Influence of Surface Gas-Phase Earth Permeation Plus Laser Melting Solidification on Microstructure and Corrosion Resistance of Pure Iron

The samples of pure Fe were treated by surface gas-phase RE permeation plus laser melting solidification (LMS). The microstructures were observed by Scanning Electron Microscope (SEM) and X-ray Photoelectron Spectroscopy (XPS), meanwhile the corrosion resistance was investigated by electrochemical impedance spectroscopy (EIS) and anedic polarization. The results show that this treatment can remarkably improve the density and uniformity of microstructure, and enhance corrosion resistance of the pure Fe surface.     

Effect of Y2O3 Content on Microstructure of Gradient Bioceramic Composite Coating Produced by Wide-Band Laser Cladding

Hydroxyapatite (HA) ,a kind of bioactive materi-al , has wide application prospect in hard tissue re-placemen and repairment due to its si milar chemicalcomposition and crystallographic structure to that ofbone mineral[1 ,2]. Since HA has lowstrength (50 …     

Microstructure and Wear Properties of Laser Coating Reinforced by Ti（CxN1-x） on Adamite Roller

Fe-based layer with Ti(C_IN_I-x) particulates on Adamite roller surface was obtained by a 5 kW traverse-flowing CO₂ laser cladding technology. The microstructures of the layer were detected by optical microscopy (OM), X-ray diffraction (XRD), scanning electron microscopy (SEM), and electron probe microscopy analysis (EMPA). The tests of wear resistance was carried out on the test machine. It was seen that a good metallurgical bonding between the coating and the substrate was achieved. The microstructure contains bulky dendritic crystal and small size Ti(C_IN_I-x) grains that are uniformly distributed in the solid solution matrix. The wear tests showed that the laser coating provided an excellent wear resistance property at room temperature.     

Microstructure of Nano-Y203／Cobalt Based ,Alloy Composite Coating byLaser Cladding

Composite coatings made of nano-Y203/cobalt-based alloy and produced by crosscurrent CO2 laser on Ni-based superalloy are introduced. Cross-section or surface of the coatings was examined to reveal their microstructure using optical microscope, SEM, including EDS microanalysis, TEM and XRD. The results show that some equilibrium or non-equilibrium phases, such as γ-C0, Cr23C6, Y203 and ε-Co exist in the coatings. Fine and short dendritic microstructure andcolumnar to equiaxed transition (CET) occurred by adding nano-Y203 particles. With the increasing amount of nano-Y203(1%, mass fraction), fully equiaxed crystallization appeared. These are caused by nano-Y203 particles acting as new nucleation site and rapid solidification of the melt. The results also show that inhomogeneous dispersion of nano-Y203 resultsin the formation of ε-Co phase in the coatings. The sub-microstructure of the clad is stacking fault. The mechanism of theformation of equiaxed grains is also analyzed.     

Influence of Lanthanum on Tribological Properties and Microstructure of Laser Clad B ＋ Fe ＋ Si Composite Coatings

The effects of rare earth ferrosilicon on the microstructure and anti-wear properties of laser-clad Fe-based alloy coating were investigated. The composition of Fe, B4C and rare earth ferrosillcon powders with different contents of lanthanum were clad onto a 45 # carbon steel substrate. Microstructural features, chemical compositions, phase structure,hardness, friction and wear properties by scanning electron microscopy (SEM), X-ray photoelectron microscopy (XPS),hardness tester, block-on-ring friction and wear tester of the clad coating were determined. Experimental results show that the friction coefficient of the clad coating doped with rare earth ferrosilicon is reduced while the wear resistance of clad coating doped with rare earth ferrosilicon is enhanced. When the content of lanthanum increases to 1.92%, the clad coating shows the best anti-wear ability, and as the content of lanthanum exceeds 1.92%, the wear weight loss increases quickly. The rare earth ferrosilicon to be doped in the clad coatings helps to disperse the boride phase (Fe2B, FeB, B4C)particles and refine the grain of boride phase. The enhancement of clad coating‘s wear resistance is due to the existence of dispersed boride phases.     

