Algal wastewater treatment systems for seasonal climates: application of a simple modelling approach to generate local and regional design guidelines

Algal waste stabilisation ponds (WSP) provide a means of treating wastewater, and also a potential source of water for re-use in irrigation, aquaculture or algal biomass cultivation. The quantities of treated water available and the periods in which it is suitable for use or discharge are closely linked to climatic factors. This paper describes the application, at a continent-wide scale, of a modelling approach based on the use of readily available climate datasets to provide WSP design and performance guidelines linked to geographical location. Output is presented in regionally-based contour maps covering a wide area of Russia and central Asia and indicating pond area, earliest discharge date, discharge duration, wastewater inflow:outflow ratio and salinity under user-specified conditions. The results confirm that broad-brush discharge guidelines of the type commonly used in North America can safely be applied; but suggest that a more detailed approach is worthwhile to optimise operating regimes for local conditions. The use of long-series climate data can also permit tailoring of designs to specific sites. The work considers a simple 2-pond system, but other configurations and operating regimes should be investigated, especially for the wide range of locations across the world that are intermediate between the ‘one short discharge per year’ mode and year-round steady-state operation.     

Assessment of bioavailability and effects of chemicals due to remediation actions with caging mussels (Anodonta anatina) at a creosote-contaminated lake sediment site

A study was conducted at Lake J?ms?nvesi in Central Finland, to identify the potential ecotoxicological risks of the remediation operation of a creosote-/PAH-contaminated lake sediment, made by capping during the years 1998-1999. Mussels (Anodonta anatina) were deployed to the lake at the same time as the remediation operation was started in November 1998. The contaminated area (0.5 ha) was covered by a filter geotextile (polypropylene), gravel and sand (1-1.5m) which were spread out on the ice and let to sink onto the bottom of the lake when the ice melted in May 1999. The possible impacts of capping to the adjacent environment were assessed from mussels exposed and particulate material settled (SPM) to collectors placed on the lake bottom. Mussel tissue, SPM, the water inside the collector were analyzed for polycyclic aromatic compounds (PAH)-compounds. Biological endpoints included body condition, glycogen and protein contents of adductor muscle. Mussels and SPM exposed downstream to the contaminated site (Site 3) contained the highest total PAH concentrations. Biota-sediment accumulation factors of acenaphthene, phenanthrene, anthracene, fluoranthene, pyrene and benzo(a)anthracene of mussels varied from 0.79 to 1.45. The glycogen and protein concentrations were lowest in adductor muscle from mussels exposed to conditions at Site 3. Concentrations of some PAH-compounds were found distinctly increased adjacent to the remediated area, possibly due to the agitation of contaminated sediment due to the capping. It is also possible that resuspension of sediment around remediated area (containing some PAHs) spread the deposited PAH-compounds.     

Seismic response of a geological,historical and architectural site: the Gerace cliff (southern Italy)

Bulletin of Engineering Geology and the Environment - Several historical towns and sites in Italy and other parts of Southern Europe were built on topographic reliefs, and they host inestimable...     

Assessment of soil and groundwater impacts by treated urban wastewater reuse. A case study: application in a golf course (Girona, Spain)

Starting in July 2000, treated wastewater of urban origin has been used for the "Serres de Pals" golf course irrigation (Girona, Spain). To evaluate if the soil and the aquifer underneath are affected by the utilization of this type of water, samples have been taken along a period of several months from the wastewater treatment plant, the stabilization lagoon, groundwater and soil profiles. Analyses have been performed for total coliforms and aerobic bacteria, soil water pressure and soil water content as well as chemical analyses of the irrigation water, aquifer and water of the vadose zone. Soil profiles taken at several times during the study indicate the absence of coliforms except for a short period during summer. In the vadose zone an increase of more than 1000 mg kg(-1) of NaO(2) in the top 60 cm of soil was observed while Cl(-) concentration in the aquifer reached up to 1200 mg l(-1) ten months after starting the irrigation.     

Homing in(n) on the Economic Benefits of 2010 FIFA World Cup: Opportunities for and Misgivings of Bed-and-Breakfast Operators in Gauteng, South Africa

This study examines the perceived potential benefits of the 2010 Fédération Internationale de Football Association (FIFA) World Cup Football Tournament for bed-and-breakfast (B&B) establishments—an integral part of the tourism accommodation sector in South Africa. From responses to a questionnaire sent to a sample of B&B proprietors in Gauteng, the major centre for the tournament, it is clear that they have serious reservations. The basis for their misgivings appears to be the manner in which FIFA has managed accommodation–provision agreements and the role played by South African government agencies, the Local Organising Committee and the tourism sector.     

