共查询到19条相似文献,搜索用时 125 毫秒
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研究了国产硫化剂 T C Y(1 ,3 ,5三巯基2 ,4 ,6均三嗪) 对国产活性氯型聚丙烯酸酯橡胶( A C M) 硫化胶性能的影响。结果表明,与皂( 钠皂/ 钾皂)/ 硫黄和3 # 硫化剂( N, N双肉桂叉1 ,6己二胺) 硫化体系相比,硫化剂 T C Y 硫化体系硫化的活性氯型 A C M 硫化胶压缩永久变形小,物理性能和耐热老化性能良好;在硫化剂 T C Y硫化体系中,硫化剂 T C Y 的用量为075 ~100 份较合适,促进剂可采用促进剂 P Z, Z D C 和 B Z;活性氯型 A C M 一段硫化胶的硫化程度高,可不进行二段硫化,若要使硫化胶的压缩永久变形大幅度减小,可进行短时间(6 h) 的高温(180 ℃) 二段硫化。 相似文献
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NBR的溴化酚醛树脂硫化体系和聚丙烯酸酯橡胶(ACM)的硫化剂ABS会相互干扰,产生硫化不相容性,导致NBR,ACM和NBR/ACM共混物性能下降。通过在NBR/ACM共混物中加入溴化酚醛树脂对NBR进行动态硫化,然后加入ABS对ACM进行静态硫化的方法,能够较好地解决这两种不相容硫化体系的相容性问题,所得到的共混物表现出良好的物理性能,且优于相应的静态硫化共混物。同时考察了NBR/ACM的共混比对共混物性能的影响。 相似文献
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对导电炭黑(CSF)作为NBR的填料时,其填充量、硫化时间和增塑剂用量等因素对NBR/CSF混炼胶加工性能和硫化特性及硫化胶物理性能和电性能的影响进行了研究,并与乙炔炭黑(ACET)进行了对比。结果表明,随着CSF用量的增大,混炼胶的炭黑结合NBR量、门尼粘度[ML(1+4)100℃]、屈服强度和拉伸强度均增大,扯断伸长率和挤出膨胀率降低,挤出物外观变优,焦烧时间和正硫化时间延长,硫化速度放慢,硫化胶的物理性能有所降低,导电性能提高;硫化胶体积电阻率随硫化时间延长和施加负荷的增大而降低,随温度升高和增塑剂DOP用量增大而升高。NBR/CSF混炼胶的结合橡胶量、门尼粘度和混炼胶应力应变性能及硫化胶导电性能等均高于NBR/ACET混炼胶。 相似文献
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研究了硫黄和3,3′二氯4,4′二氨基二苯基甲烷(MOCA)对聚丁二烯型PU[又称端羟基液体聚丁二烯(HTLPB)型PU,简称HTLPB型PU]的双重硫化体系。根据HTLPB中含有羟基官能团和分子链中含有双键的特点,考察了用其端基和双键共同硫化的协同效应。结果表明,当用硫黄与MOCA进行双重硫化时,硫化胶的物理性能比单独使用MOCA或硫黄硫化时高,在预聚物中游离—NCO质量分数为0024,硫黄用量为08份,MOCA用量在占理论用量的80%时,硫化胶的物理性能最佳。 相似文献
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介绍了望远镜橡塑装饰包皮的胶料配方设计、生产工艺和产品性能。望远镜橡塑装饰包皮胶料的主体材料采用NBR/PVC(并用比83/17)并用体系;硫化体系由硫黄(1-25 份) 和促进剂TMTD(0-29 份)、促进剂DM(0-42 份)、促进剂M(0-42 份)组成;增塑剂选用增塑剂DBP(8-3 份);黑色胶料的防老剂选用防老剂2246(1-6 份),非黑色胶料的防老剂选用防老剂264(2-0 份);黑色胶料的补强填充剂选用HAF/GPF(并用比83/17) 并用体系,非黑色胶料的补强填充剂选用白炭黑/ 陶土( 并用比75/17)并用体系。NBR 的塑炼采用低温、小辊距和低容量的三段塑炼法;NBR与PVC的共混采用常温共混工艺;混炼胶的威氏塑性值控制在0-28~0-30 之间;制品在平板硫化机上硫化完毕后,再在160~170 ℃的烘箱中热处理15~30 min。胶料物理性能良好,成品性能满足设计要求。 相似文献
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2.7 氯化丁基橡胶(CIIR)橡胶通过氯化可与各种橡胶进行并用。表26为CIIR/SBR(丁苯橡胶)并用的无硫硫化体系。图3为表26中含不同硫化体系并用胶的物理性能,图中①~⑦编号与表26的配方编号相对应。表26 CIIR/SBR并用与硫化体系配 方 编 号①②③④⑤⑥⑦CIIR/SBR100/075/2525/7575/2550/5050/5025/75硫化体系 氧化锌5555555 促进剂TMTD111.50.150.150.150.15 促进剂DM2111.51.51.51.5 促进剂T… 相似文献
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研究不同牌号乙烯丙烯酸酯橡胶(AEM)及聚酯/聚醚混合型增塑剂种类和用量对硫化胶性能的影响。结果表明:AEM Vamac G硫化胶的耐低温性能较好,而AEM Vamac GLS硫化胶的物理性能、耐老化性能和耐油性能较好,选择并用比为50/50的AEM Vamac G/AEM Vamac GLS并用胶作为主体材料,硫化胶的物理性能、耐油性能和耐低温性能可更好地平衡;添加增塑剂TP-759的硫化胶的耐低温性能较好,添加增塑剂RS-735的硫化胶的耐热老化性能较好,两者耐油性能相当;随着增塑剂用量的增大,硫化胶的耐低温性能提高,拉伸强度降低,拉断伸长率和压缩永久变形增大,油浸泡后体积变化率减小。 相似文献
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Polyglycidylmethacrylate grafted butadiene rubber (PGMA‐g‐BR) was synthesized by a graft solution copolymerization technique. The PGMA content was determined through titration against HBr. The PGMA‐g‐BR was blended with styrene butadiene rubber/butadiene acrylonitrile rubber (SBR/NBR) blends with different blend ratios. The SBR/NBR (50/50) blend was selected to examine the compatibility of such blends. Compatibility was examined using scanning electron microscopy (SEM), differential scanning calorimetry (DSC), and viscosity measurements. The scanning electron micrographs illustrate the change of morphology of the SBR/NBR rubber blend as a result of the incorporation of PGMA‐g‐BR onto that blend. The Tgs of SBR and NBR in the blend get closer upon incorporation of PGMA‐g‐BR 10 phr, which indicates improvement in blend homogeneity. The intrinsic viscosity (η) versus blend ratio graph shows a straight‐line relationship, indicating some degree of