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我国稀土氨基酸固体配合物的研究进展 总被引:23,自引:4,他引:19
本文概述了近十年来,我国在稀土氨基酸固体配合物方面的研究进展,介绍了它们的研究意义、应用价值、合成方法、成键特性、配合物的热稳定性、晶体的多聚链状结构等。 相似文献
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GENG 《中国稀土学报(英文版)》2010,28(6):820-823
Rare earth dements have unique physical, magnetic, luminescent and catalytic properties. They have been successfully used as medicine and probes in luminescent resonance energy transfer (LRET) for bioassays, as well as reagents for diagnosis in magnetic resonance imaging (MRI). In this progress report, we will focus on recent progress on how rare earth amino complexes bind to DNA and change DNA structure, especially on DNA B-Z transition induced by rare earth amino acid complex and its potential impact on Alzheimer's disease (AD). 相似文献
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NMRspectroscopyofbiofluidhasbroughtnew chemistryintolifescienceandclinicalmedicine,and NMRspectroscopy basedapproachhasbeensuccess fullyappliedtothestudiesofbiochemicaleffectsand inborndiseaseswiththeadventofhighfieldNMR spectrometers[1].Inrecentyears,highresolutionNMRhasbeenusedtotherapidmulticomponentanal ysisoflowmolecularweightcompoundsinbiofluid,includingurine,bile,cerebrospinalfluid,saliva,milkandsynovialfluidforclinicaldiagnosisofinborn diseasesandinvestigationofbiochemicaleffectsof… 相似文献
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土壤中可给态稀土元素的研究进展 总被引:14,自引:0,他引:14
本文综述了土壤中可给态稀土元素与植物生长的相关性,土壤中可给态稀土浸提剂的选择以及定量测定方法的研究,详细讨论了我国主要土壤中可给态稀土元素的含量、分布及其影响因子,并提出在今后研究中应值得关注的几个方面,为合理施用稀土微肥提供科学依据。 相似文献
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Using common phosphate as a check, we studied the growth and yield of potato by new rare earth agro-materials including rare earth phosphate (base fertilizer), rare earth whole plant nutrient fertilizer, and amino acid chelated rare earth ( top dressing), which were used in a single or mixed way in Dingxi city, Gansu Province.The results are as follows that ( 1 ) After using new rare earth materials, the plant height increases by 0.4 ~ 5.6 cm and the ripen period is delayed by 4 ~ 9 d.(2) They can improve the potato economic characteristics, enhance productivity, decrease black leg and late blight.The disease index is decreased by 1.6% ~ 10.6%, single plant potato number increases by 0.3 ~ 0.5, and single plant yield increases by 80 g ~ 130 g.(3) The effect of increased yield is significant, and mixed use is better than single use.In the single material treatments, rare earth phosphate is the best, rare earth whole plant nutrient fertilizer and amino acid chelated rare earth are the second, and the increased rate are 14.5%, 8.4%, 9.2% so the material mixture-rare earth phosphate mixed of rare earth whole plant nutrient fertilizer or with amino acid chelated rare earth is economically useable, and increase rate are 25.2% and 24.4% compared with common phosphate. 相似文献
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《中国稀土学报(英文版)》2016,(6)
Using Chinese cabbage and rape as test material and examining the same soil conditions at different seasons(spring and autumn), the effects of mixed rare earth fertilizer on the yield and nutrient quality of leafy vegetables were studied to provide a theoretical basis for the application of mixed rare earth fertilizer in agriculture. Results showed a seasonal difference in the nutrient quality of Chinese cabbage and rape. For crops planted in autumn, the soluble sugar and vitamin C content were higher, the titratable acid and nitrate content were lower, and the sugar acid ratio was higher relative to crops planted in spring. Mixed rare earth treatments promoted growth of both crops during both seasons. The plot yield, stem and leaf fresh and dry matter weight, and dry and fresh ratio increased. These increases for Chinese cabbage were greater in autumn than in spring while for rape, the increases were greater in spring