共查询到20条相似文献,搜索用时 15 毫秒
1.
A new procedure has been developed to measure the temperature distribution of the polymer melts along the screw axis during injection by using a small sheath thermocouple. At the same time, the effects of molding conditions on temperature distribution has been studied. The temperature distribution of the polymer melt along the screw axis during injection can be obtained from the difference between the standard temperature profile and the temperature profile of the polymer melt with unknown and non-uniform temperature measured under the same rate of injection. The temperature of a polymer melt within a shot is not uniform. The difference between the maximum and the minimum temperature within a shot may exceed 10°C in some cases. There are two major factors which govern the effects of molding conditions on the temperature distribution of the polymer melts during injection. The first is the amount of shear heating in the metering zone. The second is the amount of heat absorbed into the polymer in the compression and feed zones. 相似文献
2.
A theoretical and experimental study of heat transfer to polymer melts flowing through circular tubes is presented. The mathematical model provides for shear heating and expansion cooling effects, and also heat of reaction during flow for various wall boundary conditions. Experimental results, obtained using low density polyethylene, show reproducible temperature and velocity profiles. The measured inlet melt temperature profile and the axial wall temperature profile provide the boundary conditions for the calculations. The experimental data confirm the predictions of the magnitude of the shear heating and expansion cooling effects during tube flow. 相似文献
3.
This article investigates the radial extrudate swell and velocity profiles of polystyrene melt in a capillary die of a constant shear‐rate extrusion rheometer, using a parallel coextrusion technique. An electro‐magnetized capillary die was used to monitor the changes in the radial extrudate swell profiles of the melt, which is relatively novel in polymer processing. The magnetic flux density applied to the capillary die was varied in a parallel direction to the melt flow, and all tests were performed under the critical condition at which sharkskin and melt fracture did not occur in the normal die. The experimental results suggest that the overall extrudate swell for all shear rates increased with increasing magnetic flux density to a maximum value and then decreased at higher densities. The maximum swelling peak of the melt appeared to shift to higher magnetic flux density, and the value of the maximum swell decreased with increasing wall shear rate and die temperature. The effect of magnetic torque on the extrudate swell ratio of PS melt was more pronounced when extruding the melt at low shear rates and low die temperatures. For radial extrudate swell and velocity profiles, the radial swell ratio for a given shear rate decreased with increasing r/R position. There were two regions where the changes in the extrudate swell ratio across the die diameter were obvious with changing magnetic torque and shear rate, one around the duct center and the other around r/R of 0.65–0.85. The changes in the extrudate swell profiles across the die diameter were associated with, and can be explained using, the melt velocity profiles generated during the flow. In summary, the changes in the overall extrudate swell ratio of PS melt in a capillary die were influenced more by the swelling of the melt around the center of the die. Polym. Eng. Sci. 44:2298–2307, 2004. © 2004 Society of Plastics Engineers. 相似文献
4.
The effects of long-chain branching and of temperature on the melt elasticity in shear of polyethylene were investigated using die swell measurements and relating them to recoverable shear strain, normal stress, and shear modulus. Die swell measurements, as a function of shear rate, were obtained for high- and low-density polyethylenes at temperatures ranging from 130° to 225°C. The samples were characterized by GPC and intrinsic viscosity for molecular weight distributions and degrees of long-chain branching. The importance of annealing the extrudates at temperatures above the polymer melting temperature to achieve equilibrium, or strain-free, values of die swell was demonstrated. The effect of long-chain branch was to decrease elastic deformation. At constant shear stress, the melt elasticity of both high- and low-density polyethylene was found to be essentially independent of temperature. Thus, at constant shear rate, elastic deformation decreased with increasing temperature, and it was demonstrated that this decrease could be quantitatively defined in terms of previously determined shear rate–temperature viscosity superposition shift factors. 相似文献
5.
The effect of die wall temperature on the flow of polymer melts in circular capillary dies was studied. At constant flow rates, it was found that die wall temperature had a greater effect on the pressure drop than melt temperature. A capillary die with two circular channels with different diameters was designed to simulate the profile extrusion. Changes of wall temperature varied the flow rate ratio between the two channels. An implicit finite difference method was used to simulate the velocity and temperature profiles inside the die. Values predicted by this model matched well with experimental data for both dies. 相似文献
6.
