Experimental investigation and development of new correlation for thermal conductivity and viscosity of BioGlycol/water based SiO2 nanofluids

Nanofluids are a new class of engineered heat transfer fluids which exhibit superior thermophysical properties and have potential applications in numerous important fields. In this study, nanofluids have been prepared by dispersing SiO₂ nanoparticles in different base fluids such as 20:80% and 30:70% by volume of BioGlycol (BG)/water (W) mixtures. Thermal conductivity and viscosity experiments have been conducted in temperatures between 30 °C and 80 °C and in volume concentrations between 0.5% and 2.0%. Results show that thermal conductivity of nanofluids increases with increase of volume concentrations and temperatures. Similarly, viscosity of nanofluid increases with increase of volume concentrations but decreases with increase of temperatures. The maximum thermal conductivity enhancement among all the nanofluids was observed for 20:80% BG/W nanofluid about 7.2% in the volume concentration of 2.0% at a temperature of 70 °C. Correspondingly among all the nanofluids maximum viscosity enhancement was observed for 30:70% BG/W nanofluid about 1.38-times in the volume concentration of 2.0% at a temperature of 70 °C. The classical models and semi-empirical correlations failed to predict the thermal conductivity and viscosity of nanofluids with effect of volume concentration and temperatures. Therefore, nonlinear correlations have been proposed with 3% maximum deviation for the estimation of thermal conductivity and viscosity of nanofluids.     

Experimental thermal conductivity of ethylene glycol and water mixture based low volume concentration of Al2O3 and CuO nanofluids

Thermal conductivity of ethylene glycol and water mixture based Al₂O₃ and CuO nanofluids has been estimated experimentally at different volume concentrations and temperatures. The base fluid is a mixture of 50:50% (by weight) of ethylene glycol and water (EG/W). The particle concentration up to 0.8% and temperature range from 15 °C–50 °C were considered. Both the nanofluids are exhibiting higher thermal conductivity compared to base fluid. Under same volume concentration and temperature, CuO nanofluid thermal conductivity is more compared to Al₂O₃ nanofluid. A new correlation was developed based on the experimental data for the estimation of thermal conductivity of both the nanofluids.     

Heat transfer and friction factor of water based TiO2 and SiO2 nanofluids under turbulent flow in a tube

The heat transfer coefficient and friction factor of TiO₂ and SiO₂ water based nanofluids flowing in a circular tube under turbulent flow are investigated experimentally under constant heat flux boundary condition. TiO₂ and SiO₂ nanofluids with an average particle size of 50 nm and 22 nm respectively are used in the working fluid for volume concentrations up to 3.0%. Experiments are conducted at a bulk temperature of 30 °C in the turbulent Reynolds number range of 5000 to 25,000. The enhancements in viscosity and thermal conductivity of TiO₂ are greater than SiO₂ nanofluid. However, a maximum enhancement of 26% in heat transfer coefficients is obtained with TiO₂ nanofluid at 1.0% concentration, while SiO₂ nanofluid gave 33% enhancement at 3.0% concentration. The heat transfer coefficients are lower at all other concentrations. The particle concentration at which the nanofluids give maximum heat transfer has been determined and validated with property enhancement ratio. It is observed that the pressure drop is directly proportional to the density of the nanoparticle.     

Experimental studies on thermal conductivity of blends of ethylene glycol-water-based TiO2 nanofluids

A set of three nanofluids of different blends were prepared with ethylene glycol–water and TiO₂ nanoparticles and are characterized for thermal conductivity as a function of temperature and volume concentration of nanoparticles. The measurements were taken in the temperature range from 30 °C to 70 °C, which happens to be most widely used range of temperature for many cooling applications in heat transfer equipment. Nanofluids were prepared by dispersing the nanoparticles in base fluids such as (1) water, (2) ethylene glycol plus water in the ratio of 40%:60% and 3) ethylene glycol plus water in the ratio of 50%:50% by weight. Based on the experimental results, it is observed that the thermal conductivity of TiO₂ nanofluids, considered in the present investigation, increases with increase in percentage of volume concentration of TiO₂ and also with temperature. Current experimental investigation presents valuable data on the measured thermal conductivity of TiO₂ nanofluids for very low volume concentrations from 0.2% to 1.0% of nanoparticles in the temperature range of 30 °C–70 °C.     

