Experimental investigation of solar-hydrogen energy system performance

Recently, the Solar-hydrogen energy system (SHES) becomes a reality thanks as well as a very common topic to energy research in Egypt as it is now being the key solution of different energy problems including global warming, poor air quality and dwindling reserves of liquid hydrocarbon fuels. Hydrogen is a flexible storage medium for energy and can be generated by the electrolysis of water. It is more particularly advantageous and efficient when the electrolyzer is simply coupled to a source of renewable electrical energy. This paper examines the operation of alkaline water electrolysis coupled with solar photovoltaic (PV) source for hydrogen generation with emphasis on the electrolyzer efficiency. PV generator is simulated using Matlab/Simulink to obtain its characteristics under different operating conditions with solar irradiance and temperature variations. The experimental alkaline water electrolysis system is built in the fluid mechanics laboratory of Menoufiya University and tested at certain input voltages and currents which are fed from the PV generator. The effects of voltage, solution concentration of electrolyte and the space between the pair of electrodes on the amount of hydrogen produced by water electrolysis as well as the electrolyzer efficiency are experimentally investigated. The water electrolysis of different potassium hydroxide aqueous solutions is conducted under atmospheric pressure using stainless steel electrodes. The experimental results showed that the performance of water electrolysis unit is highly affected by the voltage input and the gap between the electrodes. Higher rates of produced hydrogen can be obtained at smaller space between the electrodes and also at higher voltage input. The maximum electrolyzer efficiency is obtained at the smallest gap between electrodes, however, for a specified input voltage value within the range considered.     

PEM electrolysis for production of hydrogen from renewable energy sources

PEM electrolysis is a viable alternative for generation of hydrogen from renewable energy sources. Several possible applications are discussed, including grid independent and grid assisted hydrogen generation, use of an electrolyzer for peak shaving, and integrated systems both grid connected and grid independent where electrolytically generated hydrogen is stored and then via fuel cell converted back to electricity when needed. Specific issues regarding the use of PEM electrolyzer in the renewable energy systems are addressed, such as sizing of electrolyzer, intermittent operation, output pressure, oxygen generation, water consumption and efficiency.     

Electrolytic hydrogen based renewable energy system with oxygen recovery and re-utilization

The Hydrogen Research Institute (HRI) has developed a stand-alone renewable energy (RE) system based on energy storage in the form of hydrogen. When the input devices (wind generator and photovoltaic array) produce more energy than is required by the load, the excess energy is converted by an electrolyzer to electrolytic hydrogen, which is then stored after stages of compression, purification and filtration. Conversely, during a time of input energy deficit, this process is reversed and the hydrogen produced earlier is reconverted to electrical energy through a fuel cell. The oxygen which has been produced by the electrolyzer during the hydrogen production is also stored at high pressure, after having gone through a purification and drying process. This stored oxygen can be re-utilized as oxidant in place of compressed air in the fuel cell. The modifications of the electrolyzer for oxygen storage and re-utilization of it as oxidant for the fuel cell are presented. Furthermore, the HRI has designed and developed the control system with power conditioning devices for effective energy management and automatic operation of the RE system. The experimental results show that a reliable autonomous RE system can be realized for such seasonal energy sources, using stored hydrogen as the long-term energy buffer, and that utilizing the electrolyzer oxygen by-product as oxidant in the fuel cell increases system performance significantly.     

Hybrid energy system for hydrogen production in the Adrar region (Algeria): Production rate and purity level

The following work treat the prediction of the production rate and purity level of hydrogen produced by an alkaline electrolyzer fed by a renewable source in a hybrid energy system HES in the locality of Adrar in the south of Algeria. This work is made for different renewable energy penetration rate from 0% to 60% of conventional power (Genset generator). The cell electrolyzer model permits to predict the production rate of hydrogen with accuracy, according to operating parameters, climatic conditions and the load of the site of Adrar. The study permits to introduce a model of hydrogen purity level based on the operating parameters and the power supplying the alkaline electrolyzer. It also shows that the great influence of the intermittent energy supplying the electrolyzer on the production rate and purity level of hydrogen. The prediction of production rate and purity level by the models allow to obtain a distribution and storage of hydrogen produced according to predetermined selection criteria imposed by the operator.In the process of electrolysis, the oxygen is considered as by-product of the hydrogen production. The amount and purity level were estimated jointly.An HES-H₂ production program under MATLAB^®/SIMULINK^® has been developed to simulate the hourly evolution of the production rate and purity level of hydrogen and oxygen produced by an electrolyzer for different penetration rate of renewable energies in an HES.     

