聚合物SiON波导的可变光衰减器性能研究

利用弯曲聚合物SiON波导设计了一种新型可变光衰减器,该器件由输入、输出直波导,S型的弯曲波导,以及在聚合物SiON波导弯曲部位镀上的电极组成.通过外加电场的作用来调节波导覆盖层的折射率,从而达到衰减波导中光能量的目的.现采用光束传播法(BPM)对设计的新型光衰减器进行了仿真设计,结果表明,设计的光衰减器具有大的动态可调衰减范围(45.3 dB),低的插入损耗(0.8 dB).     

Ultrasensitive thermal sensors based on whispering gallery modes in a polymer core optical ring resonator

This study proposes a thermal sensor based on whispering gallery modes (WGMs) in a polymer core optical ring resonator (PCORR). The thermal sensitivity and detection limit (i.e., the temperature resolution) for WGMs of various orders and polarizations are theoretically studied as a function of the ring wall thickness. The results show that the temperature detection limits can be as low as 4×10(-5) and 6×10(-6) K for laser linewidths of 2 and 0.3 MHz, respectively. The ultrahigh temperature resolution makes the PCORR a very promising platform for temperature measurement. The analysis also shows that the WGM of a lower order has better thermal sensing performance and a thinner optimal thickness of the ring resonator.     

Dispensed polymer waveguides and laser-fabricated couplers for optical interconnects on printed circuit boards

Optical interconnects can provide chip-to-chip data communication with much needed bandwidth as processor speed and density keep growing. Optical waveguides and couplers are essential components for implementing optical interconnections. Techniques for directly dispensing polymer waveguides in laser-ablated trenches on printed circuit boards and for fabricating optical couplers are presented for quick prototype of optical interconnects. High-quality UV curable polymer waveguides were routinely fabricated. High-efficiency couplers, blazed grating couplers on sloped waveguides, sloped facet metal film couplers, and reflective-undercut facet couplers can be fabricated by using excimer laser ablation.     

Fan-out routing and optical splitting techniques for compact optical interconnects using single-mode polymer waveguides

Polymer waveguide (WG) S-bends are necessary for fan-out routing techniques and optical splitting in high-density optical interconnects. Designing and manufacturing of optimal S-bends are critical for minimizing optical link loss while maintaining overall size and layout constraints. Complete structural loss analysis is demonstrated theoretically and shown experimentally utilizing both radial and transitional loss in single-mode (SM) polymer WG radial arc, cosine, and raised-sine S-bend profiles. SM polymer WG straights were first fabricated to measure standard propagation loss. SM WG S-bends were fabricated incorporating straight lead-in and lead-out sections to incorporate transitional loss present in workable designs. S-bend designs were measured at different dimensions and matched to theoretical losses. Compact cosine and radial arc S-bends exhibited the lowest structure loss for low and high NA WGs, respectively. High-speed performance of SM WG straights and S-bends was measured at 10 Gbit/s demonstrating low error rate. Optical splitters designed with S-bends and tapers were also evaluated and fabricated. Trade-off between optimal loss and minimal device size is discussed.     

Fully microfabricated and integrated SU-8-based capillary electrophoresis-electrospray ionization microchips for mass spectrometry

We present a fully microfabricated and monolithically integrated capillary electrophoresis (CE)-electrospray ionization (ESI) chip for coupling with high-throughput mass spectrometric (MS) analysis. The chips are fabricated fully of a negative photoresist SU-8 by a standard lithographic process which enables straightforward batch fabrication of multiple chips with precisely controlled dimensions and, thus, reproducible analytical performance from chip to chip. As the coaxial sheath flow interface is patterned as an integral part of the SU-8 chip, the fluidic design is dead-volume-free. No significant peak broadening occurs so that very narrow peak widths (down to 2-3 s) are obtained. The sheath flow interface also enables comprehensive optimization of both the CE and the ESI conditions separately so that the same chip design is adaptable to diverse analytical conditions. Plate numbers of the order of 105 m-1 and good resolution are routinely reached for small molecules and peptides within a 2 cm separation length and a typical cycle time of only 30-90 s per sample. In addition, a limit of detection of 100 nM corresponding to a total amount of only 4.5 amol (per injection volume of 45 pL) and excellent quantitative linearity (R2 = 0.9999; 100 nM to 100 microM) were obtained in small-molecule analysis using verapamil as a test compound. The quantitative repeatability was proven good (8.5-21.4% relative standard deviation, peak area) also for the other drug substances and peptides tested.     

