Analysis of exhaust waste heat recovery from a dual fuel low temperature combustion engine using an Organic Rankine Cycle

This paper examines the exhaust waste heat recovery potential of a high-efficiency, low-emissions dual fuel low temperature combustion engine using an Organic Rankine Cycle (ORC). Potential improvements in fuel conversion efficiency (FCE) and specific emissions (NO_x and CO₂) with hot exhaust gas recirculation (EGR) and ORC turbocompounding were quantified over a range of injection timings and engine loads. With hot EGR and ORC turbocompounding, FCE improved by an average of 7 percentage points for all injection timings and loads while NO_x and CO₂ emissions recorded an 18 percent (average) decrease. From pinch-point analysis of the ORC evaporator, ORC heat exchanger effectiveness (?), percent EGR, and exhaust manifold pressure were identified as important design parameters. Higher pinch point temperature differences (PPTD) uniformly yielded greater exergy destruction in the ORC evaporator, irrespective of engine operating conditions. Increasing percent EGR yielded higher FCEs and stable engine operation but also increased exergy destruction in the ORC evaporator. It was observed that hot EGR can prevent water condensation in the ORC evaporator, thereby reducing corrosion potential in the exhaust piping. Higher ? values yielded lower PPTD and higher exergy efficiencies while lower ? values decreased post-evaporator exhaust temperatures below water condensation temperatures and reduced exergy efficiencies.     

Assessment of hydrogen production from waste heat using hybrid systems of Rankine cycle with proton exchange membrane/solid oxide electrolyzer

A techno-economic assessment of hydrogen production from waste heat using a proton exchange membrane (PEM) electrolyzer and solid oxide electrolyzer cell (SOEC) integrated separately with the Rankine cycle via two different hybrid systems is investigated. The two systems run via three available cement waste heats of temperatures 360 °C, 432 °C, and 780 °C with the same energy input. The waste heat is used to run the Rankine cycle for the power production required for the PEM electrolyzer system, while in the case of SOEC, a portion of waste heat energy is used to supply the electrolyzer with the necessary steam. Firstly, the best parameters; Rankine working fluid for the two systems and inlet water flow rate and bleeding ratio for the SOEC system are selected. Then, the performance of the two systems (Rankine efficiency, total system efficiency, hydrogen production rate, and economic and CO₂ reduction) is investigated and compared. The results reveal that the two systems' performance is higher in the case of steam Rankine than organic, while a bleeding ratio of 1% is the best condition for the SOEC system. Rankine output power, total system efficiency, and hydrogen production rate rose with increasing waste heat temperature having the same energy. SOEC system produces higher hydrogen production and efficiency than the PEM system for all input waste heat conditions. SOEC can produce 36.9 kg/h of hydrogen with a total system efficiency of 23.8% at 780 °C compared with 27.4 kg/h and 14.45%, respectively, for the PEM system. The minimum hydrogen production cost of SOEC and PEM systems is 0.88 $/kg and 1.55 $/kg, respectively. The introduced systems reduce CO₂ emissions annually by about 3077 tons.     

Cycle variations in a hydrogen internal combustion engine

The cycle variation characteristics of a port fuel injection hydrogen internal combustion engine (PFI-HICE) have been extensively investigated. The covariance of indicated mean effective pressure (COV_imep) is the best parameter for evaluating the cycle variations in the PFI-HICE. COV_imep decreases as fuel–air ratio increases from 1000 to 5500 rpm, and engine speed minimally affects COV_imep. The effect of ignition advance angle on COV_imep is determined by fuel–air ratio. The ignition advance angles that correspond to the minimum COV_imep of the PFI-HICE decrease as fuel–air ratio increases. The effect of ignition advance angle on COV_imep diminishes as fuel–air ratio increases. The COV_imep of the PFI-HICE rapidly decreases as throttle increases when the throttle is less than 20%. Injection timing only slightly affects COV_imep under high-speed conditions, and COV_imep increases when hydrogen is injected in intake periods under low-speed conditions. These results indicate that studying COV_imep improves the stability of PFI-HICEs.     

