共查询到19条相似文献,搜索用时 109 毫秒
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本文分别研究了在超声波辐照作用下聚乙酸乙烯酯(PVAc)和部分水解聚丙烯酰胺(HPAM)在乙醇/水(55/45)中的降解和两者的嵌段共聚反应.结果表明:PVAc的降解速率大致可以用Ovenall方程表示,而HPAM的偏离较大.在25℃、频率为18.2kHz、逆变器主回路输入电流为2.4A的超声强度下,将浓度为0.50%的PVAc/HPAM(1/1)乙醇/水(55/45)溶液辐照10分钟,所得共聚物产率为4.3%.通过溶解试验、电子显微镜、相差显微镜、元素分析、IR和NMR分析了共聚物的结构,证明该共聚物主要为嵌段体. 相似文献
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本文分别研究了在高速搅拌下水溶液中聚氧化乙烯(PEO)和聚丙烯酰胺(PAM)的机械降解.在一定浓度范围内极限链长和降解速率常数随浓度变化而变化.在给定浓度下速率常数与搅拌时间有关.每一分子的断链次数对搅拌时间的依赖性可用如下方程描述:B_O=(P_O/P_∞-1)〔1-exp(-K_OP_∞t)exp(1/2K_1P_∞t~2)〕.据实验结果推测:在0.5%的水溶液中,无论PEO或PAM分子可能皆不形成缠结结构.由降解前后聚合物的GPC法分析可知,经降解的聚合物分子量分布变窄. 相似文献
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以羟基封端聚砜齐聚物(简称聚砜齐聚物)和二甲胺封端聚二甲基硅氧烷齐聚物(简称聚硅氧烷齐聚物)的缩聚,可得到聚砜-聚二甲基硅氧烷嵌段共聚物。改变两种齐聚物的分子量,可以合成出具有从塑料到橡胶性能的各种嵌段共聚物。 相似文献
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用遥爪羟基聚苯乙烯与聚乙二醇和二氯甲烷在氢氧化钾存在下合成了氧亚甲基连接的聚氧乙烯 -聚苯乙烯多嵌段共聚物 ,采用FT -IR、1HNMR、分子量测定和凝胶渗透色谱分析表征共聚物的结构 ,研究了共聚物的乳化性能和相转移催化性能。结果表明 ,该类共聚物具有较好的乳化性能和相转移催化性能 相似文献
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用遥爪羟基聚苯乙烯与聚乙二醇和二氯甲烷在氢氧化钾存在下合成了氧亚甲基连接的聚氧乙烯-聚苯乙烯多嵌段共聚物,采用FT-IR、^1HNMR,分子量测定和凝胶渗透色谱分析表征共聚物的结构,研究了共聚物的乳化性能和相转移催化性能,结果表明,该类共聚物具有较好的乳化性能和相转移催化性能。 相似文献
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将聚对苯二甲酸乙二酯-聚四亚甲基醚(PET-PTMG)嵌段共聚物中共混少量聚对苯二甲酸丁二酯-聚四亚甲基醚(PBT-PTMG),或在PET-PTMG合成中加入一定量丁二醇形成硬链段共聚酯,则相应的共混物或共聚物的结晶速度提高。本工作采用光学解偏振仪及小角激光散射方法研究了上述产物的结晶过程。 相似文献
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以氧化还原引发体系为主,配合其它引发剂组成新型复合引发体系。在低温条件下采用水溶液聚合法引发丙烯酰胺和丙烯酸共聚工艺路线制备高分子量聚丙烯酰胺。考查各项因素对聚合反应的影响,最终确定最优化工艺条件:单体浓度0.0035mol/g,氧化还原引发剂14mg/L,EDTA10mg/L,偶氮35mg/L,体系温度0℃,pH值7.0,聚合物分子量为1.943×10^7。 相似文献
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《国际聚合物材料杂志》2012,61(1):73-80
The possibility of converting polyethylene terephthalate (PET) waste into terephthalic acid as a primary material by using different techniques through trans-esterification, with an alcohol and through hydrolysis in basic medium, has been investigated. In addition, utilization of activating agents such as inorganic salts and phase transfer catalysts has been investigated.Mineral water and beverage bottles were collected, cleaned and crushed into flakes suitable for the intended experiments. Also, the main products of chemical conversion of such wastes were isolated and confirmed by authentication with standard terephthalic acid through Thin Layer Chromatography (TLC) technique. The reaction yield % was determined to optimize the corresponding experimental conditions and the obtained results have been presented and discussed. 相似文献
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R. Unger H. Reuter S. Höring E. Donth 《Polymer-Plastics Technology and Engineering》2013,52(1-2):1-25
DSC investigations are reported for a broad assortment of blends and copolymers of the immiscible poly(ethylene oxide) (PEO)/poly(tert-butyl) methacrylate) (PTBMA) system. Contrary to expectations, the PEO crystallization and melting behavior of the copolymer system is similar to that of the PEO/poly(methyl methacrylate) (PMMA) copolymer system (which is usually considered to be miscible in the melt). This is discussed with the concept of a UCST-type granulated demixing in the latter. In both systems the crystallization is rather sensitive to the block structure, even for comparable molecular weights and compositions. This indicates some importance of DSC as an additional tool in copolymer characterization. Free PEO ends favor the crystallization in all cases. 相似文献
