Combustion and emissions performance of a hybrid hydrogen–gasoline engine at idle and lean conditions

Due to the narrow flammability of gasoline, pure gasoline-fueled spark-ignited (SI) engines always encounter partial burning or even misfire at lean conditions. Gasoline engines tend to suffer poor combustion and expel large emissions at idle conditions because of the high variation in the intake charge and low combustion temperature. Comparatively, hybrid hydrogen engines (HHE) fueled with the mixtures of hydrocarbon fuels and hydrogen seem to achieve lower emissions and gain higher thermal efficiencies than the original hydrocarbon-fueled engines due to the wide flammability and high flame speed of hydrogen. Since a HHE only requires a small amount of hydrogen, it also removes concerns about the high production and storage costs of hydrogen. This paper introduced an experiment conducted on a four-cylinder SI gasoline engine equipped with a hydrogen port-injection system to explore the performance of a hybrid hydrogen–gasoline engine (HHGE) at idle and lean conditions. The injection timings and durations of hydrogen and gasoline were governed by a hybrid electronic control unit (HECU) developed by the authors, which can be adjusted freely according to the commands from a calibration computer. During the test, hydrogen flow rate was varied to ensure that hydrogen volume fraction in the intake was constantly kept at 3%. For the specified hydrogen addition level, gasoline flow rate was reduced to make the engine operate at idle and lean conditions with various excess air ratios. The test results demonstrated that cyclic variations in engine idle speed and indicated mean effective pressure were eased with hydrogen enrichment. The indicated thermal efficiency was obviously higher for the HHGE than that for the original gasoline engine at idle and lean conditions. The indicated thermal efficiency at an excess air ratio of 1.37 was increased from 13.81% for the original gasoline engine to 20.20% for the HHGE with a 3% hydrogen blending level. Flame development and propagation periods were also evidently shortened after hydrogen blending. Moreover, HC, CO and NOx emissions were all improved after hydrogen enrichment at idle and lean conditions. Therefore, the HHE methodology is an effective and promising way for improving engine idle performance at lean conditions.     

Experimental study on combustion and emissions performance of a hybrid hydrogen–gasoline engine at lean burn limits

Lean combustion is an effective way for improving the spark-ignited (SI) engine performance. Unfortunately, due to the narrow flammability of gasoline, the pure gasoline-fueled engines sometimes suffer partial burning or misfire at very lean conditions. Hydrogen has many excellent combustion properties that can be used to extend the gasoline engine lean burn limit and improve the gasoline engine performance at lean conditions. In this paper, a 1.6 L port fuel injection gasoline engine was modified to be a hybrid hydrogen–gasoline engine (HHGE) fueled with the hydrogen–gasoline mixture by mounting an electronically controlled hydrogen injection system on the intake manifolds while keeping the original gasoline injection system unchanged. A self-developed hybrid electronic control unit (HECU) was used to flexibly adjust injection timings and durations of gasoline and hydrogen. Engine tests were conducted at 1400 rpm and a manifolds absolute pressure (MAP) of 61.5 kPa to investigate the performance of an HHGE at lean burn limits. Three hydrogen volume fractions in the total intake gas of 1%, 3% and 4.5% were adopted. For a specified hydrogen volume fraction, the gasoline flow rate was gradually reduced until the engine reached the lean burn limit at which the coefficient of variation in indicated mean effective pressure (COVimep) was 10%. The test results showed that COVimep at the same excess air ratio was obviously reduced with the increase of hydrogen enrichment level. The excess air ratio at the lean burn limit was extended from 1.45 of the original engine to 2.55 of the 4.5% HHGE. The engine brake thermal efficiency, CO, HC and NO_x emissions at lean burn limits were also improved for the HHGE.     

Effect of spark timing on the performance of a hybrid hydrogen–gasoline engine at lean conditions

