锰在永磁材料中的应用

概述了锰在永磁材料中的应用,其主要为Fe-Mn系永磁合金、Mn-Al系永磁合金、Mn-Bi系永磁合金、稀土锰基化合物、永磁薄膜以及Mn在永磁材料中的掺杂。     

Rapid Solidification of Sm-Co Permanent Magnets

In this article, we report the microstructural evolution of rapidly solidified Sm-Co alloys from 4 to 16 at. pct Sm. We have observed a wide variety of phase formation and microstructures, ranging from primary Co dendrite formation to eutectic structures to the formation of the metastable SmCo₇ compound. In particular, we observed nonequilibrium formation of Co along with SmCo₇, whose presence caused a decrease in coercivity from ∼10 kOe to 500 Oe. Alloying elements reduced the scale of the microstructure, effectively offsetting the detrimental effects of the Co phase formation and leading to a recovery of the coercivity. The eutectic structure with Co rods surrounded by SmCo₇ provides a natural path to nanoscale hard/soft magnetic nanocomposites, where control of scale and phase content is critical. This article is based on a presentation made in the symposium entitled “Phase Transformations in Magnetic Materials”, which occurred during the TMS Annual Meeting, March 12–16, 2006, in San Antonio, Texas, under the auspices of the Joint TMS/MPMD and ASMI-MSCTS Phase Transformations Committee.

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钕铁硼永磁材料化学镀镍工艺研究

研究了Ｎｄ－Ｆｅ－Ｂ永磁材料化学镀镍磷合金的防护工艺。在测试各种性能的基础上，主要就前处理工艺和施镀工艺进行了实验和优化，提出了适宜的工艺流程和工艺条件。     

永久磁体新材料和新工艺

扼要地介绍了在较低温度下制造永久磁体的机械合金化新技术，并对一些永久磁体新材料的主要性能进行了对比阐述。     

稀土永磁体的新应用

介绍了稀土永磁体在电机、减振器、磁选机、研磨、生产传输线等方面的最新应用趋势。     

HDDR法制备各向同性SmFeN永磁体的研究

研究了HDDR法制备各向同性Sm2Fe17Nx磁体的制备、结构与磁性能,发现SmFe铸态组织主要由Sm2Fe17、SmFe2、SmFe3和α-Fe四种相组成,而经过1050℃均匀化退火13h后形成了所需要的接近单相组织的Sm2Fe17相合金。铸锭经过粉碎球磨、HDDR、渗氮处理后,经压制成型得到各向同性的高矫顽力的Sm2Fe17Nx磁体。获得的磁体矫顽力达到了1300kA/m。     

黏结Nd-Fe-B永磁材料及其应用与发展

主要介绍了黏结Nd-Fe-B永磁材料制备工艺及其在高科技应用领域的不断发展、拓展,同时,综述了黏结Nd-Fe-B永磁材料的发展动态和生产状况,并指出黏结Nd-Fe-B永磁材料作为一种新型材料在现代科学技术中的地位,说明其拥有着良好的应用与发展前景。     

Nd-Fe-B磁体热等静压烧结的实验研究

研究了热等静压烧结对Nd-Fe-B磁体的致密度、显微组织及磁性能的影响.结果表明:与常压烧结磁体相比,热等静压烧结磁体的内部存在较多的孔洞,致密度、晶粒取向度及磁性都有所降低.用加热Ar气热膨胀而产生热等静压进行烧结的办法不适于制造高性能的烧结磁体.     

Coercivity of 2:17 Based Permanent Magnets

High-quality permanent magnets either are based on large nucleation fields or strong pinning forces of domain walls (dws). In the case of 2:17 based magnets depending on the temperature range considered both hardening mechanisms have been discussed. The dominant hardening mechanisms at temperatures below around 700 K are repulsive or attractive pinning of domain walls at the cell walls (1:5 structure) between the nanostructured pyramidal cells (2:17 structure). Micromagnetic calculations of the pinning forces sensitively depend on the shape of the interaction potential between the dw and the microstructure. In the case of the 2:17 based magnets these calculations become rather complex if the domain wall width is of the order of the potential width. In this case the domain wall is modified due to the space dependent local anisotropy which changes from K₁^2:17 to K₁^1:5 of the cell boundary phase over a distance D of the intergranular phase boundary. Using the K₁(r)-profiles as determined from the chemical composition obtained by high-resolution EDX measurements the coercive field due to domain wall pinning is determined self-consistently as a function of the pinning-potential parameters taking into account the modification of the domain wall by the space dependent material parameters. It is shown that the coercive field of the high-temperature magnets as a function of the width of the cell boundary phase varies between 3 T for a sharp boundary (D = 0 nm) and 1 T for a wide boundary (D = 4 nm). On the basis of micromagnetism the condition for the dominance of pinning or nucleation is investigated. It is shown that in the case of 2:17 based high-temperature magnets with increasing temperature the hardening mechanisms change from repulsive to attractive pinning and nucleation starts at around 700 K. The temperature ranges where the transitions take place sensitively depend on the Cu content and on the annealing parameters.     

Production of Permanent Magnets for Magnetically Hard Alloys Using Rare-Earth Metals

Metallurgist - A requirement for improving powder metallurgy technology of alloys for permanent magnets containing rare-earth metals based on the use of secondary resources and a replacement of...     

