Shock tube investigation of propane-air mixtures with a pilot diesel fuel or cotton methyl ester

The propane (or LPG) is one of the best candidates as an alternative fuel in dual-fuel engines which operate primarily on any type of gaseous fuel using pilot injection of diesel to achieve ignition. The ignition delay has received considerable attention in the published literature for various gaseous fuels using different dual-fuel engines which showed that the ignition delay in a dual-fuel engine is different from that in a diesel engine especially at low loads. In this research, the measurement of ignition delay of propane-air mixtures with a pilot diesel fuel or cotton methyl ester (CME) similar to mixtures used in dual-fuel engines have been performed in a shock tube. The operating conditions were the equivalence ratio ranging from 0.3 to 1.2, the initial pressure varied from 0.4 to 1.0 bar, the initial temperature varied from 423 to 673 K, the relative mass of pilot liquid fuel and the type of liquid fuel. The ignition-delay times were measured using a piezo-electric pressure transducer, charge amplifier, data acquisition card, PC computer and LabVIEW program. From the results, it is shown that, the minimum ignition-delay time for the dual-fuel combustion was observed at stoichiometric equivalence ratio for propane-air mixtures with a pilot diesel fuel or CME. Higher initial temperatures and pressures reduced the ignition delay. Also, the ignition delays of propane-air mixtures are affected by changes in pilot fuel quantities and properties.     

Diesel and rapeseed methyl ester (RME) pilot fuels for hydrogen and natural gas dual-fuel combustion in compression-ignition engines

This paper presents experimental results of rapeseed methyl ester (RME) and diesel fuel used separately as pilot fuels for dual-fuel compression-ignition (CI) engine operation with hydrogen gas and natural gas (the two gaseous fuels are tested separately). During hydrogen dual-fuel operation with both pilot fuels, thermal efficiencies are generally maintained. Hydrogen dual-fuel CI engine operation with both pilot fuels increases NO_x emissions, while smoke, unburnt HC and CO levels remain relatively unchanged compared with normal CI engine operation. During hydrogen dual-fuel operation with both pilot fuels, high flame propagation speeds in addition to slightly increased ignition delay result in higher pressure-rise rates, increased emissions of NO_x and peak pressure values compared with normal CI engine operation. During natural gas dual-fuel operation with both pilot fuels, comparatively higher unburnt HC and CO emissions are recorded compared with normal CI engine operation at low and intermediate engine loads which are due to lower combustion efficiencies and correspond to lower thermal efficiencies. This could be due to the pilot fuel failing to ignite the natural gas-air charge on a significant scale. During dual-fuel operation with both gaseous fuels, an increased overall hydrogen-carbon ratio lowers CO₂ emissions compared with normal engine operation. Power output (in terms of brake mean effective pressure, BMEP) as well as maximum engine speed achieved are also limited. This results from a reduced gaseous fuel induction capability in the intake manifold, in addition to engine stability issues (i.e. abnormal combustion). During all engine operating modes, diesel pilot fuel and RME pilot fuel performed closely in terms of exhaust emissions. Overall, CI engines can operate in the dual-fuel mode reasonably successfully with minimal modifications. However, increased NO_x emissions (with hydrogen use) and incomplete combustion at low and intermediate loads (with natural gas use) are concerns; while port gaseous fuel induction limits power output at high speeds.     

An experimental study of the flame propagation and combustion characteristics of LPG fuel

This work investigates the flame propagation and combustion characteristics of LPG (Liquefied Petroleum Gas) fuel. To clarify the combustion process of the heavy duty LPG engine, the flame propagation and combustion characteristics were investigated using a CVCC (constant volume combustion chamber) and a port injection type heavy duty LPLi (Liquefied Petroleum Liquid injection) engine system. Both the laser deflection method and the high-speed Schlieren photography method were employed to measure the flame propagation speed of LPG fuel. In addition, the single cylinder heavy duty LPLi engine was manufactured to analyze the combustion characteristics of the LPG.The experimental results indicated that the laser deflection method showed the measuring accuracy of this method to be less than 5% when compared with the result of the high-speed camera. According to the CVCC and heavy duty LPLi engine experimental results, the flame propagation reached a maximum speed at the stoichiometric equivalence ratio, regardless of operating conditions, and the effect of the equivalence ratio on both flame propagation and combustion characteristics was greater than that of ambient conditions. In addition, we found that the coefficient of variation of combustion duration increased when the equivalence ratio decreased. Furthermore, the combustion stability worsened as the equivalence ratio moved into the lean region.     