Performance of a combined organic Rankine cycle and vapor compression cycle for heat activated cooling

Heat activated cooling has the potential of utilizing thermal sources that currently go unused such as engine exhaust heat or industrial waste heat. Using these heat sources can provide enhanced energy utilization and reduced fuel usage in applications where cooling is needed. The concept developed here uses waste heat from stationary and mobile engine cycles to generate cooling for structures and vehicles. It combines an organic Rankine cycle (ORC) with a conventional vapor compression cycle. A nominal 5 kW cooling capacity prototype system was developed based on this concept and tested under laboratory conditions. In order to maintain high system performance while reducing size and weight for portable applications, microchannel based heat transfer components and scroll based expansion and compression were used. Although the system was tested off of its design point, it performed well achieving 4.4 kW of cooling at a measured heat activated COP of 0.48. Both the conversion and 2nd law efficiencies were close to the model results, proving it to be an attractive technology. The measured isentropic efficiency of the scroll expander reached 84%, when the pressure ratio was close to the scroll intrinsic expansion ratio. The reduced cooling capacity was attributed to off design operation.     

低品位热能驱动有机朗肯循环的变工况特性

构建有机朗肯循环变工况分析模型,研究热源条件对系统变工况性能的影响规律。结果表明:随着热源温度升高,系统的最佳蒸发压力线性增大,而涡旋膨胀机的等熵效率逐渐减小。相比额定工况,热源温度变化-30.0K与30.0K时,净输出功率变化了-32.4%与18.4%,热效率降低了4.0%与11.4%,热回收效率变化幅度分别为-9.8%及8.9%;当热源温度从423增大至483K时,系统不可逆损失的变化率为-37.1%与45.5%,火用效率的变化率为6.7%与-17.5%。相比热源流量,热源温度对系统变工况性能的影响更大。     

Parametric optimization and performance analysis of a waste heat recovery system using Organic Rankine Cycle

Parametric optimization and performance analysis of a waste heat recovery system based on Organic Rankine Cycle, using R-12, R-123 and R-134a as working fluids for power generation have been studied. The cycles are compared with heat source as waste heat of flue gas at 140 °C and 312 Kg/s/unit mass flow rate at the exhaust of ID fans for 4 × 210 MW, NTPC Ltd. Kahalgaon, India. Optimization of turbine inlet pressure for maximum work and efficiencies of the system along the saturated vapour line and isobaric superheating at different pressures has been carried out for the selected fluids. The results show that R-123 has the maximum work output and efficiencies among all the selected fluids. The Carnot efficiency for R-123 at corrected pressure evaluated under similar conditions is close to the actual efficiency. It can generate 19.09 MW with a mass flow rate of 341.16 Kg/s having a pinch point of 5 °C, First law efficiency of 25.30% and the Second law efficiency of 64.40%. Hence selection of an Organic Rankine Cycle with R-123 as working fluid appears to be a choice system for utilizing low-grade heat sources for power generation.     

Diagnosis and control of abnormal combustion of hydrogen internal combustion engine based on the hydrogen injection parameters

In order to improve the limitation of evaluating the abnormal combustion problem of hydrogen internal combustion engine by single index, the abnormal combustion risk coefficient is proposed and defined based on AHP(Analytic Hierarchy Process)-entropy method. The abnormal combustion risk of PFI hydrogen internal combustion engine is comprehensively evaluated from multiple indexes such as the uniformity coefficient of the mixture, the temperature of the hot area, the maximum temperature rise rate, the residual amount of hydrogen in the intake port and the cylinder temperature at the end of the exhaust. The influence of hydrogen injection parameters on abnormal combustion was explored. The results show that the temperature and the maximum temperature rise rate in the hot area decrease first and then increase with the increase of hydrogen injection angle and hydrogen injection flow rate. Although large hydrogen injection angle and hydrogen injection flow rate can reduce the cylinder temperature at the end of exhaust, they will increase the residual hydrogen amount in the intake port. Appropriate hydrogen injection angle and hydrogen injection flow scheme can ensure that all parameters are at a better level, so that the risk coefficient of abnormal combustion decreases by 2.1%–5.5%, and the possibility of abnormal combustion is reduced.     

