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铝材无烟化学抛光剂的研制 总被引:1,自引:1,他引:0
为了消除传统的三酸抛光对环境和人体健康的危害,开发了以磷酸-硫酸为基液的无烟化学抛光技术.该技术的关键是在基础液中添加一些具有特殊作用的化合物来替代硝酸,在H3PO4(85%):H2SO4(98%)=(2.5~3.0):1.0,ρ(Al3 )=5~12 g/L,复合添加剂量为3~8 g/L,温度为95~115 ℃,时间为2.5~4.0 min的条件下,可以提高化学抛光质量,抑制铝材的点蚀,减缓全面腐蚀,获得较好的抛光效果. 相似文献
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采用真空座滴法和熔铸法研究了在Al-Zn-Mg-Cu 合金中加入稀土(Ce、Y) 对Al2Zn2M g2Cu/Al2O3陶瓷界面润湿性的影响。结果表明,Al-Zn-Mg-Cu 合金中加入稀土可有效降低铝合金/Al2O3界面的接触角, 改善界面结合状态; 稀土改善界面润湿性存在一最佳含量范围, 添加Ce 的最佳含量约为0. 5w t% , Y 约为0. 7w t%。稀土改善润湿性的作用主要是稀土与Al2O3膜、Al2O3陶瓷发生反应。Mg、Zn、Cu 等合金元素在界面富集并参与界面反应对润湿性有利; 稀土与Mg、Zn、Cu 等合金元素适当组合改善润湿性的效果比单一稀土明显。 相似文献
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目前以H3PO4、H2SO4为基础的两酸无烟化学抛光体系对高硅铝合金的抛光效果不理想。在磷酸+硫酸+双氧水的基础液中,添加一定量的硫酸铁、三氧化二铬以及过硫酸铵,考察了不同质量的添加物对6063高硅铝合金化学抛光效果的影响。采用简单正交试验方式,以试样的反光率及麻点数量表征试样的抛光效果,优选了较优的抛光液成分。结果表明:按硫酸(85%)10 m L、磷酸(95%)20 m L、双氧水2 m L、硫酸铁0.1 g、三氧化二铬0.1 g、过硫酸铵0.1 g配制的抛光液抛光效果最佳。 相似文献
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Cu2+对铝阳极氧化膜电解着色效果及耐蚀性的影响 总被引:2,自引:0,他引:2
1 前言 铝合金两步阳极氧化着色法(浅田法)已在机械、电子、建筑、航空领域得到广泛应用.在生产中,着色液特别容易受到Cu2+的污染,使着色效果发生变化,降低膜的耐蚀性,严重影响产品质量.本文以Ni2+盐电解液为着色体系,研究了Cu2+对着色效果及膜层耐蚀性的影响,并对Cu2+的影响原因作了初步探讨. 相似文献
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1 前言 铝合金两步阳极氧化着色法(浅田法)已在机械、电子、建筑、航空领域得到广泛应用.在生产中,着色液特别容易受到Cu2+的污染,使着色效果发生变化,降低膜的耐蚀性,严重影响产品质量.本文以Ni2+盐电解液为着色体系,研究了Cu2+对着色效果及膜层耐蚀性的影响,并对Cu2+的影响原因作了初步探讨. 相似文献
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铝材无烟化学抛光工艺及其推广应用 总被引:1,自引:1,他引:0
铝材除机械抛光外,电化学抛光和三酸化学抛光都能达到相当满意的光亮度,但电解抛 光能耗大,六价铬废水难处理,三酸化学抛光产生的氮氧化物黄烟严重损害工人身体健康, 污染大气。长期以来,人们一直在努力寻求能够取代三酸化学抛光的无烟化学抛光工艺,然 而至今没有见到真正成熟稳定的工艺应用于工业生产,只有零星的、局部的、阶段性的应用 。显然,铝材无烟化学抛光工艺要成为一门普遍推广应用的技术,不但需要工艺本身的提高 ,还需要为人们所认识和掌握。 1 无烟化学抛光工艺鉴于铝材无烟化学抛光工艺的社会需求,我所于1997年承担… 相似文献
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Solovey G Ponce Dawson S 《Philosophical transactions. Series A, Mathematical, physical, and engineering sciences》2010,368(1933):5597-5603
Calcium signals participate in a large variety of physiological processes. In many instances, they involve calcium entry through inositol 1,4,5-trisphosphate (IP(3)) receptors (IP(3)Rs), which are usually organized in clusters. Recent high-resolution optical experiments by Smith & Parker have provided new information on Ca(2+) release from clustered IP(3)Rs. In the present paper, we use the model recently introduced by Solovey & Ponce Dawson to determine how the distribution of the number of IP(3)Rs that become open during a localized release event may change by the presence of Ca(2+) buffers, substances that react with Ca(2+), altering its concentration and transport properties. We then discuss how buffer properties could be extracted from the observation of local signals. 相似文献
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The electron spin resonance (ESR) and optical absorption spectra of Cu2+ were measured in thallium borate glasses in order to investigate the effects of glass transition temperature,T
g, upon the responses of cupric ion in alkali borate glasses. The ESR of Tl2+ induced by-ray irradiation was also obtained. An abrupt increase in the covalency of in-plane Cu2+-O-bonding was observed in the Tl2O system as well as in the Na2O system in a similar B2O3 composition range althoughT
g for the Tl2O glasses has little dependency on the composition compared with the Na2O glasses. The trend in the variation of the S-character of the Tl2+ unpaired electron with composition agreed with that of the covalency of in-plane Cu2+-O-bonding. The structure of the anion group present in Tl2O glasses was also examined by laser reman spectroscopy. 相似文献
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酸改性膨润土吸附去除镍镉离子的研究 总被引:11,自引:0,他引:11