Experimental investigation on dual fuel operation of acetylene in a DI diesel engine

Depletion of fossils fuels and environmental degradation have prompted researchers throughout the world to search for a suitable alternative fuel for diesel engine. One such step is to utilize renewable fuels in diesel engines by partial or total replacement of diesel in dual fuel mode. In this study, acetylene gas has been considered as an alternative fuel for compression ignition engine, which has excellent combustion properties.Investigation has been carried out on a single cylinder, air cooled, direct injection (DI), compression ignition engine designed to develop the rated power output of 4.4 kW at 1500 rpm under variable load conditions, run on dual fuel mode with diesel as injected primary fuel and acetylene inducted as secondary gaseous fuel at various flow rates. Acetylene aspiration resulted in lower thermal efficiency. Smoke, HC and CO emissions reduced, when compared with baseline diesel operation. With acetylene induction, due to high combustion rates, NO_x emission significantly increased. Peak pressure and maximum rate of pressure rise also increased in the dual fuel mode of operation due to higher flame speed. It is concluded that induction of acetylene can significantly reduce smoke, CO and HC emissions with a small penalty on efficiency.     

Combustion heat release analysis of ethanol or n-butanol diesel fuel blends in heavy-duty DI diesel engine

An experimental study is conducted to evaluate the effects of using blends of diesel fuel with either ethanol in proportions of 5% and 10% or n-butanol in 8% and 16% (by vol.), on the combustion behavior of a fully-instrumented, six-cylinder, turbocharged and after-cooled, heavy duty, direct injection (DI), ‘Mercedes-Benz’ engine installed at the authors’ laboratory. Combustion chamber and fuel injection pressure diagrams are obtained at two speeds and three loads using a developed, high-speed, data acquisition and processing system. A heat release analysis of the experimentally obtained cylinder pressure diagrams is developed and used. Plots of histories in the combustion chamber of the heat release rate and temperatures reveal some interesting features, which shed light into the combustion mechanism when using these promising bio-fuels that can be derived from biomass (bio-ethanol and bio-butanol). The key results are that with the use of these bio-fuels blends, fuel injection pressure diagrams are very slightly displaced (delayed), ignition delay is increased, maximum cylinder pressures are slightly reduced and cylinder temperatures are reduced during the first part of combustion. These results, combined with the differing physical and chemical properties of the ethanol and n-butanol against those for the diesel fuel, which constitutes the baseline fuel, aid the correct interpretation of the observed engine behavior performance- and emissions-wise.     

Investigation of the combustion of neat cottonseed oil or its neat bio-diesel in a HSDI diesel engine by experimental heat release and statistical analyses

An experimental study is conducted to evaluate the effects of using neat cottonseed oil or its neat ME (methyl ester) bio-diesel, on the combustion behavior of a standard, high speed, direct injection (HSDI), ‘Hydra’ diesel engine located at the authors’ laboratory. Combustion chamber and fuel injection pressure diagrams are obtained at medium and high load using a developed, high-speed, data acquisition and processing system. A heat release analysis of the experimentally obtained cylinder pressure diagrams is developed and used. Plots of histories in the combustion chamber of the heat release rate and other related parameters reveal some interesting features, which shed light into the combustion mechanism when using these bio-fuels. These results, combined with the differing physical and chemical properties of the bio-fuels between themselves and against those for the diesel fuel, which constitutes the baseline fuel, aid the correct interpretation of the observed engine behavior performance- and emissions-wise. Moreover, the possible existence of cyclic (combustion) variability is examined as reflected in the pressure indicator diagrams, by analyzing for the maximum pressure and its rate, and the dynamic injection timing and ignition delay, by using statistical analysis for averages, standard deviations and probability density functions. The key results are that with the use of these bio-fuels against the neat diesel fuel case, the ignition delay is hardly affected, the fuel injection pressure diagrams are very slightly advanced accompanied with higher injection pressures, maximum cylinder pressures remain the same with the vegetable oil and slightly increased with the bio-diesel, maximum cylinder pressure rates are increased with the bio-diesel and decreased with the vegetable oil, while the cyclic irregularity is not affected with these bio-fuels remaining at the acceptable neat diesel fuel case levels.     