A. Rudin 《Polymer Engineering and Science》1970,10(2):94-101
The two main flow defects which appear to originate in the processing machine or die are melt fracture and sharkskin. Both are associated with the elastic nature of the polymer melt. Processing variations that decrease the elastic nature of the melt diminish the severity of the effects of melt fracture. These include increased die length and temperature and shear at temperatures at which polymer segmental mobility is not too high. The sheared, less elastic melt structure may sometimes be stabilized by polymeric additives. A simple model is presented to account for this behavior, which is illustrated with examples of polyethylene and plasticized PVC. 相似文献
7.
David Porter 《Polymer Engineering and Science》1993,33(7):437-444
The elastic deformation of polymer macromolecules in a shear field is used as the basis for quantitative predictions of viscoelastic flow effects in a polymer melt. Non-Newtonian viscosity, capillary end correction factor, maximum die swell, and die swell profile of a polymer melt are predicted by the model. All these effects can be reduced to generic master curves, which are independent of polymer type. Macromolecular deformation also influences the brittle failure strength of a processed polymer glass. The model gives simple and accurate estimates of practically important processing effects, and uses fitting parameters with the clear physical identity of viscoelastic constants, which follow well established trends with respect to changes in polymer composition or processing conditions. 相似文献
8.
A well-designed coathanger die may deliver a polymer melt through the die more uniformly. However, it is difficult to optimize the manifold profile because of the complexity of flow distribution with regard to problems of die geometry, temperature, shear, and viscoelastic effects. The empirical methods have been widely used to design the manifold of a flat slit die. But this approach is time consuming and causes die material waste due to the iterative design process. With computer simulation, die designers can repeat modifications to obtain the optimal manifold shape easily. In this research, the Taguchi method was used to investigate the influences of the materials, die geometry, and processing conditions on optimizing the manifold profile. The comparison of the thickness distributions with and without modified manifold showed that the modified manifold improves the thickness uniformity significantly. 相似文献
9.
Jin Sung Choi Sang Hyuk Im Min Young Song O Ok Park Hansol Cho Jin Taek Hwang 《应用聚合物科学杂志》2005,95(5):1100-1104
A gradient refractive index rod was successfully prepared by a new fabrication method using laminar shear mixing, and a graded index polymer optical fiber that satisfied IEEE1394b was obtained from the method. To fabricate the gradient refractive index rod, a liquid monomer mixture with a relatively low refractive index was placed in a prepared cylindrical glass reactor and a transparent polymer rod with a higher refractive index was introduced at the center of the reactor. The reactor and the polymer rod were then rotated concurrently with a small rotating speed difference to generate a Couette flow in the liquid phase. The centrifugal force generated by rotation and the polymer diffusion into the liquid monomer mixture developed a graded concentration profile in a radial direction. The Couette flow could reduce the concentration fluctuation in a tangential direction. In addition, the graded index profile could be controlled by the copolymer composition of the rod and its diameter. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 95: 1100–1104, 2005 相似文献
10.
This article proposes a new experimental technique to simultaneously measure radial die swell and velocity profiles of polystyrene melt flowing in the capillary die of a constant shear rate rheometer. The proposed technique was based on parallel coextrusion of colored melt‐layers into uncolored melt‐stream from the barrel into and out of the capillary die. The size (thickness) ratio of the generated melt layers flowing in and out of the die was monitored to produce the extrudate swell ratio for any given radial position across the die diameter. The radial velocity profiles of the melt were measured by introducing relatively light and small particles into the melt layers, and the times taken for the particles to travel for a given distance were measured. The proposed experimental technique was found to be both very simple and useful for the simultaneous and accurate measurement of radial die swell and velocity profiles of highly viscous fluids in an extrusion process. The variations in radial die swell profiles were explained in terms of changes in melt velocity, shear rate, and residence time at radial positions across the die. The radial die swell and velocity profiles for PS melt determined experimentally in this work were accurate to 92.2% and 90.8%, respectively. The overall die swell ratio of the melt ranged from 1.25 to 1.38. The overall die swell ratio was found to increase with increasing piston speed (shear rate). The radial extrudate swell profiles could not be reasoned by the shear rate change, but were closely linked with the development of the velocity profiles of the melt in the die. The die swell ratio was high at the center (~1.9) and low (~0.9) near the die wall. The die swell ratio at the center of the die reduced slightly as the piston speed was increased. Polym. Eng. Sci. 44:1960–1969, 2004. © 2004 Society of Plastics Engineers. 相似文献
11.
