共查询到20条相似文献,搜索用时 0 毫秒
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《Advanced Powder Technology》2022,33(12):103848
The suppression mechanism of NaHCO3 on micron/nano PMMA dust cloud flame based on thermal analysis was investigated. The results showed that the pyrolysis oxidation processes of 30 μm and 100 nm PMMA dusts were suppressed by NaHCO3, and the apparent activation energy E and pre-exponential factor A were increased. The flame combustion intensity and propagation velocity of both micro and nano PMMA dusts were decreased obviously. Compared with 30 μm PMMA, NaHCO3 maintained an efficient suppression on 100 nm PMMA with the mass ratio of NaHCO3 increased with no suppression saturation phenomenon appeared. And 100 nm PMMA were more sensitive to particle size of NaHCO3. In the flame preheat zone, the suppression effect of NaHCO3 was mainly dominated by physical suppression, including the cooling effect of both pyrolysis reaction and products and the dilution effect on the concentration of combustible reactant. In the combustion reaction zone, the suppression effect of NaHCO3 was mainly dominated by chemical suppression. The free radicals were absorbed by the active groups NaOH, forming the Na?NaOH suppression cycle. The E of nano PMMA dust flame was sustainably increased in both preheat and combustion reaction zones, contributing to the continuous high efficiency suppression and the sensitiveness to the particle size of explosion suppressant. 相似文献
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《Advanced Powder Technology》2014,25(2):710-715
Circulating Fluidized Beds are increasingly used in gas–solid and gas–catalytic reactions. A recent development involves their use in physical gas–solid processes such as drying, VOC adsorption or solar energy capture and storage. The heat transfer from the wall of the CFB to the flowing gas–solid suspension is the major design parameter, and was studied for different powders at different operating conditions as determined by the gas velocity and solids circulation flux. Measured values of the heat transfer coefficients are discussed, and compared with empirical predictions of Molodtsof–Muzyka, and Gorliz–Grace. Whereas Gorliz–Grace predicts heat transfer coefficients correctly within a narrow range of operating conditions only, the Molodtsof–Muzyka approach can be simplified into a linear relationship. 相似文献
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Leonid Victorovich Abdurakhimov Maxim Yurievich Brazhnikov Alexander Alexeevich Levchenko 《Journal of Low Temperature Physics》2008,150(3-4):431-434
Excitation of the surface of liquid hydrogen by a harmonic force at low frequencies leads to the formation of turbulent cascade in the system of capillary waves. We have found that the probability density function for a high-frequency surface deviation from equilibrium state in the regime of developed turbulence is well approximated by the Gaussian distribution. 相似文献
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介绍一起液氧内压缩流程中液氧泵回流阀爆裂事故的经过和破坏情况,初步认为事故的原因可能是阀门制造缺陷导致升压过程中上阀体破裂后高压液氧泄漏,进而引发化学性爆炸。最后提出了防止液氧泵回流阀燃爆的预防措施。 相似文献
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Katsuhide Ohira 《低温学》2004,44(1):59-68
Slush hydrogen is a two-phase solid-liquid cryogenic fluid consisting of solid hydrogen particles in liquid hydrogen. Compared to liquid hydrogen, the density is about 16% greater at a solid mass ratio (solid fraction) of 50%, and the cryogenic heat capacity (enthalpy) is about 18% higher. Various applications are anticipated, including fuel for reusable space shuttles, coolant for cold neutron generation, as well as the transport and storage of hydrogen as a clean energy source. At a solid fraction of within 50%, piped transport can be conducted in the same way as for normal fluids. This paper reports on the slush hydrogen technology in terms of the measurement of the density and the mass flow rate. 相似文献
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采用安全系统工程的方法 ,对液氧贮槽爆炸进行了事故树分析 ,通过求事故树最小割集 ,进行结构重要度分析 ,从而对液氧贮槽爆炸的事故原因进行分析、预测 ,并提出了相应的预防控制措施 相似文献
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《低温学》2015