Thermal conductivity of ethylene glycol and water mixture based Fe3O4 nanofluid

Thermal conductivity of ethylene glycol and water mixture based Fe₃O₄ nanofluid has been investigated experimentally. Magnetic Fe₃O₄ nanoparticles were synthesized by chemical co-precipitation method and the nanofluids were prepared by dispersing nanoparticles into different base fluids like 20:80%, 40:60% and 60:40% by weight of the ethylene glycol and water mixture. Experiments were conducted in the temperature range from 20 °C to 60 °C and in the volume concentration range from 0.2% to 2.0%. Results indicate that the thermal conductivity increases with the increase of particle concentration and temperature. The thermal conductivity is enhanced by 46% at 2.0 vol.% of nanoparticles dispersed in 20:80% ethylene glycol and water mixture compared to other base fluids. The theoretical Hamilton–Crosser model failed to predict the thermal conductivity of the nanofluid with the effect of temperature. A new correlation is developed for the estimation of thermal conductivity of nanofluids based on the experimental data.     

Nanocomposite electrolytes with fumed silica in poly(methyl methacrylate): thermal,rheological and conductivity studies

Composite polymer electrolytes (CPEs), were prepared by adding hydrophilic fumed silica in different proportions upto 5 wt.% to gel polymeric electrolyte (GPE) comprising liquid electrolyte (1 M LiClO₄ in propylene carbonate) immobilized with 15 wt.% poly(methyl methacrylate) (PMMA). The effect of fumed silica content in the CPEs on the ionic conductivity and viscosity over a wide temperature range was investigated. The resultant CPEs showed room temperature conductivity (σ₂₅) as high as 3.8 mS cm⁻¹ along with viscosity value of 3700 P for 2 wt.% SiO₂ addition. Fumed silica addition both to the liquid electrolyte and to the GPE exhibits similar conductivity behaviour and this suggests a passive role of PMMA. The shear thinning behaviour, pointing towards easy processablity, high thermal stability and low volatility, makes these CPEs potential candidates as solid-like electrolytes for electrochemical devices.     

Experimental study on the thermo-physical properties of car engine coolant (water/ethylene glycol mixture type) based SiC nanofluids

The engine coolant (water/ethylene glycol mixture type) becomes one of the most commonly used commercial fluids in cooling system of automobiles. However, the heat transfer coefficient of this kind of engine coolant is limited. The rapid developments of nanotechnology have led to emerging of a relatively new class of fluids called nanofluids, which could offer the enhanced thermal conductivity (TC) compared with the conventional coolants. The present study reports the new findings on the thermal conductivity and viscosity of car engine coolants based silicon carbide (SiC) nanofluids. The homogeneous and stable nanofluids with volume fraction up to 0.5 vol.% were prepared by the two-step method with the addition of surfactant (oleic acid). It was found that the thermal conductivity of nanofluids increased with the volume fraction and temperature (10–50 °C), and the highest thermal conductivity enhancement was found to be 53.81% for 0.5 vol.% nanofluid at 50 °C. In addition, the overall effectiveness of the current nanofluids (0.2 vol.%) was found to be ~ 1.6, which indicated that the car engine coolant-based SiC nanofluid prepared in this paper was better compared to the car engine coolant used as base liquid in this study.     