Design and economic analysis of high-pressure proton exchange membrane electrolysis for renewable energy storage

The proton exchange membrane (PEM) electrolysis with a high-pressure cathode can help avoid the utilization of a hydrogen compressor and improve the efficiency of hydrogen transmission. The economic analysis of the entire process from hydrogen production to transportation was conducted in this study, and the advantages of high-pressure PEM electrolysis were proved. The economic analysis has also illustrated the influence of the cathode pressure and membrane thickness involved in PEM electrolysis on the energy consumption and capital expenditure of the electrolyzer from the perspectives of hydrogen permeability, ohmic impedance, and structural design. Although the output pressure of hydrogen is increased several tens of times, the proper structure and unchanged thickness of the membrane can help satisfy the strength and safety requirements of the electrolyzer simultaneously. In addition, the energy consumption and cost increase associated with the high-pressure electrolyzer can be limited to an acceptable range. The impact of the renewable energy scale on the decision and selection for PEM or ALK is also analyzed; PEM has an advantage over ALK in large-scale renewable energy hydrogen production scenarios because of its own wider upper and lower load limits compared to those of ALK.     

High temperature electrolysis of hydrogen bromide gas for hydrogen production using solid oxide membrane electrolyzer

Using solid oxide membrane, this paper presents the theoretical modeling of the high temperature electrolysis of hydrogen bromide gas for hydrogen production. The electrolysis of hydrogen halides such as hydrogen bromide is an attractive process, which can be coupled to hybrid thermochemical cycles. The high temperature electrolyzer model developed in the present study includes concentration, ohmic, and activation losses. Exergy efficiency, as well as energy efficiency parameters, are used to express the thermodynamic performance of the electrolyzer. Moreover, a detailed parametric study is performed to observe the effects of various parameters such as current density and operating temperature on the overall system behavior. The results show that in order to produce 1 mol of hydrogen, 1.1 V of the applied potential is required, which is approximately 0.8 V less compared to high temperature steam electrolysis under same conditions (current density of 1000 A/m² and temperature of 1073 K). Furthermore, it is found that with the use of the presented electrolyzer, one can achieve energy and exergy efficiencies of about 56.7% and 53.8%, respectively. The results presented in this study suggest that, by employing the proposed electrolyzer, two-step thermochemical cycle for hydrogen production may become more attractive especially for nuclear- and concentrated solar-to-hydrogen conversion applications.     

Researching and adjusting the modes of joint operation of a photoelectric converter and a high pressure electrolyzer

The article describes the experimental studies of hydrogen (oxygen) generation processes by the electrolysis method that were fulfilled with the use of the energy plant model involving a solar energy photovoltaic converter (working surface area is of S = 1.5 m²) and a membrane-less high-pressure electrolyzer (capacity is of 0.002 m³ of hydrogen per hour with an operating pressure of 0.3 MPa). Under experimental studies we have adjusted the modes of joint operating the photoelectric converter and the membrane-less high pressure electrolyzer depending on the changes of solar insolation. We have determined the ways to increase the electrolyzer efficiency. It was found that the level of current density, which determines the electrolyzer efficiency by hydrogen, depends on the solar insolation level. The obtained experimental data, as to adapting an electrolyzer to be feed from a photoelectric converter, give the possibility to develop the algorithms of automatic control of the electrolyzer when it operates in composition of an autonomous energy plant.     

Development of large scale unified system for hydrogen energy carrier production and utilization: Experimental analysis and systems modeling

The world's largest class hydrogen energy carrier production, storage, and utilization system has been operated in order to obtain basic data for practical use of the system using renewable energy. In this system, an alkaline water electrolyzer is combined with hydrogenation reactors to produce methylcyclohexane (MCH). Since electrolyzer behavior directly affects hydrogenation reaction, behaviors of the 150 kW class water electrolyzer against fluctuating electricity inputs were experimentally investigated. The cell stack voltage and hydrogen flow rate changed following temporal changes of the input current, whereas the temperature response was slow due to the large heat capacity of the system. Hydrogenation reactors performance using the hydrogen from the electrolyzer are reported. Then, based on the experiment data, a numerical simulation model for the electrolyzer was developed, which predicts the experimental result using fluctuating electricity very well. Furthermore, using the simulator, the heat utilization from the hydrogenation reaction for the electrolyzer warm-up process was investigated.     

