Using hybrid modeling for life cycle assessment of motor bike and electric bike

Life-cycle assessment (LCA) is environmental evaluation of products, materials, and processes over their life cycle. Truncation uncertainty and corresponding uncertainty are main problems occurred in process life cycle assessment (PLCA) modeling and economic input-output life cycle assessment (EIOLCA) modeling. Through combination of these two modelings in different life cycle stage and use of an uncertainty reduction strategy, a hybrid life cycle assessment modeling method was proposed in this study. Case studies were presented on gasoline-powered motorbikes (M-bike) and electricity-powered electric bike (E-bike). Web-based software was developed to analyze process environmental impacts. Results show that the largest part of life cycle energy (LCE) is consumed at use stage. Less energy is consumed in life cycle of E-bike than that of M-bike. GWP (Global Warming Potential), CO (Carbon Monoxide), PM10 (particulate matter) emission of M-bike are higher than that of E-bike, especially at use stage, AP (acidification Potential) emission of E-bike is higher than that of M-bike. Comprehensively, E-bike is energy efficient and less emitting, and better choice for urban private transportation.     

Decision-making of biomass ethanol fuel policy based on life cycle 3E assessment

To evaluate the environmental, economic, energy performance of biomass ethanol fuel in China and to support the decision-making of biomass ethanol energy policy, an assessment method of life cycle 3E (economy, environment, energy) was applied to the three biomass ethanol fuel cycle alternatives, which includes cassava-based, corn-based and wheat-based ethanol fuel. The assessments provide a comparison of the economical performance, energy efficiency and environmental impacts of the three alternatives. And the development potential of the three alternatives in China was examined. The results are very useful for the Chinese government to make decisions on the biomass ethanol energy policy, and some advises for the decision-making of Chinese government were given. Foundation item: Project (50175070) supported by the National Natural Science Foundation of China; Project (G-0205-06347) supported by European Commission Funding     

Synthesis and photophysical and electrochemical properties of new cyclometalated platinum complex containing oxadiazole ligand

A new cyclometalated platinum complex containing 2, 5-bis（naphthalene-1-yl）-1,3,4-oxadiazole ligand was synthesized and characterized. The UV-Vis absorptions and photoluminescent properties of the ligand and its platinum complex were investigated A characteristic metal-ligand charge transfer absorption peak at 439 nm in the UV spectrum and a strong emission peak at 625 nm in the photoluminescence spectrum were observed for this complex in dichloromethane. Cyclic voltammtry （CV） analysis shows that the EHOMO （energy level of the highest occupied molecular orbital） and ELUMO （energy level of the lowest unoccupied molecular orbital） of the platinum complex are about -5.69 and -3.25 eV, respectively, indicating that the oxadiazole-based platinum complex has a potential application in electrophosphorescent devices used as a red-emitting material.     

Life cycle inventory analysis of CO_2 and SO_2 emission of imperial smelting process for Pb-Zn smelter

1　INTRODUCTIONImperialSmeltingProcess (ISP) ,isaprocessavailableforproductionofzincandlead .Atpresent,about 13operatingISPsmeltersproduceabout 13%ofglobalzincandlead[1] .ButISPisasignificantcontributortoindustrialgreenhouseandacidityemis sionsduetoitshighenergyconsumption .Althoughcellemissionshavebeenreducedconsiderablyinre centyears ,thegrowingglobalconcernonenviron mentalissuesisimposingpressureontherelatedcom paniestoreducetheiremissions .Becauseofthelargenumberoffeedstreams ,by…     

城市客运交通碳排放水平估算及低碳途径——以天津市为例

从生命周期的角度,对城市客运交通各种出行方式进行碳排放计量.在明确了碳排放计量标准的基础上,以小汽车出行方式为例,对确定分析系统的边界、进行清单分析以及建立计算模型3个步骤进行了说明,分析了小汽车出行方式生命周期内温室气体的排放情况及其演化过程.此外,对比了自行车、电动自行车、常规公交、地铁、出租车以及小汽车出行方式之间温室气体单位里程的排放情况.提出了城市低碳交通发展途径,结合问卷调查和多项Logit模型对行政管理政策和定价收费政策进行了定量研究.     

