Operation of first solar-hydrogen system in China

The first solar-hydrogen (S-H) system in China, which consists a 2 kW PV cell array, a 48 V/300Ah lead-acid battery bank, an 0.5 Nm³/h hydrogen production capacity alkaline water electrolyzer, a 10 Nm³ LaNi₅ alloy hydrogen storage tank and a 200 W H₂/air PEM fuel cell, was installed in the Institute of Nuclear and New Energy Technology (INET) of Tsinghua University and has been operated for several months. The goal of the system was to study the technical and economical feasibility of using such a system to produce hydrogen in large scale for the future hydrogen energy society. With two months operation, experimental results reveal 40.68% energy transformed to hydrogen with 7.21 kWh/Nm³ H₂ electricity consumption. Economic analysis results illustrate that the present system is not cost-efficient and the energy conversion efficiencies of PV panel and electrolyzer are suggested to increase in technology improvement to cut down cost.     

Simulation of design and operation of hydrogen energy utilization system for a zero emission building

Nearly 40% of the total greenhouse gases (GHGs) are emitted from the energy consumption in buildings in Japan, which should be reduced to address global warming. A hydrogen energy utilization system with renewable energy (RE) was designed by MATLAB/Simulink simulations for realizing a zero emission building (ZEB), comprising a hydrogen-producing electrolyzer, a hydrogen storage tank, fuel cell, and battery for short-term power storage with estimated specifications of 3.0 Nm³/h, 36 Nm³, 4.2 kW, and 10 kW/17 kWh, respectively. We identified a small low-rise building (total floor area: ∼1000 m², demand: ∼5 kW) as the planned ZEB to construct and operate a bench-scale system. A 20-kW photovoltaic (PV) system was selected as the RE source. Two hydrogen production processes (constant power of 10 kW or with excess PV power) were evaluated by simulating 48-h operations on fine and cloudy days, where the former showed higher efficiency. The results with excess power on a fine day agreed well with that of actual operation, validating our simulation models. Further, the constant case was suitable for practical application.     

Thermal management and power saving operations for improved energy efficiency within a renewable hydrogen energy system utilizing metal hydride hydrogen storage

To ensure the energy efficiency of renewable hydrogen energy systems, power conservation and thermal management are necessary. This study applies these principals to the operation of metal hydride tanks (MHTs) in a bench-scale hydrogen system, named Hydro Q-BiC?, comprising photovoltaic panels (20 kW), an electrolyzer (5 Nm³/h), MHTs containing a TiFe-based MH (40 Nm³), fuel cells (FC; 3.5 kW(power)/2.5 kW(heat)), and Li-ion batteries (20 kW/20 kWh). Here, we show that in a modified hydrogen production operation, with limited use of auxiliaries for cooling the MHTs, the power consumption of the MHTs was reduced by more than 99% compared to a typical operation. The thermal requirements for the MHTs were reduced by ceasing production in a pressurized state. During the hydrogen use operation, the power consumption was reduced to 1/4 and the FC heat output could be fully used; hence, the overall energy efficiency (power-to-hydrogen-to-power/heat) was as high as ~ 60% (43% for the typical operation).     

Construction and operation of hydrogen energy utilization system for a zero emission building

A bench-scale stationary hydrogen energy utilization system with renewable energy (RE) that realizes a zero emission building (ZEB) is presented. To facilitate compactness, safety, and mild operation conditions, a polymer electrolyte membrane (PEM) electrolyzer for hydrogen production (5 Nm³/h), PEM fuel cells (FC) for hydrogen use (3.5 kW), and metal hydride (MH) tanks for hydrogen storage (80 Nm³) are incorporated. Each hydrogen apparatus and Li-ion batteries (20 kW/20 kWh) are installed in a 12-ft. container and 20-kW photovoltaic panels provide power. A building energy management system (BEMS) controlled these system components in an integrated manner. The PEM Ely and FC have fast start-up and high efficiency under partial load operations, indicating suitability for daily start-stop operations. An AB-type TiFe-based alloy (520 kg) is used as the MH (not an AB₅-type rare earth alloy that has been commonly used in bench-scale hydrogen store) because, in addition to being low-cost, it is non-hazardous material under Japanese regulations. The results of a 24-h operation experiment verify ZEB attainment. PEM FC and TiFe-based tanks thermal integration results indicate that hydrogen use operation is achievable without external heat sources.     

