Corrosion failure analyses of an elbow and an elbow-to-pipe weld in a natural gas gathering pipeline

The internal corrosion of a 90° elbow was found in a natural gas gathering pipeline in Northeast China. The welded joint between the elbow and the downstream pipe was also severely corroded. The 90° elbow was forged of 16Mn steel. The downstream pipe (Φ 76 mm × 9 mm) was made of 20G steel. To determine failure causes, the elbow and the welded joint were taken as a whole and investigated systematically. The influence of the flow disturbance induced by the elbow on the damage at the welded joint was considered. The internal damage at the elbow and that at the welded joint were studied using field investigation, visual examination, scanning electron microscopy (SEM), energy-dispersive spectroscopy (EDS), X-ray powder diffraction (XRD), hardness tests, and computational fluid dynamics (CFD) techniques. The results showed that erosion corrosion from solid particles and corrosive liquid droplets entrained in the natural gas flow was the main cause of the internal damage at the elbow and the welded joint. The welded joint was attacked by the particles with the highest velocity magnitudes and the most dangerous impact angles. The flow disturbance induced by the elbow, the special location of the welded joint, and the angular misalignment due to poor welding quality jointly caused the substantially more severe damage at the welded joint.     

Failure analysis of natural gas pipes

Incident involving failures of 6 months old API 5L X42 (NPS8) and SDR 17, 125 mm medium density polyethylene pipe (MDPE) supplying natural gas to an industrial customer has caused serious 7 h supply disruption. Study was performed to identify the most probable cause of the pipes failures. The study conducted by reviewing the existing design and construction data, visual physical inspection, pipe material analysis, structural analysis using NASTRAN and Computational Fluid Dynamics analysis (CFD) using FLUENT. Investigations revealed that high pressure water jet from leaked water pipe had completely mixed with surrounding soil forming water soil slurry (high erosive properties) formed at a close vicinity of these pipes. Continuous impaction of this slurry upon the API 5L X42 pipe surface had caused losses of the pipe coating materials. Corrosion quickly ensued and material loss was rapid because of the continuous erosion of oxidised material that occurred simultaneously. This phenomenon explains the rapid thinning of the steel pipe body which later led to its failure. Metallurgical study using photomicrograph shows that the morphology of the steel material was consistent and did not show any evidence of internal corrosion or micro fractures. The structural and CFD simulation results proved that the location, rate and the extent of erosion failures on the pipe surfaces can be well predicted, as compared with actual instances.     

Experimental and numerical studies on corrosion failure of a three-limb pipe in natural gas field

A bursting incident occurred in a three-limb pipe, having 16Mn steel for the main pipe and 316L + L416 composite metal for the branch pipe, in a natural gas field. The failure analysis was performed by means of inspection, experiments and computational fluid dynamics (CFD) simulation. The CFD results indicated the radical change in the flow characteristics inside the three-limb pipe due to its upright structure and the formation of a low vortex in the downstream near the junction, which indicated the condensation of water vapor containing high salinity. The condensed brine saturated with CO₂ adhered to the inner wall surface of the main pipe. In such a corrosive medium, 16Mn steel acts as an anode and is preferentially corroded due to galvanic corrosion. In addition, the downstream area, covered by low vortex, exhibited high shear stress and droplet impingement stress, resulting in an increase in flow erosion. Thus, the failure of the three-limb pipe can be attributed to the synergistic effect of galvanic corrosion and flow erosion.     

The study of tribological and corrosion behavior of plasma nitrided 34CrNiMo6 steel under hot and cold wall conditions

This paper reports on a comparative study of tribological and corrosion behavior of plasma nitrided 34CrNiMo6 low alloy steel under modern hot wall condition and conventional cold wall condition. Plasma nitriding was carried out at 500 °C and 550 °C with a 25% N₂ + 75% H₂ gas mixture for 8 h. The wall temperature of the chamber in hot wall condition was set to 400 °C. The treated specimens were characterized by using scanning electron microscopy (SEM), X-ray diffraction (XRD), microhardness and surface roughness techniques. The wear test was performed by pin-on-disc method. Potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) tests were also used to evaluate the corrosion resistance of the samples. The results demonstrated that in both nitriding conditions, wear and corrosion resistance of the treated samples decrease with increasing temperature from 500 °C to 550 °C. Moreover, nitriding under hot wall condition at the same temperature provided slightly better tribological and corrosion behavior in comparison with cold wall condition. In consequence, the lowest friction coefficient, and highest wear and corrosion resistance were found on the sample treated under hot wall condition at 500 °C, which had the maximum surface hardness and ε-Fe_2–3N phase.     