Experimental investigation and model development for thermal conductivity of α-Al2O3-glycerol nanofluids

In order to investigate the effect of nanoparticle volume fraction, nanoparticle size and temperature on the thermal conductivity of glycerol based alumina (α-Al₂O₃) nanofluids, a set of experiments were carried out for temperature ranging from 20 °C to 45 °C. The nanofluids contained α-Al₂O₃ nanoparticles of three different sizes (31 nm, 55 nm and 134 nm) were prepared by two-step method at volume fractions ranging from 0.5% to 4%. The experimental results show that α-Al₂O₃-glycerol nanofluids have substantially higher thermal conductivity than the base fluid and the maximum enhancement of the relative thermal conductivity was 19.5% for the case of 31 nm at 4% volume fraction. The data analyses indicated that the volume fraction and size of the nanoparticles have significant effects on the thermal conductivity ratio (TCR) of Al₂O₃-glycerol nanofluids, while the temperature has almost no significant effect on the data for range of this study. At room temperature, the effective thermal conductivity remains almost constant for 50 h at 4% volume fractions. The comparison of the obtained experimental data and predictions from some existing theoretical and empirical models reveals that the thermal conductivity ratio and its trend could not be accurately explained by the models in open literature. Consequently, a new empirical correlation based on the experimental data has been developed in this study.     

Fabrication and thermo-physical properties characterization of ethylene glycol—MoS2 heat exchange fluids

This study reports on the fabrication and thermo-physical properties evaluation of ethylene glycol (EG) based heat exchange fluids containing molybdenum disulfide nanoparticles (MoS₂ NPs) and micrometer sized particles (MPs). For this purpose, MoS₂ NPs and MPs (with average size of 90 nm and 1.2 μm; respectively) were dispersed and stabilized in EG with particle loading of 0.25, 0.5, 1 wt%. To study the real effect of MoS₂ NP/MP the use of surfactants was avoided and ultrasonic agitation was used for dispersion and preparation of stable MoS₂ NFs/MFs. The objectives were investigation of impact of MoS₂ particle size (including NP/MP) and particle loading on thermo-physical properties of EG based MoS₂ NFs/MFs including thermal conductivity (TC) and viscosity of NFs/MFs at 20 °C. All suspensions (NFs/MFs) exhibited a higher TC than the EG as base liquid and NFs showed higher TC enhancement values than the MFs. A TC enhancement of 16.4% was observed for NFs containing 1 wt% MoS₂ NPs while the maximum increase in viscosity of 9.7% was obtained for the same NF at 20 °C. It indicates this NF system may have some potential to be utilized in heat transfer applications.     

Experimental investigation on the thermo-physical properties of Al2O3 nanoparticles suspended in car radiator coolant

Nanofluid is a new type of heat transfer fluid with superior thermal performance characteristics, which is very promising for thermal engineering applications. This paper presents new findings on the thermal conductivity, viscosity, density, and specific heat of Al₂O₃ nanoparticles dispersed into water and ethylene glycol based coolant used in car radiator. The nanofluids were prepared by the two-step method by using an ultrasonic homogenizer with no surfactants. Thermal conductivity, viscosity, density, and specific heat have been measured at different volume concentrations (i.e. 0 to 1 vol.%) of nanoparticles and various temperature ranges (i.e. from 10 °C to 50 °C). It was found that thermal conductivity, viscosity, and density of the nanofluid increased with the increase of volume concentrations. However, specific heat of nanofluid was found to be decreased with the increase of nanoparticle volume concentrations. Moreover, by increasing the temperature, thermal conductivity and specific heat were observed to be intensified, while the viscosity and density were decreased.     

Investigation of thermal conductivity and viscosity of Fe3O4 nanofluid for heat transfer applications

Experimental investigations and theoretical determination of effective thermal conductivity and viscosity of magnetic Fe₃O₄/water nanofluid are reported in this paper. The nanofluid was prepared by synthesizing Fe₃O₄ nanoparticles using the chemical precipitation method, and then dispersed in distilled water using a sonicator. Both experiments were conducted in the volume concentration range 0.0% to 2.0% and the temperature range 20 °C to 60 °C. The thermal conductivity and viscosity of the nanofluid were increased with an increase in the particle volume concentration. Viscosity enhancement was greater compared to thermal conductivity enhancement under at same volume concentration and temperature. Theoretical equations were developed to predict thermal conductivity and viscosity of nanofluids without resorting to the well established Maxwell and Einstein models, respectively. The proposed equations show reasonably good agreement with the experimental results.     