Performance investigation of hydrogen production from a hybrid wind-PV system

In this study, a hybrid system consisted of 10 kW wind and 1 kWp PV array is built to meet the load demand of a raise chucker partridge raising facility by renewable energy sources. The facility has an average energy consumption of about 20.33 kWh/day, with a peak demand of 2.4 kW. The solar radiation data and wind data of the region are analyzed for sizing of the renewable energy system. The performance of each alternative system is examined in terms of energy efficiency, and H₂ production capacity of the hybrid system from due to excessive electrical energy is studied. A Matlab-Simulink Software is used for analyzing the system performance. The average range of state of charge varies between 56.6% and 88.3% monthly from April to July. The amount of hydrogen production by excess electricity is 14.4 kg in the month of July, due to the high wind speed and solar radiation. Energy efficiency of the electrolyser is found to be varying between 64% and 70% percent. Energy efficiency of each hybrid system is calculated. The overall energy efficiency of wind-electrolyser system varies between 5% and 14% while the energy efficiency of PV-electrolyser system changes within a narrower range, as between 7.9% to and 8.5%, respectively.     

Development of membrane reformer system for highly efficient hydrogen production from natural gas

A membrane reformer is composed of a steam reformer equipped with palladium-based alloy membrane modules and can perform steam reforming reaction of natural gas and hydrogen separation processes simultaneously, without shift converters and purification systems. We have developed a membrane reformer system with nominal hydrogen production capacity of 40 Nm³/h. The system has demonstrated the potential advantages of the membrane reformer: simple system configuration as benefited by single-step production of high-purity hydrogen (99.999% level), compactness, and high-energy efficiency of 70–76%. We are promoting development towards commercialization of the membrane reformer technology, focusing on further improvement of energy efficiency, proof of long-term durability and reliability, and establishment of system engineering technologies. The target of our current project is to develop a membrane reformer system that can produce 99.99% or higher-purity hydrogen from natural gas at a rate of 40 Nm³/h with hydrogen production energy efficiency of over 80%.     

An experimental aluminum-fueled power plant

An experimental co-generation power plant (CGPP-10) using aluminum micron powder (with average particle size up to 70 μm) as primary fuel and water as primary oxidant was developed and tested. Power plant can work in autonomous (unconnected from industrial network) nonstop regime producing hydrogen, electrical energy and heat. One of the key components of experimental plant is aluminum-water high-pressure reactor projected for hydrogen production rate of ∼10 nm³ h⁻¹. Hydrogen from the reactor goes through condenser and dehumidifier and with −25 °C dew-point temperature enters into the air-hydrogen fuel cell 16 kW-battery. From 1 kg of aluminum the experimental plant produces 1 kWh of electrical energy and 5-7 kWh of heat. Power consumer gets about 10 kW of electrical power. Plant electrical and total efficiencies are 12% and 72%, respectively.     

Off-grid hybrid renewable energy system with hydrogen storage for South African rural community health clinic

Most inhabitants of rural communities in Africa lack access to clean and reliable electricity. This has deprived the rural dwellers access to modern healthcare delivery. In this paper, an off-grid renewable energy system consisting of solar PV and wind turbine with hydrogen storage scheme has been explored to meet the electrical energy demands of a health clinic. The health clinic proposed is a group II with 10 beds located in a typical village in South Africa. First, the wind and solar energy resources of the village were analysed. Thereafter, the microgrid architecture that would meet the energy demand of the clinic (18.67 kWh/day) was determined. Some of the key results reveal that the average annual wind speed at 60 m anemometer height and solar irradiation of the village are 7.9 m/s and 4.779 kWh/m²/day, respectively. The required architecture for the clinic composes of 40 kW solar PV system, 3 numbers of 10 kW wind turbines, 8.6 kW fuel cell, 25 kW electrolyser and 40 kg hydrogen tank capacity. The capital cost of the microgrid was found to be $177,600 with a net present cost of $206,323. The levelised cost of energy of the system was determined to be 2.34 $/kWh. The project has a breakeven grid extension distance of 8.81 km. Since this distance is less than the nearest grid extension distance of 21.35 km, it is established that the proposed renewable energy microgrid with a hydrogen storage system is a viable option for the rural community health clinic.     