Nonlinear optical properties and thermal stability of the poled polymer NTAB/PEK-c

Films of high glass transition temperature polymer polyetherketone doped with chromophore 2,2′-[4-[(5-nitro-2-thiazolyl)azophenyl]-amino]-bisethanol (NTAB) were prepared, poled by the corona-onset poling setup which includes a grid voltage making the surface-charge distribution uniform at elevated temperature. The thickness of the films was measured by the Model 2010 Prism Coupler system. Second harmonic generation d₃₃ was measured by the second harmonic generation method, and the d₃₃ is 38.12 pm/V at 1064 nm under the absorption correction. The nonlinear optical activity maintains 80% of its initial value.     

Preparation of a new electro-optic polymer cross-linkable via copper-free thermal Huisgen cyclo-addition and fabrication of optical waveguides by Reactive Ion Etching

High-quality trails of ridge waveguides were successfully fabricated using a new cross-linkable polymer (PCC01) by UV photolithography followed by Reactive-Ion Etching (RIE) process. The cross-linking reaction of PCC01 is based on the copper-free Huisgen cyclo-addition between an azide and an acetylene group. The new cross-linkable polymer (PCC01) consists of a structural modification of the previously described materials (Scarpaci et al. Polym. Chem.2011, 2, 157), because the ethynyl group is functionalized by a methyl group instead of the TMS protecting group. This feature prevents the formation of silica (SiO(2)) generated by trimethylsilyl groups and which was stopping the engraving process before completion. Herein, we describe the synthesis, the NLO characterizations, and the fabrication of a high-quality ridge waveguide with PCC01. The new cross-linkable polymer PCC01 not only solves the problems encountered with our previously described polymers, but also presents an enhancement of the electro-optic stability, because d(33) coefficients up to 30 pm/V stable at 150 °C were recorded.     

Ultraviolet photobleaching process of azo dye doped polymer and silica films for fabrication of nonlinear optical waveguides

We describe the effect of UV photobleaching of poled polymer and silica films and the application of UV photobleaching to waveguide-type optical devices. Disperse Red 1-doped poled polymer and silica films with large and stable second-order nonlinearity were used as nonlinear optical materials. We investigated the mechanism of UV photobleaching of poled films by the changes in absorption spectrum and nonlinearity and refractive index. Moreover, simple fabrication of both the channel waveguide and the chi((2)) diffraction grating based on UV photobleaching is demonstrated.     

Plasticizer-free polymer containing a covalently immobilized Ca2+-selective ionophore for potentiometric and optical sensors

A derivative of a known Ca2+-selective ionophore, ETH 129, was synthesized to contain a polymerizable acrylic moiety (AU-1) and covalently grafted into a methyl methacrylate-co-decyl methacrylate polymer matrix. The polymer containing AU-1 was prepared via a simple one-step homogeneous polymerization method. It exhibited mechanical properties suitable for the fabrication of plasticizer-free ion-selective membrane electrodes and bulk optode films by solvent-casting and spin-coating techniques, respectively. The segmented sandwich membrane technique was utilized to assess the binding constant of free and covalently bound ionophores to calcium and to study their diffusion coefficients in the membrane phase. Diffusion was greatly diminished for the bound ionophore. This was confirmed in ion-selective electrode membranes containing no calcium ions in the inner solution, which should normally show apparent super-Nernstian response slopes in dilute calcium solutions. The response slope was Nernstian down to submicromolar concentration levels, indicating slow mass transport of calcium in the membrane. Optical-sensing films with the new copolymer matrix, unblended and blended with PVC-DOS, also confirmed that covalently bound ionophores are fully functional for maintaining selective ion extraction and binding properties of the sensing membrane.     

Mechanisms of pulsed laser microbeam release of SU-8 polymer "micropallets" for the collection and separation of adherent cells

The release of individual polymer micropallets from glass substrates using highly focused laser pulses has been demonstrated for the efficient separation, collection, and expansion of single, adherent cells from a heterogeneous cell population. Here, we use fast-frame photography to examine the mechanism and dynamics of micropallet release produced by pulsed laser microbeam irradiation at lambda = 532 nm using pulse durations ranging between 240 ps and 6 ns. The time-resolved images show the laser microbeam irradiation to result in plasma formation at the interface between the glass coverslip and the polymer micropallet. The plasma formation results in the emission of a shock wave and the ablation of material within the focal volume. Ablation products are generated at high pressure due to the confinement offered by the polymer adhesion to the glass substrate. The ablation products expand underneath the micropallet on a time scale of several hundred nanoseconds. This expansion disrupts the polymer-glass interface and accomplishes the release of the pallet from its glass substrate on the microsecond time scale (approximately 1.5 micros). Our experimental investigation demonstrates that the threshold energy for pallet release is constant (approximately 2 microJ) over a 25-fold range of pulse duration spanning the picosecond to nanosecond domain. Taken together, these results implicate that pallet release accomplished via pulsed laser microbeam irradiation is an energy-driven plasma-mediated ablation process.     