Study on Key Techniques for Producing High Performance NdFeB Sintered Permanent Magnets

ＮｄＦｅＢｍａｇｎｅｔｓｈａｖｅｂｅｅｎｉｍｐｒｏｖｅｄｄｒａ ｍａｔｉｃａｌｌｙｓｉｎｃｅｉｔｗａｓｉｎｖｅｎｔｅｄｉｎ 1 983 .Ｔｗｏｔｙｐｅｓｏｆｓｉｎｔｅｒｅｄｍａｇｎｅｔｓ ,ｈｉｇｈｅｎｅｒｇｙｐｒｏｄ ｕｃｔｓ ((ＢＨ ) ｍａｘ)ａｎｄｄｏｕｂｌｅｈｉｇｈ (ｈｉｇｈ(ＢＨ ) ｍａｘａｎｄｈｉｇｈｃｏｅｒｃｉｖｉｔｙ (ｉＨｃ) )ａｒｅｔｈｅｔｗｏｔｅｎｄｅｎｃｉｅｓｆｏｒＮｄＦｅＢｓｉｎｔｅｒｅｄｍａｇｎｅｔｓ .Ｂｏｔｈｆａｃｔｏｒｉｅｓａｎｄｒｅｓｅａｒｃｈｉｎｓｔｉｔｕｔｅｓａｒｅｆｏｃｕｓ…     

高性能纳米晶镨铁硼稀土永磁材料的研究现状

讨论了合金成分及制备工艺与纳米晶复合永磁材料磁性能的关系,分析了稀土含量、添加合金化元素、快淬速度、晶化退火温度和时间对合金磁性能的影响机理,综述了纳米晶复合永磁材料开发研究的现状、存在问题及发展方向。     

采用速凝铸造工艺制备烧结NdFeB永磁体

概述了国内外在生产烧结NdFeB永磁体中,采用速凝铸造工艺制备磁体合金的研究进展,并介绍了一些有利于提高磁体性能的先进方法。同时分析总结了速凝铸造对提高磁体性能的部分机理。     

Permanent Magnets Design and Magnetic Field Analysis of Multi-disc Coreless Permanent Magnet Synchronous Motor

This paper presents a new multi-disc coreless permanent magnet synchronous motor whose permanent magnets are arranged in the “Halbach array”. Unit motor combined structure is adopted to simplify processing technology of the motor. Airgap magnetic flux density is increased taking advantage of high remanence and coercive force of NdFeB permanent magnet material and high gathering magnetism function of Halbach array. This also makes coreless motor possible. The structure and the characteristics of the motor using Halbach array are also introduced. The FEM analysis has been done to build the mathematical model and study the magnetic field characteristics of the motor. And finally the interrelated design parameters of permanent magnet and arrangement between unit motors are determined according to the results of die FEM analysis.     

我国烧结钕铁硼永磁体的高速发展

综述了我国烧结钕铁硼永磁材料的生产、应用和市场的发展现状。目前这种永磁体的生产量、国内用量及国内外市场销量都居世界之冠，其发展前景仍然看好。针对存在的问题提出了建议。     

HD处理烧结磁体制备各向异性NdFeB磁粉

研究了通过吸氢破碎(HD)处理由烧结NdFeB磁体制取各向异性磁粉的方法.实验结果表明:HD处理温度是该处理过程中的关键参数,对于最终获得的各向异性磁粉的矫顽力具有显著的影响,同时HD处理温度的变化决定了烧结磁体破碎过程中的断裂方式.当HD处理温度为220℃时,磁体主要以沿晶断裂方式破碎,再经过950℃温度下的热处理,获得的各向异性磁粉的矫顽力达到490 kA/m.     

Spark Plasma Sintering Nd-Fe-B Permanent Magnets With Good All-Around Property

In present study, sintered Nd-Fe-B permanent magnets with different compositions were fabricated by using both Spark Plasma Sintering (SPS) technique and conventional sintering technique. Microstructure and compositions of both magnets are observed by scanning electron microscope with energy dispersive X-ray detector. Magnetic properties, mechanical properties, and chemical stabilities of both Nd-Fe-B magnets are investigated. Compared with the conventional sintered magnets, SPS Nd-Fe-B magnets possess comparable magnetic properties, better corrosion resistance and mechanical properties. Further investigation shows that the good all-around properties of the SPS magnets result from their unique microstructure. In detail, the grain size of Nd₂Fe₁₄B main phase is fine and uniform, only a few Nd-rich phase forms along the grain boundaries of Nd₂Fe₁₄B, while most of them agglomerates into the triple junctions. As a result, SPS process is expected to be a promising method for the production of new Nd-Fe-B magnets with good all-around properties.     

New Systems of Rare Earth Permanent Magnets for Generation of Extrahigh Magnetic Fields

Various systems, which are composed of rare-earth permanent magnets and generate strong magnetic fields, are calculated. Strong fields are taken to mean the fields with the strength, which exceeds the magnet induction. Calculated values of the strength of strong fields can mount to 20–150 kOe. Depending on form of domains where this fields are localized they can be classified as linear and point fields, the corresponding systems can be named linear and point as well. It was shown that the maximal linear field can be obtained in Halbach cylinder (prism), in which this field tends to H_x = 4πM_s ln(a/x) with increasing of number of component sectors. The maximal point field is reached in systems composed of many conical magnets, divided by many sectors. The strength of such field tends to the value H_x = 8πM_s ln(a/x). Experimental values of strong fields measured in some systems by various methods are in good agreement with calculated data.