Feasibility study of hydrogen production from wind power in the region of Ghardaia

A feasibility study on hydrogen production from wind power on the site of Ghardaia is carried out. This study is based on the estimation of the hydrogen rate produced by a 5 kW electrolyser fed by the electricity provided by a 10 kW wind turbine.Wind speed data were used to study the monthly variation of the wind power delivered and its variation according to the height of the wind turbine tower.The obtained results show that it is possible to improve the system output by increasing the height of the wind turbine tower. Indeed, it has been obtained 3200 Nm³ of hydrogen production for a 30 m wind turbine height and 4200 Nm³ at 60 m.In addition, it has been noticed that hydrogen production varies strongly with the months of the year. Thus, the production has reached a maximum of 395 Nm³ in May and a minimum of 187 Nm³ during November and October.     

Hydrogen generation from small-scale wind-powered electrolysis system in different power matching modes

This study presents a techno-economic evaluation on hydrogen generation from a small-scale wind-powered electrolysis system in different power matching modes. For the analysis, wind speed data, which measured as hourly time series in Kirklareli, Turkey, were used to predict the electrical energy and hydrogen produced by the wind–hydrogen energy system and their variation according to the height of the wind turbine. The system considered in this study is primarily consisted of a 6 kW wind-energy conversion system and a 2 kW PEM electrolyzer. The calculation of energy production was made by means of the levelized cost method by considering two different systems that are the grid-independent system and the grid-integrated system. Annual production of electrical energy and hydrogen was calculated as 15,148.26 kWh/year and 102.37 kg/year, respectively. The highest hydrogen production is obtained in January. The analyses showed that both electrical energy and hydrogen production depend strongly on the hub height of wind turbine in addition to the economic indicators. In the grid-integrated system, the calculated levelized cost of hydrogen changes in the range of 0.3485–4.4849 US$/kg for 36 m hub height related to the specific turbine cost. The grid-integrated system can be considered as profitable when the excess electrical energy delivered by system sold to the grid.     

Hydrogen-based PEM auxiliary power unit

Hydrogen is an energy carrier which can be used for the storage of intermittent and renewable energy sources. In this paper, the general characteristics of an integrated and automated hydrogen-based auxiliary power unit (APU) are presented. A PEM water electrolyzer (production capacity ranging from zero up to 1 Nm³ H₂/h), which can be powered by a panel of photovoltaic cells, is used to produce hydrogen at day hours. Hydrogen is dried and stored in hydride reservoir tanks (the storage capacity of individual reservoirs is 1 Nm³ H₂). Then hydrogen is used for the co-generation of heat and electricity at night hours using a PEM fuel cell (1 kW maximum output power). The main electrochemical and technological features of the overall system are presented. This kind of APU can potentially be used as an electric power source for domestic applications, for the production of electricity on remote sites or as a mobile hydrogen refuelling station for transport applications in urban areas.     

Wind energy,electricity, and hydrogen in the Netherlands

The curbing of greenhouse gases (GHG) is an important issue on the international political agenda. The substitution of fossil fuels by renewable energy sources is an often-advocated mitigation strategy. Wind energy is a potential renewable energy source. However, wind energy is not reliable since its electricity production depends on variable weather conditions. High wind energy penetration rates lead to losses due to power plant operation adjustments to wind energy. This research identifies the potential energetic benefits of integrated hydrogen production in electricity systems with high wind energy penetration. This research concludes that the use of system losses for hydrogen production via electrolysis is beneficial in situations with ca. 8 GW or more wind energy capacity in the Netherlands. The 2020 Dutch policy goal of 6 GW will not benefit from hydrogen production in terms of systems efficiency. An ancillary beneficial effect of coupling hydrogen production with wind energy is to relieve the high-voltage grid.     

Potential and costs for the production of electrolytic hydrogen in alcohol and sugar cane plants in the central and south regions of Brazil

This project verified the potential for the production of hydrogen via water electrolysis by using the exceeding electrical energy resultant from alcohol and sugar plants that use sugar cane bagasse as fuel. The studies were carried out in cogeneration plants authorized by the Electrical Energy National Agency (ANEEL). The processing history of sugar cane considered was based on the 2006/2007 harvests. The total bagasse produced, electrical energy generated and exceeding electrical energy in a year were calculated. It was obtained an average energy consumption value of 5.2 kWh Nm⁻³ and the hydrogen production costs regarding the amount of sugar cane processed that ranged from US$ 0.50 to US$ 0.75 Nm⁻³. The results pointed that the costs for the production of hydrogen via the bagasse exceeding energy are close to the production costs that use other sources of energy. As the energy generated from the bagasse is a renewable one, this alternative for the production of hydrogen is economical and environmentally viable.     

