海水环境下铝酸盐水泥基材料的抗蚀性能研究

研究了海水环境下铝酸盐水泥与单掺硅灰、矿渣组成的复合水泥浆体的抗压强度和水化产物变化规律。结果表明,海水对铝酸盐水泥具有侵蚀作用;掺入矿物掺合料能够促进铝酸盐水泥的水化,改善水泥浆体孔隙结构,生成水化钙铝黄长石等水化产物,有利于浆体结构密实和强度发展,进而提高铝酸盐水泥强度及抗蚀性能,且随着矿物掺合料掺量的增多,抗蚀性能逐渐提升。与矿渣相比,硅灰对提高铝酸盐水泥抗蚀性能具有更好的效果,海水环境下掺入10%硅灰,28 d抗压强度最高,超过淡水环境下空白组。     

硅灰对硫铝酸盐水泥水化行为的影响机理

通过抗压强度、凝结时间、电阻率测定以及X射线衍射(XRD)、扫描电镜(SEM)和孔溶液分析,研究了掺硅灰硫铝酸盐水泥浆体的水化行为.结果表明:5%掺量(质量分数,下同)的硅灰可以很好地改善水泥浆体的抗压强度,10%硅灰掺量的试样抗压强度只在1,28d时稍高于空白试样;掺入硅灰明显缩短了硫铝酸盐水泥的凝结时间;硫铝酸盐水泥的主要晶体水化产物是钙矾石,28d时的钙矾石量稍高于3d时,掺硅灰试样的钙矾石量要高于空白试样;掺硅灰试样的电阻率变化曲线高于空白试样,表明硅灰的掺入能够加快水泥的水化速率;硬化水泥浆体的孔溶液碱度随着硅灰掺量的增加而降低,掺硅灰试样的Ca2+浓度高于空白试样,表明硅灰促进了熟料的溶解,5%硅灰掺量试样的Al 3+浓度最低,表明其促进水化的效果更明显.     

硅灰对硫铝酸盐水泥力学和电磁传输性能的影响

研究了硅灰掺量对硫铝酸盐水泥力学性能和电磁传输性能的影响.结果表明：随着硅灰掺量的增加,硫铝酸盐水泥的抗压强度和抗折强度均先增大后降低,硅灰的最优掺量为10%;硫铝酸盐水泥的电磁传输性能随着硅灰掺量的增加而增大,与未掺硅灰的样品相比,硅灰-硫铝酸盐水泥在3.94~5.99 GHz频段范围内电磁传输性能均有所提升,电磁透射率峰值最高提升了23.9%.     

高强水泥基灌浆料配合比的正交试验研究

通过正交试验,研究了硫铝酸盐水泥、标准砂、硅灰、减水剂和膨胀剂掺量对水泥基灌浆料的流动度、3 d抗压强度和28 d抗压强度的影响。试验结果表明:硅灰掺量对灌浆料的流动度影响最大,减水剂掺量对水泥基灌浆料3 d抗压强度的影响最大,硅灰掺量对水泥基灌浆料28 d抗压强度的影响最大。通过正交试验分析优化得到高强水泥基灌浆料的配合比:硫铝酸盐水泥掺量为75%、标准砂掺量为40%、减水剂掺量为12%、硅灰掺量为2%、膨胀剂掺量为1.1%。     

矿物掺合料对铁铝酸盐水泥力学性能影响研究

针对铁铝酸盐水泥早期水化热高的问题,提出采用掺加矿物掺合料的方法改善铁铝酸盐水泥性能。研究了单独掺加不同掺量粉煤灰、矿粉、石灰石粉、粉煤灰微珠、硅灰的铁铝酸盐水泥用水量、力学性能,以及复合掺加粉煤灰-矿粉、粉煤灰微珠-矿粉、粉煤灰微珠-硅灰及石灰石灰石粉-矿粉的铁铝酸盐水泥用水量、力学性能。结果表明,粉煤灰等掺合料均会降低铁铝酸盐水泥强度,但是对用水量的影响不同,粉煤灰及硅灰会显著增加铁铝酸盐水泥用水量,石灰石粉及粉煤灰微珠会降低用水量。当掺合料单独掺加或复合掺加等量取代30%水泥时,复合胶凝体系的抗压强度降至45.0MPa左右,掺合料的掺量宜控制在30%以内。     