A highly efficient six-stroke internal combustion engine cycle with water injection for in-cylinder exhaust heat recovery

A concept adding two strokes to the Otto or Diesel engine cycle to increase fuel efficiency is presented here. It can be thought of as a four-stroke Otto or Diesel cycle followed by a two-stroke heat recovery steam cycle. A partial exhaust event coupled with water injection adds an additional power stroke. Waste heat from two sources is effectively converted into usable work: engine coolant and exhaust gas. An ideal thermodynamics model of the exhaust gas compression, water injection and expansion was used to investigate this modification. By changing the exhaust valve closing timing during the exhaust stroke, the optimum amount of exhaust can be recompressed, maximizing the net mean effective pressure of the steam expansion stroke (MEP_steam). The valve closing timing for maximum MEP_steam is limited by either 1 bar or the dew point temperature of the expansion gas/moisture mixture when the exhaust valve opens. The range of MEP_steam calculated for the geometry of a conventional gasoline engine and is from 0.75 to 2.5 bars. Typical combustion mean effective pressures (MEP_combustion) of naturally aspirated gasoline engines are up to 10 bar, thus this concept has the potential to significantly increase the engine efficiency and fuel economy.     

The distinctive characteristics of combustion duration in hydrogen internal combustion engine

As a practical solution to reduce the emission pollution and energy crisis, the research and development of HICE has been processed in several decades. The focus of this paper is trying to explore the new features of the combustion duration in HICE not only by engine experiment, but also by analysis of the physical properties of hydrogen, especially the obvious difference from that of gasoline. Firstly, the laminar flame speed difference between hydrogen and gasoline was studied and discussed. Secondly, a distinctive rule of combustion duration in HICE was discovered by analyzing the experiment data. Finally, as a key reference point to the HICE operation, a new characteristic of the location of 50% mixture combust up was proposed and analyzed, this will be helpful for the calibration of optimum ignition timing.     

补燃型不可逆联合循环热机的性能分析

在原有的不可逆联合动力循环模型的基础上,建立了一个存在热阻、热漏、补燃、内不可逆性的定常流联合卡诺热机循环模型。研究其在补燃作用下的功率和效率特性并对其进行优化,导出功率、效率的基本优化关系,分析了补燃对最优性能的影响。     

The characteristic of polytropic coefficient of compression stroke in hydrogen internal combustion engine

The polytropic coefficient has important effect on the calculation of the instantaneous heat release rate and its comparison with specific heat ratio contains the information of the gas-surroundings heat exchange. This article studies the polytropic coefficient characteristics from 1000 rpm to 5000 rpm and the equivalence ratio from 0.24 to 0.55 by using experimental data from a 2.0 L hydrogen engine. The polytropic coefficient increase from 1.3 to 1.35 with the increase of engine speed from 1000 rpm to 4000 rpm, and then it decrease to around 1.34. This characteristic can be used to calculate the heat release rate more accurately. The study of the effect of equivalence ratio suggested that the polytropic coefficient decreased with the increase of equivalence ratio. The polytropic coefficient of hydrogen engine ranges from 1.28 to 1.35, which is less than the gasoline of 1.32–1.4. And the rising period of polytropic coefficient of ‘hydrogen – 0.55’ at 4500 rpm is very longer than others, which showed that the gases properties had effect on the heat transfer. These characteristics could not only be used for heat transfer calculation, but they can also enrich the research of polytropic coefficient for hydrogen internal combustion engine.     

An onboard hydrogen generator for hydrogen enhanced combustion with internal combustion engine

Hydrogen enhanced combustion (HEC) for internal combustion engine is known to be a simple mean for improving engine efficiency in fuel saving and cleaner exhaust. An onboard compact and high efficient methanol steam reformer is made and installed in the tailpipe of a vehicle to produce hydrogen continuously onboard by using the waste heat of the engine for heating up the reformer; this provides a practical device for the HEC to become a reality. This use of waste heat from engine enables an extremely high process efficiency of 113% to convert methanol (8.68 MJ) for 1.0 NM of hydrogen (9.83 MJ) and low cost of using hydrogen as an enhancer or as a fuel itself. The test results of HEC from the onboard hydrogen production are presented with 2 gasoline engine vehicles and 2 diesel engines; the results indicate a hike of engine efficiency in 15–25% fuel saving and a 40–50% pollutants reduction including 70% reduction of exhaust smoke. The use of hydrogen as an enhancer brings about 2–3 fold of net reductions in energy, carbon dioxide emission and fuel cost expense over the input of methanol feed for hydrogen production.     