Stand-alone PEM water electrolysis system for fail safe operation with a renewable energy source

A complete stand-alone electrolyser system has been constructed as a transportable unit for demonstration of a sustainable energy facility based on hydrogen and a renewable energy source. The stand-alone unit is designed to support a polymer electrolyte membrane (PEM) stack operating at up to ∼4 kW input power with a stack efficiency of about 80% based on HHV of hydrogen. It is self-pressurizing and intended for operation initially at a differential pressure of less than 6 bar across the membrane electrode assembly with the hydrogen generation side being at a higher pressure. With a slightly smaller stack, the system has been operated at an off-site facility where it was directly coupled to a 2.4 kW photovoltaic (PV) solar array. Because of its potential use in remote areas, the balance-of-plant operates entirely on 12 V DC power for all monitoring, control and safety requirements. It utilises a separate high-current supply as the main electrolyser input, typically 30–40 V at 100 A from a renewable source such as solar PV or wind. The system has multiple levels of built-in operator and stack safety redundancy. Control and safety systems monitor all flows, levels and temperatures of significance. All fault conditions are failsafe and are duplicated, triggering latching relays which shut the system down. Process indicators monitor several key variables and allow operating limits to be easily adjusted in response to experience of system performance gained in the field.     

Hydrogen production from wind energy in Western Canada for upgrading bitumen from oil sands

Hydrogen is produced via steam methane reforming (SMR) for bitumen upgrading which results in significant greenhouse gas (GHG) emissions. Wind energy based hydrogen can reduce the GHG footprint of the bitumen upgrading industry. This paper is aimed at developing a detailed data-intensive techno-economic model for assessment of hydrogen production from wind energy via the electrolysis of water. The proposed wind/hydrogen plant is based on an expansion of an existing wind farm with unit wind turbine size of 1.8 MW and with a dual functionality of hydrogen production and electricity generation. An electrolyser size of 240 kW (50 Nm³ H₂/h) and 360 kW (90 Nm³ H₂/h) proved to be the optimal sizes for constant and variable flow rate electrolysers, respectively. The electrolyser sizes aforementioned yielded a minimum hydrogen production price at base case conditions of $10.15/kg H₂ and $7.55/kg H₂. The inclusion of a Feed-in-Tariff (FIT) of $0.13/kWh renders the production price of hydrogen equal to SMR i.e. $0.96/kg H_2, with an internal rate of return (IRR) of 24%. The minimum hydrogen delivery cost was $4.96/kg H₂ at base case conditions. The life cycle CO₂ emissions is 6.35 kg CO₂/kg H₂ including hydrogen delivery to the upgrader via compressed gas trucks.     

Testing of a small-scale stand-alone power system based on solar energy and hydrogen

An experimental small-scale stand-alone power system based on hydrogen and solar energy has been tested. The system performance and operational experience are reported. Future expansion of the test-facility is taken into consideration using solutions with wide working ranges. The test-facility is designed for testing of individual components, for subsystems, and for complete power system operation. The complete power system in this study consists of a 4.8 kW programmable power supply, 1.5 kW electrolyser, a hydrogen purification unit (99.999% H₂ quality), a 14 Nm³ H₂ metal hydride storage, a 0.5 kW fuel cell, a 300 Ah lead-acid battery, and a 0.6 kW programmable load. Possible applications for such small-scale power systems are mountain cabins, remote islands, and telecommunication stations, among others. The basic idea in this particular power system configuration was to make it as simple as possible; the fuel cell and the metal hydride unit were air-cooled, and the components were connected in parallel without DC/DC converters. The only control action possible in the power system (presented in this study) was to switch the components either ON or OFF. However, connecting the components electrically in parallel without DC/DC converters gives no degrees of freedom regarding the ability to regulate power and voltage levels of the different components. Air-cooled metal hydrides might fail to deliver hydrogen due to poor heat transfer.     