Experimental-stochastic investigation of the combustion cyclic variability in HSDI diesel engine using ethanol–diesel fuel blends

An experimental investigation is conducted to evaluate the combustion characteristics of a fully instrumented, high-speed, direct injection (HSDI), standard ‘Hydra’ diesel engine, at various loads when using ethanol–diesel fuel blends up to 15% by vol. ethanol. In each test, combustion chamber and fuel injection pressure diagrams of many consecutive cycles were obtained using a specially developed, high-speed, data acquisition and processing system. Following a performance and exhaust emissions investigation and a heat release analysis of the measured cylinder pressure diagrams reported by the authors, the present work focuses on the cycle-by-cycle combustion variation (cyclic variability) as reflected in the pressure indicator diagrams, by analyzing for the maximum pressure, maximum pressure rate, (gross) indicated mean effective pressure, and dynamic injection timing and ignition delay. These parameters were analyzed using stochastic analysis techniques for averages, standard deviations, coefficients of variation, probability density functions, auto-correlations, power spectra and cross-correlation coefficients. Thus, any cause and effect relationship between cyclic pressure variations and the injection system or the kind of fuel used can be revealed, given the concern for the low cetane number of ethanol blends promoting cyclic variability that can lead to degraded performance and emissions characteristics.     

Study on the controlling strategies of homogeneous charge compression ignition combustion with fuel of dimethyl ether and methanol

The controlling strategies of homogeneous charge compression ignition (HCCI) fueled by dimethyl ether (DME) and methanol were investigated. The experimental work was carried out on a modified single-cylinder diesel engine, which was fitted with port injection of DME and methanol dual fuel. The results show that exhaust gas recirculation (EGR) rate and DME percentage are two important parameters to control the HCCI combustion process. The ignition timing and combustion duration can be regulated in a suitable range with high indicated thermal efficiency and low emissions by adjusting the DME percentage and EGR rate. EGR cannot extend the maximum indicate mean effective pressure (IMEP) of HCCI operation range with dual fuel, but can enlarge the DME percentage range in normal combustion. The combustion efficiency largely depends on DME percentage, and EGR can improve combustion efficiency. The results also show that HC emissions strongly depend upon DME percentage, and CO emissions have good coherence to the peak mean temperature in cylinder. In normal combustion, adopting large DME percentage and high EGR rate can attain an optimal HCCI combustion.     

Combustion analysis of Jatropha, Karanja and Polanga based biodiesel as fuel in a diesel engine

Non-edible filtered Jatropha (Jatropha curcas), Karanja (Pongamia pinnata) and Polanga (Calophyllum inophyllum) oil based mono esters (biodiesel) produced and blended with diesel were tested for their use as substitute fuels of diesel engines. The major objective of the present investigations was to experimentally access the practical applications of biodiesel in a single cylinder diesel engine used in generating sets and the agricultural applications in India. Diesel; neat biodiesel from Jatropha, Karanja and Polanga; and their blends (20 and 50 by v%) were used for conducting combustion tests at varying loads (0, 50 and 100%). The engine combustion parameters such as peak pressure, time of occurrence of peak pressure, heat release rate and ignition delay were computed. Combustion analysis revealed that neat Polanga biodiesel that results in maximum peak cylinder pressure was the optimum fuel blend as far as the peak cylinder pressure was concerned. The ignition delays were consistently shorter for neat Jatropha biodiesel, varying between 5.9^° and 4.2^° crank angles lower than diesel with the difference increasing with the load. Similarly, ignition delays were shorter for neat Karanja and Polanga biodiesel when compared with diesel.     

Effect of engine operating conditions on the size of primary particles composing diesel soot agglomerates

Particulate matter emitted by diesel engines is mainly formed by soot agglomerates, which are composed of primary particles forming irregular clusters. The primary particles have small variations in size and shape, although a narrow distribution can be effectively found. Soot agglomerates were collected with a thermophoretic sampling device installed in the exhaust pipe of a direct-injection diesel engine, and the samples were analysed using high resolution transmission electron microscopy. The size distributions of the primary particles have been shown to be quasi-monodisperse. Their mean size was obtained from averaging 10 primary particles per image, and five images per operating mode. The sampling location, the engine speed, the air/fuel ratio and the exhaust gas recirculation were independently modified, and some variations in the primary particle size were observed, mainly when the air/fuel ratio and the engine speed were varied. A time integrated equation has been proposed for estimating the rate of growth of the particles, which provided good fitting to the measured sizes. This equation uses as input the instantaneous cylinder pressure experimental data, as well as the temperature and heat release records obtained from the analysis of the cylinder pressure data (combustion diagnostic).     