Hydrogen addition is an effective way for improving the performance of spark-ignited (SI) engines at stoichiometric and especially lean conditions. Spark timing also heavily influences the SI engine performance. This paper experimentally investigated the effect of spark timing on performance of a hydrogen-enriched gasoline engine at lean conditions. The experiment was carried out on a four-cylinder, port-injection gasoline engine which was modified to be an electronically controlled hybrid hydrogen–gasoline engine (HHGE) by adding a hydrogen port-injection system on the intake manifolds while keeping the original gasoline injection system unchanged. A hybrid electronic control unit (HECU) was developed to govern the injection timings and durations of hydrogen and gasoline to enforce the timely mixing of hydrogen and gasoline in the intake ports at the expected blending levels and excess air ratios. During the test, the engine speed was fixed at 1400 rpm and the manifolds absolute pressure (MAP) was kept at 61.5 kPa. The hydrogen volume fraction in the intake was increased from 0% to 3% through adjusting the hydrogen injection duration. For a specified hydrogen addition level, gasoline injection duration was reduced to ensure the engine operating at two excess air ratios of 1.2 and 1.4, respectively. The spark timing for a specified hydrogen addition level and excess air ratio was varied from 20 to 50 °CA BTDC with an interval of 2 °CA. The test results showed that the indicated mean effective pressure (Imep) first increased and then decreased with the increase of spark advance. The optimum spark timing for the max. Imep (OST) was retarded for the HHGE at a specified excess air ratio. The max. indicated thermal efficiency appeared at the OST. Flame development period was shortened whereas flame propagation period was prolonged with the decrease of spark advance. The coefficient of variation in indicated mean effective pressure generally gained its minimum value at the OST. HC and NOx emissions were continuously decreased with the retarding of spark timing. However, the effect of spark timing on CO emission was found insignificant.     

An experimental study on performance and emission characteristics of a methane–hydrogen fuelled gasoline engine

In this paper, the performance and emission characteristics of a conventional twin-cylinder, four stroke, spark-ignited (SI) engine that is running with methane–hydrogen blends have been investigated experimentally. The engine was modified to realize hydrogen port injection by installing hydrogen feeding line in the intake manifolds. The experimental results have been demonstrated that the brake specific fuel consumption (BSFC) increased with the increase of hydrogen fraction in fuel blends at low speeds. On the other hand, as hydrogen percentage in the mixture increased, BSFC values decreased at high speeds. Furthermore, brake thermal efficiencies were found to decrease with the increase in percentage of hydrogen added. In addition, it has been found that CO₂, NO_x and HC emissions decrease with increasing hydrogen. However, CO emissions tended to increase with the addition of hydrogen generally increase. It has been showed that hydrogen is a very good choice as a gasoline engine fuel. The data are also very useful for operational changes needed to optimize the hydrogen fuelled SI engine design.     

On-board generation of hydrogen to improve in-cylinder combustion and after-treatment efficiency and emissions performance of a hybrid hydrogen–gasoline engine

Hydrogen on-board fuel reforming has been identified as a waste energy recovery technology with potential to improve Internal combustion engines (ICE) efficiency. Additionally, can help to reduce CO₂, NO_x and particulate matter (PM) emissions. As this thermochemical energy is recovered from the hot exhaust stream and used in an efficient way by endothermic catalytic reforming of petrol mixed with a fraction of the engine exhaust gas. The hydrogen-rich reformate has higher enthalpy than the petrol fed to the reformer and is recirculated to the intake manifold, which will be called reformed exhaust gas recirculation (rEGR).The rEGR system has been simulated by supplying hydrogen (H₂) and carbon monoxide (CO) into a conventional Exhaust Gas Recirculation (EGR) system. The hydrogen and CO concentrations in the rEGR stream were selected to be achievable in practice at typical gasoline exhaust temperatures (temperatures between 300 and 600 °C). A special attention has been paid on comparing rEGR to the baseline ICE, and to conventional EGR. The results demonstrate the potential of rEGR to simultaneously increase thermal efficiency, reduce gaseous emissions and decrease PM formation.Complete fuel reformation can increase the calorific value of the fuel by 28%. This energy can be provided by the waste heat in the exhaust and so it is ideal for combination with a gasoline engine with its high engine-out exhaust temperatures.The aim of this work is to demonstrate that exhaust gas fuel reforming on an engine is possible and is commercially viable. Also, this paper demonstrates how the combustion of reformate in a direct injection gasoline engine via reformed Exhaust Gas Recirculation (rEGR) can be beneficial to engine performance and emissions.     

Combustion characteristics of a lean premixed LPG–air combustor

Fuel/air mixing effects in a premixer have been examined to investigate the combustion characteristics, such as the emission of NO_x and CO, under simulated lean premixed gas turbine combustor conditions at normal and elevated pressures of up to 3.5 bar with air preheat temperature of 450 K. The results obtained have been compared with a diffusion flame type gas turbine combustor for emission characteristics. The results show that the NO_x emission is profoundly affected by the mixing between fuel and air in the combustor. NO_x emission is lowered by supplying uniform fuel/air gas mixture to the combustor and the NO_x emission reduces with decrease in residence time of the hot gases in the combustor. The NO_x emission level of the lean premixed combustor is a strong function of equivalence ratio and the dependency is smaller for a traditional diffusion flame combustor under the examined experimental conditions. Furthermore, the recirculation flow, affected by dome angle of combustor, reduces the high temperature reaction zone or hot spot in the combustor, thus reducing the NO_x emission levels.     