在静态条件下,研究了改性膨润土对重金属离子的吸附性能和吸附机理,着重探讨了改性膨润土去除模拟水样中重金属离子Ni2 ,Cd2 的适宜条件及改性膨润土的再生方法.结果表明,改性膨润土对Ni2 ,Cd2 具有较好的吸附性能;pH值是影响改性膨润土对重金属离子吸附的重要因素,不同的金属离子都有其适宜的pH值范围.吸附的最佳条件是pH值5.0~7.0,废水中Ni2 ,Cd2 含量不大于45 mg/L,搅拌时间约60 min.利用改性膨润土吸附处理Ni2 ,Cd2 含量小于45 mg/L的模拟水样,效果很好,Ni2 ,Cd2 的去除率均可分别达到98.5%以上,出水可达到国家排放标准. 相似文献
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锰矿尾渣对Cu2+和Ni2+的吸附性能研究 总被引:4,自引:0,他引:4
研究了锰矿尾渣对重金属离子Cu2 和Ni2 的吸附性能,分析了锰矿尾渣的吸附动力学,就吸附时间、Cu2 和Ni2 浓度及pH值等因素对锰矿尾渣吸附性能的影响作了系统考察,并对锰矿尾渣的吸附机理进行了初步探讨.结果表明,在温度为25°℃、pH值为7.5的条件下,锰矿尾渣对Cu2 和Ni2 的吸附容量可达到1.6 mg/g以上,去除率均可达到97.5%以上,适宜于处理含低浓度Cu2 或Ni2 的废水.锰矿尾渣的吸附机理为离子交换吸附和表面配位吸附. 相似文献
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I. Z. Babievskaya N. F. Drobot K. S. Gavrichev O. A. Noskova V. A. Krenev S. V. Korostin Yu. V. Permyakov 《Inorganic Materials》2002,38(6):586-596
Using thermodynamic analysis of the Fe–C–NaCl–H2O–O2 system and experimental studies (x-ray diffraction and Mössbauer spectroscopy) of exothermic mixtures containing Fe metal, activated carbon, water, and NaCl, we identified the state of Fe and determined the phase composition of the reaction products at different stages of oxidation with atmospheric oxygen. The calculation and experimental results are in reasonable agreement. Under the conditions of restricted access for air, the main oxidation product is magnetite, Fe3O4. Free access for air leads to the formation of hydrous ferric oxide, Fe2O3 · nH2O. The most stable phase under the conditions of interest is goethite, Fe2O3 · H2O (-FeOOH). Storage of incompletely oxidized samples away from air for 7–14 days leads to partial reduction of iron(III) oxide phases to Fe3O4 and -Fe. 相似文献
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Photoluminescence of Ba2SiO4 and Ca2SiO4 activated with Eu2+ was investigated at various temperatures (from 10 K to 300 K) and pressures (from ambient to 200 kbar). At ambient pressure and room temperature, under UV excitation both phosphors yielded a green emission band with maxima at 505 nm and 510 nm for Ba2SiO4 and Ca2SiO4, respectively. The energies of these bands depended on pressure; the pressure shifts were ?12:55 cm?1/kbar for Ba2SiO4:Eu2+; and ?5:59 cm?1/kbar for Ca2SiO4:Eu2+. In the case of Ca2SiO4:Eu2+, we observed additional broadband emission at lower energies with a maximum at 610 nm (orange band). The orange and green emission in Ca2SiO4:Eu2+ had different excitation spectra: the green band could be excited at wavelengths shorter than 470 nm, whereas the orange band — at wavelengths shorter than 520 nm. The pressure caused a red shift of orange emission of 7.83 cm?1/kbar. The emission peaked at 510 nm was attributed to the 4f65d→4f7(8S7=2) transition of Eu2+ in the β — Ca2SiO4:Eu2+ phase, whereas the emission peaked at 610 nm — to the γ — Ca2SiO4:Eu2+ phase. The emission of Ba2SiO4:Eu2+ peaked at 505 nm was attributed to the 4f65d→ 4f7(8S7/2) transition of Eu2+ in the β — Ba2SiO4 phase. 相似文献
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Yu. A. Barbanel’ R. B. Dushin V. V. Kolin V. P. Kotlin L. G. Mashirov S. N. Nekhoroshkov 《Radiochemistry》2006,48(2):148-151
Absorption spectra of the NpO 2 + ion in UO 2 2+ -containing NaCl-KCl-CsCl (0.300:0.245:0.455) and LiCl-KCl-CsCl (0.575:0.165:0.260) eutectic melts in the region of the 5f-5f transitions, 700–2000 nm, were studied at 650 and 500°C, respectively. Processing of the spectra allowed the previously discovered phenomenon, cation-cation interaction of actinides in melts, to be interpreted for the first time in terms of the mass action law. It was shown that, at the concentrations of the interacting components studied (C Np = 0.2 M and C U = 0.1–2 M), a 1: 1 NpO 2 + ·UO 2 2+ cation-cation complex is formed. Its concentration stability constant was estimated at 0.06(6) and 0.11 1 mol?1 for the NaCl-KCl-CsCl and LiCl-KCl-CsCl systems, respectively. 相似文献