共查询到19条相似文献,搜索用时 343 毫秒
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几种中空纤维膜对氧气,环氧丙烷透过性的比较 总被引:1,自引:0,他引:1
为选定适合气-固-液三相生物反应过程膜反应器中的膜材料,采用氧电极测试了几各收集到的聚砜、聚丙烯及聚氟乙烯中空纤维膜对氧气的通透性,其中的聚丙烯中空纤维适于做膜生物反应器中的透气膜,同时还测定了聚砚、聚偏氟乙和聚丙烯腈地水溶液中环氧丙烷的通透性,在实验条件下它们之间的差异不大。 相似文献
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在膜均相反应器中,利用分离膜结构中的微孔作为液体微量分布器,将膜一侧的反应物均匀微量地加入到膜另一侧反应物中进行反应,有利于过饱和度及其分布的控制。在膜气液反应器中,气-液两相分别位于微孔膜两侧,互不分散,膜能有效提供稳定、巨大面积的气液界面,有利于气液传质、过程控制和工业放大等。另外,介绍利用膜反应器制备纳米材料的原理和主要研究结果。 相似文献
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再铸Nafion膜的制备与应用 总被引:14,自引:2,他引:12
采用溶液-浇铸法用商业化Nafion膜的溶解液制备再铸Nafion膜,对再铸Nafion膜进行了氧气渗透系数测试和电池性能评价,并与厚度相近的商业化Nafion膜进行比较,同时对再铸Nafion膜组装的PEMFC进行了短期稳定性考查,实验结果表明:通过溶液-浇铸法制备的再铸Nafion 膜可以应用于质子交换膜燃料电池,再铸Nafion膜的氧气渗透系数和电池性能与商业化Nafion膜相近,再铸Nafion膜组装PEMFC在150h之内未见电池性能下降。 相似文献
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用TEM、X-Ray、SEM等技术研究了Ni42Cr6Fe玻封合金在高温湿H2中形成的氧化膜及氧化物晶须的结构。结果表明:氧化膜主要由Cr2O3和(Fe,Mn)Cr2O4两组相成,氧化膜底层是以Cr2O3为主的组织,氧化膜表层是以(Fe,Mn)Cr2O4为主的组织;Si在氧化膜与合金界面分布,Al则在内氧化层中形成内氧化物质点;氧化膜表面生长的氧化物晶须的杆部为(Fe,Mn)Cr2O4单晶,头部为 相似文献
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熔模离心法制备高纯氧化铝基质膜管 总被引:18,自引:4,他引:14
无机膜以其耐高温、耐腐蚀、性能稳定等优点,在化工、食品、医药、环保等领域的应用日益广泛.本文提出了高铝基质膜管的一种新的制备方法熔模离心法.这种方法脱模容易,可以一次获得孔径由大到小逐渐过渡的梯度管.采用这种方法我们已在实验室制得了顶层孔径为0.2μm,通量为158m3·m-2·h-1,显气孔率为58%的梯度管,可以直接作为微滤膜管,也可作为支撑体管,进一步修饰后用于超滤、催化、反应,成为一种新型的催化剂材料和膜反应器 相似文献
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陈崇正 《高分子材料科学与工程》2002,18(4):121-123,128
通过磁控溅射在PET织物上沉积用于新型防水透湿织物的氟碳高分子膜。为了解其在空气中的氧化机理和控制其结构及憎水性的变化,利用光电子能谱(XPS)和接触角测定仪对溅射氟碳膜的时间效应进行了研究。发现由于不饱和键及自由基的存在,随着放置时间的增加及氧化作用的进行,氧/碳比值逐渐增大。部分双键及自由基被氧化导致原-CF-,-C-CF,-C-和带有悬垂键的组分中产生-C=O,-C-D-并产生断键,从而使其氟含量减少,碳的相对比例增加。上述结构变化导致随放置时间增加膜表面自由能极性分量增加而膜的憎水性降低。 相似文献
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McLeary EE Buijsse EJ Gora L Jansen JC Maschmeyer T 《Philosophical transactions. Series A, Mathematical, physical, and engineering sciences》2005,363(1829):989-1000; discussion 1035-40
In this paper, we propose an improved hydroisomerization process, making use of membrane reactor technology. Linear alkanes are selectively supplied from a hydrocarbon feed (consisting of branched and linear alkanes) through an inert tubular membrane to a packed bed of catalyst. The results indicate that n-, mono- and di-branched components in a gas mixture can be separated with a selectivity factor of greater than 20 with a zeolite membrane under dedicated parameter settings. The RON-value of the product was calculated to be as high as 90 in a single pass reactor, which is 50 points higher than the feed value. The flux through the membrane could be optimized to give a STY/ATY ratio for the reactor of 877 m-1, which falls within the limits of technical feasibility. 相似文献