Corrosion investigation of the inlet section of REAC pipes in the refinery

The corrosion failure causes of the inlet section of reactor effluent air cooler (REAC) in the refinery was investigated by using Aspen software, HTRI Xchanger Suite simulator (HTRI), Computational Fluid Dynamics (CFD) technology and erosion corrosion experiments. The result shows that the severe erosion corrosion failure mainly occurs in the first row of REAC pipelines, and the field with localized corrosion is mainly distributed in a range of 5.8 m away from the inlet of air coolers and reveals an inhomogeneous thinning. At the REAC inlet, the NH₄HS concentration is about 12 wt% (> 10 wt%), the shear stress is high and oil phase is not appeared, thus the corrosion failure easily occurs at the inlet region. Meanwhile, the liquid phase fraction is larger at the bottom of the pipeline, forming corrosive solution and resulting in serious thinning. In the second and third passes, water and oil phase flow increases, i.e., both the NH₄HS concentration and the shear stress greatly decrease. In addition, the water in oil emulsion can segregate the contact between the tube wall and the corrosive medium. Therefore, beyond the range of corrosion failure region and in the second/third passes, the risk of erosion corrosion is markedly reduced.     

Effects of thermal treatment on the mechanical properties of poly(p-phenylene benzobisoxazole) fiber reinforced phenolic resin composite materials

Thermal degradation behaviors of the poly(p-phenylene benzobisoxazole) (PBO) fiber and phenolic resin matrix were investigated. The unidirectional PBO fiber reinforced phenolic resin composite material laminates were fabricated and exposed in a muffle furnace of 300 °C, 550 °C, 700 °C, and 800 °C for 5 min, respectively, to study the effects of thermal treatment on mechanical properties of the composites. After undergone thermal treatments at 300 °C, 550 °C and 700 °C for 5 min, the flexural strength was reduced by 17%, 37% and 80%, respectively, the flexural modulus was decreased by 5%, 14% and 48%, respectively, and the interlaminar shear strength (ILSS) was lowered by 12%, 48% and 80%, respectively. Thermal treatment at 300 °C, the phenolic resin began to pyrolyze and shrink resulted in the irreversible damage of the composites. After 550 °C thermal treatment, the phenolic resin pyrolyzed mostly but the PBO fiber had no obvious pyrolyze, the interface had sever broken. After 700 °C thermal treatment, the phenolic resin formed amorphous carbonaceous and PBO fiber pyrolyzed mostly so the mechanical properties dropped dramatically. At being heated at 800 °C for 5 min, the fiber was nearly totally pyrolyzed and and kept fibrous carbonaceous although the specimen became too brittle to stand any load thereon.     

Hot shear deformation constitutive analysis and processing map of extruded Mg–12Li–1Zn bcc alloy

The hot shear deformation behavior of an extruded Mg–12Li–1Zn alloy was studied by shear punch test (SPT) in the temperature range 200–300 °C, and in the shear strain rate range 1.2 × 10⁻³–6.0 × 10⁻² s⁻¹. Based on the constitutive analysis of the SPT data, it was found that a sine hyperbolic function could properly describe the hot shear deformation behavior of the material. The activation energy of 108 kJ mol⁻¹ calculated from sine hyperbolic function together with the power-law stress exponents of 3.6–4.7 is indicative of lattice-diffusion-controlled dislocation climb mechanism as an operative deformation mechanism. As a new approach, the shear processing map was developed in order to determine the optimum processing condition, which was found to be 300 °C and 1.2 × 10⁻³ s⁻¹. Domains of the processing map are also interpreted on the basis of the associated microstructural observations. It was found that the post-deformation microstructure is sensitive to the Zener–Hollomon parameter, so that DRX was encouraged with decreasing Z-value.     