Selection of a diesel fuel surrogate for the prediction of auto-ignition under HCCI engine conditions

Homogeneous charged compression ignition (HCCI) is a promising combustion concept able to provide very low NO_x and PM diesel engine emissions while keeping good fuel economy. Since HCCI combustion is a kinetically controlled process, the availability of a kinetic reaction mechanism to simulate the oxidation (low and high temperature regimes) of a diesel fuel is necessary for the optimisation, control and design of HCCI engines. Motivated by the lack of information regarding reliable diesel fuel ignition values under real HCCI diesel engine conditions, a diesel fuel surrogate has been proposed in this work by merging n-heptane and toluene kinetic mechanisms. The surrogate composition has been selected by comparing modelled ignition delay angles with experimental ones obtained from a single cylinder DI diesel engine tests. Modelled ignition angle results are in agreement with the experimental ones, both results following the same trends when changing the engine operating conditions (engine load and speed, start of injection and EGR rate). The effect of EGR, which is one of the most promising techniques to control HCCI combustion, depends on the engine load. High EGR rates decrease the n-heptane/toluene mixture reactivity when increasing the engine load but the opposite effect has been observed for lower EGR rates. A chemical kinetic analysis has shown that the influence of toluene on the ignition time is significant only at low initial temperature. More delayed combustion processes have been found when toluene is added, the dehydrogenation of toluene by OH (termination reaction) being the main kinetic path involved during toluene oxidation.     

Combustion and emissions characteristics of compression-ignition engine using dual ammonia-diesel fuel

This study investigated the combustion and emissions characteristics of a compression-ignition engine using a dual-fuel approach with ammonia and diesel fuel. Ammonia can be regarded as a hydrogen carrier and used as a fuel, and its combustion does not produce carbon dioxide. In this study, ammonia vapor was introduced into the intake manifold and diesel fuel was injected into the cylinder to initiate combustion. The test engine was a four-cylinder, turbocharged diesel engine with slight modifications to the intake manifold for ammonia induction. An ammonia fueling system was developed, and various combinations of ammonia and diesel fuel were successfully tested. One scheme was to use different combinations of ammonia and diesel fuel to achieve a constant engine power. The other was to use a small quantity of diesel fuel and vary the amount of ammonia to achieve variable engine power. Under the constant engine power operation, in order to achieve favorable fuel efficiency, the preferred operation range was to use 40-60% energy provided by diesel fuel in conjunction with 60-40% energy supplied by ammonia. Exhaust carbon monoxide and hydrocarbon emissions using the dual-fuel approach were generally higher than those of using pure diesel fuel to achieve the same power output, while NO_x emissions varied with different fueling combinations. NO_x emissions could be reduced if ammonia accounted for less than 40% of the total fuel energy due to the lower combustion temperature resulting in lower thermal NO_x. If ammonia accounted for the majority of the fuel energy, NO_x emissions increased significantly due to the fuel-bound nitrogen. On the other hand, soot emissions could be reduced significantly if a significant amount of ammonia was used due to the lack of carbon present in the combination of fuels. Despite the overall high ammonia conversion efficiency (nearly 100%), exhaust ammonia emissions ranged from 1000 to 3000 ppmV and further after-treatment will be required due to health concerns. On the other hand, the variable engine power operation resulted in relatively poor fuel efficiency and high exhaust ammonia emissions due to the lack of diesel energy to initiate effective combustion of the lean ammonia-air mixture. The in-cylinder pressure history was also analyzed, and results indicated that ignition delay increased with increasing amounts of ammonia due to its high resistance to autoignition. The peak cylinder pressure also decreased because of the lower combustion temperature of ammonia. It is recommended that further combustion optimization using direct ammonia/diesel injection strategies be performed to increase the combustion efficiency and reduce exhaust ammonia emissions.     