GIS-based kinematic slope instability and slope mass rating (SMR) maps: application to a railway route in Sivas (Turkey)

The paper discusses the use of kinematic stability and slope mass rating (SMR) maps in GIS based on field studies recording the relationships between the bedding/joint geometry relative to the orientation of the free face. The results indicated the potential for both planar and wedge type failures in many locations along a railway route. Whilst the results showed the procedure to be a useful first assessment of slope stability, it is recommended that the construction of the maps by kinematic slope stability and SMR analysis within the GIS medium should be used in conjunction with more sophisticated slope stability models taking into account of the material strengths, hydrostatic pressures, seepage forces, active forces, passive forces, etc.     

Particle‐associated polycyclic aromatic hydrocarbons in a representative urban location (indoor‐outdoor) from South Europe: Assessment of potential sources and cancer risk to humans

PM₁₀‐bound polycyclic aromatic hydrocarbons (PAHs) levels were monitored at urban locations (outdoor/indoor) within the city of Madrid between May 2017 and April 2018. Fourteen PAH congeners were measured, potential emission sources were identified as were potential carcinogenic risks. The ΣPAHs averaged 0.577 and 0.186 ng/m³ in outdoor and indoor air, with a high linear correlation per individual mean PAH and month. The largest contributors to the ΣPAHs were the high‐molecular‐weight PAHs. Principal component analysis‐multiple linear regression results showed that emissions from diesel and vehicular processes explained 27% and 23% of the total variance of outdoor and indoor air, while combustion processes accounted for 30% and 25% in ambient and indoor air, respectively. During the cold season, biomass burning plus coal and wood combustion were additional sources of outdoor emissions. The heavy‐, medium‐ and light‐molecular‐weight PAH originating from outdoor sources accounted for 72%, 80%, and ~60% of the indoor levels of the three respective PAH groups. Average BaP concentration was 0.029 and 0.016 ng/m³ in outdoor and indoor air, respectively. Estimated BaPeq concentration averaged 0.072, 0.035, and 0.027 ng/m³ for outdoor, indoor, and indoor‐generated individual PAH concentrations, respectively. The estimated carcinogenic risk falls within the range of acceptable risk targeted by the US‐EPA.     

Design and application of a stratified sampling strategy to study the regional distribution of cyanobacteria (Ile-de-France, France)

This study describes the design and application of a stratified sampling strategy of waterbodies to assess and analyze the distribution of cyanobacteria at a regional scale (Ile-de-France, IDF). Ten groups of hydrographical zones were defined within the IDF on the basis of their anthropogenic and geomorphologic characteristics. Sampling effort (n = 50) was then randomly allocated according to the number of waterbodies in each group. This sampling strategy was tested in August 2006, using a field probe to estimate total phytoplankton as well as cyanobacteria biomasses. The sampled waterbodies exhibited a wide range of phytoplankton (<1-375 μg equiv. Chla L⁻¹) and cyanobacteria biomasses (<1-278 μg equiv. Chla L⁻¹). 72% of the waterbodies in the IDF were classified as eutrophic (42% hypereutrophic), and 24% of the sites studied were dominated by cyanobacteria. Waterbodies connected to hydrographical networks (n = 26) showed significantly higher total (p < 0.0001; 3.5 times greater) and cyanobacterial (p < 0.001, 3.2 times greater) biomasses than the isolated ones (n = 24). No significant overall relationship was found through contingency analysis between waterbody trophic status and global land use categories (urban, periurban, and rural) within their hydrographical zones. However, concerning the waterbodies linked to hydrographical networks, the percentage of land covered by forest appeared as a good indicator of phytoplankton and cyanobacterial biomasses. This observation may be a consequence of lower amounts of nutrients being discharged into waterbodies from highly forested hydrological zone than from urban and/or agricultural areas. Our results illustrate a successful means of selecting representative waterbodies to conduct a regional assessment of cyanobacteria distribution using accessible GIS analyses.     