Dynamic production,storage, and use of renewable hydrogen: A technical-economic-environmental analysis in the public transport system in São Paulo state,Brazil

This article proposes a calculation methodology that starts from the demand calculation to supply a fleet bus with renewable hydrogen based on the electrolysis process until the energetic, economic, and environmental analyses, involving all the processes of the productive chair. Also considering the dynamic behaviour of the following hydrogen processes: production, storage, and use. The simplified scheme of the proposed system configuration to be studied consists of the use of alternative and renewable sources of energy (solar-wind-biogas) to generate electrical energy in order to produce hydrogen from electrolysis of the water, which is stored in its gaseous state and subsequently redirected to a filling station to be used as vehicle fuel in buses. The results show that to feed one bus the hybrid system generates an average of 78,110 kWh/month with an installed capacity of 1101.905 kW, producing 1209.90 kgH₂/month through the electrolysis process from water. The results also show a range of electricity generation costs between 1.130 and 0.123 US$/kWh and H₂ production between 0.963 and 0.110 US$/kWh. Concluding that the application of renewable energies to produce hydrogen and electricity for the public transport sector is an attractive alternative in the future throughout the country, because the proposed system is technically, economically and ecologically viable.     

Estimation of electrolytic hydrogen production potential in Venezuela from renewable energies

An initial estimation of the potential for hydrogen (H₂) production in Venezuela is made, obtained by water electrolysis using electricity from renewable sources, taking advantage of the great potential of the country for solar, wind and mini hydro energies. For the first two, its potential maps is obtained from insolation and wind speed maps, respectively, prepared from satellite data, and for mini-hydro, the potential is obtained from documentary information. To calculate the amount of H₂ to produce is used the Higher Heating Value, considering the electrolytic system overall efficiency of 75%, including power requirements of the electrolyzer, auxiliary equipment, and system losses. In addition, in the calculation of usable renewable potential are excluded land areas under special administration, marine, lake and urban areas, and other limitations are considered concerning energy conversion efficiencies and useful areas available for the location of the different renewable technologies.     

Thermodynamics analysis of a hybrid system based on a combination of hydrogen fueled compressed air energy storage system and water electrolysis hydrogen generator

In front of the opportunity of the rapid development of renewable energy power generation, energy storage is playing a more important role in improving its utilization efficiency. In this paper, a hybrid energy system based on combination of hydrogen fueled compressed air energy storage system and water electrolysis hydrogen generator is proposed. The superfluous renewable energy power is charged by compressing the air and/or producing hydrogen through water electrolysis. A hydrogen combustor is introduced to raise the air temperature in the discharging process. A thermodynamic model of the proposed system is built. Energy and exergy analysis found that under the design condition, the proposed system can achieve a round trip efficiency of 65.11%, an exergy efficiency of 79.23%, and an energy storage density of 5.85 kWh/m³. The exergy loss of water electrolysis hydrogen generator and hydrogen combustor rank in the top two of all components. Sensitivity analysis indicates that the outlet temperature of hydrogen combustor and specific energy consumption of water electrolysis hydrogen generator are the crucial influencing factor of system performance.     

Levelized costs of energy and hydrogen of wind farms and concentrated photovoltaic thermal systems. A case study in Morocco

This work deals with the evaluation of levelized costs of energy and hydrogen of wind farms and concentrated photovoltaic thermal systems. The production of hydrogen is ensured by an alkaline water electrolyser supplied by the electric current generated by the renewable energy sources. The study is carried out on the basis of meteorological data from the Tangier region, in Morocco. Mathematical models are developed to assess the performance and efficiency of renewable sources in terms of energy and hydrogen production for different installed powers. The comparison between the current results and those of previous work shows that the discrepancy did not exceed 6% for both electrical and thermal efficiency of the concentrated photovoltaic/thermal system. The results show that the energy consumption ratios of the electrolyzer are 61 and 64 kWh.kg⁻¹ for wind and solar energy, respectively. Wind and solar hydrogen production efficiencies are also 66 and 62%, respectively. Results show that levelized costs of energy and hydrogen decrease with the increase in installed wind and photovoltaic capacity. The overall results also show that the Tangier region can produce energy and hydrogen at low cost using wind energy compared to concentrated photovoltaic installations. For the hybridization of the two green sources studied, this is highly recommended provided that the capacity of the electrolyzer to be installed is optimal in order to effectively improve the production of hydrogen.     

