Manufacture and characterisation of thermoplastic composites made from PLA/hemp co-wrapped hybrid yarn prepregs

PLA/hemp co-wrapped hybrid yarns were produced by wrapping PLA filaments around a core composed of a 400 twists/m and 25 tex hemp yarn (Cannabis sativa L) and 18 tex PLA filaments. The hemp content varied between 10 and 45 mass%, and the PLA wrapping density around the core was 150 and 250 turns/m. Composites were fabricated by compression moulding of 0/90 bidirectional prepregs, and characterised regarding porosity, mechanical strength and thermal properties by dynamic mechanical thermal analysis (DMTA) and differential scanning calorimetry (DSC). Mechanical tests showed that the tensile and flexural strengths of the composites markedly increased with the fibre content, reaching 59.3 and 124.2 MPa when reinforced with 45 mass% fibre, which is approximately 2 and 3.3 times higher compared to neat PLA. Impact strength of the composites decreased initially up to 10 mass% fibre; while higher fibre loading (up to 45 mass%) caused an increase in impact strength up to 26.3 kJ/m², an improvement of about 2 times higher compared to neat PLA. The composites made from the hybrid yarn with a wrapping density of 250 turns/m showed improvements in mechanical properties, due to the lower porosity. The fractured surfaces were investigated by scanning electron microscopy to study the fibre/matrix interface.     

Characterisation of polylactic acid biocomposites made from prepregs composed of woven polylactic acid/hemp–Lyocell hybrid yarn fabrics

This paper describes the mechanical properties and water absorption characteristics for biocomposites made from woven PLA/hemp/Lyocell prepregs. The aim was to improve the properties with the addition of Lyocell fibre into a hybrid yarn. Well-aligned hybrid yarns composed of hemp/PLA, hemp–Lyocell/PLA, respective, Lyocell/PLA were made by wrap spinning. Unidirectional satin fabrics were made by weaving with PLA (warp) and the hybrid yarns (weft). Uniaxial composites were fabricated with 30 fibre mass% using compression moulding. The composites were investigated for tensile, flexural and impact properties. Combining hemp with Lyocell in a PLA matrix improves the mechanical properties, compared to hemp/PLA composites. The composite made from the satin Lyocell/PLA fabric gave the best mechanical properties. The type of fibre reinforcement compositions did not significantly affect the water absorption of the biocomposites. Scanning electron microscopy showed that fibre pull-outs appear more often in hemp/PLA composites than in composites also including Lyocell fibre.     

Thermomechanical properties of bio-based composites made from a lactic acid thermoset resin and flax and flax/basalt fibre reinforcements

Low viscosity thermoset bio-based resin was synthesised from lactic acid, allyl alcohol and pentaerythritol. The resin was impregnated into cellulosic fibre reinforcement from flax and basalt and then compression moulded at elevated temperature to produce thermoset composites. The mechanical properties of composites were characterised by flexural, tensile and Charpy impact testing whereas the thermal properties were analysed by dynamic mechanical thermal analysis (DMTA) and thermogravimetric analysis (TGA). The results showed a decrease in mechanical properties with increase in fibre load after 40 wt.% for the neat flax composite due to insufficient fibre wetting and an increase in mechanical properties with increase fibre load up to 60 wt.% for the flax/basalt composite. The results of the ageing test showed that the mechanical properties of the composites deteriorate with ageing; however, the flax/basalt composite had better mechanical properties after ageing than the flax composite before ageing.     

Mechanical properties of textile-inserted PP/PP knitted composites using injection–compression molding

This paper concentrates on the experimental investigation of the self-reinforced all-polypropylene composites. There exists an optimum processing condition to produce high quality specimens by injection–compression molding. Tensile and 3-point bending properties of the virgin PP materials were nearly unaffected by the introduction of reinforcing knit layer(s) due to very low fibre content of the knitted fabrics used. 3-point bending properties were also unaffected by the surface of indentation-flexure. The applied impact energy was maintained at 5 J for the homo-PP and 27 J for the block-PP materials, respectively, to cause penetration during drop-weight impact tests. It is interestingly noteworthy that the self-reinforced homo-PP composites exhibited superior energy absorption capability when compared with the virgin matrix materials. The corresponding plate bending performances of the self-reinforced homo-PP composites also revealed consistent improvement as compared to their virgin counterparts. On the other hand, although virgin block-PP material exhibited better impact performances than its composite reinforced by the homo-PP knitted fabric, a notably small increase in the reinforcement fibre content revealed considerable improvement in the impact properties comparable to those of the virgin block-PP matrix materials. These self-reinforced homo-PP/block-PP materials have clearly indicated that they have the potential to out-perform the block-PP materials via modification and/or manipulation of the reinforcement knit structural/geometrical parameters and the content of reinforcement fibres. Both static and dynamic impact properties are likely to be affected by the local area properties of the tested face under indentation, and thereby contributing to the improved performances of the composite specimens with the knit face under the impact.     