硫铝酸盐水泥基结构加固胶的研究

以硫铝酸盐水泥为主要原料制备水泥基结构加固胶,详细讨论和分析了水胶比和硅灰掺量两个因素对胶体抗压强度的影响,并通过二次回归正交设计和方差分析,得出了结构胶3d和28d抗压强度随水胶比、硅灰掺量的变化模型,选择配合比较为理想的结构胶进行植筋验证试验,研究表明硫铝酸盐水泥基结构加固胶满足植筋要求.     

装配式混凝土结构用高性能钢筋套筒灌浆料制备及性能研究

采用快硬硫铝酸盐水泥、硅酸盐水泥和石膏三元胶凝材料复配体系,制备高性能微膨胀钢筋套筒灌浆料,研究了硫铝酸盐水泥与硅酸盐水泥复配比例、水胶比、硅灰掺量、骨料品种对灌浆料流动性和力学性能的影响。结果表明:硫铝酸盐水泥与硅酸盐水泥复配能提高灌浆料的早期抗压强度,当复配比例为2∶8时,1、3 d抗压强度分别达到35.7、61.7 MPa;随水胶比增大,灌浆料流动度增大,抗压强度下降,水胶比为0.26时,灌浆料的初始流动度为335 mm,1、3、28 d抗压强度分别为36.0、61.7、90.6 MPa;适量硅灰能提高灌浆料强度,硅灰掺量为3.0%时,各龄期抗压强度最高,1、3、28 d抗压强度分别为36.9、63.6、92.1 MPa。     

不同掺量改性组分对硫铝酸盐灌浆水泥性能的影响

本文简要介绍了灌浆材料,主要针对目前遇到的问题和满足灌浆注浆的要求,分别以快硬硫铝酸盐水泥和硅酸盐水泥为基础,加入粉煤灰、硅灰、偏高岭土等改性优化组分,以及掺加少量减水剂和消泡剂设计不同的原料配比,配制出灌浆水泥。并对其物理力学性能、流动度和泛霜程度进行研究,通过试验结果得出了最优配料方案：水灰比0.7,硫铝酸盐水泥78%、硅灰掺量7%,偏高岭土掺量5%和粉煤灰10%。按此配比设计的硫铝酸盐水泥基灌浆材料流动性、强度和泛霜程度均满足要求。最优配比的硫铝酸盐水泥基灌浆材料的流动性能良好,7d、28d抗折强度和抗压强度满足要求、抗霜性能高。     

不同温度下矿物掺合料对硫铝酸盐水泥水化的影响

研究了20℃、35℃、50℃养护条件下硅灰和矿粉对硫铝酸盐水泥水化的影响,分析了抗压强度、孔溶液p H值和水化产物的变化规律。结果表明:随着养护温度的升高,掺矿粉和硅灰的硫铝酸盐水泥抗压强度提高,但50℃养护条件下纯硫铝酸盐水泥浆体在28 d的抗压强度有明显倒缩现象,是由于高温下水化产物分解所致;掺入硅灰可以有效改善硫铝酸盐水泥后期抗压强度倒缩问题,掺入矿粉由于其细度和活性的限制改善能力有限。     

硅灰掺量对水泥基灌浆料早期性能的影响研究

通过在水泥基灌浆料中掺加硅灰,研究硅灰掺量对该灌浆料早期性能的影响。试验结果表明,掺加一定量的硅灰可以提高灌浆料的流动度并改善灌浆料的表面状态,从而增加灌浆料的可灌性和密实性,并能够明显提高灌浆料的抗折强度和抗压强度,当硅灰掺量为2%时,和未掺加硅灰相比,灌浆料1d和3d抗折强度分别增加43%和22%,1d和3d抗压强度分别增加50%和73%。     