A polymer melt entering a capillary die from a cylinder undergoes a convergent flow in which there is a complex combination of extensional and shear flows. The convergent flow plays an important role in controlling the in situ fibrillation of thermotropic liquid crystalline polymer (TLCP) in a thermoplastic matrix melt. This study examines effects of the convergent flow on development of TLCP fibrils in a TLCP/poly(ethylene naphthalate) (PEN) blend. A capillary rheometer was used and the extent of the convergent flow was varied by changing capillary dimension and shear rate. With a given capillary die, the TLCP fibrillation was found to increase with increasing shear rate because of the increased deformation of TLCP droplets. The establishment of a fully developed shear velocity profile by using a relatively long die is considered to be necessary to retain the TLCP fibrils initiated in the convergent flow region. At a given high shear rate, TLCP fibrillation improves with increasing capillary diameter (≤2 mm) because of the increased difference in velocity between the capillary and the cylinder. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 91: 1505–1513, 2004 相似文献
12.
PVC profile extrusion compounds have a unique morphology. While other polymers gradually decrease in extrusion die swell with increasing length/thickness (L/D) ratio, PVC profile extrusion compounds have a low die swell, quite independent of the die's L/D ratio in the range of 5 to 20. The fact that the die land length can be changed without changing the extrudate swell is an important consideration, which makes die design and balancing dies simpler and easier for PVC profile extrusion compounds. While other polymers substantially increase extrudate swell with increased shear rate, the swell of the PVC profile compounds is not much affected by shear or extrusion rate. This unique behavior allows wider processing latitude in profile extrusion and faster extrusion rates than with other polymers. Another unique factor in the rheology of PVC profile extrusion compounds is that extrusion die swell increases with increasing melt temperature, while other polymers have decreasing die swell with increasing melt temperature. The unusual rheology of PVC profile extrusion compounds is attributed to its unique melt morphology, where the melt flow units are 1 um bundles and molecules that have low surface to surface interaction and entanglement at low processing temperatures but increased melting and increased entanglement at higher processing temperatures. Other polymers, unlike PVC, have melt flow at the molecular level. 相似文献
13.
The nonisothermal flow of Carreau fluid in a coat‐hanger die is studied. A general three‐dimensional finite volume code is developed for the purpose of flow analysis. The isobars, the isotherms, and the velocity distribution are obtained. Simulation results illustrated that the highest temperature occurred by the center of manifold, rather than the die‐lip region because of the combined effects of high shear rate and poor heat conduction, which is important for processing those heat‐sensitive materials. In the regions where die gap is relatively small, the wall temperature plays a key role in deciding temperature distribution in the melt. The validity of simulation results is verified experimentally. POLYM. ENG. SCI., 46:406–415, 2006. © 2006 Society of Plastics Engineers. 相似文献
14.
15.
In this work, a new methodology is developed that describes the viscoelastic scaling of a polymer‐physical foaming agent (PFA) solution in a detailed and internally consistent manner. The approach is new in that while previous researchers have largely focused on scaling down experimentally obtained high pressure polymer‐PFA solution viscosity data onto a master curve for the viscosity of the undiluted polymer melt at a reference temperature and atmospheric pressure, we have generated the shear viscosity data required for our simulations by systematically scaling up the viscosity values obtained from measurements on a pure polymer melt to the desired temperature, pressure, and concentration values characterizing the flow. Simulations have been run for the flow of a polymer‐PFA solution through an extrusion foaming die with an abrupt axisymmetric contraction and good qualitative agreement is obtained with experimental pressure drop measurements obtained previously in our laboratory. The pressure drop rates and temperature rise rates have been estimated at the surface of incipient nucleation. Because of the short residence times in the die for the microcellular foaming process, approximating the flow through the die as a single phase flow in our simulations still gives useful insights into the dynamics of the flow. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007 相似文献
16.