Properties of yarn pull-out in para-aramid fabric structure and analysis by statistical model

The aim of this study is to analyze and determine the pull-out properties of para-aramid woven fabrics. Para-aramid Kevlar29® and Kevlar129® woven fabrics were used to conduct the pull-out tests. They have high and low fabric densities. A yarn pull-out fixture was developed to test various fabric sample dimensions. Data generated from single and multiple yarn pull-out tests in various dimensions of Kevlar29® and Kevlar129® woven fabrics included fabric pull-out forces, yarn crimp extensions in the fabrics and fabric displacements. The regression model showed that yarn pull-out forces depend on fabric density, fabric sample dimensions and the number of pulled ends in the fabric. Yarn crimp extensions depend on the crimp ratios of the fabric and fabric density. Fabric displacements depend on fabric sample dimensions and the number of pulled yarns.     

Preparation and characterization of flax biocomposites made of seed mucilage reinforced by fibers

Natural biocomposites were prepared from flax fibers and mucilage polysaccharides extracted from flax seeds, as a matrix, in two steps: impregnation and compression molding. The ribbons were preimpregnated with water plasticized mucilage. Solid mucilage (30%, w/w) was added to the ribbon impregnated with 20% mucilage, and the composite was compression molded. The solidified mucilage was homogeneous and rigid (2 GPa) with an elastic deformation of approximately 1%. The mechanical properties of the composites were in the ranges of 7–10 GPa, 300–400 MPa and 4–5% for the modulus, maximal strength and strain, respectively. The two latter parameters were larger than the ones for the fiber. The experimental values of the modulus and strength were in accordance with the values computed using the rule of mixture, which indicated a good interface between the fibers and the matrix. This was confirmed visually with scanning electron microscopy. The water sorption behavior of the composites was intermediate between the mucilage and the fiber alone.     

Fabrication and mechanical behaviors of cementitious composites reinforced by 3D woven lattice sandwich fabrics

Glass fibers were firstly woven to form three-dimensional (3D) woven lattice sandwich fabrics (WLSFs) which then were applied to reinforce cementitious foams and mortars to fabricate novel ductile cementitious composites. Failure behaviors of WLSF reinforced cementitious composite structures were studied through compression and three-point bending experiments. The WLSF greatly enhances the strength of cementitious foams at a level of four times. For cementitious mortars, compression strength of WLSF reinforced blocks is a little greater for the fraction of the textile is small as well as the compression strength of the textile pillars is not strong. But in flexure, excellent stretching ability of the glass fiber textiles greatly improves the flexural behavior of WLSF reinforced cementitious composite panels. Load capacity and ultimate deflection of these composite panels were greatly enhanced. Flexural capacity of the WLSF reinforced beam is four times greater. Reinforced by WLSF, failure of the cementitious composite is ductile.     

Influence of fibre architecture on the tensile,compressive and flexural behaviour of 3D woven composites

This paper presents a comprehensive study on the tensile, compressive, and flexural performance of six types of 3D woven carbon-fibre/epoxy composites which were manufactured using a traditional narrow fabric weaving loom and resin transfer moulding. Four orthogonal and two angle-interlock weaves were tested with the primary loading direction parallel to the warp direction. The mechanical performance was found to be affected by the distribution of resin rich regions and the waviness of the load-carrying fibres, which were determined by the fibre architectures. The binding points within the resin rich regions were found to be the damage initiation sites in all weave types under all loading conditions, which were confirmed with both visual observation and digital image correlation strain maps. Among all weave types, the angle interlock weave W-3 exhibited the highest properties under all loading conditions.     

Microstructure,flexural properties and durability of coir fibre reinforced concrete beams externally strengthened with flax FRP composites

This study investigated the flexural behaviour of plain concrete (PC) and coir fibre reinforced concrete (CFRC) beams externally strengthened by flax fabric reinforced epoxy polymer (FFRP) composites. PC and CFRC beams without and with FFRP (i.e. 2, 4 and 6 layers) reinforcement were tested under three- and four-point bending. The microstructures of coir fibre, coir/cement matrix, flax/epoxy matrix, and FFRP/concrete interfaces were analysed using scanning electronic microscope (SEM). Test results indicated that the peak load, flexural strength, deflection and fracture energy of both PC and CFRC specimens enhanced proportional to an increase of FFRP layers. Coir further increased load, strength and energy of the specimens remarkably. It was also found that the thickness and coir influenced the failure modes while the test method influenced the load and energy of the specimens remarkably. SEM studies showed effective bond at coir/cement, flax/epoxy and FFRP/concrete interfaces. Therefore, it concluded that natural FFRP composites can be used to repair or retrofit existing concrete structures.     