compatibility. Thermal stability of the compatibilized and uncompatibilized rubber blend vulcanizates was investigated by determination of the physicomechanical properties before and after accelerated thermal aging. Of all the vulcanizates with different blend ratios under investigation, the SBR/NBR (25/75) compatibilized blend possessed the best thermal stability. However, the SBR/NBR (75/25) compatibilized blend possessed the best swelling performance in brake fluid. The effect of various combinations of inorganic fillers on the physicomechanical properties of that blend, before and after accelerated thermal aging, was studied in the presence and absence of PGMA‐g‐BR. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 99: 1559–1567, 2006 相似文献
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Sung‐Seen Choi 《应用聚合物科学杂志》2000,75(11):1378-1384
Variation of the crosslink density of a rubber vulcanizate depending on the rubber composition after the thermal aging was studied with single rubber, biblend, and triblend vulcanizates of natural rubber (NR), butadiene rubber (BR), and styrene‐butadiene rubber (SBR). The efficient vulcanization (EV) system was employed to minimize the influence of free sulfur in the vulcanizate on the change of the crosslink density. Thermal aging was performed at 40, 60, and 80°C for 20 days with 5‐day intervals. The crosslink densities of the vulcanizates after the thermal aging increase. For the single rubber vulcanizates, variation of the crosslink density by the thermal aging has the order: SBR > BR > NR. For the biblend vulcanizates, variations of the crosslink densities of the NR/SBR and SBR/BR blends are larger than that of NR/BR blend. Variation of the crosslink density of the vulcanizate increases by increasing the SBR content in the vulcanizate. Variation of the crosslink density of the rubber vulcanizate depending on the rubber composition was explained by miscibility of the blends, combination reaction of the pendent groups, and mobility of the pendent group. © 2000 John Wiley & Sons, Inc. J Appl Polym Sci 75: 1378–1384, 2000 相似文献
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This article examines the physical and mechanical characteristics of mixtures of two different synthetic rubbers, namely styrene-butadiene rubber (SBR) and nitril-butadiene rubber (NBR), with novolac type phenolic-resin (PH). According to Taguchi experimental design method, it is shown that the addition of PH increases the crosslinking density of rubber phase probably due to its curative effects. Thermal analysis of the blends indicates that, contrary to NBR/PH blend, thermal stability of SBR/PH blend is dependent on sulfur content due to predominant polysulfidic crosslinks formed in SBR. Slight shift in glass-transition temperature (Tg) of pure SBR and NBR vulcanizates by the addition of PH suggests that both SBR/PH and NBR/PH are incompatible blends with a partially soluble PH in the rubber phase. Two-phase morphology of the mixtures is also evidenced by scanning electron microscopy. Correlation of the rubber/PH modulus versus PH concentration by Halpin-Tsai model shows a deviation from the model. Presence of PH in the rubber phase is thought to vary the mechanical properties of the rubber phase by changing both the crosslinking density and rigidity of the molecular network of the rubber, leading to misuse of modulus of pure rubber in Halpin-Tsai equation. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献