Side radical influence on the nonlinear optical properties and thermal stability of poled polymer films

Films of polyetherketone doped with the chromophores Disperse Red 1 (DR1) and Disperse Red 13 (DR13) were prepared by spin-coating method. By the in situ Second-harmonic Generation (SHG) signal intensity measurement, the optimal poling temperatures were obtained. For the investigated polyetherketone polymer doped with DR1 (DR1/PEK-c) and polyetherketone polymer doped with DR13 (DR13/PEK-c) films, the optimal poling temperatures were 150°C and 140°C, respectively. Under the optimal poling conditions, the high second-order nonlinear optical coefficient ₃₃ ⁽²⁾ = 11.02 pm/V has been obtained for the DR1/PEK-c; and for DR13/PEK-c at the same conditions the coefficient is 17.9 pm/V. The SHG signal intensity DR1/PEK-c could maintain more than 80% of its initial value when the temperature was under 100°C, and the SHG signal intensity of the DR13/PEK-c could maintain more than 80% of its initial value when the temperature was under 135°C.     

Plasmonic/metallic passive waveguides and waveguide components for photonic dense integrated circuits: a feasibility study based on microwave engineering

To investigate the potential for dense integration of photonic components, we analyse passive plasmonic/ metallic waveguides and waveguide components at optical frequencies by using mostly microwave engineering approaches. Four figures of performance are formulated that are utilised to compare the characteristics of four different slab waveguides with zero frequency cut-off modes. Three of these are metallic based whereas the fourth one, which also serves as a reference, is dielectric based with high index-contrast. It is found that all figures of performance cannot be optimised independently; in particular there is a trade-off between the waveguide Q-value and the transversal field confinement. Microwave methods are used to design several photonic transmission line components. The small Q-value of the metallic waveguides is the main disadvantage when using materials and telecom frequencies of today. Hence plasmonic waveguides do not offer full functionality for some important integrated components, being severe for frequency-selective applications. To achieve a dense integration, it is concluded that new materials are needed that offer Q-values several orders of magnitude higher than metals.     

Hybridized 1T/2H-MoS2/graphene fishnet tube for high-performance on-chip integrated micro-systems comprising supercapacitors and gas sensors

The emerging micro-nano-processing technologies have propelled significant advances in multifunctional systems that can perform multiple functions within a small volume through integration.Herein,we present an on-chip multifunctional system based on a 1T/2H-MoS₂/graphene fishnet tube,where a micro-supercapacitor and a gas sensor are integrated.A hybrid three-dimensional stereo nanostructure,including M0S₂ nanosheets and graphene fishnet tubes,provides K⁺ions with a short diffusion pathway and more active sites.Owing to the large layer spacing of IT-M0S₂ promoting fast reversible diffusion,the on-chip micro-supercapacitor exhibits excellent electrochemical properties,including an areal capacitance of 0.1 F·cm^-2(1 mV·s^-1).The variation in the conductivity of 2H-MoS₂ when ammonia molecules are adsorbed as derived from the first-principles calculations proves the Fermi level-changes theory.Driven by a micro-supercapacitor,the responsivity of the gas sensor can reach 55.7%at room temperature(27℃).The multifunctional system demonstrates the possibility of achieving a two-dimensional integrated system for wearable devices and wireless sensor networks in the future.     

An integrated decision-making approach for designing and selecting product concepts based on QFD and cumulative prospect theory

In this paper, both unbalanced linguistic terms and a risk decision-making problem with developers’ bounded rationality are considered; an integrated approach of Quality Function Deployment (QFD) and Cumulative Prospect Theory (CPT) is proposed to help increase customer satisfaction and facilitate product concepts selection. Firstly, QFD is employed to provide a customer-driven tool for developers, which can be used to generate product concept alternatives. Subsequently, enhanced information entropy is utilised to prioritise competing Customer requirements (CRs) based on unbalanced linguistic terms. These terms can be directly processed without being translated into fuzzy numbers, where the risk of information loss in fuzzification can be minimised. Product concept alternatives can be generated based on the outcomes of the subsequent QFD process. Moreover, CPT can be considered as a novel method by incorporating the developers’ psychological characteristics under risk, which can help identify the most relevant product concepts. The cost prospect values of each alternative can be calculated by the function based on the cost reference point. The deficit and profit prospect values can be obtained by aggregating the values and weights of potential results, where functions from the enhanced CPT are used. The order of all alternatives can be ranked based on their overall prospect values. Finally, the proposed approach can be evaluated by a case study concerning the development of a new hydraulic breaker. The deliverables of this study are used to evaluate the relative advantages of the proposed approach over existing multi-attribute utility ones.     

