Design of a combined heat,hydrogen, and power plant from university campus waste streams

This paper presents analysis of a combined heat, hydrogen, and power (CHHP) plant for waste-to-energy conversion in response to the 2012 Hydrogen Student Design Contest. Our team designed the CHHP plant centered on a molten carbonate fuel cell (Fuel Cell Energy DFC-1500) fueled by syngas derived primarily from an oxygen-fed municipal waste gasifier. Catalytic methanation and supplemental utility natural gas increase the fuel methane content to meet the DFC-1500 fueling requirements for maintaining stack thermal energy balance. Internal reforming converts excess fuel from the fuel cell to an H₂-rich stream, which is purified downstream in a pressure-swing adsorption system. The separated H₂ (1000 kg per day) is compressed for storage to provide fuel for a campus fleet of PEM fuel cell buses. The system provides more than 1.1 MWe for the campus grid with approximately 20% of the fuel cell power used for H₂ compression and running the plant. Heat recovery steam generators provide steam for the methanation reactor and 0.4 MW of thermal energy for district heating or steam turbine-driven chillers. Cost analysis indicates that the system requires incentives for economic viability with current estimated operating costs, but advances to reduce capital expenses of comparable urban waste-driven CHHP systems can make them attractive for future implementation.     

Modeling of hydrogen and electrical energy storages in wind/PV energy system on the Lake Baikal coast

The paper presents a research on a green power supply system (producing no carbon dioxide and other harmful emissions) in the area of Baikal Lake, for the maximum loads of 10 kW and 100 kW. The system includes photovoltaic converters, wind turbines, batteries for electric energy storage and a system for hydrogen production, storage and energy use. Calculations based on the optimization mathematical model demonstrated the efficiency of the combined use of wind and solar energy in the considered areas, as well as the simultaneous storage of electric energy and hydrogen. The electric energy storage is most efficient for short-term time intervals whereas an increase in the duration of continuous energy “standstills” up to several days makes the storage of hydrogen more cost-effective.     

Decision-making between a grid extension and a rural renewable off-grid system with hydrogen generation

Most populations in rural Africa have no access to electricity, in this study, a comparative analysis between grid extension and the implementation of renewable off-grid hybrid power system is carried out. The objective of the study is to determine the best feasible option. Napier, a farming village in the Western Cape province of South Africa was selected as the site for the comparative analysis and HOMER PRO software was used to develop an optimal system using the wind and solar resources of the selected site. The load profile considered in the analysis includes lighting, cooking and hot water demands. The best feasible option is determined based on the Net Present Cost of each feasible scenario. Sensitivity analysis on the current cost and the projected cost of hydrogen storage w conducted to observe the impact of the cost of hydrogen storage on the renewable off-grid system cost of energy.     

Thermodynamic and economic optimization of a MCFC-based hybrid system for the combined production of electricity and hydrogen

In this paper, a biogas fuelled power generation system is considered. The system is based on a molten carbonate fuel cell (MCFC) stack integrated with a micro gas turbine for electricity generation, coupled with a pressure swing absorption system (PSA) for hydrogen production.     

A novel combined biomass and solar energy conversion-based multigeneration system with hydrogen and ammonia generation

In the present study, an innovative multigeneration plant for hydrogen and ammonia generation based on solar and biomass power sources is suggested. The proposed integrated system is designed with the integration of different subsystems that enable different useful products such as power and hydrogen to be obtained. Performance evaluation of designed plant is carried out using different techniques. The energetic and exergetic analyses are applied to investigate and model the integrated plant. The plant consists of the parabolic dish collector, biomass gasifier, PEM electrolyzer and hydrogen compressor unit, ammonia reactor and ammonia storage tank unit, Rankine cycle, ORC cycle, ejector cooling unit, dryer unit and hot water production unit. The biomass gasifier unit is operated to convert biomass to synthesis gaseous, and the concentrating solar power plant is utilized to harness the free solar power. In the proposed plant, the electricity is obtained by using the gas, Rankine and ORC turbines. Additionally, the plant generates compressed hydrogen, ammonia, cooling effect and hot water with a PEM electrolyzer and compressed plant, ammonia reactor, ejector process and clean-water heater, respectively. The plant total electrical energy output is calculated as 20,125 kW, while the plant energetic and exergetic effectiveness are 58.76% and 55.64%. Furthermore, the hydrogen and ammonia generation are found to be 0.0855 kg/s and 0.3336 kg/s.     

