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有机硅由于其特殊物性及化学结构,可通过与聚氨酯(PU)共聚反应或物理共混的方式,提高合成革及表面处理剂的一些性能,如:耐折叠、耐水解、耐磨耗、手感以及观感等;同时,有机硅还可用作生产过程助剂,起到润湿、流平、助剥离等效果。1有机硅在合成革用PU和涂饰剂中的应用 相似文献
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采用4种不同结构的有机硅氧烷改性异氰酸酯得到聚氨酯预聚体,作为制备无溶剂合成革面层的B组分。探讨了有机硅改性聚氨酯预聚体对无溶剂合成革面层及成品革的性能影响。结果表明:与未改性的相比,有机硅改性的无溶剂合成革面层,拉伸强度从5.73 MPa增加至7.82 MPa,断裂伸长率从342%增加至472%,吸水率从8.05%降低至3.36%,面层的热稳定性得到提高;制备的成品革柔软度从8.16提高至10.57,TaberH–221 000 g耐磨从856转增加至1 426转,合成革的剥离强度保留率有所增加。当采用PDMS–2改性得到的聚氨酯预聚体,其制备的无溶剂合成革综合性能较佳。 相似文献
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以羟丙基硅油改性二苯基甲烷二异氰酸酯(MDI)型聚氨酯合成了一种有机硅改性聚氨酯预聚体,将预聚体乳化后制备了一种有机硅改性水性聚氨酯。确定了乳液最佳配方,讨论了各工艺条件对改性水性聚氨酯整理棉织物综合性能的影响。结果表明,原棉织物、聚氨酯乳液整理和改性水性聚氨酯整理的棉织物表面粗糙度(SMD)分别为2.625、2.605和2.190,弯曲刚度B分别为0.0894、0.0869和0.0464,可见聚氨酯乳液整理前后棉织物的表面特性和柔顺性变化不大,但经有机硅改性水性聚氨酯整理后棉织物的表面特性和柔顺性则大为改善。 相似文献
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为提高聚醚型聚氨酯材料耐磨性能,在其分子链上引入端羟基有机硅进行共聚改性,所合成的改性聚氨酯/有机硅材料的相容性较好,然后将其制成标准合成革样品进行威士伯耐磨性测试,目的是探索引入低表面能链段方法改进耐磨可行性。实验结果表明:所改性的合成革聚氨酯面层树脂与改性前相比,其100%模量变低,制得的合成革手感更为柔软;合成革的威士伯耐磨性显著提升,明显优于采用聚碳酸酯二醇合成聚氨酯面层树脂。因此,端羟基有机硅可提高聚醚型聚氨酯的耐磨性能,并可增强其柔性。 相似文献
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以小分子二元醇、异氰酸酯、异佛尔酮二胺(IPDA)和聚酯多元醇为原料合成了一种脂肪族聚氨酯树脂,用作合成革表面处理剂,使合成革表面达到雾面特黑的效果。考察了不同种类二元醇和异氰酸酯所合成的聚氨酯树脂及其粘度对合成革雾面处理剂黑度和雾度的影响。结果表明,小分子二元醇采用1,6-己二醇、异氰酸酯采用异佛尔酮二异氰酸酯(IPDI)和六亚甲基二异氰酸酯(HDI)质量比为1.0∶2.6的混合物时,树脂粘度控制在3000~12000 mPa·s,脂肪族聚氨酯树脂处理合成革表面时雾面特黑效果明显。 相似文献
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以二羟甲基丙酸(DMPA)为亲水扩链剂,4种同等相对分子质量、具有不同软段结构的二元醇为软段,异佛尔酮二异氰酸酯(IPDI)为硬段,制备了一系列水性聚氨酯。结果表明,聚己二酸新戊二醇酯(PNA)基、聚己内酯(PCL)基[HW1]水性聚氨酯的粒径较小,聚碳酸酯(PCDL)基水性聚氨酯的耐水性最好,聚四亚甲基醚二醇(PTMG)基的耐热性能较为优异,PCL基水性聚氨酯可在100%模量和断裂伸长率取得最佳的平衡。应用性能测试结果显示,PCL基、PCDL基水性聚氨酯所制备的合成革表面处理剂,具有更好的表面颜色牢度、附着性及耐磨性、不粘着性。 相似文献
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以聚酯二元醇(PBA2000)、二羟甲基丙酸(DMPA)为亲水扩链剂,1,4-丁二醇(BDO)小分子扩链剂,通过在聚氨酯中加入聚有机硅二元醇(分子量1 000),控制R值不变,改变有机硅二元醇比例合成一系列的聚氨酯乳液,并对有机硅水性聚氨酯及其在合成革中的应用性能进行研究。结果表明,有机硅二元醇的引入使水性聚氨酯乳液粘度由37.27 Pa·s降低到19.35 Pa·s,胶膜吸水率由18.8%减小到12.5%,拉伸强度逐渐降低,作为涂饰剂用于合成革顶层,使合成革干、湿色牢度分别由3.5、4等级提高到5,展色性良好。 相似文献
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通过双组分浇注工艺制备出一系列的无溶剂聚氨酯合成革,探讨了异氰酸酯组分(B组分)-NCO质量分数、异氰酸酯指数(r值)、软段类型及有机硅改性对合成革性能的影响。傅里叶变换红外光谱(FT-IR)谱图表明,有机硅多元醇(OF-OH-702E)与异氰酸酯充分反应接入聚氨酯链段,动态热机械分析(DMA)表明,双组分聚氨酯通过OF-OH-702E改性后玻璃化转变温度(Tg)从-26.4℃下降至-40.35℃。实验数据表明,B组分中的软段聚碳酸酯二元醇(PCDL-2000)与OF-OH-702E质量比为90/10,-NCO质量分数为16wt%时,与聚四氢呋喃二元醇(PTMG-2000)型A组分按照r值为1.05反应产物综合性能最佳,制备出的无溶剂合成革剥离强度达110N/cm3,Taber H-22 1000g耐磨1620转,-20℃8.7万次耐折牢度,70℃95RH%恒温恒湿测试10周剥离强度保留率为85.2%,满足运动鞋用合成革标准。 相似文献
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以苯酐聚酯二元醇(PS)、聚己内酯多元醇(PCL)、1,4-丁二醇(BDO)、二苯甲烷二异氰酸酯(MDI)等为原料,合成了湿法革用聚氨酯树脂.分别研究了PS相对分子质量、PCL用量、硬段含量等对聚氨酯树脂膜的模量及其耐水解性能的影响.结果表明,PS和PCL复配可以制得耐水解性能优异,且成本较低的湿法合成革用聚氨酯树脂. 相似文献
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李燕杰 《纤维素科学与技术》2009,17(3):39-42,52
木质素是聚氨酯合成革中优良的填充剂,其赋予了聚氨酯合成革特殊的物理性能和加工性能,可降低成本。不同的木质素筛余物对木质素/聚氨酯共混体的黏度及聚氨酯合成革的剥离强度有一定的影响,当木质素筛余物质量分数控制在5.5%~6.5%,能得到较佳的作用效果。 相似文献
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Thomas Balasingh Sudha Palanisamy Thanikaivelan Kavati Phebe Aaron Kaliappa Krishnaraj Bangaru Chandrasekaran 《应用聚合物科学杂志》2009,114(3):1761-1767
Natural leather is processed from hides and skins of animals. Synthetic leathers are becoming popular as an alternative material owing to limited availability and varying size of natural leathers. There is a need to understand the properties of natural and synthetic leathers to select proper material for an application. In this study, materials used for apparel application such as natural sheep nappa leather and synthetic polyurethane (PU)‐based leather have been chosen and analyzed for comfort, chemical, physical, and structural properties. It was found that natural sheep nappa