Effect of liquid oilfield-related media on slow crack growth behavior in polyethylene pipe grade materials

Polyethylene, as non-polar material, shows a high affinity especially to liquid non-polar aromatic and aliphatic hydrocarbons, and liquid hydrocarbons (LHC) to a certain extent migrate into the bulk material by sorption, leading to material plasticization (i.e., drop in modulus and yield stress). This paper aims to study the crack growth mechanism and failure behavior of commercial pipe grade materials when exposed to deionized water or LHC (90/10 wt% i-octane/toluene) under the simultaneous application of cyclic loads. The results of the cyclic crack growth experiments with three PE 100 pipe grades, using cracked round bar (CRB) specimens and performed at two different temperatures (35 °C and 60 °C), are compared in terms of the specimen lifetimes, and the micro-modes and kinetics of failure by referring to concepts of fracture mechanics. Most importantly, while crack advance is preceded by crack-tip crazing in water, shear yielding takes place at crack-tips in the LHC environment.     

Cavitation erosion resistance of heat-treated NiTi

NiTi (Ti–50.8 at.% Ni) specimens were solution-treated at 1000 °C, followed by aging between 200 and 600 °C. The cavitation erosion resistance of all the aged specimens in deionized water was improved relative to the solution-treated specimen, with a maximum increase of about 8.7 times, which was achieved by aging at 500 °C. The results also indicate that both austenite and martensite contribute to the high cavitation erosion resistance of NiTi. It is also shown that a simple macro-indentation test employing a Rockwell indenter may be used for preliminary screening of heat-treated NiTi with respect to cavitation erosion resistance.     

Solid particle erosion behavior of carbidic austempered ductile iron modified by nanoscale ceria particles

In this study, the solid-particle erosion behavior of carbidic austempered ductile iron (CADI) containing different amounts of ceria nanoparticles was investigated. Attempt was made to correlate the erosion resistance of the material to its microstructure and mechanical properties. It was demonstrated that the erosion resistance of CADI was improved by adding ceria nanoparticles. The maximum erosion rate of unmodified CADI occurred at the impact angle of 60–75°, which slightly shifted to lower angles when ceria nanoparticles were added, corresponding to more ductile characteristic. During erosion tests, the retained austenite in CADI partially transformed to martensite although the transformation was suppressed by the addition of ceria nanoparticles. The ceria-modified CADI showed a considerably increased erosion resistance at various impact angles.     

Effects of winding angle on the behaviour of glass/epoxy pipes under multiaxial cyclic loading

The effects of winding angle on the behaviour of glass/epoxy composite tubes under multiaxial cyclic loading were investigated. The performance of such composite tubes was studied using an indigenous automated test procedure that is compatible with the internal qualification requirements of the composite pipe manufacturers. Glass fibre reinforced epoxy (GRE) composite pipes with three winding angles, namely, [± 45°]₄, [± 55°]₄, and [± 63°]₄, were tested. A novel automated test rig was fabricated to accommodate five stress ratios, ranging from pure axial to pure hoop loadings. The cyclic pressure test was conducted until droplets of water were seen on the outer surface of the pipe. Failure envelopes were then constructed based on the first ply failure (FPF) points determined from the axial stress to hoop strain response at five stress ratios. Three functional failure modes, namely, tensile axial, weepage, and local leakage failures, were observed during the tests. The results indicate that each winding angle dominates a different optimum pressure loading condition, namely, [± 55°]₄ for pure hydrostatic loading, [± 45°]₄ for hoop to axial loading, and [± 63°]₄ for quad hoop to axial loading. The envelopes show a strong dependence on the stress ratio and winding angle.     

Hybrid materials design to control creep in metallic pipes

A hybrid material has been developed to improve creep performance in pressurized metallic pipes subjected to high-temperatures. Model materials were selected for an investigation of reinforcement design parameters in architectured materials. Brass pipes (65 wt.% Cu/35 wt.% Zn) with austenitic stainless steel reinforcement were pressurized and creep rupture tested at 673 K. Compared to unreinforced pipes of equal dimensions, a 47-times reduction in the effective strain rate was observed with a 50° reinforcement angle. A ‘neutral angle’ of 54.7 ± 1.5° was determined experimentally, where tangential (hoop) and longitudinal stresses on the pipe can be balanced and strains minimized. For initial angles below the neutral angle, creep strain was shown to facilitate a shift in orientation towards the neutral angle. For an initial angle of 42°, this shift towards the neutral angle resulted in instantaneous creep rate dropping from 170% of the mean creep rate to 60% of the mean creep rate over 820 h, when the final angle was measured to be 50°. A high-temperature prototype (tungsten braid oriented at 53° over a 253MA stainless steel pipe) was shown to give a creep life extension in excess of 300-times at 1313 K.     