Characterization of a novel natural cellulose fabric from Manicaria saccifera palm as possible reinforcement of composite materials

Identifying novel natural fibers/fabrics with proper properties as reinforcement material is a new challenge in the field of bio-composites. Hence, the aim of this paper is to study the possibility of using a natural fabric extracted from Manicaria saccifera palm as a novel reinforcement in composites. This fabric was extensively characterized by chemical composition analysis, infrared spectroscopy (FTIR) analysis, morphological studies (SEM), thermo-gravimetric analysis (TGA) and physical /mechanical properties studies. From SEM analysis it was identified globular protrusions spread uniformly over the fiber which could help the mechanical interlock with the resin. As well, Manicaria fabric showed good thermal stability, low density, low moisture content and good tensile properties. Further, their properties are comparable to most natural cellulose fabrics and some synthetic fabrics, such as fiber glass fabrics. Manciaria saccifera fabric showed to be a suitable candidate as natural reinforcement material for the development of bio- composite.     

Kenaf/polypropylene nonwoven composites: The influence of manufacturing conditions on mechanical,thermal, and acoustical performance

The kenaf/polypropylene nonwoven composites (KPNCs), with 50/50 blend ratio by weight, were produced by carding and needle-punching techniques, followed by a compression molding with 6-mm thick gauge. The uniaxial tensile, three-point bending, in-plane shearing, and Izod impact tests were performed to evaluate the composite mechanical properties. The thermal properties were evaluated using thermogravimetric analysis (TGA), differential scanning calorimetry (DSC) and dynamic mechanical analysis (DMA). The performance of sound absorption and sound insulation was also investigated. An adhesive-free sandwich structure was found to have excellent sound absorption and insulation performance. Based on the evaluation of end-use performance, the best processing condition combination of 230 °C and 120 s was determined, and the correlation between mechanical properties and acoustical behavior was also verified by the panel resonance theory.     

Pull-through performance of carbon fibre epoxy composites

An investigation of the through-thickness properties of carbon fibre prepreg laminates, Non-Crimp Fabric laminates and non-crimp 3D orthogonal woven composites by pull-through testing was performed. Influence of matrix system and curing temperature on the performance of the 3D woven composites was investigated.     

Effect of fabric compaction and yarn waviness on 3D woven composite compressive properties

3D-woven fabrics incorporate through-thickness reinforcement and can exhibit remarkable inter-laminar properties that aid damage suppression and delay crack propagation. However, distortions in the internal architecture such as yarn waviness can reduce in-plane properties, especially in compression. The degree of yarn waviness present in a 3D woven fabric can be affected by a range of factors including weave parameters and manufacturing-induced distortions such as fabric compaction. This paper presents a thorough analysis of the effect of fabric compaction and yarn waviness on the mechanical properties and failure mechanisms of an angel-interlock fabric in compression. Tests were conducted on coupons moulded to different volume fractions and data compared to previous measurements of local yarn angle. Major findings show the importance of yarn straightness on compressive strength and how this can be affected by optimising moulding thickness. Failure initiation was also found to be heavily influenced by weave style and yarn interlacing.     

Mechanical behaviour of plain-knit reinforced injected composites: Effect of inlay yarns and fibre type

This paper investigates the effect of inlay yarns and fibre type (E-glass, basalt, carbon) to improve the mechanical behaviour of plain knit reinforced composites (epoxy matrix). The tensile behaviour of the dry reinforcement was investigated in the wale and course-directions and has shown that the course-wise deformation is drastically reduced whereas the strength is strongly increased when inlay yarns are included. Fibre type has a weak effect on deformation and strength. For the composite material, processed by Liquid Composite Moulding, the carbon fibre reinforcement gives always the best results whatever the testing direction. Inlay yarns decrease the 0° mechanical properties, whereas 45° and 90° are increased. Moreover a quasi-isotropic behaviour is obtained when using two inlay yarns, irrespective of the fibre types.     

High performance thermoplastic composite from flat knitted multi-layer textile preform using hybrid yarn

Modern flat knitting machines using high performance yarns are able to knit fabrics including the reinforcement yarns arranged differently into knit structures. Due to their improved mechanical properties, composites made from multi-layer knit fabrics show great potential in lightweight applications. This paper reports on the development of flat knitted multi-layer textile preforms for high performance thermoplastic composites using hybrid yarns made of glass (GF) and polypropylene (PP) filaments. Such textile preforms with different reinforcements were used to consolidate into 2D thermoplastic composites. Moreover, the mechanical properties of these composites were studied. The mechanical properties of 2D composites were found to be greatly affected by different arrangements of reinforcement yarns. The integration of reinforcement yarns as biaxial inlays (warp and weft yarns) is found to be the best solution for knitting, whereas tuck stitch shaped and unidirectional arranged reinforcements offer also promising application possibilities.     