Integration of molten carbonate fuel cell and looped multi-stage thermoacoustically-driven cryocooler for electricity and cooling cogeneration

Thermal management is essential for high-temperature molten carbonate fuel cell (MCFC) because the accumulated waste heat may degrade the durability. In this paper, looped multi-stage thermoacoustically-driven cryocooler (LMTC) is proposed to reuse the waste heat from MCFC for cooling production, which not only can tackle with the thermal management issue but also can provide additional usages. Accounting various irreversible dissipation, the models of MCFC, LMTC and MCFC-LMTC hybrid system are analytically formulated. Performance features of MCFC-LMTC hybrid system are revealed and the advantages are expounded via calculation examples. Calculations indicate that the maximum power density and corresponding efficiency of the hybrid system are 1688.9 W m^?2 and 39.7%, which are 11.4% and 1.3% bigger than that of the sole MCFC system, respectively. By comparing with other available systems, the superiority of using LMTC to recover MCFC waste heat for refrigeration is clearly demonstrated. Considerable parametric studies show that the heat-transfer coefficient of hot heat exchange for LMTC is not suggested to be greater than 2.5 × 10^?3 W m^?2 K^?1. In addition, an increase in the working temperature, working pressure of MCFC, reactant concentration or engine stage number of LMTC positively benefits the hybrid system performance, while an increase in the thermodynamic loss coefficient worsens the hybrid system performance. The obtained results may offer new insights into improving the performance of MCFCs through thermal management approaches.     

Lifetime optimization of a molten carbonate fuel cell power system coupled with hydrogen production

In this paper, a biogas fuelled energy system for combined production of electricity and hydrogen is considered. The system is based on a molten carbonate fuel cell stack integrated with a micro gas turbine. Hydrogen is produced by a pressure swing absorption system. A multi-objective optimization is performed, considering the electrical efficiency and the unit cost of electricity as the objective functions.The system operation is affected by variations in fuel composition, ambient temperature and performance degradation of the components occurring during its lifetime. These effects are considered while defining the objective functions.     

风电与燃气轮机互补发电系统发电成本分析

在采用风电场与小型燃气轮机组成的互补系统发电特性参数的基础上,详细分析了互补系统发电成本的构成和各自的计算方法。采用新疆达坂城风电场的风速数据,基于互补系统的发电特性参数和风电场与燃气轮机电站的发电成本构成,应用改进过的等额支付折算法,在当前的技术条件和价格下,计算了风电场子系统和燃气轮机电站子系统各自的折旧成本、燃料成本和运行维护成本,得到了整滚发电系统发电成本的计算方法,为在新疆地区实现这种互补发电系统提供经济分析基础。     

Impact of a large penetration of wind generation on the GB gas network

Wind power is expected to be the major element of renewable electricity generation in Great Britain (GB) by 2020 with a capacity of around 30 GW. The potential impact of a large amount of wind generation on the GB gas network was investigated using a combined gas and electricity network model. The varying nature of gas and electric power flows, network support facilities such as gas storage and compressors, and the power ramping characteristics of various power plants were considered. Three case studies were modelled, one case uses the existing network and the other two make use of a hypothesised network in 2020 with two distinct levels of wind generation representing low and high wind periods. The simulation results show that a large penetration of wind generation will influence the electricity generation mix as the wind power varies. Gas-fired generation is used to compensate for wind variability. This will cause increased flows and compressor power consumption on the gas network. Linepack depletion during low wind periods was shown to limit the ability of the gas network to fully supply gas-fired generators.     

Biomass based microturbine system for electricity generation for isolated communities in amazon region

This paper presents the development stages of a micro-scale system for electricity generation from biomass with 500 W of power. The proposed system is based on an open steam power cycle, whose conception was aimed at seeking solutions to meet the needs for energy supply in isolated communities in the Amazon region. In addition the great biomass potential in the region is an opportunity for the application of biomass energy to increase the economic activity and develop new technologies. The tests performed demonstrate that the steam turbine is the critical component to the commercial-scale feasibility of the presented technology, particularly when it's proposed manufacturing of the system by small regional industries.     