Combustion behaviors of a direct-injection engine operating on various fractions of natural gas–hydrogen blends

Combustion behaviors of a direct injection engine operating on various fractions of natural gas–hydrogen blends were investigated. The results showed that the brake effective thermal efficiency increased with the increase of hydrogen fraction at low and medium engine loads and high thermal efficiency was maintained at the high engine load. The phase of the heat release curve advanced with the increase of hydrogen fraction in the blends. The rapid combustion duration decreased and the heat release rate increased with the increase of hydrogen fraction in the blends. This phenomenon was more obviously at the low engine speed, suggesting that the effect of hydrogen addition on the enhancement of burning velocity plays more important role at relatively low cylinder air motion. The maximum mean gas temperature and the maximum rate of pressure rise increased remarkably when the hydrogen volumetric fraction exceeds 20% as the burning velocity increases exponentially with the increase of hydrogen fraction in fuel blends. Exhaust HC and _CO2${\mathrm{CO}}_2$ concentrations decreased with the increase of the hydrogen fraction in fuel blends. Exhaust _NOx${\mathrm{NO}}_x$ concentration increased with the increase of hydrogen fraction at high engine load. The study suggested that the optimum hydrogen volumetric fraction in natural gas–hydrogen blends is around 20% to get the compromise in both engine performance and emissions.     

Combustion and emissions behaviour for methanol–gasoline blended fuels in a multipoint electronic fuel injection engine

The purpose of this study is to experimentally investigate the performance, combustion and pollutant emissions of a multipoint electronic fuel injection gasoline engine using methanol–gasoline blends. The results indicated that, with the increase in methanol (CH₃OH) content in the blends, the maximum engine torque and power are slightly decreased, the brake specific fuel consumption is evidently increased and brake thermal efficiency remains almost identical. At low engine loads and speeds, gasoline is observed to have faster combustion velocity, but the blends are faster at high engine loads and speeds. The carbon monoxide of the blends is slightly lower, hydrocarbon is slightly higher at high engine loads and nitrogen oxide is lower for M10 at low engine loads. The emissions of formaldehyde are evidently higher with the increase in CH₃OH content, but CH₃OH and acetaldehyde emissions of the blends show little variation.     

Comparison and analysis of the emissions of a small non-road spark-ignition engine operating under different alcohol–gasoline blended fuels

In this experimental study we focused our interest on comparing the effect of lower and higher molecular mass alcohol–gasoline-blended fuels on the regulated emissions emitted by a small non-road spark-ignition engine. Twenty-one test fuels were used in this experimental study that included gasoline as a reference as well as low and high molecular mass alcohol–gasoline blends containing 5%, 10%, 20% and 40% v/v. In exhaust gases that originated from alcohol gasoline test fuels, low CO/HC and high CO₂/NO_x emissions were observed as the total percentage of alcohol in the blend increased. Methanol–gasoline blends seemed to achieve good combustion efficiency, but the engine will require a catalytic converter against high NO_x emissions. Butanol–gasoline blends in several cases gave lower emissions in comparison with the ethanol and propanol–gasoline blends. Finally, the pentanol–gasoline blends showed exactly the same emission patterns as those of neat gasoline.     

Parametric study on combustion characteristics of virtual HCCI engine fueled with methane–hydrogen blends under low load conditions

Homogeneous charge compression ignition (HCCI) is an alternative combustion strategy employed for automotive systems. It has a higher thermal efficiency with lower nitric oxides and particulate matter emissions that are below current emission requirements. However, owing to difficulties associated with combustion control, HCCI engines have disadvantages in terms of combustion instability, such as low-speed-low-load or high-speed-high-load conditions.This study investigates the effects of different parameters on HCCI engine combustion using numerical methods. The parametric study is carried out at low loads (25% part load), and a reference intake temperature of 550 K is used to preheat the air–fuel mixture. The GRI-3.0 chemical reaction mechanism involving 53 species and 325 reactions is used for 1-D simulations describing the combustion process fueled with methane and hydrogen added methane. By changing the variables, including compression ratio, excess air ratio, and hydrogen content, the combustion behavior is investigated and discussed. The results show that an increase in compression ratio resulted in a faster start of combustion and caused higher in cylinder pressure and heat-release rate. When the excess air ratio was increased, the start of combustion was delayed and lower in-cylinder pressure and heat release rate were observed. The results were similar for varying compression ratios.     

