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介绍了涂料产品VOC含量与VOC释放量的不同点,突出了VOC释放测试的重要性.综述了内墙涂料VOC释放测试的相关标准以及影响VOC释放量的关键因素,并详细阐述了不同VOC释放标识体系的指标要求,最后探讨了当前标识体系存在的问题及未来的发展方向. 相似文献
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实木家具是室内空气污染的重要来源。到目前为止,我国实木家具有害物质检测还一直停留在单一甲醛项目的检测控制上,因此迫切的需要对实木家具中除甲醛外的污染物散发种类及含量进行研究评价,进而推动我国家具产品VOC限量标准尽早出台。 相似文献
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分析了水性涂料中VOC的危害程度,提供了水性涂料降低VOC的方法,并初步探讨了这些方法有可能带来的缺陷和解决手段。 相似文献
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本文对室内装饰用的人造板的甲醚释放规律进行研究。试验结果表明,人造板甲醛释放量随温度升高而增加;随含水率增加而增大:随人造板放置时间增长,而逐渐降低。人造板封边与否,则明显影响甲醛释放量。本论文的研究可以为室内甲醛污染的治理提供依据。 相似文献
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煤中氮在热解过程中释放规律的数学模拟 总被引:1,自引:1,他引:1
以化学渗透模型(CPD)为基础构建煤的结构,以实验数据为基础,通过对煤中氮在热解阶段反应历程的描述,以及对NOx的主要前驱体HCN和NH3生成的动力学表达,建立了煤热解阶段氮释放的模型,将模型的计算结果与五种煤在管式固定床反应器中热解阶段形成HCN和NHx的测定结果进行比较,研究发现:模型能够相对准确的预测HCN形成(误差在20%以内),但由于没有考虑惰质组的影响,对部分煤NHx的模拟误差较大(甚至超过50%),模型也表达出在快速热解条件下随温度升高,HCN和NHx的生成量增加;随煤阶增加,HCN生成量减少;随惰质组含量增加,NHx的生成量增加的释放规律。 相似文献
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涂料中VOC测试方法简述 总被引:2,自引:0,他引:2
从挥发性有机化合物(VOC,Volatile Organic Compound)的定义和VOC对环境和人体造成的危害出发,介绍了几种国际标准测定方法及原理,着重介绍了气相色谱在测定VOC中的应用、定性定量分析方法和影响测定结果的因素,阐明了对涂料中VOC测试方法研究的意义。 相似文献
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Dong Hwa Kang Dong Hee Choi Kwang Woo Kim 《Journal of Adhesion Science and Technology》2013,27(5-6):683-698
To reduce the risk of indoor air pollution caused by synthetic building materials, low-volitile organic compounds (VOC) building materials, including adhesives, are commonly used in building construction. Although adhesives do not directly contact indoor air, they affect VOC mass transfer at the surface of finishing materials by diffusion. This study investigates VOC emission and sorption behaviors of building materials with low-VOC adhesives. Small chamber emission and sorption experiments were designed in parallel to field measurements to examine the onsite VOC emission and sorption rates of adhesive-bonded building materials. It was found that the onsite emission rates from a wallpaper composite (polyvinyl chloride wallpaper?+?paper adhesive?+?gypsum board) were higher than the emission rates detected in the small-scale chamber, which demonstrates the possible sorption effect of the wallpaper composite. The results of the sorption chamber experiment confirm that the wallpaper is a sorptive building material and that the bonding of wallpaper to gypsum board increases the sorption and re-emission rates. These results indicate that even though low-VOC adhesive-bonded materials are used, additional indoor air quality control techniques should be applied to minimize re-emission by sorption processes over long periods of time. 相似文献
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建材中挥发性有机化合物(VOC)的散发是一个复杂传质过程。为准确把握传质特性,首先建立了一套描述干建材散发行为的显性完全解析模型,适用于模拟对人体最不利的无换气情况;代入有关文献中的传质参数预测了环境舱浓度,与文献中对应的实验数据及数值算法预测值吻合良好。然后基于对模型的分析提出一套简便快捷的实验方法,能够利用不同VOC背景值下干建材在密闭舱中散发的平衡浓度或逐时浓度,求取预测散发过程的4个重要的传质参数:可散发浓度C0、扩散系数D、分配系数K和对流传质系数hm;实验部分测算了两类密度板中甲醛散发的C0、D、K、hm,代入数值算法预测了密闭舱和直流舱的环境舱浓度,与实验数据吻合良好。该套模型和测定方法能够应用于建材散发的模拟研究。 相似文献
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A multi-phase model for the emission of VOC from dry building materials is developed. Dry building materials are viewed as
porous media. A general adsorption isotherm is used to construct the concentration equation in the porous media. The boundary
conditions at the material-air interface are presented for both CFD model and one compartment model. With the use of Henry’s
law for the adsorption isotherm, an analytical solution is obtained and further is validated with the comparison of the experiment
performed by Yang et al. [1], yielding a relatively good agreement. The effects of the model parameters on the emission are
investigated in detail. Increasing the effective diffusion coefficient and the partition coefficient tends to promote the