Thermal conductivity measurement of methanol-based nanofluids with Al2O3 and SiO2 nanoparticles

In this study, the methanol-based nanofluids with Al₂O₃ and SiO₂ nanoparticles are prepared by dispersing nanoparticles in pure methanol using an ultrasonic equipment. The main objective of this paper is to measure the thermal conductivity of the methanol-based nanofluids. We have also measured the zeta potential, particle size and Tyndall effect for the present nanofluids. The transient hot-wire method is applied for measuring the thermal conductivity of methanol-based nanofluids. The measurement uncertainty in repeatability is obtained as 1.95% for deionized (DI) water and 1.34% for pure methanol, respectively. The effective thermal conductivity of methanol-based nanofluids is measured at a temperature of 293.15 K. The results show that the thermal conductivity increases with an increase of the nanoparticle volume fraction, and the enhancement is observed to be 10.74% and 14.29% over the basefluid at the volume fraction of 0.5vol% for Al₂O₃ and SiO₂ nanoparticles, respectively. Clustering of nanoparticles is considered to be the main reason for the thermal conductivity enhancement.     

Direct numerical simulation of thermal conductivity of nanofluids: The effect of temperature two-way coupling and coagulation of particles

An Eulerian–Lagrangian based direct numerical simulations (DNS) model was developed to investigate the effective thermal conductivity of nanofluids. A two-way coupling term to resolve the temperature interactions between the solid particles and fluid field was considered. The model also considered various forces acting on the nanoparticles. Cu/water nanofluids with 100 nm particles and Al₂O₃/water nanofluids with 80 nm particles were simulated at different volume fractions and the effective thermal conductivity of nanofluids was calculated. The present results suggest that the particle conductivity and forces acting on nanoparticle are necessary while predicting the effective thermal conductivity of nanofluids.     

Experimental investigation of the thermophysical properties of AL2O3-nanofluid and its effect on a flat plate solar collector

Experimental investigations have been carried out for obtaining the thermophysical properties of 60:40 (by mass) ethylene glycol/water mixture and water based alumina nanofluids. The effect of density and viscosity on the pumping power for flat plate solar collector has been investigated as well. Nanofluids of 0.05–0.1%v/v concentrations were prepared and characterized. Water based alumina nanofluids were found more preferable against sedimentation and aggregation than ethylene glycol/water mixture based nanofluids. The measured thermal conductivities of both types of the nanofluids increased almost linearly with concentration and are consistent in their overall trend with previous works done at lower concentrations by different researchers. In contrast to thermal conductivity, viscosity measurements showed that the viscosity of the Al₂O₃–water nanofluids exponentially decreases with increasing temperature. Furthermore, the measured viscosities of the Al₂O₃–water nanofluids showed a non-linear relation with concentration even in the low volume concentration except 0.05%v/v at below 40 °C. On the other hand, Al₂O₃–EG/water mixture exhibited Newtonian behavior. Existence of a critical temperature was observed beyond which the particle suspension properties altered drastically, which in turn triggered a hysteresis phenomenon. The hysteresis phenomenon on viscosity measurement, which is believed to be the first observed for EG/water-based nanofluids, has raised serious concerns regarding the use of nanofluids for heat transfer enhancement purposes. Results suggest that nanofluids can be used as a working medium with a negligible effect of enhanced viscosity and/or density. Results also show that the pressure drop and pumping power of the nanofluid flows are very close to that of the base liquid for low volume concentration.     