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研究了以焦炉煤气为原料在BaCo0.7Fe0.2Nb0.1O3-δ(BCFNO)透氧膜反应器中制合成气。实验结果表明,BCFNO膜反应器的自催化性能差。加入催化剂后,膜反应器的重整性能得到明显提高,在875℃,焦炉煤气中甲烷转化率为87.0%,产物中氢气和一氧化碳选择性分别为78.3%、105.6%,透氧量达到15.8ml/(cm2.min)。焦炉煤气中的甲烷在膜反应器中反应路径为首先焦炉煤气中的氢气与膜片透过去的氧反应生成水,然后甲烷再与水重整生成氢气和一氧化碳。实验过程中,透氧膜没有出现破裂,BCFNO透氧膜反应器在富氢的焦炉煤气下显示出很好的稳定性。 相似文献
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Laser-activated membrane introduction mass spectrometry (LAMIMS), a high-throughput screening method, evaluates heterogeneous catalysts under realistic reactor conditions. It is a precise, versatile system requiring no moving parts. The catalyst array is supported on carbon paper overlaid upon a silicone rubber membrane configured in a variation of membrane introduction mass spectrometry as introduced by Cooks. The carbon paper serves as a heat-dissipating gas diffusion layer that permits laser heating of catalyst samples far above the decomposition temperature of the polymer membrane that separates the array from the mass spectrometer vacuum chamber. A computer-controlled CO2 bar code writing laser is used for fine-tune heating of the catalyst spots above the base temperature of the LAMIMS reactor. The detailed design and performance of LAMIMS is demonstrated on arrays of "real world" bulk water-gas shift catalysts using natural and isotopically labeled reactor feed streams. A bulk catalyst array spot can be evaluated for activity and selectivity in as little as 1.5 min. All array screening results were confirmed by industrial microreactor evaluations. 相似文献
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In this work, the removal of ammonia from synthesis purge gas of an ammonia plant has been investigated. Since the ammonia decomposition is thermodynamically limited, a membrane reactor is used for complete decomposition. A double pipe catalytic membrane reactor is used to remove ammonia from purge gas. The purge gas is flowing in the reaction side and is converted to hydrogen and nitrogen over nickel-alumina catalyst. The hydrogen is transferred through the Pd-Ag membrane of tube side to the shell side. A mathematical model including conservation of mass in the tube and shell side of reactor is proposed. The proposed model was solved numerically and the effects of different parameters on the rector performance were investigated. The effects of pressure, temperature, flow rate (sweep ratio), membrane thickness and reactor diameter have been investigated in the present study. Increasing ammonia conversion was observed by raising the temperature, sweep ratio and reducing membrane thickness. When the pressure increases, the decomposition is gone toward completion but, at low pressure the ammonia conversion in the outset of reactor is higher than other pressures, but complete destruction of the ammonia cannot be achieved. The proposed model can be used for design of an industrial catalytic membrane reactor for removal of ammonia from ammonia plant and reducing NO(x) emissions. 相似文献