emission and increase the peak value of the concentration in the air. The effect of the porosity depends on the degree of
the dependence of the effective diffusion coefficient on the porosity. When a weak dependence exists, the increase of the
porosity tends to suppress the emission and decrease the peak value of the concentration in the air. However, when a strong
dependence exists, the increase of the porosity tends to promote the emission and increase the peak value of the concentration
in the air. 相似文献
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《Journal of Adhesion Science and Technology》2013,27(15):1783-1799
A volatile organic compound (VOC) analyzer is a portable device to measure the four main aromatic hydrocarbon gases: toluene, ethylbenzene, xylene and styrene. With the VOC analyzer, a semiconductor gas sensor eliminates the need for the carrier gas which is required for conventional gas chromatography. In addition, since the semiconductor gas sensor is supersensitive to gas components, it is not necessary to use a conventional gas concentrator or other complicated equipment. Compared with other measurement methods, the VOC analyzer is useful for measuring toluene, ethylbenzene, xylene and styrene in new buildings because of its ease in obtaining field results and repeating the test. For easy, fast and economic testing of total (TVOC) emission from adhesives used for building materials, we developed a test method using the VOC analyzer and compared its measurement of VOC emissions from building materials such as adhesives, paints and wood-based panels with that of the 20-l chamber method, which is the standardized test method in Korea. There was a good correlation between the TVOC emission concentrations determined by the VOC analyzer and the TVOC emission factor (EF) by the 20-l chamber. Based on this good correlation, the VOC analyzer is expected to gain widespread use in the manufacturing field application where a quick and easy test for VOC emission from adhesives for building materials is required. Furthermore, the VOC analyzer offers the potential to become an easier, faster and more economical technique than the currently used standard methods. 相似文献
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Semi-conductor metal oxide gas sensors for online monitoring of oak wood VOC emissions during drying
This study presents a semi-conductor metal oxide gas sensor system for the online flue gas monitoring during oak wood drying. Oak wood flakes and solid oak wood were heated on laboratory scale. The emissions were analyzed by gas chromatography–mass spectrometry and monitored by a semi-conductor metal oxide gas sensor setup. The calibrated sensor system was able to detect different drying and degradation stages of the oak wood flakes by online monitoring acetic acid and furans/methoxyphenols at 25–240?°C. The system also allowed a monitoring of acetic acid emission from solid wood at 75?°C. This sensor application has the potential to online monitor the flue gas of oak lumber drying and optimize the drying process. 相似文献
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室内及车内环境中材料散发的挥发性有机化合物(VOC)是造成空气品质低劣的重要因素之一, 显著影响着人们的舒适度和身体健康。材料VOC散发特性由3个关键参数表征:初始可散发浓度C0、扩散系数Dm和分配系数K。测定上述散发关键参数是研究材料VOC散发规律进而预测人体暴露和健康风险的基础。基于目前应用最广泛的直流舱中材料VOC的散发过程, 提出了同时测定C0和Dm的浓度轨迹法。该方法通过预设K值, 然后对环境舱浓度的对数进行线性拟合, 根据斜率和截距获得关键参数C0和Dm。敏感性分析表明, 不同的K值对测定的C0和Dm值影响很小。通过对文献中的直流舱散发实验数据进行处理, 结果表明该测定方法具有较高的精度。 相似文献
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VOC emissions from the composting of the organic fraction of municipal solid waste using standard and advanced aeration strategies 总被引:3,自引:0,他引:3 下载免费PDF全文
Caterina Maulini‐Duran Belen Puyuelo Adriana Artola Xavier Font Antoni Sánchez Teresa Gea 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2014,89(4):579-586
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