风电与燃气轮机互补系统发电成本敏感性分析

详细讨论了大型风电场与燃气轮机组成的互补发电系统发电成本的主要影响因子及其对系统的敏感性。通过对互补发电系统发电成本理论公式的研究,推导了互补系统中各项影响因子相对于发电成本的数学方程和影响尺度,得到了影响发电成本几个关键的影响因子。通过采用敏感性分析原理,对这些主要的影响因子在不同变化条件下对互补发电系统发电成本的影响进行了详细的分析与讨论,提出降低系统发电成本的可行性措施及其努力的方向,为在新疆地区实现这种互补发电系统提供经济分析上的基础。     

Economic analysis of a combined heat and power molten carbonate fuel cell system

Fuel cells can be attractive for use as stationary combined heat and power (CHP) systems. Molten carbonate fuel cell (MCFC) power plants are prime candidates for the utilization of fossil based fuels to generate high efficiency ultra clean power. However, fuel cells are considerably more expensive than comparable conventional technologies and therefore a careful analysis of the economics must be taken. This work presents analysis on the feasibility of installing both a FuelCell Energy DFC^® 1500MA and 300MA system for use at Adams Thermal Systems, a manufacturing facility in the U.S. Midwest. The paper examined thoroughly the economics driving the appropriateness of this measure. In addition, a parametric study was conducted to determine scenarios including variation in electric and natural gas rates along with reduced installation costs.     

Development and assessment of a solar,wind and hydrogen hybrid trigeneration system

A solar-wind hybrid trigeneration system is proposed and analyzed thermodynamically through energy and exergy approaches in this paper. Hydrogen, electricity and heat are the useful products generated by the hybrid system. The system consists of a solar heliostat field, a wind turbine and a thermochemical copper-chlorine (Cu-Cl) cycle for hydrogen production linked with a hydrogen compression system. A solar heliostat field is employed as a source of thermal energy while the wind turbine is used to generate electricity. Electric power harvested by the wind turbine is supplied to the electrolyzer and compressors and provides an additional excess of electricity. Hydrogen produced by the thermochemical copper-chlorine (Cu-Cl) cycle is compressed in a hydrogen compression system for storage purposes. Both Aspen Plus 9.0 and EES are employed as software tools for the system modeling and simulation. The system is designed to achieve high hydrogen production rate of 455.1 kg/h. The overall energy and exergy efficiencies of the hybrid system are 49% and 48.2%, respectively. Some additional results about the system performance are obtained, presented and discussed in the paper.     

Performance investigation of a combined MCFC system

This study investigates the performance of a combined industrial molten carbonate fuel cell (MCFC) system, including a turbo expander, which was recently installed by Enbridge Inc. in Toronto, Canada. It entails a comprehensive thermodynamic analysis regarding energy and exergy calculations, subject to varying operating conditions. Furthermore, a simplified and novel method is used for a cost analysis to assess the amortization of the system. The results from the base case study suggest that an overall energy efficiency as high as 60% is achievable while fuel cell stack energy and exergy efficiencies of 50.6% and 49.3%, respectively, are reached. The cost analysis indicates that the amortization of the system may take up to 15 years of operational time, depending on the price of electricity and natural gas. However, carbon offsets may make a paramount contribution to the overall savings and economic viability of future combined MCFC systems.     

Exergy analysis and optimization of a biomass gasification, solid oxide fuel cell and micro gas turbine hybrid system

A hybrid plant producing combined heat and power (CHP) from biomass by use of a two-stage gasification concept, solid oxide fuel cells (SOFC) and a micro gas turbine was considered for optimization. The hybrid plant represents a sustainable and efficient alternative to conventional decentralized CHP plants. A clean product gas was produced by the demonstrated two-stage gasifier, thus only simple gas conditioning was necessary prior to the SOFC stack. The plant was investigated by thermodynamic modeling combining zero-dimensional component models into complete system-level models. Energy and exergy analyses were applied. Focus in this optimization study was heat management, and the optimization efforts resulted in a substantial gain of approximately 6% in the electrical efficiency of the plant. The optimized hybrid plant produced approximately 290 kW_e at an electrical efficiency of 58.2% based on lower heating value (LHV).     