Generating efficiency and emissions of a spark-ignition gas engine generator fuelled with biogas–hydrogen blends

We investigated the generating efficiency and pollutant emissions of a four-stroke spark-ignition gas engine generator operating on biogas–hydrogen blends of varying excess air ratios and hydrogen concentrations. Experiments were carried out at a constant engine speed of 1200 rpm and a constant electric power output of 10 kW. The experimental results showed that the peak values of generating efficiency, maximum cylinder pressure, and NO_x emissions were elevated at an excess air ratio of around 1.2 as the hydrogen concentration was increased. CO₂ emissions decreased as the excess air ratio and hydrogen concentration increased, due to lean-burn conditions and hydrogen combustion. An efficiency per NO_x emissions ratio (EPN) was defined to consider the relationship between the generating efficiency and NO_x emissions. A maximum EPN value of 0.7502 was obtained with a hydrogen concentration of 15%, for an excess air ratio of 2.0. At this EPN value, the NO_x and CO₂ emissions were 39 ppm and 1678.32 g/kWh, respectively, and the generating efficiency was 29.26%. These results demonstrated that the addition of hydrogen to biogas enabled the effective generation of electricity using a gas engine generator through lean-burn combustion.     

Combustion and emission characteristics of an off-road diesel engine fuelled with biodiesel–diesel blends

In this work, the combustion and emission characteristics were studied in a 186FA diesel engine fuelled with biodiesel–diesel to examine the effect of the percentage of biodiesel in the blends, and the experimental investigation was conducted with various blending ratios of biodiesel under different operating conditions. In addition, the combustion noise of the diesel engine fuelled with biodiesel–diesel was analysed, and then the emission characteristics of NO_x and soot were studied through simulation analysis where the formation rate and distribution of NO_x and soot for pure diesel and B20 fuel were described. Based on the simulation data of the original diesel engine fuelled with B20 fuel, the swirl ratio and fuel injection timing were optimised and the technical measures were suggested to reduce the two different emissions simultaneously. The simulation results showed the emission characteristics were optimal when the swirl ratio was 2.7 and fuel injection timing was 7.5° degree of crank angle before top dead centre respectively.     

Experimental and modeling study of performance and emissions of SI engine fueled by natural gas–hydrogen mixtures

Based on CFD software and reaction kinetics software, multi-dimensional CFD Model coupled with detail reaction kinetics is built to study the combustion process in H₂/CNG Engine. Detail reaction mechanism is used to simulate the chemistry of combustion and a combustion model considering the turbulent mixing effects was also applied. To reduce the computation time, the coupled software is reprogrammed to have the function of parallel computing and the revised software is computed in a Massively Parallel Processor. The model is validated using the experiment data from a modified diesel engine. The results show: cylinder pressure from simulation has a good agreement with experiment data and CO and NO_x emission is well predicted by the model in a wide range.     

Combustion characteristics and flame-kernel development of a laser ignited hydrogen–air mixture in a constant volume combustion chamber

Laser ignition of hydrogen–air mixture was carried out in a constant volume combustion chamber (CVCC) at 10 bar initial chamber filling pressure and 373 K chamber temperature. A Q-switched Nd:YAG laser at 1064 nm with a pulse duration of 6–9 ns was used for plasma generation and ignition of combustible hydrogen–air mixture. Pressure–time history of different hydrogen–air mixtures was measured in the CVCC and flammability limits of hydrogen–air mixture were measured. Flame kernel development was investigated for different air–fuel mixtures using Shawdowgraphy and flame propagation distances were calculated. Minimum ignition energy was measured for hydrogen–air mixtures of different air–fuel ratios and effect laser pulse energy on pressure–time history in the CVCC was experimentally measured. Upon increasing the laser pulse energy, time taken to attain peak cylinder pressure reduced which resulted in faster combustion in hydrogen–air mixtures however the peak cylinder pressure remained similar.     