Predicting efficiency of solar powered hydrogen generation using photovoltaic-electrolysis devices

Hydrogen fuel for fuel cell vehicles can be produced by using solar electric energy from photovoltaic (PV) modules for the electrolysis of water without emitting carbon dioxide or requiring fossil fuels. In the past, this renewable means of hydrogen production has suffered from low efficiency (2–6%), which increased the area of the PV array required and therefore, the cost of generating hydrogen. A comprehensive mathematical model was developed that can predict the efficiency of a PV-electrolyzer combination based on operating parameters including voltage, current, temperature, and gas output pressure. This model has been used to design optimized PV-electrolyzer systems with maximum solar energy to hydrogen efficiency. In this research, the electrical efficiency of the PV-electrolysis system was increased by matching the maximum power output and voltage of the photovoltaics to the operating voltage of a proton exchange membrane (PEM) electrolyzer, and optimizing the effects of electrolyzer operating current, and temperature. The operating temperature of the PV modules was also an important factor studied in this research to increase efficiency. The optimized PV-electrolysis system increased the hydrogen generation efficiency to 12.4% for a solar powered PV-PEM electrolyzer that could supply enough hydrogen to operate a fuel cell vehicle.     

Methylcyclohexane production under fluctuating hydrogen flow rate conditions

Energy storage using liquid organic hydrogen carrier (LOHC) is a long-term method to store renewable energy with high hydrogen energy density. This study investigated a simple and low-cost system to produce methylcyclohexane (MCH) from toluene and hydrogen using fluctuating electric power, and developed its control method. In the current system, hydrogen generated by an alkaline water electrolyzer was directly supplied to hydrogenation reactors, where hydrogen purification equipment such as PSA and TSA is not installed to decrease costs. Hydrogen buffer tanks and compressors are not equipped. In order to enable MCH production using fluctuating electricity, a feed-forward toluene supply control method was developed and introduced to the system. The electrolyzer was operated under triangular waves and power generation patterns of photovoltaic cells and produced hydrogen with fluctuating flow rates up to 7.5 Nm³/h. Consequently, relatively high purity of MCH (more than 90% of MCH mole fraction) was successfully produced. Therefore, the simplified system has enough potential to produce MCH using fluctuating renewable electricity.     

Energy and exergy analyses of hydrogen production via solar-boosted ocean thermal energy conversion and PEM electrolysis

Energy and exergy analyses are reported of hydrogen production via an ocean thermal energy conversion (OTEC) system coupled with a solar-enhanced proton exchange membrane (PEM) electrolyzer. This system is composed of a turbine, an evaporator, a condenser, a pump, a solar collector and a PEM electrolyzer. Electricity is generated in the turbine, which is used by the PEM electrolyzer to produce hydrogen. A simulation program using Matlab software is developed to model the PEM electrolyzer and OTEC system. The simulation model for the PEM electrolyzer used in this study is validated with experimental data from the literature. The amount of hydrogen produced, the exergy destruction of each component and the overall system, and the exergy efficiency of the system are calculated. To better understand the effect of various parameters on system performance, a parametric analysis is carried out. The energy and exergy efficiencies of the integrated OTEC system are 3.6% and 22.7% respectively, and the exergy efficiency of the PEM electrolyzer is about 56.5% while the amount of hydrogen produced by it is 1.2 kg/h.     

Hydrogen production by methanol aqueous electrolysis using photovoltaic energy: Algerian potential

Hydrogen is considered as the most promising energy carrier for providing a clean, reliable and sustainable energy system. It can be produced from a diverse array of potential feed stocks including water, fossil fuels and organic matter. Electrolysis is the best option for producing hydrogen very quickly and conveniently. Water electrolysis as a source of hydrogen production has recently gained much attention since it can produce high purity hydrogen and can be compatible with renewable energies. Besides the water electrolysis, aqueous methanol electrolysis has been reported in several studies. The aqueous methanol electrolysis proceeds at much lower voltage than that with the water electrolysis. As a result of the substantially lower operating voltage, the energy efficiency for methanol electrolysis can be higher than that for water electrolysis. In this paper, we are interesting to methanol electrolysis in order to produce hydrogen. The relation linking hydrogen production rate to the power needed to electrolyse a unit volume of aqueous methanol solution has been determined. Using this relation, the potential of hydrogen from aqueous methanol solution using a PV solar as the energy system has been evaluated for different locations in Algeria.     