leather has enhanced water vapor permeability whereas other comfort properties such as softness and drape ability are comparable to synthetic PU leather. Whereas synthetic PU leather dominated most of the physical properties, especially percentage elongation and stitch tear strength, in specific directions on account of polyester knitted base fabric. Chemical properties of natural sheep nappa leather and synthetic PU leather depended on the individual material composition and characteristics. Scanning electron microscopic (SEM) analysis provided convincing evidence for some of the quantified comfort and physical properties. The results of this study would be useful in selection of proper material for apparel application as well as in providing directions for future research in synthetic leather manufacture. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2009 相似文献
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Elena Orgilés-Calpena Francisca Arán-Aís Ana M. Torró-Palau César Orgilés-Barceló José Miguel Martín-Martínez 《International Journal of Adhesion and Adhesives》2009,29(3):309-318
To adjust the rheology of waterborne polyurethane adhesives, different amounts of a hydrophobically modified ethoxylated polyurethane thickener (HEUR) were added. The thickened adhesive solutions were characterized by flow rheology, pH measurements, particle size, solids content and confocal microscopy. The thickened solid adhesive films were characterized by IR spectroscopy, plate-plate rheology, dynamic mechanical thermal analysis (DMTA), differential scanning calorimetry (DSC) and thermogravimetric (TG) analysis. The adhesion was measured from T-peel test of plasticized PVC/polyurethane adhesive/plasticized PVC and leather/polyurethane adhesive/SBR rubber joints. The addition of the HEUR thickener increased the viscosity of the polyurethane dispersion, and a shear-thinning behaviour was observed due to polyurethane–thickener interactions. The addition of thickener improved the rheological properties of the polyurethane, more noticeable as the content of the thickener increased. The crosslinking of the thickened polyurethane was studied by confocal microscopy. Although the addition of the thickener did not greatly affect the thermal properties of the polyurethane, an improvement in the adhesive strength of leather/adhesive/SBR rubber joints was obtained. 相似文献
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Synthesis of waterborne polyurethane–silver nanoparticle antibacterial coating for synthetic leather
An antibacterial coating composed of silver nanoparticles and waterborne polyurethane was synthesized for use on synthetic leather. In this study, silver nanoparticles were prepared and used as nanofiller to impart antibacterial property. Silver nanoparticles were synthesized by using poly(vinyl pyrrolidone) as dispersant and sodium borohydride (NaBH4) as reducing agent. Silver nanoparticles were characterized by transmission electron microscopy (TEM), Fourier-transform infrared (FTIR) spectroscopy, and X-ray diffraction (XRD) analysis. The optimum dispersant was selected according to the zeta potential of dispersions. Waterborne polyurethane was synthesized by using isophorone diisocyanate, 2-bis(hydroxymethyl)propionic acid, triethylamine, and polytetramethylene ether glycol. Waterborne polyurethane–silver antibacterial coating was obtained by ultrasonic dispersion, and then cast on the surface of synthetic leather. The antibacterial property and coating adhesion were investigated. The results showed silver nanoparticles homogeneously dispersed in waterborne polyurethane and adhesion reaching grade 4. Antibacterial testing showed bacterial reduction of 99.99% for Escherichia coli and 87.5% for Staphylococcus aureus. 相似文献