Cooperative downconversion in Y3Al5O12 : RE3+,Yb3+ (RE = Tb,Tm, and Pr) nanophosphors

Abstract— Efficient near‐infrared (NIR) quantum cutting (QC) through cooperative downconversion in Y₃Al₅O₁₂ : RE³⁺,Yb³⁺ (RE = Tb, Tm, and Pr) nanophosphors has been demonstrated, which involves the conversion of the visible photon from RE³⁺ into the NIR emission of Yb³⁺ with the optimal quantum efficiency approaching 200%. The authors have analyzed the measured luminescence spectra and decay lifetimes and propose a mechanism to rationalize the NIR QC effect. The results indicate the potential of developing RE³⁺‐Yb³ dual‐ion‐based nanophosphors for the downconversion of high‐energy photons to multiple photons with an energy greater than the bandgap of silicon‐based‐photonics display devices.