A comprehensive experimental investigation of combustion and heat release characteristics of a biodiesel (hazelnut kernel oil methyl ester) fueled direct injection compression ignition engine

In the present study, hazelnut (Corylus avellana L.) kernel oil was transesterified with methanol using potassium hydroxide as catalyst to obtain biodiesel and a comprehensive experimental investigation of combustion (cylinder gas pressure, rate of pressure rise, ignition delay) and heat release (rate of heat release, cumulative heat release, combustion duration and center of heat release) parameters of a direct injection compression ignition engine running with biodiesel and its blends with diesel fuel was carried out. Experiment parameters included the percentage of biodiesel in the blend, engine load, injection timing, injection pressure, and compression ratio. Results showed that hazelnut kernel oil methyl ester and its blends with diesel fuel can be used in the engine without any modification and undesirable combustion and heat release characteristics were not observed. The modifications such as increasing of injection timing, compression ratio, and injection pressure provided significant improvement in combustion and heat release characteristics.     

Ignition control of homogeneous-charge compression ignition (HCCI) combustion through adaptation of the fuel molecular structure by reaction with ozone

The present paper describes a method of controlling the time of ignition in homogeneous-charge compression ignition (HCCI) combustion. In the described experiments some control of ignition timing in HCCI combustion is achieved through alteration of the fuel molecular structure using a chemical reaction of the fuel with ozone, prior to introduction of the fuel into the combustion chamber. Controlling ignition timing is essential, in achieving high thermal efficiency and low pollutant emission in HCCI engine operation. To this end, ignition should occur in the vicinity of piston top-dead-centre (TDC), the point of maximum compression of the fuel-air charge. The present paper proposes a method of controlling the time of ignition of the fuel-air charge by adapting the ignitability of the fuel through prior chemical reaction of the fuel with ozone. Ozone can be readily produced using air in conjunction with a corona discharge ozoniser and may be brought into contact with the fuel in a reaction chamber before its injection into the engine. It was shown through experiments that an acetal fuel which has undergone treatment with ozone, ignites earlier during the engine cycle in HCCI combustion, than fuel which has not undergone treatment with ozone, as a result of changes in its molecular structure prior to combustion. The observed changes in molecular structure consisted primarily in the formation of peroxides within the fuel. This method can be used to operate an engine in HCCI combustion mode with some control over the point of ignition of the fuel-air charge by varying the proportions of fuel previously treated with ozone and fuel not treated with ozone. The experiments showed that the time of ignition could be controlled, whilst keeping other parameters such as the load and speed of the engine, and pressure and temperature of the intake air and fuel, constant.     

Fuelling of aircraft radial piston engines by ES95 and 100LL gasoline

The cost of maintaining aeroplanes is still considerable. It concerns especially operation cost where fuel is a substantial part. At the moment the special 100LL gasoline is used to fuel aircraft piston engines. It is about 20% more expensive than ES95 gasoline featuring comparable properties.The article shows the results of test-bed research conducted on the radial piston aircraft engine fuelled by aircraft 100LL gasoline and automotive ES95 gasoline. The object of research was ASz-62IR engine by WSK PZL-Kalisz that was equipped with an experimental fuel injection system. Power, fuel consumption, head temperatures and indicated pressure in cylinders were analysed in the selected typical operating points. The testing was carried out in steady state. It was proved that it is possible to exchange fuels with no engine power loss and merely an insignificant increase of fuel consumption but with significant increase of IMEP cycle-to-cycle variation.     

Combustion and emission characteristics of a diesel engine fuelled with diesel–propane blends

In this paper, the combustion and emission characteristics of a direct injection diesel engine operating on diesel–propane blends were investigated. The results showed that under the same operating condition, the effective thermal efficiency increased with the increase of propane proportion in the blends. Ignition delay and combustion durations of diesel–propane blends were decreased with the increase of propane proportion in the blends. Maximum cylinder pressure, maximum rate of pressure rise, maximum rate of heat release and maximum mean combustion temperature of the diesel–propane blends increased with the increase of propane proportion in the blends. Simultaneous reduction in exhaust CO, HC and smoke emissions could be realized when operating on the diesel–propane blends. Exhaust NO_x emission gave an increasing trend when operating on the diesel–propane blends.     

The influence of fuel composition on a heavy-duty, natural-gas direct-injection engine

This work investigates the implications of natural-gas composition on the combustion in a heavy-duty natural-gas engine and on the associated pollutant emissions. In this engine system, natural gas is injected into the combustion chamber shortly before the end of the compression stroke; a diesel pilot that precedes the natural-gas injection provides the ignition source. The effects of adding ethane, propane, hydrogen, and nitrogen to the fuel are reported here. The results indicate that these additives had no significant effect on the engine’s power or fuel consumption. Emissions of unburned fuel are reduced for all additives through either enhanced ignition or combustion processes. Black carbon particulate matter emissions are increased by ethane and propane, but are virtually eliminated by including nitrogen or hydrogen in the fuel.     