17.
《塑料、橡胶和复合材料》2013,42(5):187-192
AbstractMelt temperature is an important parameter in the melt processing of polymers. However, it is not possible to control melt temperature directly, only to influence it using processing parameters such as processing temperature settings. It is therefore important to know the influence of controllable process parameters on melt temperature. In this work, the relationships between controllable process parameters and melt temperature have been investigated for a 50 mm S + B single screw extruder. The extruder was equipped with a thermocouple mesh at the die inlet to determine melt temperature. It was found that melt pressure, die size, feed section barrel temperature, and compression section barrel temperature had a negligible effect on the melt temperature profiles generated, while increasing the screw speed resulted in higher melt temperatures. The metering section barrel temperature had a significant effect on melt temperature, thermal conduction effects being more important than shear heating effects. Equipment wall temperatures, downstream of the screw, produced changes in the melt temperature in the melt located within 7 mm of the wall. It was found that melt temperatures can be significantly different from those set on the equipment. 相似文献
18.
P. C. Powell 《Polymer Engineering and Science》1974,14(4):298-307
The procedures developed in this paper enable the die designer to estimate the dimensions of the die at the exit and to define a flow channel within the body of the die appropriate to the required dimensions and output rate of the extruded product. Design procedures are given for predicting die swell (and hence die exit dimensions) from a knowledge of product dimensions, output rate and the basic shear, elasticity, and viscosity data. Within the body of the die the length and included angle of a convergent tapered section should be such that the critical tensile deformation rate is not exceeded. At the die entry the taper angle is related to the tensile and shear viscosities. Analytical expressions based on flow data are given for predicting pressure drops resulting from flow through circular and slot dies of constant cross-section and through conical and wedge-shaped dies. A numerical example shows how the theory may be applied to the design of a die for a thin-walled tube. For the resultant die design, the likely effects are predicted to changes in output rate and melt temperature for the chosen material, of changes in grade of the same type of polymer, and of changes in polymer type. 相似文献
19.
《塑料、橡胶和复合材料》2013,42(1):14-22
AbstractFlow visualisation has been used to study the in process flow behaviour of a low density polyethylene melt as it is processed through planar hyperbolic and abrupt entry slit dies on a commercial scale extruder. The former die profile consisted of a planar hyperbolic section that gradually merged with a parallel slit and was designed to promote constant extensional strain rates at the centreline of flow. The melt was processed through these dies at several flowrates. Extensional strain rates were determined by performing particle velocimetry at the centreline of melt flow in the contraction regions of each die. Constant extensional strain rate conditions were approached at low flowrates in the hyperbolic die. Constant strain rates were not attained for the hyperbolic die at high flowrates nor, as expected, for the abrupt entry die. Analysis of flows using birefringence showed significant shear boundaries developed at the wall of the hyperbolic die at high flowrates. Such boundaries, in combination with the non-Newtonian behaviour of the viscoelastic polymer melt, lead to non-constant strain rates along the centreline of the die at higher flowrates. Stress, strain, and strain rate data for the low density polyethylene melt are presented which, although derived under flow conditions that are not strictly steady in the Lagrangian sense, are experimentally accessible and informative. Stresses and strains derived from the flow visualisation technique are compared with constant strain rate data obtained from a Rheometrics RME elongation rheometer. Close agreement was found between data from the two techniques. 相似文献
20.
An analytical model based on the heat penetration through the die wall was preposed to calculate the effect of die wall temperature on the flow of polymer melt in profile dies. Model prediction matched well with the experimental data measured from a modified Instron capillary rheometer. The model was applied to an extrusion line with an L-shaped profile die. Dynamic responses of the profile extrusion line based on this die were measured and modeled. The pairing of manipulated variables and controlled variables was analyzed. 相似文献