Fundamental experiment of pumpless Rankine-type cycle for low-temperature heat recovery

This paper proposes a new pumpless Rankine-type cycle for power generation from low-temperature heat sources. The new cycle mainly consists of an expander, two heat exchangers, and switching valves for the expander and heat exchangers. Instead of using a working fluid pump, the switching valves method (SVM) is employed to control the cycle. The SVM makes each heat exchanger switch between functioning as an evaporator and functioning as a condenser. In this arrangement, the working fluid flows back and forth between the two heat exchangers without a working fluid pump. Therefore, the new cycle does not involve problems caused by a pump. In the first basic experiment carried out to clarify the feasibility of the proposed cycle, the function of the expander was emulated by using an expansion nozzle. HFC245fa was used as the working fluid. The experimental results confirm that the proposed cycle works and that it has the potential to produce power. Fundamental time-varying characteristics of the proposed cycle are also shown and discussed.     

Numerical study of heat transfer characteristics of semi-coke and steam in waste heat recovery steam generator for hydrogen production

With the steam obtained from the waste heat of high temperature semi-coke, the hydrogen production through gasification method is considered more commercially. The heat transfer of semi-coke bed and steam was investigated using an unsteady convection heat transfer three-dimensional model of semi-coke. The effects of particle size, steam flow and particle bed thickness on heat transfer characteristics were considered. The particle temperature calculated by three-dimensional model was in good agreement with the corresponding particle temperature of experiment. The heat transfer characteristics of single particle, the particle temperature, the amount of heat recovery and the heat flux were investigated. The results show that, in the first 10 min of the heat transfer of semi-coke bed and steam, the bottom particle temperature decreases rapidly, but the top particle temperature is almost unchanged. The heat transfer rate evolution of the single particle in different positions is revealed. The heat transfer rate evolution of the bottom particle is different from that of the middle particle and top particle, and the heat transfer rate evolution of middle particle is similar to that of the top particle. The particle size, the steam flow and the particle bed thickness have great influence on the heat transfer mechanism of semi-coke and steam, and the 7.5 kg/h is considered to be the best steam flow for heat recovery. The intrinsic heat transfer mechanism between semi-coke bed and steam was revealed.     

Energetic and exergetic analysis of waste heat recovery from a microturbine using organic Rankine cycles

This article examines the exhaust waste heat recovery potential of a microturbine (MT) using an organic Rankine cycle (ORC). Possible improvements in electric and exergy efficiencies as well as specific emissions by recovering waste heat from the MT exhaust gases are determined. Different dry organic working fluids are considered during the evaluation (R113, R123, R245fa, and R236fa). In general, it has been found that the use of an ORC to recover waste heat from MTs improves the combined electric and exergy efficiencies for all the evaluated fluids, obtaining increases of an average of 27% when the ORC was operated using R113 as the working fluid. It has also been found that higher ORC evaporator effectiveness values correspond to lower pinch point temperature differences and higher exergy efficiencies. Three different MT sizes were evaluated, and the results indicate that the energetic and exergetic performance as well as the reduction of specific emissions of a combined MT‐ORC is better for small MT power outputs than for larger MTs. This article also shows how the electric efficiency can be used to ascertain under which circumstances the use of a combined MT‐ORC will result in better cost, primary energy consumption, or emission reduction when compared with buying electricity directly from electric utilities. Copyright © 2012 John Wiley & Sons, Ltd.     

Second law analysis of a diesel engine waste heat recovery with a combined sensible and latent heat storage system

The exhaust gas from an internal combustion engine carries away about 30% of the heat of combustion. The energy available in the exit stream of many energy conversion devices goes as waste. The major technical constraint that prevents successful implementation of waste heat recovery is due to intermittent and time mismatched demand for and availability of energy. The present work deals with the use of exergy as an efficient tool to measure the quantity and quality of energy extracted from a diesel engine and stored in a combined sensible and latent heat storage system. This analysis is utilized to identify the sources of losses in useful energy within the components of the system considered, and provides a more realistic and meaningful assessment than the conventional energy analysis. The energy and exergy balance for the overall system is quantified and illustrated using energy and exergy flow diagrams. In order to study the discharge process in a thermal storage system, an illustrative example with two different cases is considered and analyzed, to quantify the destruction of exergy associated with the discharging process. The need for promoting exergy analysis through policy decision in the context of energy and environment crisis is also emphasized.     