Life cycle of remanufactured engines

The life cycle index of remanufactured engines was assessed by using the method of life cycle assessment (LCA). A remanufactured engine of a certain domestic brand was taken as researching object. Engine reproducing engineering was investigated from three aspects which were energy, material and environment. The application of LCA on remanufacturing engines was discussed in detail with a practical case. The results indicate that remanufacturing an engine can save 55 kg steels, 8.3 kg aluminum and 113 kW · h electric powers and reduce emissions of 565 kg CO₂, 6.09 kg CO, 1.01 kg NO _x , 3.985 kg SO _x and 288.725 kg solid waste. The remanufacturing of engines possesses great economic value and practicability. Foundation item: Project (50235030) supported by the National Natural Science Foundation of China     

Developing remanufacturing engineering, constructing cycle economy and building saving-oriented society

In the course of creating immense wealth, manufacturing industry has excessively consumed the resources and energy in the earth, and seriously polluted the environment. To take progress as the sustainable development way, save resource and improve environment, our nation has been advocating to construct the cycle economy and saving-oriented society. Taking the remanufacturing engineering as the representative, the “4R” rule (Reduce, Reuse, Recycle and Remanufacture) is the important measure to get the goal. Remanufacturing engineering is the industrialization of high-tech maintenance of the waste and worn productions, and is one of the most active factors in “4R”. The development of high and new technology takes the important effect to promote the remanufacturing engineering. Foundation item: Project (50235030) supported by the National Natural Science Foundation of China     

Benefit analysis and contribution prediction of engine remanufacturing to cycle economy

The first automobile engine remanufacture company in China, Jinan Fuqiang Power Co, Ltd, was introduced. The engine remanufacturing technological process of this company was described. The benefit statistic of remanufacturing 10 000 Styer engines were analyzed, and the contribution of engine remanufacturing to cycle economy was predicted. The results show that remanufacturing engineering could use the maximal additional values of obsolete engines, and make contributions to materials conservation, capital saving, energy conservation and environment protection. 10 000 engines are supposed to be remanufactured per year, the following benefits would be obtained: reclaiming additional values of RMB3.23 hundred million, saving metallic materials about 7.65 thousand tons, saving energy of 16 million kilowatt-hours, reducing emission of CO₂ about 11.3–15.3 thousand tons, and providing employment for 500 persons. According to the survey and analysis, tremendous benefits will be gained by the year of 2020. For example, reclaiming additional values per year of 1424–2236 hundred million RMB, saving energy per year of 60–90 hundred million kilowatt-hours, reducing emission of CO₂ about 6.67–9.69 million tons. It can be deduced that developing remanufacturing will play an important role in enriching the cycle economy and accelerating the development of national economy. Foundation item: Key Project(50235030) supported by the National Natural Science Foundation of China     

Recycling process assessment of mechanical recycling of printed circuit board

A comprehensive assessment index system was established. The mechanical recycling process of printed circuit board was evaluated according to the comrehensive evaluation index system using the fuzzy analytic hierarchy process. A process assessment software system of mechanical recycling was established to evaluate different recycling technologies. And the software system was developed in the environment of VB 6.0 and Access 2000. Foundation item: Project (50375044) supported by the National Natural Science Foundation of China; project (05021008) supported by Annual Emphasis Project of Anhui Province     

Life cycle inventory analysis of CO2 and SO2 emission of imperial smelting process for Pb-Zn smelter

Based on the principle of life cycle assessment, CO₂ and SO₂ emission of Imperial Smelting Process in a certain zinc-lead smelter was analyzed by life cycle inventory method. According to the system expansion and substitution method, the environmental impacts of co-products were allocated among the main products of zinc, lead and sulfuric acid. The related impacts were assessed by use of Global Warming Potential (GWP) and Acidification Potential (ACP). The results show that the GWP index from 1998 to 2000 is 11.53, 11.65, 10.93 tCO₂-eq/tZn respectively, the ACP index decreases from 14.88 kgSO₂-eq/tZn in 1998 to 10.99 kgSO₂-eq/tZn in 2000. Power and electricity generation, followed by smelting and zinc distillation, are mainly responsible for GWP. Sintering individually affects ACP. Reduction in greenhouse gas emissions of the ISP may come from energy conservation measures rather than from technological developments. And recycling more secondary Pb and Zn materials effectively treated by ISP, and reducing the amount of primary metal are the main ways to put SO₂ emission under control. Biography of the first author: LI Qi-hou, postdoctor, born in Aug. 1972, majoring in ecodesign and the structure and morphology control of powders.     