Erosion corrosion failure analysis of the elbow in sour water stripper overhead condensing reflux system

The erosion corrosion failure of elbow of one oil refinery was investigated by using Aspen software, CFD technology and experiments. And the gas–liquid equilibrium distribution of H₂S and NH₃ and multiphase flow simulation in the overhead system of a sour water stripper were obtained. The result shows that the component mole fraction of H₂S and NH₃ rises markedly with decreasing temperature. At the outlet of air cooler, the temperature drops to 85 °C to form high concentration of ammonium bisulfide (NH₄HS), which would cause serious erosion corrosion at a certain flow rate and reveals an inhomogeneous thinning. The liquid phase fraction mainly distributes on the outside part of elbow, the more sour water accumulates there resulting in localized corrosion thinning. Meanwhile, the experiments show that when the concentration of NH₄HS reaches 10 wt.%, the corrosion rates increase rapidly with increased velocity. Thus controlling the concentration of NH₄HS below 10 wt.% in reflux drum would reduce the risk of erosion corrosion failure.     

Temperature effects on the time dependent viscoelastic behaviour of carbon/epoxy composite materials: Application to T700GC/M21

In this study, strain rate and low temperature dependencies of the viscoelastic behaviour of the T700GC/M21 composite material are characterised and analysed. Dynamic tests for various environmental temperatures are performed on hydraulic jack equipped with an environmental chamber. Three speeds, between 8.33 · 10⁻⁴ m s⁻¹ and 0.5 m s⁻¹, at three temperatures (20 °C, −40 °C and −100 °C) are tested. The increase of the shear modulus with the decrease of the temperature is more pronounced between −40 °C and −100 °C than between 20 °C and −40 °C. Complementary DMA (Dynamic Mechanical Analysis) tests are performed on the M21 epoxy resin to characterise the viscoelastic behaviour of the matrix which contributes to the viscoelastic behaviour of the laminate. DMA tests highlight a low temperature transition called β transition (−67 °C for the 1 Hz test) which is responsible of the larger increase of the storage modulus, for the epoxy matrix, between −40 °C and −100 °C. Consequently the β transition could also be at the origin, for the composite, of the observed larger increase of the shear modulus with respect to the strain rate, for strain rates higher than 10 s⁻¹.     

Root causes of fire in a solvent pipe at a petrochemical plant

The root causes of a leak followed by a small fire in a 2 in. solvent pipe in a Petrochemical Plant are discussed. The fire occurred during blanket heating to 300 °C to dissolve polymer clogs. Fractographic and metallographic analyses showed that the failure is characterized by intergranular through the thickness propagation of longitudinal cracks initiated at the outer pipe surface. This cracking mode is called r-type cavitation. The leaking solvent self ignited, polymer deposits inside the pipe carbonized, microstructure changed. All these indicate that pipe temperature during blanket heating reached 550 °C, much above the specified 300 °C maximum. At this temperature yield strength of the pipe material got below nominal hoop stress due to normal internal pressure. The failure of the temperature control system in one of the heating blanket sets was the main event that caused the fire. However, other conditions and exceeded barriers are discussed, related with safety procedures and insufficient support of the ongoing investigation by the contractor involved in the incident. As a result, changes in the declogging and safety procedures were introduced.     

Bonding strength of heat treated compressed Eastern redcedar wood

The objective of this study was to evaluate effect of heat treatment and compression on some properties of Eastern redcedar (Juniperus virginiana) including bonding strength, hardness and surface quality. Specimens were exposed to three temperature levels of 120 °C, 160 °C and 190 °C for 6 h before they were compressed using 2.5 MPa pressure for 5 min. Polyvinyl acetate (PVAc) bonded specimens showed 23.6% reduction in their shear strength when they were exposed to a temperature of 120 °C. Such strength reduction values were 44.4% and 64.1% for the specimens exposed to temperature levels of 160 °C and 190 °C, respectively. The lowest average Janka hardness value of 214.08 kg was determined for the samples exposed to a temperature of 190 °C while those treated with a temperature of 120 °C had the highest hardness value of 397.73 kg. It appears that combination of heat treatment and compression enchanced overall surface quality of the samples in the form of their roughness determined using stylus type equipment.     