内燃机排气余热ORC中异丁烷-CO2混合工质的可燃性分析

针对内燃机高温排气与ORC工质的匹配问题,提出了一组安全且环保的烷烃/CO_2混合工质。为了解决混合工质泄漏后可燃的问题,按照美国ASTME681-2009标准提出测量异丁烷-二氧化碳混合工质可燃区域的实验手段。实验结果表明,异丁烷的可燃下限随阻燃剂二氧化碳的加入基本不变,可燃上限随着阻燃剂的加入迅速减小。并基于临界火焰温度理论建立了预测异丁烷-二氧化碳混合工质可燃极限的模型,与试验值相比较表明,预测模型可以较好地预测异丁烷的可燃下限,上限预测误差较大。     

内燃机余热驱动的储热式有机朗肯循环试验研究

为了提高尾气余热利用率并削弱热源波动对有机朗肯循环的影响,提出了一种集成相变储热换热器的有机朗肯循环（organic Rankine cycle,ORC）系统,利用相变材料削弱尾气余热波动并储存热量。搭建了内燃机尾气余热直接驱动的储热式有机朗肯循环试验台架,开展了内燃机稳态工况和阶跃变工况下储热式有机朗肯循环的热力学性能和动态性能试验研究。结果表明,内燃机稳态工况下尾气平均温度和平均流量为342℃和0.142kg/s,蒸发压力为0.75MPa条件下储热式ORC系统平均输出功率约3.43kW,平均热效率可达到12.7%,平均尾气余热回收率可达40.1%。内燃机阶跃工况下,工质出口温度、蒸发压力和过热度均呈现快速下降的趋势。试验结果还表明储热式ORC具备完全抵御发动机工况小幅波动的能力。在发动机工况阶跃变化比例过大时,储热换热器可以实现对尾气的补热,从而延长储热式ORC的安全工作时间。     

Experimental investigation of a scroll expander for an organic Rankine cycle

This paper presents experimental investigation of the performance of an organic Rankine cycle (ORC) with scroll expander which utilizes renewable, process and waste heats. An ORC test bench is built with a scroll expander‐generator unit modified from a refrigeration compressor‐electrical drive unit. A detailed experimental investigation within the test bench is performed with the organic working fluid R134a. The results show that scroll expander can effectively be used in low‐power ORC to generate mechanical work or electricity from low‐temperature thermal sources (e.g. 80–200 °C, respectively). The experiments are performed under fixed intake conditions into the expander. The pressure ratio and the load connected to the expander‐generator unit were varied. It is found that an optimum pressure ratio and an optimum angular speed co‐exist. When operating optimally, the expander's isentropic efficiency is the highest. The optimum angular speed is around 171 rad/s which corresponds to a generated voltage of 18.6 V. The optimum pressure ratio is about 4. The isentropic efficiency at optimum operation is found in the range of 0.5 to 0.64, depending on the intake conditions. The volumetric efficiency overpasses 0.9 at optimum operation and degrades significantly if the load is increased over the optimum load. A regenerative ORC equipped with the studied expender‐generator unit that operates under 120 °C heat source and has an air cooled condenser generates 920 W net power with efficiencies of 8.5% energetically and 35% exergetically. Copyright © 2014 John Wiley & Sons, Ltd.     

Effect of excess hydrogen on hydrogen fueled internal combustion engine under full load

Detailed hydrogen-air chemical reaction mechanisms were coupled with three dimension grids of an experimental hydrogen fueled internal combustion engine (HICE) to establish a combustion model based on CONVERGE software. The influence of excess hydrogen coefficient on the combustion and emission characteristics of HICE under full load was studied based on the CFD model. Simulation results showed that excess hydrogen leaded to higher concentration of OH species in flame front, and quicker hydrogen-oxygen reaction and flame propagation speed, which in turn leaded to higher pressure and temperature in cylinder. The rise of pressure and temperature in turn contributed to the increase of indicate power but un-burned hydrogen leaded to decrease of efficiency. NOx, especially NO emissions decreased significantly with excess hydrogen under full load not only because increased of H concentration, and decreased of O and OH concentration, which leaded to reverse reaction of NO formation through thermal NO routes. Low excess hydrogen coefficient can achieve a good trade-off between power and emissions under full load.