Effect of Microstructure on Impact Wear Resistance Impact Fatigue Resistance and of Medium Cr-Si Cast Iron

A great amount of iron grinding balls in tube mills have been consumed. Under this impact abrasive wear working condition, the failure of wear resistant alloying white irons grinding balls is mainly caused by fatigue spalling. The impact wear resistance of martensitic high chromium cast iron （Cr of 15%） is not high sometimes, but its cost is not low. Thus, medium Cr-Si wear resistant cast iron is recommended. The influence of the iron on impact fatigue resistance and impact wear resistance is pronounced. Ball-on-ball impact fatigue test and high stress impact wear test of the grinding balls have been carried out. The results show that the impact fatigue resistance （IFR） and impact wear resistance （IWR） of medium Cr-Si cast iron are superior to those of martensitic high chromium cast iron （Cr of 15%）. The main reasons are that （1） the stress in medium Cr-Si cast iron is released in the as-cast state; （2） the matrix is fine pearlite with better toughness and plasticity; （3） the pearlite is more stable compared with a retained austenite under repeated impact load and less phase transformation can take place; （4） high silicon content im- proves the morphology of eutectic carbide; （5） there is no seeondary carbide which results in less crack sources. All these factors are beneficial to improvement of impact fatigue spalling resistance. The eutectic carbide M7C3 is the main constituent to resist wear.     

Effect of Rare Earths on Microstructure and Properties of TiC-based Cermet／Cu Alloy Composite Wear Resistant Materials

The effect of rare earth (RE) oxide on the microstructure and properties of TiC-based cermet/Cu alloy composite hardfacing materials was investigated by using scanning electron microscope (SEM), transmission electron microscope(TEM), impact test and wear test. The mechanism of RE oxide for improving the phase structure and the impact toughness was also discussed. The experimental results indicate that the microstructure of the matrix can be refined, and the micro- porous defects can be eliminated by adding RE oxide into the composite materials. The polycrystalline and amorphous phase structure is formed at the interface of cermet and matrix metal. The formed structure enhances the conjoint strength of interface. The frictional wear resistance can be improved obviously, although the microhardncss of the matrix metal can not be effectively increased by adding RE oxide.     

宽带激光熔覆WCp/Ni基合金梯度复合涂层的组织和耐磨性

为了消除激光熔覆过程中产生的裂纹，设计了一种梯度复合涂层并研究了其组织和耐磨性，结果表明，熔覆层与基材之间形成了良好的冶金结合。梯度复合涂层中有未完全溶化的铸造WCp和共晶组织γ-Ni Ni3B，还有凝固结晶析出的白色不规则块状组织M7C3、M6C、WC以及深灰色不规则块状组织W2C0复合涂层中形成了少量的非晶、纳米晶及高密度位错复合涂层耐磨性的最高值是基材的3倍以上。     

铁基合金激光熔覆涂层的高温回火组织及其磨损性能

研究了铁基合金激光熔覆涂层的高温回火组织.结果表明,高温回火(690 ℃×1 h)时在M7C3与γ-奥氏体的相界面原位形成M6C 及M23C6,非平衡相γ中析出M23C6、M2C及MC碳化物.该涂层具有二次硬化特征及较高的磨损性能.     

Effect of Laser Power on Microstructure and Wear Resistance of WCP/Ni Cermet Coating

Laser cladding nickel-based alloy coating （Ni60） and nickel-based composite coating doped with WC particles by 35 % （WCp/Ni） were produced on the low-carbon steel substrate by CO2 continuous wave laser with power of 5 kW using the injected powder technique. The effect of laser power on microstructure and wear resistance of laser cladding WCp/Ni cermet coating was investigated. The WCp/Ni alloy coating with evenly distributed WC ceramic phases and the better bond with the substrate alloy was obtained at a power of 2.2 kW. Diffusion solution reaction happened between WC particles and the substrate alloy during laser cladding, and led to the formation of block rich-tungsten carbide on the edges of the WC particles, especially at higher power. The WCp/Ni alloy coating consists of the undissolved WC particles, the block or dendritic rich-tungsten carbide, the bar-like rich-chromium carbide, and dendrite solid solution and eutectic structure among the carbides. Microhardness and wear resistance of the WCp/Ni coating at different powers were much higher or better than those of Ni60 alloy coating, and the best results were obtained at power of 2.2 kW.     