Dielectric,mechanical and thermal properties of polymer/BaTiO3 composites for embedded capacitor

Barium titanate (BaTiO₃) filled polymethylmethacrylate (PMMA) composites were prepared using the simple solution method followed by hot pressing. The content of BaTiO₃ was varied from 0 to 65 vol.%. Scanning electron microscopy showed good dispersion and adhesion of BaTiO₃ with the PMMA matrix. The dielectric constant of the composites increased significantly. There was weak dispersion in the dielectric constant of the composites (up to 45 vol.%) with frequency between 100 Hz and 15 MHz. The dissipation factor of the composites increased from 0.021 for pure PMMA to 0.029 for 45 vol.% composites. However, 65 vol.% composite showed dispersion in dielectric constant with increasing frequency and higher dissipation factor. The Lichtenecker equation agreed well with the experimental data. The microhardness and the glass transition temperature of the composites increased approximately 4.7-fold and 42 °C, respectively, compared to pure PMMA. The CTE of the 65 vol.% composite is close to that of copper.     

Flammability,thermal and physical-mechanical properties of cationic polymer/montmorillonite composite on cotton fabric

The flammability, thermal and mechanical properties on cotton fabric were improved by being finished with the composite containing montmorillonite. To this aim, polymer dimethyl diallyl ammonium chloride-allyl glycidyl ether (P_DMDAAC-AGE) was prepared and its structure characterized by Fourier transform infrared (FT-IR) and Nuclear magnetic resonance (¹H NMR). The quaternary ammonium salt copolymer/montmorillonite composite (P_DMDAAC-AGE/MMT) was obtained by polymer intercalation method. The X-ray diffraction (XRD) indicated that the MMT interlayer spacing increased after the polymer intercalation. Composite materials were loaded onto the cotton fabrics by a dip-pad-dry method. The thermo gravimetric analysis (TGA), vertical flame test and limiting oxygen index (LOI) results showed that the thermal and flammability properties of the cotton fabric were improved after it was finished with the composite. Tensile testing revealed an increase on mechanical properties of the finished fabric, but the physical properties hardly changed from the bending length and whiteness results. Scanning electron microscope (SEM) and energy disperse X-ray spectroscope (EDX) results verified the improvement of those properties due to the presence of montmorillonite in the composite.     

Nanostructured optical waveguide films of TiO2 and WO3−x for photonic gas sensors

Pulsed laser deposition technique was used to fabricate successfully nanostructured optical waveguide films of TiO₂ and WO_3 − x for gas-sensing applications. High-quality mode spectra, consisting of well-defined bright mode lines were observed in the samples with smooth surface. Films' structural, morphological and optical properties as well as the chemical composition were investigated by using x-ray diffraction, scanning electron and atomic force microscopy, UV-VIS-NIR, m-line and x-ray photoelectron spectroscopy, respectively.Gas sensitivity was investigated at room temperature using m-line spectroscopy technique on basis of reversible variations of the refractive index of the samples under gas exposure. Testing scheme recording the bright m-line shift as optical response was proposed.     

All-conjugated amphiphilic diblock copolymers for improving morphology and thermal stability of polymer/nanocrystals hybrid solar cells

Herein, the ability to optimize the morphology and photovoltaic performance of poly(3-hexylthiophene) (P3HT)/ZnO hybrid bulk-heterojunction solar cells via introducing all-conjugated amphiphilic P3HT-based block copolymer (BCP), poly(3-hexylthiophene)-block-poly(3-triethylene glycol-thiophene) (P3HT-b-P3TEGT), as polymeric additives is demonstrated. The results show that the addition of P3HT-b-P3TEGT additives can effectively improve the compatibility between P3HT and ZnO nanocrystals, increase the crystalline and ordered packing of P3HT chains, and form optimized hybrid nanomorphology with stable and intimate hybrid interface. The improvement is ascribed to the P3HT-b-P3TEGT at the P3HT/ZnO interface that has strong coordination interactions between the TEG side chains and the polar surface of ZnO nanoparticles. All of these are favor of the efficient exciton dissociation, charge separation and transport, thereby, contributing to the improvement of the efficiency and thermal stability of solar cells. These observations indicate that introducing all-conjugated amphiphilic BCP additives can be a promising and effective protocol for high-performance hybrid solar cells.     

Overheating effects on thermal stability and mechanical properties of Cu36Zr48Ag8Al8 bulk metallic glass

A pronounced effect of overheating is observed on the thermal stability and mechanical properties of Cu₃₆Zr₄₈Ag₈Al₈ bulk metallic glass. Higher overheated temperature enhances the thermal stability of bulk amorphous alloys, corresponding to higher specific-heat capacity and the smaller initial defect concentration. And a threshold overheating temperature is found for the fully amorphous structure. Bulk amorphous alloys exhibit good compressive plasticity at small overheat levels, whereas the compressive fracture strength and micro-hardness exhibit a significant increase first and then a slightly decrease. Mechanical properties of BMGs can be tailored in certain extent by controlling the overheated level, which is correlated with free volume and residual stresses.