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The copolymerization kinetics of ethylene oxide and propylene oxide in an atomizing-circulation reactor under semi-continuous operation is studied which is of great importance for molecular designation.The kinetic parameters are obtained by numerical optimization of the kinetic model. 相似文献
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.. AssociationNumber Figure shows the dependence of the weight-average association number 《胶体与聚合物》2003,21(3):23-26
3.2. Association Number Figure 5 shows the dependence of the weight-average association number (Nw,measured by static light scattering, solution temperature 30 °C) on hydrophobe block length for ES and ESEblock copolymers. 相似文献
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~~Block Copolymesrs of Ethylene Oxide and Styrene Oxide. New Copolymer Surfactants(Ⅱ)@David Attwood$School of Pharmacy and Pharmaceutical Science,University of Manchester!Manchester M139PL,U K
@Colin Booth$Departmentof Chemistry,U niversity of Manchester!Manchester M139PL,U K.~~… 相似文献
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Silica nanoparticles bearing hyperbranched polyglycidol (hbP) grafts are synthesized and blended with poly(ethylene oxide) (PEO) for the fabrication of composite solid polymer electrolytes (SPEs) for enhancing Li-ion conductivity. Different batches of hbPs are prepared, namely, the 5th, 6th, and 7th with increasing molecular weights using cationic ring-opening polymerization and grafted the hbPs onto the silica nanoparticles using quaternization reaction. The effect of end functionalization of hbP-grafted silica nanoparticles with a nitrile functional group (CN–hbP–SiO2) on the ionic conductivity of the blends with PEO is further studied. High dipole moments indicate polar nature of nitriles and show high dielectric constants. Among all the hbPs, the 6th-batch CN–hbP–SiO2 nanoparticles exhibit better ionic conductivity on blending with PEO showing ionic conductivity of 2.3 × 10−3 S cm−1 at 80 °C. The blends show electrochemical stability up to 4.5 V versus lithium metal. 相似文献
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《国际聚合物材料杂志》2012,61(3-4):533-546
Abstract The thermal behaviour of poly(amide-ester)s with the amide group in the side chain was studied. Polymers were sinthesized from the diphenol-amides N-(2,6-dichloro-4-nitrophenyl)-2, 2-bis(4-hydroxyphenyl)-propanamide, N-(2, 6-dichloro-4-nitrophenyl)-3,3-bis(4-hydroxyphenyl)-butanamide, and N-(2,6-dichloro-4-nitrophenyl)-4, 4-bis(4-hydroxyphenyl)-pentanamide and terephthaloyl chloride, isophthaloyl chloride and adipoyl chloride under phase-transfer conditions using several phase-transfer catalysts. The thermal decomposition temperature was influenced by both, the nature of the diacid and the length of the side chain, those derived from terephthaloyl chloride being more stable than those derived from isophthaloyl chloride and adipoyl chloride. All polymers degrade in a single-step process and the kinetics parameters were determined using the Arrhenius relationship and a computer program. 相似文献