Unconfined laminar nanofluid flow and heat transfer around a square cylinder

The momentum and forced convection heat transfer for a laminar and steady free stream flow of nanofluids past an isolated square cylinder have been studied numerically. Different nanofluids consisting of Al₂O₃ and CuO with base fluids of water and a 60:40 (by mass) ethylene glycol and water mixture were selected to evaluate their superiority over conventional fluids. Recent correlations for the thermal conductivity and viscosity of nanofluids, which are functions of particle volumetric concentration as well as temperature, have been employed in this paper. The simulations have been conducted for Pe = 25, 50, 100 and 200, with nanoparticle diameters of 30 and 100 nm and particle volumetric concentrations ranging from 0% to 4%. The results of heat transfer characteristics of nanofluid flow over a square cylinder showed marked improvement comparing with the base fluids. This improvement is more evident in flows with higher Peclet numbers and higher particle volume concentration, while the particle diameter imposes an adverse effect on the heat transfer characteristics. In addition, it was shown that for any given particle diameter there is an optimum value of particle concentration that results in the highest heat transfer coefficient.     

Investigation of thermal conductivity and viscosity of Al2O3/water–ethylene glycol mixture nanocoolant for cooling channel of hot-press forming die application

Hot-press forming process is widely used to produce lightweight chassis in automotive industries. The hot-press forming process currently uses water as coolant to quench boron steels in a closed die with a cooling channel. However, to enhance performance of hot-press forming die, the fluid with better thermal properties will be used instead of normal water. This study dispersed Al₂O₃ nanoparticles with an average diameter of 13 nm in three volume percentages base ratios of water (W) to ethylene glycol (EG) (i.e. 60:40, 50:50, and 40:60) by two-step preparation. The two main parameters in cooling rate performance are thermal conductivity and viscosity. The nanocoolant of Al₂O₃/water–ethylene glycol mixture is prepared for the volume concentration range of 0.2 to 1.0%. The thermal conductivity and viscosity are then measured at temperature range of 15 to 55 °C. The highest enhancement of thermal conductivity was observed to be 10% higher than base fluid for 1.0% volume concentration at 55 °C in 60:40 (W/EG). However, the highest enhancement of viscosity was measured to be 39% for 1.0% volume concentration in 40:60 (W/EG) at 25 °C. The convective heat transfer coefficient of 1.0% concentration in 60:40 (W:EG) at 25 °C is enhanced by 25.4% better than that of 50:50 and 40:60 (W:EG) base fluid. Therefore, this study recommends the use of Al₂O₃ in 60:40 (W:EG) mixture with volume concentration of less than 1.0% for application in cooling channel of hot-press forming die. Nanocoolant as cooling agent with higher heat transfer coefficient compared to the base fluid can reduce the cycle time and increase the productivity of hot-press forming process.     

A novel phase change material containing mesoporous silica nanoparticles for thermal storage: A study on thermal conductivity and viscosity

In this research, mesoporous silica (MPSiO₂) nanoparticles were dispersed in n-octadecane as an organic phase change material (PCM) in order to produce a novel composite for thermal storage. Stable PCMs containing 1 wt.%, 3 wt.% and 5 wt.% MPSiO₂ nanoparticles (PCM/MPSiO₂) were fabricated by dispersing MPSiO₂ in PCM. MPSiO₂ particles were investigated by SEM and TEM techniques, which showed high order of porosity and spherical particles of ca. 300 nm. The thermal conductivity in both solid and liquid phases was measured by transient plane source (TPS) technique in the temperature range of 5–55 °C. A maximum thermal conductivity enhancement of 5% for 3 wt.% MPSiO₂ at 5 °C, and 6% for 5 wt.% MPSiO₂ at 55 °C was experimentally obtained. Moreover, it was observed that enhancement in thermal conductivity is non-monotonic in solid phase with increasing MPSiO₂ particle loading. The viscosity results showed that for mass fractions of nanoparticles greater than 3% in liquid PCM, the behavior of liquid is non-Newtonian. Also, the viscosity of PCM containing MPSiO₂ nanoparticles was measured to be increased up to 60% compared to the liquid PCM for 5 wt.% MPSiO₂ at 35 °C.     