In this paper we present the development of a new hybrid energy transfer line with 30 m length. The line is essentially a flexible 30 m hydrogen cryostat that has three sections with different types of thermal insulation in each section: simple vacuum superinsulation, vacuum superinsulation with liquid nitrogen precooling and active evaporating cryostatting (AEC) system. We performed thermo-hydraulic tests of the cryostat to compare three thermo-insulating methods. The tests were made at temperatures from 20 to 26 K, hydrogen flow from 70 to 450 g/s and pressure from 0.25 to 0.5 MPa. It was found that AEC thermal insulation was the most effective in reducing heat transfer from room temperature to liquid hydrogen in ∼10 m section of the cryostat, indicating that it can be used for long superconducting power cables. High voltage current leads were developed as well. The current leads and superconducting MgB2 cable passed high voltage DC test up to 50 kV DC. Critical current of the cable at ∼21 K was 3500 A. It means that the 30 m hybrid energy system developed is able to deliver ∼50–60 MW of chemical power and ∼50–75 MW of electrical power, i.e. up to ∼135 MW in total. 相似文献
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LNG容器蒸气膨胀爆炸特性研究 总被引:3,自引:0,他引:3
对液化天然气容器机械破损后的液体过热汽化建立了非平衡相变模型.根据非平衡相变理论,讨论了蒸气膨胀爆炸的过减压极限,并按照气泡半径是否超过临界半径,把气泡的增长分成了束缚和逃逸两个时区,分时区讨论了系统各物理量的变化.通过对液化天然气典型储运工况的计算,得出了不同条件下的过减压极限、压力下降及反弹演化过程,状态参量核化速率的变化过程及最大超压.分析了蒸气膨胀爆炸的基本特性:快速显著核化和沸腾延迟,以及初始条件、损口面积和容器尺度等对物理过程的影响. 相似文献
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《低温学》2017
This paper presents experiments and modeling of the most recent set of liquid acquisition device (LAD) vertical outflow tests conducted in liquid hydrogen. The Engineering Development Unit (EDU) was a relatively large tank (4.25 m3) used to mimic a storage tank for a cryogenic storage and transfer flight demonstration test. Six 1-g propellant tank outflow tests were conducted with a standard 325 × 2300 rectangular cross-section curved LAD channel conformal to the tank walls over a range of tank pressure (158–221 kPa), ullage temperature (22–39 K), and mass flow rate (0.0103–0.0187 kg/s) per arm. An analytical LAD channel solver, an exact solution to the Navier-Stokes equations, is used to model propellant outflow for the LAD channel. Results shows that the breakdown height of the LAD is dominated by liquid and ullage gas temperatures, with a secondary effect of flow rate. The best performance is always obtained by exposing the channel to cold pressurant gas and low flow rates, consistent with the cryogenic bubble point model. The model tracks the trends in the data and shows that the contribution of flow-through-screen pressure drop is minimized for bottom outflow in 1-g, versus the standard inverted outflow. 相似文献
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《低温学》2017
Superconducting coils in AC application, such as in the stator of superconducting motors, have losses which warm up the coil and so limit the performance. Good thermal contact between the coil and the cooling agent is important. In this research we investigate the possibility of cooling the coils by a cryoliquid, such as liquid hydrogen or liquid nitrogen, flowing through capillaries in thermal contact with the coils. 相似文献
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Biogas is considered as a valuable source of renewable energy. Indeed, it can be turned into useful energy (heat, electricity, fuel) and can contribute to reduce greenhouse gas emissions. Knowledge of its safety characteristics is a very important practical issue. Experimental investigation of synthesised biogas explosion characteristics was conducted in a 20-L sphere at various temperatures (30-70 degrees C) and at atmospheric pressure. The studied biogas was made of 50% methane (CH(4)) and 50% carbon dioxide (CO(2)). It was also saturated with humidity: this composition is frequently met in digesters during waste methanisation. There are two inert gases in biogas: water vapour and carbon dioxide. Its vapour water content rises along with temperature. The presence of these inert gases modifies considerably biogas characteristics compared to the ones of pure methane: explosion limits are lowered and beyond 70 degrees C, water vapour content is sufficient to inert the mixture. Furthermore, explosion violence (estimated with the maximum rate of pressure rise values, (dp/dt)(max)) is three times lower for biogas than for pure methane at ambient temperature. 相似文献