共查询到20条相似文献,搜索用时 15 毫秒
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用高温熔融法制备了Er3 掺杂50Bi2O3-(50-x)B2O3-xGa2O3(x=0,4,8,12,15 mol%)系列玻璃,测试了上述玻璃样品的吸收光谱、荧光光谱、荧光寿命及热稳定性.分别应用Judd-Ofelt理论和McCumber理论计算了Er3 强度参数和受激发射截面.研究发现,当Ga2O3含量在mol 8%时,荧光半高宽(FWHM)、峰值发射截面(σpeak e)和4I13/2能级荧光寿命(τm)均达到了峰值,其FWHM和σpeake分别为81 nm和1.03×10-20cm2.热稳定性则随着Ga2O3含量的增加而改善,析晶开始温度(Tx)和玻璃转变温度(Tg)之间的差值(△T)最高达到了261℃.研究表明,含适当重金属Ga2O3的铋硼酸盐玻璃具有较好的光学性能和热稳定性,适合于作为高增益、低噪声的宽带掺铒光纤放大器的基质材料. 相似文献
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用熔融冷却方法制备了ZnO-BaO-Bi2O3-B2O3系低熔点玻璃,研究了Bi2O3含量对所制玻璃热学性能和体积电阻率的影响。结果表明:随着Bi2O3含量的增大,所制玻璃密度和线膨胀系数增大,而膨胀转变温度(tg)、膨胀软化温度(tf)和体积电阻率(ρv)减小;当Bi2O3摩尔分数为0~12%时,随着Bi2O3含量增大,玻璃的tg、tf和ρv显著降低;而当Bi2O3摩尔分数为12%~25%时,这种变化趋势明显减弱。 相似文献
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在制作完底电极的LaAlO3(100)衬底上,利用磁控溅射法制备了一层BaO-Nd2O3-Sm2O3-TiO2(BNST)系薄膜,再对薄膜进行退火处理.X线衍射仪(XRD)分析表明,经退火处理的BNST薄膜结晶效果良好.采用薄膜电容结构来实现电容的测量,主要研究了BNST薄膜电容的频率特性.阻抗分析测试和矢量网络分析测试表明,在测试频率为1 MHz时,介电常数为58.3,介电损耗小于2%;在1 GHz的测试频率下,介电常数为57.5,介电损耗小于3%.研究表明,制备的BNST薄膜的频率特性稳定,基本满足微波频率下使用的要求. 相似文献
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研究了Sm2O3掺杂的Bi2O3-ZnO-Nb2O5(BZN)基陶瓷(Bi1.5–SmxZn0.5)(Zn0.5Nb1.5)O7(0≤x≤1.5,BSZN)的结构x和介电性能。实验采用传统的固相反应法制备陶瓷样品,XRD分析样品的相结构。结果表明:未掺杂的BZN陶瓷其结构为立方焦绿石单相;当Sm2O3掺杂量较少(0相似文献
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Non-vacuum electrodeposition (ED) was used to prepare a biaxially textured Gd2Zr2O7 (GZO) and GZO/Gd2O3 (GO) buffer layer on a Ni-W substrate. The YBa2Cu3O7−δ (YBCO) superconductor was deposited by pulsed-laser deposition (PLD) on a simplified ED-GZO and ED-GZO/ED-GO buffer layer.
The buffer layers and YBCO superconductor were characterized by X-ray diffraction (including θ/2θ, pole figure, omega scans,
and phi scans) and atomic force microscopy. Full-width at half maximum values of the omega (ω) and phi (Φ) scans of the electrodeposited
GZO and GZO/GO layer were better than those of the Ni-W base substrate. At 77 K and a self-magnetic field, the critical current
density of PLD YBCO on the electrodeposited-based buffer layer was 3.3 × 106 A/cm2, using the field criterion of 1 μV/cm. 相似文献
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The oxidation of single-crystal silicon wafers has been investigated using an industrial thermal oxidation system. The growth characteristics and electrical properties of the oxides resulting from pure hydrogen/oxygen (H2/O2), trichloroethane/oxygen (TCA/O2) and hydrogen chlorid/oxygen (HCl/O2) mixtures have been investigated and compared. The addition of both HCl and TCA to oxygen produces higher growth rates and improved electrical characteristics. It is shown that the oxidation rate for TCA/O2 is approximately 30%–40% higher than for HCl/O2 and that comparable electrical properties can be readily obtained. A TCA/O2 ratio of 1 mol% gives the optimum process for VLSI applications, though 3 mol% HCl/O2 gives comparable results. It is suggested that the overall mechanisms governing the processes are similar. However, the TCA process is a safer and cleaner alternative because it generates HCl in situ in the oxidation chamber. 相似文献
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采用固相合成法制备了高膨胀系数钡硼硅微晶玻璃材料。通过对该微晶玻璃进行X线衍射仪(XRD)、扫描电子显微镜(SEM)测试分析研究铬掺杂对BaO-B2O3-SiO2力、热、电性能及微观机理的影响。结果显示,热膨胀系数与介电损耗随Cr2O3含量增加而增大,研究表明,加入Cr2O3会促进该体系晶粒的生长,并促使晶相由石英晶相转变为方石英晶相,方石英热膨胀系数较高,其晶相含量增多导致热膨胀系数增大。该体系Cr2O3质量分数为0.5%时,制备出具有较高热膨胀系数(18.44×10-6/℃),较高抗弯强度(187 MPa),较低相对介电常数(5.5)的封装材料。 相似文献
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We provide the first fully atomistic model of the origin of the flat band voltage shifts due to La- and Al-based capping layers, which are frequently used to control the flat band voltage in high K metal gate stacks. Supercells with substitutional La, Sr, Al or Nb at an HfO2–SiO2 interface create dipole layers which shift the flat band voltage in the observed direction. The shift only occurs for substitutions at the interface, not distributed over the HfO2 layer. The shift is due to an image charge effect combining the metal electronegativity and oxygen density. 相似文献
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In this work, the cathodoluminescence (CL) of the ZnGa2O4 phosphor for different composition ratios of ZnO/Ga2O3 is examined, and its emission behavior is compared with that of ZnGa2O4 with In2O3-mixed phosphor. The wavelength and intensity of CL vary with the crystallization of phosphor; as a consequence, the optimal
crystallization and luminescence are obtained when the molar ratio of ZnO/Ga2O3 is 1. The luminance intensity is 4.2 times enhanced when phosphor is mixed with 12 wt.% of In2O3. A maximum luminance of 503 cd/m2 and a optimal conductivity of 0.69 (MΩ m)−1 of phosphor are obtained. The CL of blue ZnGa2O4 phosphor will be enhanced by In2O3 mixed. 相似文献