An experimental study on the thermal conductivity and dynamic viscosity of TiO2-SiO2 nanofluids in water: Ethylene glycol mixture

The hybrid nanofluid has been thriving among researchers due to its potential to improve heat transfer performance. Therefore, various studies on heat transfer properties need to be carried out to provide a better understanding on hybrid nanofluid performance. In this paper, the experimental work is focused on the thermal conductivity and dynamic viscosity of TiO₂-SiO₂ nanofluids in a mixture of water and ethylene glycol (EG) with volume ratio of 60:40. The stable suspension of TiO₂-SiO₂ prepared at volume concentrations of 0.5 to 3.0%. The measurements of thermal conductivity and dynamic viscosity were performed at a temperature range of 30 to 80 °C by using KD2 Pro Thermal Properties Analyser and Brookfield LVDV III Ultra Rheometer, respectively. The thermal conductivity of TiO₂-SiO₂ nanofluids was improved by increasing the volume concentration and temperature with 22.8% maximum enhancement. Besides, the viscosity of TiO₂-SiO₂ nanofluids showed evidence of being influenced by nanofluid concentration and temperature. Additionally, the TiO₂-SiO₂ nanofluids behaved as a Newtonian fluid for volume concentration up to 3.0%. The properties enhancement ratio suggested that TiO₂-SiO₂ nanofluids will aid in heat transfer for concentrations of more than 1.5% and within the range of the temperature studied. A new correlation for thermal conductivity and dynamic viscosity of TiO₂-SiO₂ nanofluids were developed and found to be precise.     

Thermal conductivity of Cu/TiO2–water/EG hybrid nanofluid: Experimental data and modeling using artificial neural network and correlation

In the present paper, the thermal conductivity of hybrid nanofluids is experimentally investigated. The studied nanofluid was produced using a two-step method by dispersing Cu and TiO₂ nanoparticles with average diameter of 70 and 40 nm in a binary mixture of water/EG (60:40). The properties of this nanofluid were measured in various solid concentrations (0.1, 0.2, 0.4, 0.8, 1, 1.5, and 2%) and temperatures ranging from 30 to 60 °C. Next, two new correlations for predicting the thermal conductivity of studied hybrid nanofluids, in terms of solid concentration and temperature, are proposed that use an artificial neural network (ANN) and are based on experimental data. The results indicate that these two new models have great ability to predict thermal conductivity and show excellent agreement with the experimental results.     

Experimental investigation of the thermal transport properties of graphene oxide/Co3O4 hybrid nanofluids

The in-situ growth and chemical co-precipitation method was used for the synthesis of uniform dispersion of Co₃O₄ nanoparticles on the graphene oxide (GO) nanosheet. The reductions of aqueous cobalt chloride in the presence of GO with sodium borohydrate result in the formation of hybrid GO/Co₃O₄ nanoparticles. The synthesized GO/Co₃O₄ nanoparticles were characterized using X-ray power diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, transmission electron microscopy (TEM) and vibrating sample magnetometer (VSM). The hybrid nanofluids were prepared by dispersing synthesized GO/Co₃O₄ nanoparticles in water, ethylene glycol, and ethylene glycol/water mixtures. The properties such as thermal conductivity and viscosity were estimated experimentally at different volume concentrations and temperatures. The thermal conductivity enhancement of water-based nanofluid is 19.14% and ethylene glycol-based nanofluid is 11.85% at 0.2% volume concentration and at a temperature of 60 °C respectively compared to their respective base fluids. Similarly, the viscosity enhancement of water-based nanofluid is 1.70-times and ethylene glycol-based nanofluid is 1.42-times at 0.2% volume concentration and at a temperature of 60 °C respectively. The obtained thermal conductivity and viscosity data is compared with the literature values.