矿物掺合料对硫铝酸盐水泥-普通硅酸盐水泥复合体系性能的影响

研究了矿粉、硅灰和粉煤灰3种矿物掺合料对硫铝酸盐水泥-普通硅酸盐水泥复合体系的标准稠度用水量、凝结时间、水化放热、胶砂抗折及抗压强度、砂浆干缩率、抗硫酸盐侵蚀性能和水化产物的影响。结果表明:随矿物掺合料掺量的增加,复合体系的标准稠度用水量增大,凝结时间延长;掺加矿物掺合料后水化放热峰出现时间延后,总水化放热量减少,其中掺加矿粉和硅灰的试件初期水化速率减慢程度较掺加粉煤灰试件更明显;3种矿物掺合料对复合体系强度的影响差别较大,掺加3%硅灰的试件3 d抗压强度增长较快;硅灰的掺加会使砂浆干缩率增大,矿粉、粉煤灰的掺加可以减小砂浆试件的干缩;矿物掺合料的掺加会提高胶砂试件抗硫酸盐侵蚀性能,掺粉煤灰的试件抗硫酸盐侵蚀性能最好。     

高活性偏高岭土微粉的制备及复合效应的研究

本文研究了高活性偏高岭土(MK)微粉的制备及与多种矿物掺料复合效应。以10％MK替代水泥，28d抗压强度提高约10MPa；以8％MK取代水泥配制高性能混凝土，其作用效果与硅灰相当，与矿渣基复合掺料复合(8％MK与35％复合矿渣替代水泥)掺入混凝土中，使混凝土物理、力学性能优干硅灰相同掺量的复合效果；与粉煤灰复合，可以使水泥标准稠度用水量降低，抗折、抗压强度提高，干缩率减少。     

Compressive strength and stability of sustainable self-consolidating concrete containing fly ash,silica fume,and GGBS

This paper presents the findings of an experimental program seeking to understand the effect of mineral admixtures on fresh and hardened properties of sustainable self-consolidating concrete (SCC) mixes where up to 80% of Portland cement was replaced with fly ash, silica fume, or ground granulated blast furnace slag. Compressive strength of SCC mixes was measured after 3, 7, and 28 days of moist curing. It was concluded in this study that increasing the dosage of fly ash increases concrete flow but also decreases segregation resistance. In addition, for the water-to-cement ratio of 0.36 used in this study, it was observed that the compressive strength decreases compared to control mix after 28 days of curing when cement was partially replaced by 10%, 30%, and 40%of fly ash. However, a fly ash replacement ratio of 20% increased the compressive strength by a small margin compared to the control mix. Replacing cement with silica fume at 5%, 10%, 15%, and 20% was found to increase compressive strength of SCC mixes compared to the control mix. However, the highest 28 day compressive strength of 95.3 MPa occurred with SCC mixes in which 15% of the cement was replaced with silica fume.     

硅灰和偶联剂对PB-g-PS胶乳改性水泥砂浆的性能影响

质量比为50/50的聚丁二烯接枝聚苯乙烯(PB-g-PS)胶乳用于改性水泥砂浆。考察了硅灰和偶联剂含量对胶乳改性水泥砂浆的流动度、抗压和抗折强度以及吸水量的影响。研究表明:改性砂浆的流动度随偶联剂含量的增加而增加,随硅灰的含量增加而降低;适量偶联剂和硅灰能降低改性砂浆的毛细孔吸水量;胶乳的加入使抗压强度降低,部分改性砂浆的抗折强度有所提高,偶联剂和硅灰的加入极大地改善了砂浆的力学性能,改性砂浆的抗压、抗折强度最大值分别为31.25、8.18 MPa。利用SEM观察了改性砂浆的结构,改性砂浆结构更加致密,界面结构得到改善,并观察到了带状和树枝状的聚合物膜结构。综上所述,硅灰、偶联剂和胶乳三者可以复合改性水泥砂浆。     

掺稻壳灰/硅灰混凝土的性能研究

研究了稻壳灰、硅灰、稻壳灰+粉煤灰、硅灰+粉煤灰对混凝土抗压强度、抗折强度、抗硫酸侵蚀能力和抗碳化能力的影响.结果表明:掺加5％～10％稻壳灰或硅灰有助于提升混凝土的抗压强度和抗折强度,且稻壳灰、硅灰掺量越高抗压强度越高,掺硅灰混凝土相对于掺稻壳灰混凝土的抗压和抗折强度更高,掺稻壳灰+粉煤灰、硅灰+粉煤灰试件的抗压和抗...     