高温合金表面激光熔铸镍基合金涂层的组织与耐磨性能

研究了高温合金ＧＨ３３表面激光熔铸镍基合金涂层的组织和耐磨性能。结果表明,基材对涂层合金的稀释作用较小;涂层与基材之间形成良好的冶金接合;涂层基体组织为γ－Ｎｉ枝晶,枝晶间为γ－Ｎｉ、Ｍ２３（ＣＢ）６、Ｎｉ３Ｂ、Ｃｒ２Ｂ、ＣｒＢ、ＷＣ等;涂层耐磨性能的平均值较基材提高４倍以上。     

La2O3对激光熔覆TiC/Ni基复合涂层的组织和性能的影响

用5kWCO2激光器在A3钢表面激光熔覆添加有La2O3的TiC/Ni基复合涂层，研究了稀土对激光熔覆金属陶瓷复合涂层的组织，耐蚀性和耐磨性的影响。研究结果表明：复合合金粉末中添加0.4%的La2O3能够减少熔覆层的气孔，疏松，使熔覆层的组织致密。熔覆层中TiC分布均匀且细小圆滑，熔覆层的耐蚀性和耐磨性得到提高。     

TC4钛合金表面激光熔覆Ni包WC复合涂层研究

为了提高钛合金的耐磨性能及使用性能,采用激光熔覆法在TC4钛合金基体上制备了Ni与WC混合粉末涂层,研究了不同WC添加量对熔覆层的物相组成、显微组织、硬度及耐磨性能的影响。结果表明,三组不同的熔覆材料经过激光熔覆后,都可以使材料表面硬度和耐磨性能较基材大幅度增加。但是随着WC含量的增加,熔覆层均匀性降低,出现小颗粒的WC团,并且组织开始多样化,且硬度分布均匀性也有所下降。     

Ceramic-Metal Composite Coating by Laser Cladding

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表面活性剂对钛合金复合微弧氧化膜结构与耐磨性能的影响

为了在钛合金表面制备耐磨性能良好的复合微弧氧化膜层,研究了4种不同类型的表面活性剂对复合六方氮化硼(hBN)固体润滑微粒微弧氧化膜层微观结构及其耐磨性能的影响。结果表明,表面活性剂对复合微弧氧化(MAO)膜层的微观结构和耐磨性能有明显的影响,阳离子型表面活性剂十六烷基三甲基溴化铵降低了复合MAO膜层中h BN微粒含量,削弱了膜基结合,因而不利于膜层耐磨性能的改善;非离子型表面活性剂无水乙醇由于挥发性强导致膜层的致密性下降,降低了膜层的耐磨性能;阴离子型表面活性剂十二烷基苯磺酸钠对复合MAO膜层的结构和耐磨性能影响较小;阴离子型表面活性剂羧甲基纤维素钠则有效改善了hBN微粒在电解液中的分散性,进而改善其在MAO膜层中的复合及分布状况,从而明显改进了复合MAO膜层的耐磨性能。     

TiC含量对激光熔覆TiC增强双相不锈钢复合涂层性能的影响

采用激光熔覆技术在40 Cr Ni Mo基材上制备了TiC增强双相不锈钢复合熔覆层,熔覆层物相主要由奥氏体、马氏体、M₇C₃型碳化物和TiC组成。其中M₇C₃型碳化物主要包括Fe₇C₃、Cr₇C₃或者(Fe、Cr)₇C₃三种,TiC按尺寸可分为熔解后析出的微米级TiC以及粗大的未熔TiC颗粒。析出的TiC颗粒为方块状,随着TiC添加量增加,呈花瓣状长大。未熔TiC颗粒与基材形成了扩散界面,具有很好的界面结合性。当加入30 wt.%TiC时,熔覆层具有最好的耐磨性,硬度可达55.26 HRC,磨损体积为2.54×10^-2 mm³,耐磨性是基材的3.37倍。