Application of empirical mode decomposition based energy ratio to vortex flowmeter state diagnosis

To improve the measurement performance, a method for diagnosing the state of vortex flowmeter under various flow conditions was presented. The raw sensor signal of the vortex flowmeter was adaptively decomposed into intrinsic mode functions using the empirical mode decomposition approach. Based on the empirical mode decomposition results, the energy of each intrinsic mode function was extracted, and the vortex energy ratio was proposed to analyze how the perturbation in the flow affected the measurement performance of the vortex flowmeter. The relationship between the vortex energy ratio of the signal and the flow condition was established. The results show that the vortex energy ratio is sensitive to the flow condition and ideal for the characterization of the vortex flowmeter signal. Moreover, the vortex energy ratio under normal flow condition is greater than 80%, which can be adopted as an indicator to diagnose the state of a vortex flowmeter. Foundation item: Project(200801346) supported by the China Postdoctoral Science Foundation; Project(2008RS4022) supported by the Hunan Postdoctoral Scientific Program; Project(2008) supported by the Postdoctoral Science Foundation of Central South University     

Fluorescence spectroscopy characteristics of humic acid by inoculating white-rot fungus during different phases of agricultural waste composting

The white-rot fungus, Phanerochaete chrysosporium (P. chrysosporium), was inoculated during different phases of agricultural waste composting, and its effect on the fluorescence spectroscopy characteristics of humic acid (HA) was studied. The results show that the emission spectra have a sharp peak at 400 nm and a broad shoulder with the maximum centered at 460 nm. The excitation spectra have two peaks and exhibit red shift (shift to longer wavelengths) at 470 nm. The synchronous scan spectra present a number of peaks and shoulders, and the peaks at shorter wavelengths disappear gradually and form a shoulder. At the final stage of composting, the fluorescence spectra have similar shapes, but the fluorescence intensities decrease. P. chrysosporium increases the degree of aromatization and polymerization of HA when it is inoculated during the second fermentation phase, while it does not produce an obvious change on the humification degree of HA when it is inoculated during the first fermentation phase. Compared with the fluorescence spectroscopy characteristics of HA from soil, the structure of HA from compost is simpler and the activity is higher. Foundation item: Project(2005CB724203) supported by the Major State Basic Research and Development Program of China; Project(IRT0719) supported by the Program for Changjiang Scholars and Innovative Research Team in University of China; Projects(50608029, 50808073) supported by the National Natural Science Foundation of China; Project(2007185) supported by the Environmental Protection Technology Research Program of Hunan Province, China     

A bi-objective model for job-shop scheduling problem to minimize both energy consumption and makespan

The issue of reducing energy consumption for the job-shop scheduling problem in machining systems is addressed, whose dual objectives are to minimize both the energy consumption and the makespan. First, the biobjective model for the job-shop scheduling problem is proposed. The objective function value of the model represents synthesized optimization of energy consumption and makespan. Then, a heuristic algorithm is developed to locate the optimal or near optimal solutions of the model based on the Tabu search mechanism. Finally, the experimental case is presented to demonstrate the effectiveness of the proposed model and the algorithm. Foundation item: Project (50475062) supported by the National Natural Science Foundation of China; project (2004-47-19) supported by the Natural Science Foundation of Chongqing City of China     

材料生命周期清单编制的算法

材料生命周期清单编制的算法清单分析通过对生命周期中能量和原材料的需求以及环境释放的量化分析,发现改善产品环境性能的环节和方法.通过清单分析步骤的明确及流程建模等关键技术的分析,建立了清单分析数据流的主流平衡算法;根据平衡计算结果,建立了基于递归分析方法的各单元过程编目数据流的清单汇总算法;并以钢铁材料生产过程为例,开展了清单编制算法的验证和具体应用.     

Residual stresses within sprayed coatings

Some important developments of residual stress researches for coating-based systems were studied. The following topics were included the sources of residual stresses in coatings: error analysis of Stoney’s equation in the curvature method used for the measurement of coating residual stress, the modeling of residual stress and some analytical models for predicting the residual stresses in coatings. These topics should provide some important insights for the fail-safe design of the coating-based systems. Foundation item: Project(50235030) supported by the National Natural Science Foundation of China; Project(2003AA331130) supported by the National High-Tech Research and Development Program of China     

Synthesis and optophysical properties of blue-emitting iridium （Ⅲ） complex bearing oxadiazole-based picolinic acid derivative