Influence of dry and wet curing conditions on compressive strength of silica fume concrete

This paper reports a part of an ongoing laboratory investigation in which the compressive strength of silica fume concrete is studied under dry and wet curing conditions. In the study, a total of 48 concretes, including control Portland cement concrete and silica fume concrete, were produced with four different water–cement ratios (0.3, 0.4, 0.5, 0.6), three different cement dosages (350, 400, 450 kg/m³) and three partial silica fume replacement ratios (10%, 15%, 20%). A hyperplastisizer was used in concrete at various quantities to provide and keep a constant workability. Three cubic samples produced from fresh concrete were demoulded after a day; then, they were cured at 20±2 °C with 65% relative humidity (RH), and three other cubic samples were cured at 20±2 °C with 100% RH until the samples were used for compressive strength measurement at 28 days. The comparison was made on the basis of compressive strength between silica fume concrete and control Portland cement concrete. Silica fume concretes were also compared among themselves. The comparisons showed that compressive strength of silica fume concrete cured at 65% RH was influenced more than that of Portland cement concrete. It was found that the compressive strength of silica fume concrete cured at 65% RH was, at average, 13% lower than that of silica fume concrete cured at 100% RH. The increase in the water–cementitious material ratios makes the concrete more sensitive to dry curing conditions. The influence of dry curing conditions on silica fume concrete was marked as the replacement ratio of silica fume increased.     

Effect of electric arc furnace dust on the properties of OPC and blended cement concretes

This paper presents results of a study conducted to evaluate the mechanical properties and durability characteristics of ordinary Portland cement (OPC) and blended cement (silica fume and fly ash) concrete specimens prepared with electric arc furnace dust (EAFD). Concrete specimens were prepared with and without EAFD. In the silica fume cement concrete, silica fume constituted 8% of the total cementitious material while fly ash cement concrete contained 30% fly ash. EAFD was added as 2% replacement of cement in the OPC concrete and 2% replacement of the total cementitious content in the blended cement concretes. Mechanical properties, such as compressive strength, drying shrinkage, initial and final setting time, and slump retention were determined. The durability characteristics were evaluated by measuring water absorption, chloride permeability, and reinforcement corrosion. The initial and final setting time and slump retention increased due to the incorporation of EAFD in both OPC and blended cement concretes. The drying shrinkage of EAFD cement concrete specimens was more than that of concrete specimens without EAFD. The incorporation of EAFD was beneficial to OPC concrete in terms of strength gain while such a gain was not noted in the blended cement concretes. However, the strength differential between the blended cement concretes with EAFD and the corresponding concretes without EAFD was not that significant. The water absorption and chloride permeability, however, decreased due to the incorporation of EAFD in both the OPC and blended cement concretes. The corrosion resistance of OPC and blended cement concrete specimens increased due to the addition of EAFD.     

轻质多孔烧结材料的试验研究

以赤泥、粉煤灰、石英砂等为主要原料,掺加一定量的泡沫,经可塑成型、煅烧等工艺制备了一种轻质多孔烧结材料。研究煅烧温度对其抗折、抗压强度、收缩率等性能的影响;利用扫描电子显微镜对其进行微观形貌分析,探讨其烧结机理。结果表明,最佳烧结温度为1150℃,最佳试样的体积密度为691kg/m3,抗压、抗折强度分别为4.2MPa和3.2MPa,导热系数为0.110W/(m·K),烧成收缩率为3.9%。