Homogeneous charge compression ignition of LPG and gasoline using variable valve timing in an engine

The combustion characteristics and exhaust emissions in an engine were investigated under homogeneous charge compression ignition (HCCI) operation fueled with liquefied petroleum gas (LPG) and gasoline with regard to variable valve timing (VVT) and the addition of di-methyl ether (DME). LPG is a low carbon, high octane number fuel. These two features lead to lower carbon dioxide (CO₂) emission and later combustion in an LPG HCCI engine as compared to a gasoline HCCI engine. To investigate the advantages and disadvantages of the LPG HCCI engine, experimental results for the LPG HCCI engine are compared with those for the gasoline HCCI engine. LPG was injected at an intake port as the main fuel in a liquid phase using a liquefied injection system, while a small amount of DME was also injected directly into the cylinder during the intake stroke as an ignition promoter. Different intake valve timings and fuel injection amount were tested in order to identify their effects on exhaust emissions and combustion characteristics. Combustion pressure, heat release rate, and indicated mean effective pressure (IMEP) were investigated to characterize the combustion performance. The optimal intake valve open (IVO) timing for the maximum IMEP was retarded as the λ_TOTAL was decreased. The start of combustion was affected by the IVO timing and the mixture strength (λ_TOTAL) due to the volumetric efficiency and latent heat of vaporization. At rich operating conditions, the θ_90-20 of the LPG HCCI engine was longer than that of the gasoline HCCI engine. Hydrocarbon (HC) and carbon monoxide (CO) emissions were increased as the IVO timing was retarded. However, CO₂ was decreased as the IVO timing was retarded. CO₂ emission of the LPG HCCI engine was lower than that of the gasoline HCCI engine. However, CO and HC emissions of the LPG HCCI engine were higher than those of the gasoline HCCI engine.     

Fundamentals‐based low‐dimensional combustion modeling of spark‐ignited internal combustion engines

A four‐mode low‐dimensional model for the in‐cylinder combustion process in an internal combustion engine is developed. The lumped parameter ordinary differential equation model is based on two mixing times that capture the reactant mixing limitations inside the cylinder and mixing limitations caused by the input and exit stream distribution. For a given inlet and operating conditions, the model predicts the exhaust composition of regulated gases (total unburned HCs, CO, and NO_x) as well as the in‐cylinder pressure and temperature. The model is able to capture the qualitative trends observed with change in fuel composition (gasoline and ethanol blending), air/fuel ratio, spark timing, engine load, and speed. The results show good qualitative and fair quantitative agreement with the experimental results published in the literature and demonstrate the possibility of such low‐dimensional model for real‐time control. Improvements and extensions to the model are discussed. © 2010 American Institute of Chemical Engineers AIChE J, 2011     

Emissions from different alternative diesel fuels operating with single and split fuel injection

Few factors affect diesel combustion and emissions more significantly than the composition of the fuel and the fuel injection process. In this paper, both of these factors are considered by comparing conventional, synthetic and vegetable oil-derived diesel fuels and by comparing a single pulse injection and a split (pilot and main) injection process. This paper focuses on characterization of the combustion process and emissions produced by three substantially different diesel fuels: an ultra low sulfur diesel fuel (BP15), a pure soybean methyl ester (B100), and a synthetic, practically free of sulfur and aromatic compounds, Fischer-Tropsch fuel (FT) produced in a gas-to-liquid process. The study was carried out in a direct injection (DI) 2.5 L common-rail turbodiesel engine working at four engine operation modes, spanning conditions of most interest in the engine map. In all modes the engine was tested with single and split injection (pilot and main), with constant start of injection (SOI), and without exhaust gas recirculation (EGR). Using the results from thermodynamic analysis, this study confirms that the ignition character of the fuel affects the start of the combustion process, notably for the whole combustion process when the single injection is used, and during the combustion process after the pilot injection when the split injection is used. In general, the FT fuel can reduce both NOx and PM specific emissions in all modes under both single and split injection modes, bypassing the nitrogen oxides-particulate matter (NOx-PM) trade-off. Finally, this work confirms that biodiesel can reduce the particle concentration. However, in some cases an increase of PM mass emission has been observed and this increase of the PM mass emission is due to unburned or partially burned hydrocarbon (HC) emissions.