Influence of multiple irreversible losses on the performance of a molten carbonate fuel cell-gas turbine hybrid system

In this study, a new molten carbonate fuel cell-gas turbine hybrid system, which consists of a fuel cell, three heat exchangers, a compressor, and a turbine, is established. The multiple irreversible losses existing in real hybrid systems are taken into account by the models of a molten carbonate fuel cell and an open Brayton cycle with a regenerative process. Expressions for the power outputs and efficiencies of the subsystems and hybrid system are derived. The maximum power output and efficiency of the hybrid system are numerically calculated. It is found that compared with a single molten carbonate fuel cell, both the power output and efficiency of the hybrid system are greatly enhanced. The general performance characteristics of the hybrid system are evaluated and the optimal criteria of the main performance parameters are determined. The effects of key irreversibilities on the performance of the hybrid system are investigated in detail. It is found that the use of a regenerator in the gas turbine can availably improve the power output and efficiency of the system. The results obtained here are significant and may be directly used to discuss the optimal performance of the hybrid system in special cases.     

Use of hydrogen as a seasonal energy storage system to manage renewable power deployment in Spain by 2030

Spain has presented a plan (known as PNIEC) to reduce conventional energy sources (shutting down 16 GW) and to increase the use of renewable sources (incorporating 65 GW). This generation portfolio leads to a situation in which there will be a surplus of electrical energy in spring and summer, which will be lacking in autumn and winter. The plan sets a target on batteries, but insufficient to manage more than 10 TWh over 6 months. This paper proposes the deployment of electrolysers to produce hydrogen with the surplus energy, using the already existing Spanish natural gas network to store it. The resulting gas (up to 15% blend of hydrogen in natural gas) could be used subsequently in turbines to alleviate the energy deficit. With this strategy, up to 7.27 TWh of the surplus renewable energy could be reused, and 2.54 million tons of CO2 equivalent would be avoided yearly.     

Research on the generation of electricity from the geothermal resources in Simav region, Turkey

One of the greatest problems in using renewable energy sources is the great variability of energy level, both in the short and long term. Geothermal energy, by nature, has high availability because the source is not dependent on weather conditions, so it is among the most stable renewable energy sources. Geothermal energy has the potential to play an important role in the future energy supply of Turkey. Although Turkey has the second-highest geothermal energy potential in Europe, electricity generation from geothermal energy is rather low.This study examines the use of geothermal energy in electricity generation and investigates the applicability of the existent geothermal energy resources to electricity generation in the Kütahya–Simav region, Turkey. The binary cycle is used in the designed power plant for electricity generation from geothermal fluid in which the percentage of liquid is high and which is at lower temperature. In this power plant, R134a is chosen as the secondary fluid, whose boiling point temperature is lower than that of water, and is used instead of geothermal fluid in a second cycle. The thermal efficiency of the designed power plant is measured to be 12.93%.     

Co-production system of hydrogen and electricity based on coal partial gasification with CO2 capture

To solve the problems of high cost and low efficiency of conventional co-production system of hydrogen and electricity with low hydrogen-to-electricity ratio, a novel co-production system based on coal partial gasification with CO₂ capture is proposed and thermodynamically analyzed. The new system integrates the conceptions of cascade conversion of coal and cascade utilization of syngas to realize the system with high efficiency, low cost, environmental friendliness and flexible hydrogen-to-electricity ratio. The performance of the new system is evaluated by an Aspen Plus model and effects of the operating conditions are also studied. It is found that the system with capturing CO₂ of 59.7% and hydrogen-to-electricity ratio of 4.76 holds a high exergy efficiency of 54.3% when the carbon conversion ratio of the pressurized fluidized bed (PFB) gasifier is equal to 0.7. The carbon conversion ratio of the PFB gasifier is a dominant factor to decide the performance of system. In comparison with the series-type co-production system, the parallel-type co-production system and separate production system, the new system proposed in this study has exergy-saving efficiency of 17.7%, 15.1% and 8.9%, respectively.     

Spatial development of hydrogen economy in a low-carbon UK energy system

Hydrogen technologies and infrastructures might play a significant role in meeting ambitious climate and energy policy goals of the UK Government. Nonetheless, studies on hydrogen are either limited in scope in that they do not take into account the relationships with the wider energy system drivers and constraints or do not consider how a hydrogen network might develop geographically. This paper presents a framework where a spatially explicit hydrogen module is embedded in the UK MARKAL Energy System model to explore energy system trade-offs for the production, delivery and use of hydrogen at the sub-national level. A set of illustrative scenarios highlight the competitiveness of hydrogen related infrastructures and technologies as well as imported liquid hydrogen against a stringent emissions reduction target; the effect of emissions reduction trajectory on the development of hydrogen network; the intense resource competition between low carbon hydrogen production and electricity generation, and the importance of economies of scale in hydrogen supply and distribution.