Application of carbonated apatite coating on a Ti substrate by aqueous spray method

The fabrication and characterization of a carbonate-containing apatite film deposited on a Ti plate via an aqueous spray method is described. The mist of the spray solution emitted from a perpendicularly oriented airbrush was made to strike a warmed Ti substrate. The thicknesses of the sprayed film and those heat-treated at 400 °C–700 °C under Ar gas flow were in the range 1.21–1.40 μm. The results of elemental analyses and Fourier transform infrared spectroscopy of the powders that were mechanically collected from the surface of the sprayed film suggest that the film was Ca₁₀(PO₄)6(CO₃) · 2CO₂ · 3H₂O. The presence of the carbonate ion and the lattice CO₂ molecule was confirmed via the aforementioned analyses; the finding was also consistent with the X-ray diffraction patterns of the films and the chemical identity of the sprayed and heat-treated films that were measured using X-ray photoelectron spectroscopy. The sprayed film comprises a characteristic network structure, which contains round particles within the networks, as was observed by field-emission scanning electron microscopy. A scratch test indicated that the shear stress of the sprayed film (21 MPa) significantly improved to 40 and > 133 MPa after heat-treatment at 600 °C and 700 °C, respectively, under Ar gas flow for 10 min.     

Deflected ‘teardrop cracking’ in nickel based superalloys: Sustained macroscopic deflected fatigue crack growth

A sustained macroscopic deflected fatigue crack growth, the so-called ‘teardrop’ crack (TDC), has been observed under mode I (tensile) loading in Udimet 720Li when tested at 300 °C in air and at 300, 600 and 650 °C in vacuum. A definition of the onset of sustained shear crack growth is proposed and applied to different test geometries in different temperatures and environments. SEM analysis of the fracture surfaces have shown a competition between the sustained shear and mode I crack growth modes in both the terraced shear lip and flat teardrop region, which indicates that the macroscopic deflection is triggered by the free surface.The tilt angles measured from the deflections have been used to define a mixed mode plane stress test, attempting to replicate the stress state giving rise to deflected shear growth.     

Solute cluster size effect on the fatigue crack propagation resistance of an underaged Al–Cu–Mg alloy

The effect of Cu–Mg cluster size and number density on the fatigue fracture behavior of Al–Cu–Mg alloy with various aging conditions was investigated by means of transmission electron microscopy (TEM), atom probe tomography (APT), scanning electron microscopy (SEM) and fatigue testing. Results showed that the fatigue crack propagation (FCP) resistances of 170 °C/1 h and 170 °C/8 h samples were higher than that of 170 °C/0.5 h sample due to increased number density of great size Cu–Mg co-clusters (>50 atoms). These large clusters were harder to dissolve during cycle deformation, thus reduced the cyclic softening effect and enhanced the FCP resistance. Moreover, as aging prolonged, the critical shear stress (τ_m) of co-clusters by modulus hardening increased from 10.2 (MPa) in 170 °C/0.5 h sample to 12.4 in 170 °C/1 h sample and 12.1 in 170 °C/8 h sample. Thus the force required for the movement of dislocations impeded by co-clusters, as well as the resistance of FCP caused by co-clusters, in 170 °C/1 h and 170 °C/8 h sample was higher than that in 170 °C/0.5 h sample. The 170 °C/8 h sample possessed the lower FCP resistance than 170 °C/1 h sample because of the existence of S′ phase. S′ phase was a kind of semi-coherent unshearable precipitate and hence reduced the planar-reversible slip.     

Influence of cement and aggregate type on thaumasite formation in concrete

In this study the influence of binder type on the formation of thaumasite in mortar prisms made with expanded clay lightweight aggregate (LWA) or quartz sand was examined. For this purpose mortar prisms were made, which after 28 days of curing in deionised water were exposed to a sulphate solution or deionised water. The length and weight change of the prisms was recorded in triplicate as a function of time of exposure to dry–wet cycles at 5 ± 1 °C.The influence of the binder type on the expansion in the sulphate solution can be ordered from strong to weak as follows: (1) CEM I + limestone filler, (2) CEM I, (3) CEM I + fly ash, and (4) CEM III/A. Because the porosity of the LWA was able to accommodate the growing sulphate crystals, the mortar prisms made with LWA were still largely intact after 3 years of exposure. The only exception being the mortar prisms containing limestone filler. The mortar prisms made with quartz sand and exposed to the sulphate solution were all bent, broken or disintegrated after 24 weeks. The prisms exposed to deionised water showed minimal expansion. Key factors controlling the formation of thaumasite are discussed.