than autumn. The soluble sugar content, titratable acid content and sugar acid ratio were increased and the nitrate content decreased, in autumn the effects were more obvious than in spring. In spring, the vitamin C content was increased, and the increase was greater for Chinese cabbage than rape. In autumn, the vitamin C content decreased, and the decrease was greater for rape than Chinese cabbage. At the same time, the content of heavy metals such as Cu, Zn, Cd, Pb and Ni in stems and leaves decreased. This decrease was greater in spring for Chinese cabbage and in autumn for rape. 相似文献
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The voltammetric behaviors of rare earth ions-amino acids were studied.The reduction potential of Eu~(3+)was shifted positively and the peak separation of the cathodic and anodic peaks in cyclic voltammogram de-creased when a certain amino acid was added to Eu~(3+) solution.Experimental results showed that Eu~(3+) was re-duced by way of forming complexes with amino acids which were adsorbed on mercury electrode surface.Whenhistidine and formaldehyde existed simultaneously in the solution containing Eu~(3+),a well-defined reversiblecatalytic prewave of Eu~(3+) was obtained.Meanwhile,the reduction current of formaldehyde increased greatlywith the addition of histidine.The mechanism was studied.Several other rare earth ions and amino acids werealso studied preliminarily. 相似文献
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离子型稀土农用综合技术研究 总被引:1,自引:0,他引:1
把离子型稀土主要的各元素和主要配分类型,以富铈农用硝酸稀土作比较为依据,形成离子稀土复合剂在种养业上应用为目的,并研究其生理效应阐明其增效所在 相似文献
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Thedevelopmentofhigh fieldNMRspectrome terswithincreasedsensitivity,resolution,dynamic rangeandimprovedcomputingcapabilitieshasmade itpossibletouseNMRtechniqueforrapidmulticom ponentanalysisoflowMWcompoundsinbiofluids inordertoassessthetoxicologicaleffe… 相似文献
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New rare earth(RE) materials for agriculture including RE entire nutrition agent, amino acid chelated RE fertilizer, RE phosphate were used to alfalfa production in Grassland Working Station of Yili, Xinjiang Province, and repetition was 3 with 7 treatments.The result shows that by using new RE materials, the average treatment height of alfalfa increases by 12.5% compared with traditional cultural, and the yield increases from 21.8% to 41.6% compared with that of traditional cultural.These results show that the new materials have significant good effect on alfalfa production. 相似文献
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Two series of solid complexes of europium and terbium with biphenyl 4-carboxylic acid and phen were synthesized and characterized in this report. Their elemental analysis, molar conductivities and TG-DTA studies indicate that the complexes have the composition of Eu(phen)L3·1/2H2O, Eu0.5RE0.5(phen)L3·1/2H2O; Tb(phen)L3·H2O and Tb0.5RE0.5(Phen)L3·1/2H2O. (RE=Y3 , La3 and Gd3 ; L=biphenyl 4-carboxylic acid; phen=o-Phenanthroline). The studies of their IR, UV 1H NMR and molar conductivities demonstrate that biphenyl 4-carboylic acid is bounded with RE(Ⅲ) ion. Rare earth ions coordinate with two nitrogen atoms of phen molecules directly in these rare earth complexes. The fluorescence spectra and fluorescence lifetimes of the rare earth complexes show that the fluorescent intensity and lifetime of a series of europium complexes are longer than those of the series of terbium complexes as having the some ligands. There are better fluorescent intensity and lifetime of hetero-nuclear rare earth complexes than homo-nuclear rare earth complexes for europium complexes. The fluorescence emission intensity of Eu3 is raised by inert fluorescent rare earth ions (Y3 , Gd3 and La3 ), but in Tb3 hetero-nuclear rare earth complexes the intensity of Tb3 ions are quenched by the inert fluorescent rare earth ions. 相似文献