冷却水质量通量和气液比变化对传质系数、体积传热系数、出气温度的影响,在此基础上拟合得到针对风洞气流直接接触换热气液比与体积传热系数数学关系式,并计算出最优气液比。实验得出的规律对风洞气流的直接接触换热优化设计和应用起到了指导作用。     

中空纤维膜除湿组件的热质传递特性

中空纤维膜液体干燥剂空气除湿技术是一种结合液体除湿和膜分离技术的新型除湿技术,这种技术避免了气液直接接触,从本质上克服了传统液体除湿技术气液夹带的难题。中空纤维膜作为间接接触的介质,新风和除湿溶液通过膜进行共轭传质传热。探究南方湿热气候下该技术的可行性,根据南方气候条件下室内新风的特点设计并制造一种中空纤维膜除湿组件,建立相应的数学模型,研究不同进口新风工况和溶液工况下组件的除湿性能,分析组件内的传热传质机理,提出了组件性能的优化方向。研究结果可为中空纤维膜组件的设计提供基础理论。     

湿工况下泡沫金属内换热和压降的数值模拟和实验验证

泡沫金属应用到换热器空气侧有望提高析湿工况下的换热性能。为了了解湿空气在泡沫金属内的热质传递和压降特性,建立了泡沫金属内液滴形成、生长和运动特性的数值模型。基于液滴成核数目和成核临界半径得出液滴形成过程的传质率模型;通过建立液滴与湿空气相界面附近湿空气中水蒸气的组分守恒方程,得出液滴生长过程的传质率模型;通过对不同孔棱柱表面液滴的受力分析,建立在重力和风力的共同作用下的液滴接触角模型。将液滴形成及生长的传质率模型和接触角模型分别作为质量源项和表面张力源项,加入连续性方程、动量方程和能量方程组中,实现对泡沫金属内液滴生长、形成和运动过程模拟。模型的实验验证结果表明,换热量预测值与实验结果的最大偏差为11.9%,压降预测值与实验结果的最大偏差为17.7%。     

直接接触式冰浆生成器的单气泡传热特性

冰浆生成器是直接接触法冰浆制取系统的关键设备之一,而体积传热系数作为衡量冰浆生成器性能的重要参数受诸多因素影响。基于单个气泡在连续相中的上升特性,定性分析了各种因素对体积传热系数的影响。实验结果表明:进气温度下降、进气质量流量增加、水柱高度下降、喷嘴直径减小均导致体积传热系数增加。     

A new model for mass transfer in direct contact membrane distillation

The mass transfer process in direct contact membrane distillation (DCMD) for three kinds of membranes was measured. Water fluxes at different temperatures and the membrane distillation coefficients (MDC) for each membrane were obtained directly from experimental data. The fact that the MDC values of membranes with larger pore size increase with temperature indicates that Poiseuille flow plays an important role in the process of mass transfer through the membrane. Based on this conclusion, a three-parameter model, named the Knudsen diffusion-molecular diffusion-Poiseuille flow transition (KMPT) model, was developed to predict MDC and water flux for membrane distillation. The parameters of the KMPT model for each membrane employed in this study, by which MDC at various temperatures can be determined, were evaluated by a nonlinear regression. The values of MDC and water fluxes for each membrane predicted by KMPT model agree well with that obtained directly from the experiment results. A large contribution of Poiseuille flow to mass transfer was observed and can be attributed to the distribution of large pores in the membranes. The KMPT model also provides a method for estimation of the effect pore size using the ratio of the MDCs; the ratio of the Poiseuille flow to molecular diffusion MDC provides the best estimation.     

错流降膜液体干燥剂除湿/再生传热传质数学模型及分析

分析了错流降膜液体干燥剂除湿及再生传热传质过程 ,建立了基于实际除湿系统的描述再生和除湿过程的数学模型 ,考虑到除湿过程中产生的热效应 ,以氯化钙溶液为除湿剂时 ,对气侧和液侧的传热传质系数进行了理论和数值求解 .计算结果表明 ,传热传质系数与气流流动状态、除湿剂的热物理性质等因素有关     

HD低温蒸发系统中填料蒸发器传质传热的分析

通过研究系统中填料蒸发器的蒸发传质传热过程以及两相流动特性，采用计算流体力学（computational fluid dynamics，CFD）中离散相与连续相耦合的方法来模拟规整填料内部通道的蒸发传质传热过程，实现了填料蒸发器中两相传质传热的过程以及液滴流动的可视化，为研究气液两相在规整填料内的流动提供了一种模拟方法。通过与实验结果的比较，最终选用RNG k-ε湍流模型来分析规整填料内部气液两相传质传热以及流动情况。数值模拟研究了规整填料板间距对填料内部气液两相传质传热以及液滴运动影响，发现随着板间距的增大，填料内部压力降逐渐降低，出口空气中水蒸气的含量不断减小，液滴蒸发速率降低，液滴进出口质量差减小，气相出口温度逐渐降低，蒸发传质传热效率降低。随着气速的增大，出口空气中水蒸气的含量不断减小，液滴蒸发速率增加，气相出口温度降低，气液两相传质传热效率降低。     

A Multiphase Model to Analyze Transport Phenomena in Food Drying Processes

The aim of the present work is the development of a theoretical model describing the transport phenomena involved in food drying. A fundamental multiphase approach was utilized to account for the simultaneous presence of both liquid water and vapor within the sample undergoing drying. The transport equations referred to the food were coupled, by a proper set of boundary conditions, to momentum and heat and mass transfer equations referred to the drying air, thus obtaining a general model that did not rely on the specification of any heat and mass transfer coefficient at the food/air interfaces.