Dry friction characterisation of carbon fibre tow and satin weave fabric for composite applications

Composites forming processes such as resin transfer moulding (RTM) typically involve a preforming step in which dry fabric material is deformed. Frictional forces in tool–fabric and fabric–fabric contacts determine the fabric deformation behaviour to a large extent. Previous investigations of the frictional behaviour of fibrous materials were mostly performed on a particular scale, i.e. microscopic (filament), mesoscopic (tow), or macroscopic (fabric). This study aims to provide a coupling between these scales by means of friction experiments on both carbon tows and carbon fabric in contact with metal counterfaces. The frictional behaviour of both materials on metal was measured on a capstan and a flat plate-friction setup. The frictional behaviour of fabric was comparable to that of single tows for matching pressures based on the mesoscopic contact area with the metal counterface. Furthermore, the agreement of the results forms a validation of both friction characterisation methods.     

Influence of low velocity impact on fatigue behaviour of woven hemp fibre reinforced epoxy composites

The purpose of this work is to study the resistance to low velocity impact of woven hemp/epoxy matrix composites and the influence of impact damage on their residual quasi-static tensile and cyclic fatigue strengths. Impact characteristic parameters were evaluated and critically compared to those found in the literature for other similar composites. Damage mechanisms were analysed by using AE monitoring and microscopic observations. An analytical model is used to predict the fatigue lifetime of impacted specimens. Moreover a damage scenario is proposed, reduced to two phases in post-impacted fatigue behaviour, instead of three phases for non impacted specimens.     

The influence of weave architecture on the mechanical properties of self-reinforced polypropylene

The weave architecture is vital for hot compaction and the mechanical properties of self-reinforced polypropylene. Low compaction quality resulted in early damage initiation and reduced tensile strength. Interleaved films and decreased crimp in the weave architecture increased the compaction quality. The best compaction quality and tensile properties were obtained by standard fed weaves with interleaved films. The penetration impact resistance and peel strength was independent of the weave architecture. Interleaved films increased the peel strength drastically, but the impact resistance only slightly decreased. These conclusions help to select the correct weave architecture and facilitate the hot compaction process.     

Binderless all-cellulose fibreboard from microfibrillated lignocellulosic natural fibres

Fully biobased all-cellulose fibreboards are produced without the use of additional bonding agents such as polymer resins or binders as in the case of e.g. medium density fibreboard (MDF) or natural fibre reinforced plastic (NFRP). These materials make use of the self-binding capability of cellulose, exploiting the enhanced hydrogen bonded network present in micro- and nanofibrillated cellulose, resulting in good mechanical performance. After the optimisation of refinement, drying and hot-pressing conditions, binder-free panels from microfibrillated flax fibres with excellent mechanical properties of around 17 GPa and 120 MPa for flexural modulus and strength, and relatively low water sorption are achieved, making these materials competitive with conventional cellulose based composite materials. The work shows the potential of creating all-cellulose engineering materials using only the intrinsic bonding capacity of microfibrillated lignocellulose, potentially leading to environmentally friendly panel board materials, which are entirely based on renewable resources, recyclable and biodegradable.     

Compressibility of carbon woven fabrics with carbon nanotubes/nanofibres grown on the fibres

Growth of carbon nanotubes (CNT) or carbon nano-fibres (CNF) on carbon fibrous substrates is a way to increase the fracture toughness of fibre reinforced composites (FRC), with encouraging results reported in the recent years. If these nano-engineered FRC (nFRC) are destined to leave laboratories and enter industrial-scale production, a question of adapting the existing composite manufacturing methods will arise. The paper studies compressibility of woven carbon fibre performs (two types of fabrics) with CNT/CNF grown on the fibres using the CVD method. The results include pressure vs thickness and pressure vs fibre volume fraction diagrams for one and four layers of the fabric. Morphology of the nFRC is studied with SEM. It is shown that the pressure needed to achieve the target fibre volume fraction of the preform increases drastically (for example, from 0.05 MPa to more than 0.5 MPa for a fibre volume fraction of 52%) when CNT/CNF are grown on it. No change in nesting of the fabric plies is noticed. The poor compressibility can lower the achievable fibre volume fraction in composite for economical vacuum assisted light-RTM techniques and increase the pressure requirements in autoclave processing.