Manipulating the hydrogen production from acetate in a microbial electrolysis cell-microbial fuel cell-coupled system

A biological hydrogen-producing system is configured through coupling an electricity-assisting microbial fuel cell (MFC) with a hydrogen-producing microbial electrolysis cell (MEC). The advantage of this biocatalyzed system is the in-situ utilization of the electric energy generated by an MFC for hydrogen production in an MEC without external power supply. In this study, it is demonstrated that the hydrogen production in such an MEC-MFC-coupled system can be manipulated through adjusting the power input on the MEC. The power input of the MEC is regulated by applying different loading resistors connected into the circuit in series. When the loading resistance changes from 10 Ω to 10 kΩ, the circuit current and volumetric hydrogen production rate varies in a range of 78 ± 12 to 9 ± 0 mA m⁻² and 2.9 ± 0.2 to 0.2 ± 0.0 mL L⁻¹ d⁻¹, respectively. The hydrogen recovery (RH₂), Coulombic efficiency (CE), and hydrogen yield (YH₂) decrease with the increase in loading resistance. Thereafter, in order to add power supply for hydrogen production in the MEC, additional one or two MFCs are introduced into this coupled system. When the MFCs are connected in series, the hydrogen production is significantly enhanced. In comparison, the parallel connection slightly reduces the hydrogen production. Connecting several MFCs in series is able to effectively increase power supply for hydrogen production, and has a potential to be used as a strategy to enhance hydrogen production in the MEC-MFC-coupled system from wastes.     

Estimating global hydrogen production from wind

It is likely that intermittent renewable sources such as wind and solar will provide the greatest opportunity for future large-scale hydrogen production. Here, on-shore wind is examined. Global wind energy is estimated by placing one 2 MW turbine/km² over the surface of the earth. Wind energy production is based on monthly mean wind speed data. Wind turbines are grouped to form arrays that are linked to local hydrogen generation and transmission networks. Hydrogen generation is done via low-pressure electrolysis and transmission via high-pressure gas pipelines. The wind/hydrogen system is considered within a global energy system that must not only provide hydrogen, but also energy for electricity consumption at the local generation site. The technical potential of the hydrogen produced is estimated to be 116 EJ. Uneven distribution of the hydrogen-rich sites results in the need to export much of the hydrogen produced to energy-poor regions. To overcome system losses, a combined wind/HVDC/hydrogen system is considered.     

Robust hydrogen detection system with a thermoelectric hydrogen sensor for hydrogen station application

A prototype hydrogen detection system using the micro-thermoelectric hydrogen sensor (micro-THS) was developed for the safety of hydrogen infrastructure systems, such as hydrogen stations. We have designed a detection part with a pressure proof enclosure adoptable for the international standard of Exd II CT3, and carried out an explosion strength test, explosion and fire hazard tests, and an impact test. The hydrogen sensing performance of the detection part of this prototype system showed a good linear relationship between the sensing signal and hydrogen concentrations in air, for a wide range of hydrogen concentrations from 10 ppm to 40,000 ppm (4 vol.%). This prototype detection system was installed in the outdoor field of the hydrogen station and the response for H₂ gas in air of 100 ppm, 1000 ppm, and 10000 ppm was tested monthly for 1 year.     

Direct coupling of an electrolyser to a solar PV system for generating hydrogen

Hydrogen as an energy currency, carrier and storage medium may be a key component of the solution to problems of global warming, poor air quality and dwindling reserves of liquid hydrocarbon fuels. Hydrogen is a flexible storage medium and can be generated by the electrolysis of water. It is particularly advantageous if an electrolyser may be simply and efficiently coupled to a source of renewable electrical energy. This paper examines direct coupling of a polymer electrolyte membrane (PEM) electrolyser to a matched solar photovoltaic (PV) source for hydrogen generation and storage. Such direct coupling with minimum interfacing electronics would lead to substantial cost reduction and thereby enhance the economic viability of solar-hydrogen systems. The electrolyser is designed for fail-safe operation with multiple levels of safety and operational redundancy. A control system in the electrolyser unit provides for disconnection when required and for auto-start in the morning and auto shut-down at night, simultaneously addressing the goals of minimum energy loss and maximum safety. The PV system is a 2.4 kW array (20.4 m² total area) comprising 30, 12 V, 80 W, Solarex polycrystalline modules in a series–parallel configuration. The integrated system has been operated for approximately 60 days over a 4-month period from September 2007 to January 2008 with many periods of unattended operation for multiple days, experiencing weather ranging from hot and sunny (above 40 °C) to cool and cloudy. The principle and practicality of direct coupling of a suitably matched PV array and PEM electrolyser have been successfully demonstrated. Details of electrolyser operation coupled to a PV array along with modelling work to match current–voltage characteristics of the electrolyser and PV system are described.