Delayed effects of low level acute irradiation and chronic environmental radioactive contamination on DNA lymphocytes of people living in Dolon, a settlement located in the vicinity of the Semipalatinsk nuclear test site (Kazakhstan)

During 42 years several hundred nuclear tests were performed by the former USSR at the Semipalatinsk Test Site (STS, Kazakhstan), of which more than 100 were done in the atmosphere. We report here the late genetic damage of external exposure to radiation and environmental radioactive contamination in people living in Dolon, a small settlement situated in the vicinity of the STS. The comet assay was applied on DNA lymphocytes of 20 exposed women and 32 non-exposed women living at 500 km from the STS. We observed a statistically significant difference between the exposed and control groups for mean tail moment (MTM) and DNA% in the tail. The mean values of all comet assay parameters (MTM, DNA% in the tail and score) were higher in the group of women born before 1949 as compared to those born after 1950, which could reflect an effect of external irradiation in 1949 due to the most contaminating explosion. These results suggest that people exposed 50 years ago to relatively small doses of external irradiation and/or still living in an environment contaminated by small amounts of long life radionuclides, still present DNA damage which is in agreement with other cytogenetical studies performed at the same site, on the same population.     

(Science) Fiction,Ecophysical Apparatus and Skizoid Machines: Animism,Vitalism and Machinism as a Way to Rearticulate the Need to Confront the Unknown in a Contradictory Manner

François Roche of R&Sie(n) ruminates on the contradictory nature of the present: a time that is ‘vibrating’ while ultimately ‘lacking momentum’. Reclaiming ‘the scenarios and substances that condition architecture’, he rejects the large-scale flights of fancy of international signature architects and argues for the reactivation of ‘a throbbing, complex and unfinished “localism”’. In so doing, he advocates a machinism that enables fictionalisation and speculation. Copyright © 2010 John Wiley & Sons, Ltd.     

Dispersal and accumulation of Pt, Pd and Rh derived from a roundabout in Sheffield (UK): From stream to tidal estuary

The Coisley Hill roundabout, a typical urban source for PGE in stream sediments, has anomalously high values of up to 408 ppb Pt, 444 ppb Pd and 113 ppb Rh in road dust, up to 416 ppb Pt and 278 ppb Pd in gulley sediment and up to 606 ppb Pt and 1050 ppb Pd in verge soil. For samples collected at the same time, the road dust values are much higher than in sediments in the Shire Brook stream, that drains the roundabout, with values of 3-64 ppb Pt, 4-57 ppb Pd and up to 7 ppb Rh. Downstream sediments from rivers Rother and Don have lower values of 2-35 ppb Pt, 2-14 ppb Pd and up to 3 ppb Rh. The Humber estuary values are low with 6-8 ppb Pt, 5-8 ppb Pd and 1-2 ppb Rh. Pt/Pd increases down catchment with Coisley Hill 0.8, Shire Brook 1.0, Trent and Don 1.5 and the Humber estuary 2.0. Pt/Rh and Pd/Rh also increase downstream. Precious metals are generally dispersed away from their vehicle catalytic source and Pd is dispersed more than Pt and Rh but Pt and Pd are re-concentrated in acid mine drainage in the Shire Brook, with concentrations varying with stream flow. Pt and Pd values are slightly elevated at the tidal limit and in mud deposited when the river is in spate. On Coisley Hill, values of 133 ppb Pt and 230 ppb Pd occur in dust from a new road surface (two weeks old when sampled). These are similar to those on much older road surfaces suggesting that Pt and Pd collect and disperse rapidly from roads. Au is low in road dust and higher values in conurbations suggest the presence of more Au sources in urban rather than in rural areas. Au values are not diluted downstream as much as PGE suggesting different processes of dispersion and sedimentation.     

Using orthogonal pairs of rollers on concave beds (OPRCB) as a base isolation system—part II: application to multi‐story and tall buildings

Application of orthogonal pairs of rollers on concave beds (OPRCB) isolating system to short‐ and mid‐rise buildings is presented in this paper. At first, the analytical formulation of the set of equations, governing the motion of Multi Degree of Freedom (MDOF) systems, isolated by OPRCB isolators, has been developed. Then, some multi‐story regular buildings of shear type have been considered, once on fixed bases and once installed on the OPRCB isolators. Next, some horizontal and vertical accelerograms of both far‐ and near‐fault earthquakes with low‐ to high‐frequency content, particularly those with remarkable peak ground displacement values, have been selected and normalized to three peak ground acceleration levels of 0.15 g, 0.35 g and 0.7 g, and their stronger horizontal component simultaneous with their vertical component have been used for response analysis of the considered buildings. Story drifts and absolute acceleration response histories of isolated buildings have been calculated by using a program, developed in MATLAB environment by using the fourth‐order Runge–Kutta method, considering the geometrically nonlinear behavior of isolators. Maximum relative displacement and story drifts as well as absolute acceleration responses of considered isolated buildings for various earthquakes have been compared with those of corresponding fixed‐base buildings to show the high efficiency of using OPRCB isolators in multi‐story and tall regular buildings. Copyright © 2010 John Wiley & Sons, Ltd.     