Generation of combustion irreversibilities in a spark ignition engine under biogas–hydrogen mixtures fueling

Availability analysis is applied to the cylinder of a spark ignition engine during the closed part of the engine cycle when biogas–hydrogen blends, with volumetric fractions of hydrogen up to 15%, are used as fuel. The focal point is on the demonstration of the spatial distribution inside the burned gas of the combustion-generated irreversibilities for the various hydrogen concentration cases examined, which constitute one of the major sources for the defective exploitation of fuel into useful mechanical work that cannot be identified by the traditional first-law analysis. For this reason, an experimentally validated closed cycle simulation code is used, based on a multi-zone thermodynamic model of the cylinder content, applied in conjunction with a quasi-dimensional combustion model for burn rate predictions. After presenting global availability-balance-related results, pointing out the increase in the second-law efficiency of engine operation with the hydrogen enrichment of biogas, detailed information is provided regarding the spatial development of the combustion irreversibilities throughout the thermodynamically inhomogeneous burned gas, along with their link with the developed temperature field, as determined during combustion at each hydrogen fraction. It is revealed that the addition of increasing amounts of hydrogen in biogas promotes the degree of reversibility of the burning process mainly during the combustion of the later burning gas, due to the incurred increase in its combustion temperatures. On the contrary, the contribution of the early burning gas to the decrease in combustion irreversibilities with hydrogen addition seems to be less prominent.     

Experimental investigation on performance and emissions of a spark-ignition engine fuelled with natural gas–hydrogen blends combined with EGR

An experimental investigation on the influence of different hydrogen fractions and EGR rates on the performance and emissions of a spark-ignition engine was conducted. The results show that large EGR introduction decreases the engine power output. However, hydrogen addition can increase the power output at large EGR operation. Effective thermal efficiency shows an increasing trend at small EGR rate and a decreasing trend with further increase of EGR rate. In the case of small EGR rate, effective thermal efficiency is decreased with the increase of hydrogen fraction; while in the case of large EGR rate, thermal efficiency is increased with increasing of hydrogen fraction. For a specified hydrogen fraction, NO_x concentration is decreased with the increase of EGR rate and this effectiveness becomes more obviously at high hydrogen fraction. HC emission is increased with the increase of EGR rate and it decreases with the increase of hydrogen fraction. CO and CO₂ emissions show little variations with EGR rate, but they decrease with the increase of hydrogen fraction. The study shows that natural gas–hydrogen blend combining with EGR can realize high-efficiency and low-emission spark-ignition engine.     

Combustion stability limits and NOx emissions of nonpremixed ammonia-substituted hydrogen–air flames

The combustion stability (extinction) limits and nitrogen oxide (NO_x) emissions of nonpremixed ammonia (NH₃)–hydrogen (H₂)–air flames at normal temperature and pressure are studied to evaluate the potential of partial NH₃ substitution for improving the safety of H₂ use and to provide a database for the nonpremixed NH₃-substituted H₂–air flames. Considering coflow nonpremixed NH₃–H₂–air flames for a wide range of fuel and coflow air injection velocities (V_fuel and V_coflow) and the extent of NH₃ substitution, the effects of NH₃ substitution on the stability limits and NO_x emissions of the NH₃–H₂–air flames are experimentally determined, while the nonpremixed NH₃–H₂–air flame structure is computationally predicted using a detailed reaction mechanism. Results show significant reduction in the stability limits and unremarkable increase in the NO_x emission index for enhanced NH₃ substitution, supporting the potential of NH₃ as an effective, carbon-free additive in nonpremixed H₂–air flames. With increasing V_coflow the NO_x emission index decreases, while with increasing V_fuel it decreases and then increases due to the recirculation of burned gas and the reduced radiant heat losses, respectively. Given V_coflow/V_fuel the flame length increases with enhanced NH₃ substitution since more air is needed for reaction stoichiometry. The predicted flame structure shows that NH₃ is consumed more upstream than H₂ due to the difference between their diffusivities in air.     

Simulation of catalytic oxidation of lean hydrogen–methane mixtures

The combustion of preheated lean homogeneous mixtures of hydrogen with methane in air in a catalytic packed-bed reactor was modeled at atmospheric pressure. The non-equilibrium, one-dimensional model developed employs multi-step surface and gas-phase reactions and accounts for the three modes of heat transfer within the bed as well as for heat loss from the bed. The catalyst considered was platinum. It was demonstrated that the model could predict the effects of changes in operational conditions such as inlet mixture temperature, fuel composition and mixture equivalence ratio on the methane and hydrogen conversions, as well as species concentrations and gas temperature profiles along the bed. It was shown that the hydrogen is consumed completely within the early part of the reactor length in all the cases considered for simulations. It was also shown that the improving effect of hydrogen on methane conversion is particularly evident at relatively low inlet temperatures and for very lean mixtures. However, this effect diminishes significantly with increasing inlet temperature and equivalence ratio. It was also shown that the positive effect of hydrogen addition which is more pronounced at its low concentrations in the fuel mixture, decreases somewhat with a further increase of the hydrogen content. The displayed trends were in good agreement with the corresponding experimentally observed.