Structure design and control strategy of a new alkaline water electrolyzer based on heat exchange

The overall energy conversion efficiency and the power regulation performance of the volatile renewable energy alkaline water electrolyzer (AWE) hydrogen production system need to be improved. Efficient use of heat in the electrolysis process and optimization of the control strategy are technically feasible. According to the concept of heat exchange utilization, this paper proposes a series parallel modular structure of AWE, which realizes heat exchange and utilization between modules. Based on the electrothermal characteristics of AWE and the power fluctuation characteristics of volatile energy, the function positioning and control strategy of the module are proposed. Theoretical analysis, together with a case study, has been conducted to show the overall efficiency and power regulation characteristics of the traditional AWE, the traditional combined AWE and the proposed new AWE under various working scenarios. Research study results show that the proposed new structure and control strategy can effectively improve the overall energy efficiency and static as well as dynamic power regulation characteristics of the electrolyzer, with the energy efficiency increased up to 16%. Although the static power range decreases slightly in some conditions, it always maintains the ability of wide range regulation. The findings can provide reference for the research and development of new AWE that improve the power response capability and the comprehensive utilization of energy under the premise of ensuring a certain power adjustment range.     

Wind energy,electricity, and hydrogen in the Netherlands

The curbing of greenhouse gases (GHG) is an important issue on the international political agenda. The substitution of fossil fuels by renewable energy sources is an often-advocated mitigation strategy. Wind energy is a potential renewable energy source. However, wind energy is not reliable since its electricity production depends on variable weather conditions. High wind energy penetration rates lead to losses due to power plant operation adjustments to wind energy. This research identifies the potential energetic benefits of integrated hydrogen production in electricity systems with high wind energy penetration. This research concludes that the use of system losses for hydrogen production via electrolysis is beneficial in situations with ca. 8 GW or more wind energy capacity in the Netherlands. The 2020 Dutch policy goal of 6 GW will not benefit from hydrogen production in terms of systems efficiency. An ancillary beneficial effect of coupling hydrogen production with wind energy is to relieve the high-voltage grid.     

Semi-empirical model and experimental validation for the performance evaluation of a 15 kW alkaline water electrolyzer

This paper presents a semi-empirical mathematical model for predicting the electrochemical behavior of an alkaline water electrolysis system, based on the polarization curve and Faraday efficiency as a function of the current density under different operating conditions, such as, temperature and pressure. Also, the gas impurities of hydrogen in oxygen have been modeled for safety reasons due to its importance when the electrolyzer is dynamically operated using renewable energy sources. The different parameters defined in the model have been calculated by MATLAB, using a non-linear regression, on the basis of experimental data obtained in a 15 kW alkaline test bench. The simulated and measured values have been compared to ensure the accuracy and validity of the proposed model. In this sense, the error has been evaluated for the voltage with an average result of 5.67 mV per cell and for the Faraday efficiency and the gas impurities of hydrogen in oxygen with a value lower than 1%. These results show an excellent correlation between experimental and modeled data, so the model is a useful design and optimization tool for alkaline electrolyzers. Also, a sensitivity analysis has been used to determine the most influential operating variables in the performance of the electrolyzer.     

基于新能源发电的电解水制氢直流电源研究

利用新能源发电进行电解水制氢是实现新能源就地消纳和氢能利用的重要途径,以匹配电解水制氢工作特性的制氢电源为研究对象,通过分析质子交换膜电解槽电解电流、温度与电解槽端口电压、能量效率、制氢速度之间的关系,得出制氢电源需具备输出低电流纹波、输出大电流、宽范围电压输出的特性。为满足新能源电解制氢系统需求,提出一种基于Y型三相交错并联LLC拓扑结构的制氢电源方案,该方案谐振腔三相交错并联输出,满足电解槽大电流低纹波工作特性,并采用脉冲频率控制实现谐振软开关,提高变换效率。最后,搭建仿真模型和6 kW模块化实验样机,验证所提出方案的合理性与可行性。