Development of new indices to assess the contribution of moisture sources to indoor humidity and application to optimization design: Proposal of CRI(H) and a transient simulation for the prediction of indoor humidity

Many indoor and outdoor factors (e.g., the presence of occupants, hot-water supply equipment, the use of hygroscopic materials, and ventilation) contribute to indoor humidity. It is important to investigate and understand the contribution of each factor to indoor humidity and to establish an effective method for the design and control of indoor humidity. In this study, indoor humidity was treated as a linear summation of the contribution of various factors, all of which can cause an increase or decrease in indoor humidity. New indices for assessing the contribution of factors to the humidity distribution in a room are proposed as Contribution Ratios of Humidity (CRI_(H)) 1, 2, and 3 which can be calculated based on Computational Fluid Dynamics (CFD) simulations. Furthermore, a transient simulation based on CRI_(H)1 and the Contribution Ratio of Indoor Climate (CRI_(C)) was developed to predict the indoor humidity distribution. A 100-day transient analysis was performed in a living room in which moisture-buffering materials were used. The simulation results were compared with those from a well-mixed zonal model and a CFD transient analysis to confirm the effectiveness of the approach. The analysis provided the three-dimensional spatial distribution of indoor humidity and temperature with good prediction accuracy. The calculation time was approximately equal to that of the well-mixed zonal model and much faster than that of the CFD transient analysis.     

The acute toxicity of pulse-dosed, para-substituted phenols to larval American flagfish (Jordanella floridae): a comparison with toxicity to photoluminescent bacteria and predicted toxicity using log Kow

The acute toxicity of nine para-substituted phenols was determined using a pulse-exposure testing protocol and 8-day-old larval American flagfish (Jordanella floridae). Relative tolerance was assessed by determining the 2-h pulse exposure concentration causing 20 and 50% mortality (PE LC20 and PE LC50) over the subsequent 94 h. Four bioassays were run for each phenol and yielded the following mean PE LC20 values (mg 1(-1)) in descending order of toxicity: p-aminophenol, 0.06; hydroquinone, 0.13; phenol, 0.70; p-nitrophenol, 0.81; p-cyanophenol, 3.0; p-chlorophenol, 3.3; p-hydroxyacetophenone, 4.2; p-hydroxybenzyl alcohol, 6.4; and p-hydroxybenzoic acid, 170. These toxicities did not correlate significantly with either previously reported toxicity values for the photoluminescent bacteria Photobacterium phosphoreum, or with the log octanol-water partition coefficient. For some of the compounds, however, sensitivities were quite close to previously reported rainbow trout chronic no-observed-effect concentrations based on continuous exposure. Caution is urged with respect to applying "low-level" biota techniques or simple quantitative structure-activity correlations such as Kow when attempting to predict the toxicity of specific chemicals to fish.     

Comparative study of the Cd. Cu and Pb determination by AAS and by ICP-AES in river water : Application to a mediterranean river (Congost river, Catalonia, Spain)

The accuracy, precision, detection limit and rapidity in the determination of Cd, Cu and Pb in river water by AAS determination, previous extraction with APDC-MIBK system, is compared with direct determination method ICP-AES. Both methods show a similar detection limit and an analogous accuracy by the addition standard method. With a calibration curve only ICP-AES presents good accuracy, this technique is advantageous in long term precision and requires minimum sample preparation. The sample stability at different temperature conservation is studied. Finally both methods are applied to the determination of Cd, Cu and Pb in Congost river water.     

Speciation (including adsorbed species) of copper, lead, nickel and zinc in the Meuse River: Observed results compared to values calculated with a chemical equilibrium computer program

The adsorption of trace metals on sediments of the Meuse River was interpreted in terms of competition between metals and protons for surface sites. Surface constants (^*β₁^surf) were determined for Cu, Zn and Cd (10^−1.8, 10^−3.6 and 10^−3.7). The constants for Pb, Ni, Ca and Mg (10^−1.7, 10^−3.8, 10^−6.5 and 10^−5.2) were estimated using a correlation between hydrolysis and surface constants. A chemical equilibrium computer program in which surface sites (for adsorption reactions) are treated as conventional ligands was used to calculate the speciation of Cu, Pb, Ni and Zn in the Meuse River. Calculated values of the adsorbed/dissolved distribution agreed well with observed values, after some realistic data manipulation. This work indicates that dissolved trace metal concentrations in the Meuse River are controlled by adsorption and not by precipitation mechanisms. The relationship between organic matter and suspended matter greatly influences the adsorption of metals like Cu and Pb.