An iridium (III) bis[(4,6-difluorophenyl)pyridinato-N, C²][6-(6′-(4″-(5‴-phenyl-1‴, 3‴, 4‴-oxadiazole- 2‴-yl) phenoxy) hexyloxy picolinate) was synthesized and characterized by ¹H NMR and elementary analysis in order to study the effect of ancillary ligand of the oxadiazole-based picolinic acid derivative on optophysical properties of its iridium complex, and further to obtain an iridium complex with highly-efficient blue emission. The thermal stability, UV absorption and photoluminescent properties of this iridium complex were investigated. Compared with iridium (III) bis[(4,6-difluorophenyl)pyridinato-N, C²](picolinate) reported as a highly-efficient blue electroluminescent material, this iridium complex bearing an oxadiazole-based picolinic acid derivative presents higher thermal stability, more intense UV absorption at 291 nm and similar photoluminescent spectrum peaked at 469 nm. This indicates that tuning ancillary ligand of picolinic acid with an oxadiazole unit can improve the optophysical properties of its iridium complex. Foundation item: Projects(20772101, 50473046) supported by the National Natural Science Foundation of China; Project(2007FJ3017) supported by the Hunan Provincial Science Foundation, China; Project(07C764) supported by the Science Foundation of the Education Department of Hunan Province, China     

Short-term forecasting optimization algorithms for wind speed along Qinghai-Tibet railway based on different intelligent modeling theories

To protect trains against strong cross-wind along Qinghai-Tibet railway, a strong wind speed monitoring and warning system was developed. And to obtain high-precision wind speed short-term forecasting values for the system to make more accurate scheduling decision, two optimization algorithms were proposed. Using them to make calculative examples for actual wind speed time series from the 18th meteorological station, the results show that: the optimization algorithm based on wavelet analysis method and improved time series analysis method can attain high-precision multi-step forecasting values, the mean relative errors of one-step, three-step, five-step and ten-step forecasting are only 0.30%, 0.75%, 1.15% and 1.65%, respectively. The optimization algorithm based on wavelet analysis method and Kalman time series analysis method can obtain high-precision one-step forecasting values, the mean relative error of one-step forecasting is reduced by 61.67% to 0.115%. The two optimization algorithms both maintain the modeling simple character, and can attain prediction explicit equations after modeling calculation. Foundation item: Project(2006BAC07B03) supported by the National Key Technology R & D Program of China; Project(2006G040-A) supported by the Foundation of the Science and Technology Section of Ministry of Railway: Project(2008yb044) supported by the Foundation of Excellent Doctoral Dissertation of Central South University     

Electron bandstructure of kaolinite and its mechanism of flotation using dodecylamine as collector

The bulk electronic structure of kaolinite (001) plane was studied with quantum mechanical calculations. The CASTEP parameterization of ultrasoft pseudopotentials without core corrections was used to optimize the structure of kaolinite bulk and slab models. The results show that Fermi energy of kaolinite (001) plane is 3.05 eV, and the band gap is 4.52 eV. The partial density of states (PDOS) of kaolinite (001) plane indicates that Al—O and Si—O bonds on the mineral surface are highly polar. The oxygen atoms of hydroxyl groups in surface layer are capable of forming hydrogen bond with the head group of cationic collectors. The properties of dodecylamine (DDA) cation were also calculated by density function theory (DFT) method at B3LYP/6-31G (d) level for illuminating the flotation processes of kaolinite. Besides the electrostatic attraction, the mechanism between kaolinite and DDA is found to be hydrogen bonds under acidic condition. Foundation item: Project(2005CB623701) supported by the Major State Basic Research and Development Program of China; Project(50874118) supported by the National Nature Science Foundation of China; Project(2007B52) supported by the Foundation for the Author of National Excellent Doctoral Dissertation of China     

Modeling and simulation of crushing process of spiral mining head

1 INTRODUCTIONThe research of mining deep seabed cobalt-richcrust is a hotspot of international oceanology[1].Based on the mining manganese nodule ,lots of re-searches on mining cobalt crust have been madedeeply and many kinds of methods ,such as thei m-proved CLB, mining vehicle +lifting system +surface supporting ship have been put forward.Mining vehicle consists of collecting machine ,tracked treading machine and spiral mininghead[2 ,3].The first step of mining cobalt crust is tocrush…     

Residual fatigue strength of 48MnV crankshaft based on safety factor

Residual fatigue strength of 48MnV crankshaft was studied and analyzed based on safety factor. Three different status crankshafts were used to the hop-up tests, which maintain new after 500 h hop-up tests and after 1 000 h hop-up tests. Then, crankshafts were cut into unit cranks. The unit cranks were used to do endurance bending tests to get the residual fatigue strength. Finally, the results were analyzed based on safety factor. The results show that safety factor of crankshaft descends a little with the increase of the running time, and the residual safety factor is still much bigger than the endurable safety factor. Furthermore, after the crankshaft accomplishes a full life cycle, the residual fatigue strength of the crankshaft is enough to remanufacture and fulfill the next life cycle. Foundation item: Key Project (50235030) supported by the National Natural Science Foundation of China